Patents Assigned to Mizusawa Industrial Chemicals Ltd.
  • Patent number: 5419883
    Abstract: An lithium aluminum complex hydroxide salt (LAHS) and a process for preparation thereof is provided. The LAHS is represented by the formula;(Al.sub.2 Li(OH).sub.6).sub.n X, mH.sub.2 Owherein X is an inorganic or organic anion, n is a value number of X, and m is a number of not more than 3, and having an orientation degree (OD) of not less than 10, OD being defined by the formula;OD=I.sub.(002) /I.sub.(110)wherein I.sub.(002) is a relative intensity of a peak in X-ray diffraction pattern with an index of a plane (002) appearing at a spacing (d) of 7.67 .ANG. to 7.84 .ANG. and I.sub.(110) is a relative intensity of a peak in X-ray pattern with an index of a plane (110) appearing at a spacing (d) of 4.41 .ANG. to 4.45 .ANG.. This LAHS is useful for a stabilizer for chlorine-containing polymers or olefin-type resins containing halogen-containing catalyst residues.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: May 30, 1995
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kunio Goto, Shoji Shoji, Yoshinobu Komatsu, Akira Tatebe
  • Patent number: 5418043
    Abstract: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=OO). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: May 23, 1995
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kiyoshi Abe, Masao Takahashi, Yuuzi Washio, Kazumitsu Enomoto, Toshio Kitsu
  • Patent number: 5387564
    Abstract: A plastic or moldable composition of zeolite is obtained by adding 0.1-20 parts by weight of a .beta.-1.3-glucan, 1:1 layer-type clay mineral and 2:1 layer-type clay mineral together with an adequate amount of water to 100 parts by weight of zeolite powder, and then kneading the resultant mixture. The composition may be, for example, extrusion-molded to a honeycomb structure, and calcined, to provide a calcined article of honeycomb structure of zeolite which has a high dimensional accuracy and strength, and hence is useful as a drying agent, a catalyst or a carrier material therefor. The calcined article of zeolite has an excellent mechanical strength.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: February 7, 1995
    Assignees: Takeda Chemical Industries, Ltd., Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tatsuro Takeuchi, Motoya Mouri, Saji Okabayashi, Shoichi Miyamura
  • Patent number: 5384191
    Abstract: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil-absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: January 24, 1995
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kiyoshi Abe, Masao Takahashi, Yuuzi Washio, Kazumitsu Enomoto, Toshio Kitsu
  • Patent number: 5366718
    Abstract: A process for producing a columbite-type niobate and a process for producing a niobium-containing lead-type perovskite compound using the columbite-type niobate. A precursor slurry of a columbite compound composed of a fresh niobium hydroxide, a metal acetate and ammonium aqueous solution is spray-dried, and is calcined at 500.degree. C. or higher to obtain a crystalline columbite-type compound having grain sizes of 1 .mu.m or smaller to which was then mixed a lead component. The mixture is calcined, pulverized and is sintered at a temperature of 800.degree. to 1100.degree. C. to synthesize a highly dielectric material of a niobium-containing lead-type composite perovskite. The precursor of columbite is calcined at 500.degree. to 1100.degree. C. to obtain fine columbite-type niobate crystals of grain sizes of 1 .mu.m or smaller. A lead-type perovskite compound using the above crystals can be sintered at a temperature of as low as 950.degree. C.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: November 22, 1994
    Assignees: Mizusawa Industrial Chemicals Ltd., TDK Corporation
    Inventors: Teiji Sato, Hitoshi Nakata, Takayuki Ishizuki, Shoichi Iwaya, Koji Takahashi, Yuuiti Sannohe, Hitoshi Tanaka
  • Patent number: 5360859
    Abstract: A stabilizer for resin, which is composed of a lithium aluminum complex hydroxide salt represented by the following formula[Al.sub.2 Li(OH).sub.6 ].sub.n X.mH.sub.2 O (1)wherein X is an inorganic or organic anion, n is a valence number of anion X, and m is a number of not more than 3.A chlorine-containing polymer composition comprising a chlorine-containing polymer and 0.01 to 10 parts by weight, per 100 parts by weight of the chlorine-containing polymer, of the above stabilizer. There is also provided an olefin-type resin composition comprising an olefin-type resin containing halogen-containing catalyst residues and 0.01 to 10 parts by weight, per 100 parts by weight of the olefin-type resin, of the above stabilizer. The stabilizer has excellent heat stabilizing action.
    Type: Grant
    Filed: January 27, 1994
    Date of Patent: November 1, 1994
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kunio Goto, Shoji Shoji, Yoshinobu Komatsu, Akira Tatebe
  • Patent number: 5356567
    Abstract: A stabilizer for resin, which is composed of a lithium aluminum complex hydroxide salt represented by the following formulaAl.sub.2 Li(OH).sub.6).sub.n X.mH.sub.2 O . . . (1)wherein X is an inorganic or organic anion, n is a valence number of anion X, and m is a number of not more than 3.A chlorine-containing polymer composition comprising a chlorine-containing polymer and 0.01 to 10 parts by weight, per 100 parts by weight of the chlorine-containing polymer, of the above stabilizer. There is also provided an olefin-type resin composition comprising an olefin-type resin containing halogen-containing catalyst residues and 0.01 to 10 parts by weight, per 100 parts by weight of the olefin-type resin, of the above stabilizer. The stabilizer has excellent heat stabilizing action.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: October 18, 1994
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kunio Goto, Shoji Shoji, Yoshinobu Komatsu, Akira Tatebe
  • Patent number: 5298234
    Abstract: Disclosed is an alumina-silica resin additive consisting of amorphous alumina-silica particles in which a definite cubic or spherical shape is retained in primary particles and the particle sizes of both the primary particles and the secondary particles are controlled to very small values. This additive is excellent in dispersibility in a resin, non-blowing property, slip characteristic and anti-blocking property. A product obtained by surface-treating the amorphous alumina-silica particles with a certain amount of an organic lubricant is very valuable as a filler.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: March 29, 1994
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tadahisa Nakazawa, Masahide Ogawa, Kiyoshi Abe, Kazuhiko Suzuki
  • Patent number: 5266397
    Abstract: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 20 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: November 30, 1993
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kiyoshi Abe, Masao Takahashi, Yuuzi Washio, Kazumitsu Enomoto, Toshio Kitsu
  • Patent number: 5236680
    Abstract: The invention is a process for preparing amorphous silica alumina spherical particles by mixing sodium silicate or silicic acid gel with sodium aluminate and sodium hydroxide in an aqueous solution to form a gel, homogenizing the formed gel, crystallizing this intermediate product at 85.degree. C. to 200.degree. under atmospheric pressure or under hydrothermal conditions to form spherical zeolite particles with an x-ray diffraction pattern inherent to P-type zeolites and with a notched surface, treating the zeolite particles with acid to remove the sodium, thereby rendering the particles amorphous.
    Type: Grant
    Filed: June 18, 1991
    Date of Patent: August 17, 1993
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tadahisa Nakazawa, Masahide Ogawa, Kiyoshi Abe, Kazuhiko Suzuki, Takashi Tokita, Toshio Ito
  • Patent number: 5236683
    Abstract: Disclosed are amorphous silica or silica-alumina spherical particles composed of X-ray diffractometrically substantially amorphous silica or silica-alumina, wherein individual particles have a definite spherical shape and a notched surface, the circularity (A) represented by the following formula: ##EQU1## wherein r1 stands for the radius of the circumcircle of the profile of the particle in an electron microscope photo thereof and r2 stands for the radius of the inscribed circle of the profile of the particle in the electron microscope photo, is in the range of from 0.90 to 1, the notching degree (B) represented by the following formula: ##EQU2## wherein .DELTA.t stands for the depth between the peak and trough in the radial direction of notches on the profile of the particle in the electron microscope photo and r1 is as defined above, is in the range of from 1 to 10%, and the primary particle size (2r1) determined by the electron microscope method is in the range of from 0.1 to 20 .mu.m.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: August 17, 1993
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tadahisa Nakazawa, Masahide Ogawa, Kiyoshi Abe, Kazuhiko Suzuki, Takashi Tokita, Toshio Ito
  • Patent number: 5143708
    Abstract: Active analcime having a chemical composition comprising 60 to 95% by weight of SiO.sub.2, 0.3 to 20% by weight of Al.sub.2 O.sub.3 and 0.02 to 11% by weight of Na.sub.2 O based on the three components, an X-ray diffraction pattern inherent to analcime and a moisture adsorption of 5 to 30% by weight as determined under conditions of a relative humidity of 90%, an ambient temperature of 25.degree. C. and a standing time of 24 hours, wherein individual particles have a tetracosahedral or angle-rounded tetracosahedral particulate shape and the primary particle size of 0.1 to 50 .mu.m as determined according to the electron microscope method. This active analcime is obtained by acid-treating a zeolite by using an acid in an amount of 0.1 to 1.2 molar equivalents per mole of the sum of Al.sub.2 O.sub.3 and Na.sub.2 O components in the zeolite so that the crystal structure of analcime is left.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: September 1, 1992
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tadahisa Nakazawa, Masahide Ogawa, Kiyoshi Abe, Kazuhiki Suzuki, Jun Suzuki
  • Patent number: 5139760
    Abstract: Disclosed are amorphous silica-alumina spherical particles having a notched surface. The particles have a small specific surface area and a highly controlled hygroscopic property. The spherical particles are obtained by exchanging at least a part of an alkali metal ion of a P-type zeolite as the starting material with a divalent metal and firing the ion-exchanged zeolite. Since the pH value is shifted to a weakly alkaline level by the ion exchange treatment, the particles are effective as a filler for stabilizing a resin or the like when incorporated therein, and the refractive index of the particles can be made close to that of a resin in which the particles are to be incorporated.
    Type: Grant
    Filed: February 26, 1990
    Date of Patent: August 18, 1992
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Kiyoshi Abe, Kazuhiko Suzuki, Hiroshi Ogawa
  • Patent number: 5133899
    Abstract: Disclosed to a stabilizer composition for a chlorine-containing polymer, which comprises a zeolite type stabilizer; calcium hydroxide or magnesium hydroxide, a metal soap type stabilizer and perchloric acid as indispensable components.The stabilizer composition is obtained by adding a metal soap type stabilizer to a mixture of a zeolite type stabilizer and calcium hydroxide or magnesium hydroxide under attrition to cover the mixture with the metal soap type stabIlizer at a high efficiency, and adding perchloric acid to the covered mixture.In the stabilizer composition of the present invention, the initial discoloration, which is a fatal defect of the conventional zeolite type stabilizer for a chlorine-containing polymer, can be prevented, and a sufficient hydrogen chloride-capturing capacity is exerted and a high heat stability is attained without occurrence of bleeding.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: July 28, 1992
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Tadahisa Nakazawa, Masahide Ogawa, Shoji Shoji, Seizi Wakaki, Choichi Abe
  • Patent number: 5077248
    Abstract: Synthetic stevensite composed of stevensite-type sodium magnesium phylosilicate of which metallic components consist essentially of magnesium, sodium and silicon. The synthetic stevensite is characterized by having an X-ray diffraction peak at a spacing of 16 to 26 .ANG. when treated with ethylene glycol. It can be produced by a process comprising hydrothermally treating an aqueous composition containing basic magnesium carbonate and a silica-sodium component selected from the group consisting of (i) sodium silicate, (ii) sodium silicate and amorphous silica, and (iii) amorphous silica and sodium silicate.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: December 31, 1991
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Masanori Tanaka, Noriyuki Takahashi
  • Patent number: 5049365
    Abstract: Disclosed is a composite adsorbent consisting of a molded body of a homogeneous mixture comprising powdery active carbon and hydrous alumina of the pseudoboehmite type. This composite adsorbent has high mechanical strength and abrasion resistance. This composite adsorbent is excellent in the capacity of adsorbing organic components such as gasoline, and the desorption of the adsorbed components can be easily accomplished at a high desorption ratio. These excellent capacities are retained even if the adsorption-desorption cycle is repeated. Accordingly, this composite adsorbent is especially valuable as the adsorbent for an automobile canister.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: September 17, 1991
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Seiji Okabayashi, Hirofumi Watanabe, Kiyoshi Abe, Masahide Ogawa
  • Patent number: 5013603
    Abstract: Disclosed is a filler for ink jet recording paper, said filler being composed of amorphous silica having a median diameter, measured by the coulter counter method, of 2 to 15 .mu.m, an oil absorption of at least 180 ml/100 g, a refractive index, measured by the solvent method, of at least 1.450, and a moisture absorption, measured when it is caused to absorb moisture for 200 hours at a relative humidity of 90% and a temperature of 25.degree. C., of at least 35%.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: May 7, 1991
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Masao Takahashi, Toshio Kitsu, Seikichi Takahashi, Kinichi Ono
  • Patent number: 5013709
    Abstract: Disclosed is a color developer for a pressure-sensitive recording paper, which comprises an acid-treated smectite clay mineral having a specific chemical composition, an X-ray diffraction pattern peculiar to dioctahedral smectite, a specific solid NMR spectrum and a specific cation exchange capacity. This color developer shows a high whiteness, a high initial color density, excellent light resistance and weatherability, and a low viscosity.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: May 7, 1991
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Kiyoshi Abe, Hisashi Tsuchida, Hiroo Inoue, Mitsuo Saito
  • Patent number: 4968523
    Abstract: A shellfish extract concentrate is prepared by subjecting an extract of a shellfish (exclusive of oyster) having a solid concentration not higher than 30% by weight to an adsorption purification treatment with an adsorbent composed mainly of a water-insoluble inorganic magnesium compound, which has a specific surface area of at least 50 m.sup.2 /g, and concentrating the refined liquid in a substantially non-oxidizing atmosphere. In this shellfish extract concentrate, black and blackish brown coloring components are not contained, and flavor components and nutrients are not substantially lost. Accordingly, this shellfish extract concentrate is excellent in taste, flavor and hue.
    Type: Grant
    Filed: July 22, 1988
    Date of Patent: November 6, 1990
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Koichi Usui, Masahide Ogawa, Koyoshi Takai, Teiji Sato, Masanori Tanaka, Izumi Serizawa
  • Patent number: 4915923
    Abstract: Disclosed is a filler for ink jet recording paper, said filler being composed of amorphous silica having a median diameter, measured by the coulter counter method, of 2 to 15 .mu.m, an oil absorption of at least 180 ml/100 g, a refractive index, measured by the solvent method, of at least 1.450, and a moisture absorption, measured when it is caused to absorb moisture for 200 hours at a relative humidity of 90% and a temperature of 25.degree. C., of at least 35%.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: April 10, 1990
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Maso Takahashi, Toshio Kitsu, Seikichi Takahashi, Kinichi Ono