Patents Assigned to Mitsui
  • Patent number: 4946582
    Abstract: A method of selective and efficient removal of mercury from a hydrocarbon oil comprising contacting said oil with a cupric and/or stannous compound forming a reaction system. The purified hydrocarbon oil can be readily separated from the reaction system. The purified hydrocarbon oil does not contain mercury or any other catalyst poisoning component and can, therefore, be used extensively in catalytic reactions typified by hydrogenation reaction.
    Type: Grant
    Filed: January 19, 1989
    Date of Patent: August 7, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Torihata, Etsuko Kawashima
  • Patent number: 4946950
    Abstract: A glycoside of inositol which has been isolated from a hot-water extract of tea leaves. The glycoside is identified from the analytical results to be 2-O-beta-L-arabinopyranosyl-myo-inositol.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: August 7, 1990
    Assignee: Mitsui Norin Co., Ltd.
    Inventors: Yukihiko Hara, Kazuo Okushio, Kanzo Sakata
  • Patent number: 4943611
    Abstract: A resin composition for spacers of an information recording disc which comprises: (A) a random copolymer of ethylene and at least one cycloolefin having an intrinsic viscosity [.eta.] of from 0.05 to 10 dl/g, as measured in decalin at a temperature of 135.degree. C., and (B) from 0.01 to 5 parts by weight, based on 100 parts by weight, of said copolymer A, of an inorganic particles such as titania and silica having a particle size of not more than 300 .mu.m. Spacers made of the composition described herein can be welded to disc substrates within a shortened period of ultrasonic vibration to produce an information recording disc having a reduced warp angle.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: July 24, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akira Todo, Toshio Kimura, Takeshi Minoda, Masayoshi Kurisu
  • Patent number: 4943677
    Abstract: Poly(alkylene carbonates) of controlled molecular weight are made by copolymerizing carbon dioxide and one or more oxirane compounds using zinc polycarboxylate catalyst in the presence of a sterically hindered organic proton donor. The acidity of the donor is in the range of 3 to 20 pK.sub.a and the steric quality of the donor is such that it has a steric parameter (E.sub.s) of -0.38 or less. The molecular weight of the polymer can be regulated by altering the level of proton donor over a range which does not adversely affect catalyst productivity. Benzoic acid and phenol are examples of suitable proton donors. The preferred catalyst is one made from zinc oxide and a dicarboxylic acid, such as glutaric acid or adipic acid.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: July 24, 1990
    Assignees: Air Products and Chemicals, Inc., Arco Chemical Company, Mitsui Petrochemical Industries, Ltd.
    Inventor: Andrzej Rokicki
  • Patent number: 4943658
    Abstract: There is provided a liquid oxidatively modified ethylenic random copolymer, which is an oxidatively modified product of a liquid ethylenic random copolymer comprising 20 to 80 mol % of ethylene and 80 to 20 mol % of .alpha.-olefin, and has (i) a number average molecular weight (Mn) in the range of from 200 to 10,000, (ii) a molecular weight distribution (Mw/Mn) given as weight average molecular weight (Mw) divided by number average molecular weight (Mn) in the range of up to 4, and (iii) an oxygen content of from 0.1 to 20% by weight, an acid value of from 0.1 to 50, and a saponification value of from 0.1 to 100. It is prepared by contacting a corresponding ethylenic random copolymer with oxygen-containing gas at 100.degree.-250.degree. C.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: July 24, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tatsuo Kinoshita, Shuji Minami, Kinya Mizui, Ryousuke Kaneshige
  • Patent number: 4943594
    Abstract: Thermoplastic polyimide foams are provided which essentially consist of recurring units represented by the formula (I): ##STR1## wherein X is a bond, divalent hydrocarbon radical having from 1 to 10 carbon atoms etc. and R is an aliphatic radical having 2 or more carbon atoms, cycloaliphatic radical etc.The foams have an apparent density of from 0.02 to 0.2 g/cc, average cell diameter of 0.1 to 1 mm and a closed cell content of 50% or more.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: July 24, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroshi Ezawa, Toshiyuki Nakakura, Takayuki Watanabe, Hiroaki Tsushima
  • Patent number: 4943651
    Abstract: In accordance with the present invention, there is provided substituted naphthalene compounds represented by the following formula [I]. ##STR1## wherein R.sup.1 represents alkyl of 1-18 carbon atoms, R.sup.2 represents alkyl of 1-18 carbon atoms, X is a group represented by --OCH.sub.2 -- or --CH.sub.2 CH.sub.2 --, and n is 0 or 1.In accordance with the invention, moreover, there is provided liquid crystal compositions containing the substituted naphthalene compounds represented by the above-mentioned formula [I].
    Type: Grant
    Filed: March 3, 1989
    Date of Patent: July 24, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shinichi Nishiyama, Hideo Yamaoka, Tooru Yamanaka, Tohru Yamada
  • Patent number: 4942096
    Abstract: The present invention relates to a polypropylene resin composition useful as an adhesive comprising(A) from about 51 wt. % to about 99 wt. % of a modified polypropylene resin graft-modified with a radical-polymerizable polar unsaturated compound or a mixture of the modified polypropylene resin graft-modified with a radical polymerizable polar unsaturated compound with an unmodified polypropylene resin,(B) a substantially non-crystalline .alpha.-olefin copolymer, and(C) an ethylene/.alpha.-olefin coplymer having a density of from about 0.860 g/cm.sup.3 to less than about 0.910 g/cm.sup.3, a n-hexane insolubility of at least about 50 wt. % and a melting point of at least 100.degree. C.,wherein the combined weights of components (B) and (C) is from about 1 wt. % to about 49 wt. %, and the weight ratio of (B)/(C) is from about 1/99 to about 99/1.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: July 17, 1990
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masaru Abe, Yoichi Kawai, Takashi Miyazaki
  • Patent number: 4942087
    Abstract: Disclosed herein are (1) a film of a liquid crystalline wholly aromatic polyester which is non-oriented and transparent, which film can be prepared by dissolving a liquid crystalline wholly aromatic polyester in a solvent, casting the resulting solution to form a film and volatirizing the solvent from the film as cast and (2) a film of a liquid crystalline wholly aromatic polyester which is oriented and polarizing, which film can be prepared by orienting the above-mentioned non-oriented film by drawing or heating.
    Type: Grant
    Filed: December 16, 1988
    Date of Patent: July 17, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masanori Motooka, Kazuyuki Takimoto, Kunisuke Fukui
  • Patent number: 4942265
    Abstract: The process for preparing 2,2-bis(4-hydroxyphenyl)propane (bisphenol A) by reacting acetone with phenol and decomposing the resultant adduct of bisphenol A and phenol is well known. However, the quality of bisphenol A thus obtained is not always satisfactory.In the process of this invention, the adduct is washed with phenol recovered by decomposing an adduct of bisphenol A and phenol, and then bisphenol A is prepared by decomposing the washed adduct.The bisphenol A prepared by the process of this invention has an extremely high quality and is suitable for the preparation of polycarbonate used for optical parts.
    Type: Grant
    Filed: November 28, 1988
    Date of Patent: July 17, 1990
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shigeru Iimuro, Takashi Kitamura, Yoshio Morimoto
  • Patent number: 4940616
    Abstract: Anti-gas permeation property and impact strength of a container such as a bottle which is made of polyethylene terephthalate resin by biaxially orienting blow molding are improved by using a multilayered structure of the polyethylene terephthalate and the other polyester of a dicarboxylic acid component containing a specific amount of isophthalic acid and a glycol component. The container is made preferably by preparing a preform which is a laminate of the polyethylene terephthalate and the other polyester in the molten state under pressure, and by biaxially orienting blow molding the preform.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: July 10, 1990
    Assignee: Mitsui Petrochemical Industries
    Inventors: Tadao Yatsu, Nobuya Hinooka
  • Patent number: 4940681
    Abstract: The present invention relates to a ferroelectric ceramic material which is a Perovskite solid said solution comprising a solid solution represented by the formulaPb.sub.1-a M.sub.a (Mg.sub.1/3 Nb.sub.2/3).sub.x Ti.sub.y Zr.sub.z O.sub.3containing in the solution at least one oxide selected from the group A noted below and at least one oxide selected from the group B noted below, with the proviso that NiO or Fe.sub.2 O.sub.3 is necessarily contained.Group A: La.sub.2 O.sub.3, Bi.sub.2 O.sub.3 and Nd.sub.2 O.sub.3 ;Group B: NiO, Fe.sub.2 O.sub.3, SnO.sub.2 and Ta.sub.2 O.sub.5.The proposed ferroelectric ceramic material has a large piezoelectric strain constant d. The present invention is further directed to a ferroelectric ceramic which is a Perovskite solid solution comprising a solid solution represented by the formulaPb.sub.1-a M.sub.a (Mg.sub.1/3 Nb.sub.2/3).sub.x Ti.sub.y Zr.sub.z O.sub.3wherein M is Ba or Sr, x+y+z is 1, a is from 0 to 0.10, x is from 0.05 to 0.70, y is from 0.25 to 0.50 and z is from 0.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: July 10, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshihisa Ushida, Nobuki Hirai, Hiroshi Mase
  • Patent number: 4938910
    Abstract: A mandrel suitable for use in the production of a rubber hose formed from a composition comprising:(i) at least one member selected from the group consisting of(A) an ethylene-alpha-olefin random copolymer having an ethylene content of 10 to 95 mol % and a degree of crystallinity, based on X-ray determination, of 0 to 20%,(B) a propylene - C.sub.4 to C.sub.10 alpha-olefin random copolymer having a propylene content of 50 to 80 mol % and a crystal fusion heat amount, determined by a differential scanning calorimeter, of 0 to 80 Joule/g, and(C) an oligomer having the general formula: ##STR1## wherein n and p are independently zero or an integer, m is zero or 1, and R is ##STR2## and (ii) 98% to 30% by weight of a 4-methyl-1-pentene polymer, wherein the weight ratio of the component (i) to the component (ii) is from 2:98 to 70:30.This mandrel has excellent dimensional stability, durability, heat resistance, and releasability.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: July 3, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shunji Abe, Hiromi Shigemoto
  • Patent number: 4938908
    Abstract: Disclosed is a method and apparatus for producing a flexible tube of a thermoplastic resin having poor melt flowability by melting a thermoplastic resin having poor melt flowability in a screw extruder, and melt-extruding the molten thermoplastic resin from a tube die having an L/D of 30-70 provided at a mandrel rotatable with the rotation of the screw.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: July 3, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takeshi Shiraki, Yosihiro Yoshimura
  • Patent number: 4939030
    Abstract: Provided is a film for retaining freshness of vegetables and fruits which comprises a synthetic resin film, a microporous resin film and a water-absorbing layer interposed between both said films, said microporous resin film having a maximum pore diameter not larger than 30 microns and a moisture permeability not lower than 100 g/m.sup.2 /24 hr.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: July 3, 1990
    Assignees: Mitsui Toatsu Chemicals, Inc., Ferric Inc.
    Inventors: Shoichi Tsuji, Hazime Musika, Michiyasu Itoh, Junko Hayakawa, Eiji Miyashita
  • Patent number: 4939306
    Abstract: A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: July 3, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tohru Miura, Teruyuki Nagata, Koju Okazaki, Masayuki Furuya, Emiko Nishida
  • Patent number: 4937353
    Abstract: Disclosed herein is to react an aniline and an ethylene glycol at a superatmospheric pressure in preparing an indole by subjecting the aniline and ethylene glycol to a gas-phase catalytic reaction in the presence of a catalyst, thereby improving the selectivity of the reaction and the service life of the catalyst.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Akihide Kudoh, Tadatoshi Honda, Makoto Kotani, Kazuhiro Terada, Takeshi Tsuda, Shinji Kiyono
  • Patent number: 4937393
    Abstract: In the manufacturing method of ethylene glycol and/or propylene glycol, these glycols can be prepared with a highly selectivity and at a high yield by applying the catalyst comprising a carboxylic acid and a carboxylic acid salt or a metal salt of formic acid alone.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Takayoshi Masuda, Katuyoshi Asano, Naomi Hori, Shinji Ando
  • Patent number: 4937339
    Abstract: In a process for preparing isocyanurate ring-containing materials useful in the production of lacquers and foams which comprises trimerizing an organic isocyanate compound in the presence of a catalyst, the use of potassium fluoride as the catalyst makes it possible to yield the desired product rapidly without formation of by-products. More preferably, the reaction efficiency can further be enhanced by using a polyethylene oxide compound, a quaternary ammonium salt and/or a phosphonium compound in combination with potassium fluoride.
    Type: Grant
    Filed: December 16, 1988
    Date of Patent: June 26, 1990
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsunosuke Shiomura, Yoshiho Sonobe, Akihiro Yamaguchi, Ryuzi Haseyama
  • Patent number: D309417
    Type: Grant
    Filed: October 4, 1988
    Date of Patent: July 24, 1990
    Assignee: Mitsui Kinzoku Kogyo Kabushiki Kaisha
    Inventor: Shinjiro Yamada