Patents Assigned to Mitsui
  • Patent number: 4798866
    Abstract: A branched alpha-olefinic polymer composition having excellent melt flowability, good moldability and excellent melt tension and comprising at least two branched alpha-olefinic polymers each composed of (A) recurring units derived from a branched alpha-olefin containing 5 to 10 carbon atoms and having a branch at the 3-position or a position of a higher number and (B) recurring units derived from a linear alpha-olefin containing 2 to 20 carbon atoms; and a process for producing this polymer composition by a multiplicity of polymerization steps using a catalyst formed from (A) a highly stereoregular titanium catalyst component comprising magnesium, titanium, halogen and an electron donor as essential ingredient, (B) an organoaluminum compound and (C) an electron donor.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: January 17, 1989
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Junichi Yoshitake, Hiroaki Kitani, Norio Kashiwa, Takeshi Muranaka, Kenichi Tominari, Shigeki Nagamatsu
  • Patent number: 4798654
    Abstract: This invention relates to a process for preparing 2,2-bis(4-hydroxyphenyl)propane, e.g. bisphenol A and particularly to a process for preparing high quality bisphenol A with good workability by distilling the intermediate adduct of bisphenol A and phenol.The adduct of bisphenol A and phenol is fed to a distillation column. Phenol is recovered from the top of the column and bisphenol A is obtained from its bottom. In this distillation process, the adduct of bisphenol A and phenol is added with a part of recycled bottom liquid. Consequently troubles such as plugging of the distillation column are prevented, continuous operation becomes possible for a long period of time and high quality bisphenol A can be steadily obtained.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: January 17, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shigeru Iimuro, Takashi Kitamura, Yoshio Morimoto
  • Patent number: 4798781
    Abstract: Disclosed herein is a fabrication process of an optical recording medium permitting writing and reading-out of signals without any reflective layer. The medium is fabricated by coating, on a transparent thermoplastic resin substrate havnig pregrooves and pits or holes for preformatting signals, a dye solution of a phthalo/naphthalocyanine dye represented by the following general formula (I): ##STR1## wherein M means a metal, metal oxide or metal halide, and L.sub.1, L.sub.2, L.sub.3 and L.sub.4 mean individually a benzene or naphthalene ring skeleton which is unsubstituted or substituted by at least one monovalent substituent --Z selected from the class consisting of the following substituents: --R.sup.1, --OR.sup.2, --SiR.sup.3 R.sup.4 R.sup.5, --SR.sup.6, --COR.sup.7, --COOR.sup.8, --COHNR.sup.9, --NR.sup.10 R.sup.11, --R.sup.12 OR.sup.13, and --R.sup.14 X wherein R.sup.1 -R.sup.14 denote individually a hydrocarbon group having from 1 to 12 carbon atoms and X stands for a halogen atom.
    Type: Grant
    Filed: July 31, 1986
    Date of Patent: January 17, 1989
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Inc.
    Inventors: Sumio Hirose, Hiroshi Ozawa, Kenji Abe, Yoichi Hosono
  • Patent number: 4797466
    Abstract: This invention relates to a novel polyimide and describes method of its preparation, adhesives of the polyimide and the method for their application.The polyimide has recurring units of the formula ##STR1## (where R is a tetra-valent radical selected from the group consisting of aliphatic radical having not less than two carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).The polyimide can be prepared by reacting 2,6-bis(3-aminophenoxy)pyridine with tetracarboxylic dianhydride in an organic solvent and imidizing resultant polyamic acid.Various tetracarboxylic dianhydrides can be used and particularly prefered are pyromellitic dianhydride and 3,3',4,4'-benzophenonetetracarboxylic dianhydride.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: January 10, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hideaki Oikawa, Masahiro Ohta, Saburo Kawashima, Shoji Tamai, Yoshiho Sonobe, Akihiro Yamaguchi
  • Patent number: 4797177
    Abstract: An organic membrane is stretched over, or adhered to, a frame or a substrate, and that part of the membrane which extends out of the frame or substrate is cut by bringing an injection syringe-like needle into contact with, or approach to, the lateral end surface of the frame or substrate and while moving the needle along said lateral end surface, injecting an organic solvent from the needle and dissolving said membrane along the lateral end surface of the frame or substrate. By this method, the organic membrane can be cut without generating foreign matter such as cut dust.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: January 10, 1989
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshio Kaya, Makoto Fujimoto
  • Patent number: 4797242
    Abstract: A method for molding a thermosetting resin pipe having a balanced compressive strength between the axial direction and the direction normal to the pipe axis is disclosed. The method includes steps of molding a thermosetting resin in a smooth zone in the front section of a screw to such an extent that the resin after being extruded from the cylinder is capable of retaining its own shape, and orienting the resin and/or a fibrous filler randomly. An apparatus for producing such a thermosetting resin, and a thermosetting resin having a balanced compressive strength are also disclosed.
    Type: Grant
    Filed: December 23, 1986
    Date of Patent: January 10, 1989
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshiaki Fukuda, Takeshi Miyasaka, Iori Matsumoto, Nobukatsu Kato, Kenji Ema
  • Patent number: 4797265
    Abstract: A process for the production of highly concentrated phosphoric acid, comprises improvements in digesting phosphate rock with a mixed acid consisting essentially of sulfuric acid and phosphoric acid to obtain a slurry comprising phosphoric acid and hemihydrate (CaSO.sub.4.1/2H.sub.2 O), then filtering the slurry, taking out highly concentrated phosphoric acid as product acid and subsequently hydrating the hemihydrate to obtain gypsum (dihydrate: CaSO.sub.4.2H.sub.2 O).
    Type: Grant
    Filed: March 12, 1987
    Date of Patent: January 10, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Inoue, Akira Ohkoba, Kunio Sakashita, Akira Utsunomiya, Takeki Shinozaki, Minoru Ieda
  • Patent number: 4795795
    Abstract: A polyamide and/or polyimide is prepared by using N,N'-dimethylethyleneurea or N,N'-dimethylpropyleneurea as a solvent upon polycondensation of a polycarboxylic acid and a diisocyanate at a temperature above 100.degree. C. in the presence of an alkali metal carbonate, alkali metal hydrogencarbonate, alkali metal hydroxide or an alkali metal salt of a polycarboxylic acid.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: January 3, 1989
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masahiro Kouno, Kazumi Mizutani, Masanori Osawa, Kohei Shizuka, Toshihiro Toyoda, Hiromi Nakano
  • Patent number: 4795798
    Abstract: This invention discloses high-temperature adhesives having a good light-transmittance and excellent high-temperature flowability which comprises polyimide having recurring units represented by the following formula (I) ##STR1## (where R is a tetra-valent radical selected from the group consisting of aliphatic radical having not less than two carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).
    Type: Grant
    Filed: February 25, 1987
    Date of Patent: January 3, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Saburo Kawashima, Masahiro Ohta, Hideaki Oikawa, Kouji Ohkoshi, Akihiro Yamaguchi
  • Patent number: 4792389
    Abstract: The invention describes a process for producing light products, such as engine and diesel fuels, and fuel oils for conventional use by thermal conversion of heavy metal- and sulfur-rich-crude oil residues. Thermal cracking of the residues is done by mild cracking in several stages, where the residue remaining after separation of the conversion products of the preceding stage is fed to the respective subsequent stage.
    Type: Grant
    Filed: May 1, 1987
    Date of Patent: December 20, 1988
    Assignees: VEB Petrochemisches Kombinat Schwedt, Toyo Engineering Corporation, Mitsui Coke Co., Ltd.
    Inventors: Werner Frohn, Dieter Bohlmann, Hermann Franke, Werner Zimmermann, Heinz Limmer, Eberhard H/o/ pfner, Horst Lindner, Reinhard Matthey, Henner M/u/ ller, Hans Poppen, Hartmut Sch/u/ tter, Detlev Dietrich
  • Patent number: 4792565
    Abstract: Novel pyrazole derivatives of the general formula (I) ##STR1## wherein R.sup.1 represents an alkyl, haloalkyl, alkenyl, haloalkenyl or phenyl group, R.sup.2 and R.sup.3 each represent a hydrogen or halogen atom, or an alkyl, haloalkyl, alkoxy, alkoxyalkyl or phenyl group, and R.sup.4 represents an alkyl, alkenyl, haloalkenyl or phenyl group, or a heterocyclic aromatic group which contains at least one of oxygen, nitrogen and sulfur atoms and may be unsubstituted or substituted,which are useful as agricultural and horticultural fungicides. The pyrazole derivatives can be produced by reacting compounds of the general formula (III) ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above, and X represents a halogen atom,with aminoacetonitriles of the general formula (IV) ##STR3## wherein R.sup.4 is as defined above, or salts thereof.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: December 20, 1988
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hitoshi Shimotori, Tutomu Ishii, Hideo Yamazaki, Toshiaki Kuwatsuka, Yuji Yanase, Yoshinori Tanaka
  • Patent number: 4792588
    Abstract: A polyethylene composition having excellent melt moldability which substantially comprises an ultrahigh-molecular-weight polyethylene having a molecular weight of, for example, at least about 1,650,000 and a low-molecular-weight to high-molecular-weight polyethylene having a molecular weight of, for example, about 1500 to about 360,000. The composition is produced by a multi-stage polymerization process involving a step of producing the ultrahigh-molecular-weight polyethylene and a step of producing the low-molecular-weight to high-molecular-weight polyethylene.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: December 20, 1988
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Michiharu Suga, Hideo Ishikawa, Yoshinori Akana, Junichi Yoshitake, Masayuki Kondoh
  • Patent number: 4791185
    Abstract: Disclosed herein is a colorless transparent plastic lens having high refractivity and low dispersion. The lens is light, has heat resistance sufficient for post processing, and is excellent in grinding machinability and impact resistance. It is made of a sulfur-containing urethane resin, which is a polymer of a specific polythiol and a particular polyisocyanate of at least bifunctionality.
    Type: Grant
    Filed: November 5, 1987
    Date of Patent: December 13, 1988
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshinobu Kanemura, Katsuyoshi Sasagawa, Masao Imai, Teruyuki Nagata, Nobuyuki Kajimoto
  • Patent number: 4789707
    Abstract: There is disclosed a coating resin composition which contains as a crosslinking agent a melamine-formaldehyde resin which permits a paint to cure at low temperatures, permits a paint to form a coating film flexible enough for the fabrication of the coated substrate, gives off only a small amount of formaldehyde at the time of paint application, and makes it possible to increase the solids content in a paint. The melamine-formaldehyde resin is a mixed alkyl etherified methylol melamine resin, and the other composition-constituting component is an alkyd resin, polyester resin, or vinyl copolymer.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: December 6, 1988
    Assignees: Mitsui-Cyanamid Ltd., Nippon Paint Co., Ltd.
    Inventors: Tsutomu Nishimura, Yasuo Saito, Kenji Shindo, Kazutoshi Abe
  • Patent number: 4788846
    Abstract: A long flexible metal clad laminate, which has a thin aromatic polyimide film formed on a long metal foil, is caused to slide under tension, along its length, on curved surfaces of four bars arranged at specific positions, so that its curls are corrected and its dimensional stability is improved.
    Type: Grant
    Filed: October 27, 1987
    Date of Patent: December 6, 1988
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Moritsugu Morita, Kazuo Miyazaki
  • Patent number: 4789272
    Abstract: Upon transportation of synthetic rubber chips through a piping or by means of a conveyor, 2 wt. %-50 wt. % based on the weight of the synthetic rubber chips of steam of 160.degree. C. or lower, water or both steam of 160.degree. C. or lower and water is added to the synthetic rubber chips upon their transportation.
    Type: Grant
    Filed: March 17, 1987
    Date of Patent: December 6, 1988
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Toyo Engineering Corporation
    Inventors: Tetsuyuki Matsubara, Norifumi Ito, Mune Iwamoto, Toshihiko Ando
  • Patent number: 4787936
    Abstract: The inventive cement-based composition is useful as a coating material for corrosion-resistant protection on steel and iron surfaces. The composition is basically a polymer cement composition prepared by compounding a hydraulic cement with an aqueous emulsion of a polymeric constituent but characteritically the inventive composition is prepared by adding an aqueous emulsion of a hydrocarbon solvent such as kerosene containing a combination of surface active agents, i.e. oil-soluble non-ionic, water-soluble non-ionic and water-soluble cationic ones, and a saccharide compound such as glucose. By virtue of the unique formulation, the composition has a greatly extended pot-life suitable for coating works of, for example, steel rods and pipes by the dip coating method.
    Type: Grant
    Filed: July 27, 1987
    Date of Patent: November 29, 1988
    Assignees: Zairyo Kagaku Kenkyusho Co., Ltd., Mitsui Engineering & Shipbuilding Co., Ltd.
    Inventors: Kiyoshi Suzuki, Toshiaki Murata, Isao Nakata
  • Patent number: 4787993
    Abstract: This invention provides lubricants which perform stable operation even at high temperatures and under heavy loading. The lubricants are prepared by dispersing at least one of finely powdered resin selected from aromatic resin and polyimide resin into the fluid fats and oils. The flowable fats and oils may further contain molybdenum disulfide, organic molybdenum, boron nitride, or PTFE.
    Type: Grant
    Filed: July 2, 1987
    Date of Patent: November 29, 1988
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventor: Taizo Nagahiro
  • Patent number: 4785132
    Abstract: A process for preparing cyclohexanonecarboxylic acid compounds by catalytically hydrogenating the corresponding hydroxybenzoic acid compounds in a secondary alcohol or tertiary alcohol solvent.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: November 15, 1988
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tohru Miura, Teruyuki Nagata, Hideki Mizuta
  • Patent number: 4785045
    Abstract: A thermoplastic elastomer composition composed of a partially crosslinked product of a blend consisting mainly of (a) 80 to 10 parts by weight of a peroxide-crosslinkable olefinic copolymer rubber, (b) 10 to 80 parts by weight of a peroxide-crosslinkable polyolefin resin having specific properties and (c) 50 to 10 parts by weight of a peroxide-decomposable polyolefin resin, the total amount of (a)+(b)+(c) being 100 parts by weight, the crosslinked product is obtained by dynamically heat-treating said blend in the presence of (d) an organic peroxide. The thermoplastic elastomer has excellent film formability, and is useful as a waterproof sheet.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: November 15, 1988
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Katsuyoshi Yonekura, Akira Uchiyama, Akira Matsuda