Patents Assigned to Nalco Chemical Company
-
Patent number: 6369182Abstract: This invention is directed to a cationic terpolymer comprising (a) a first monomer unit selected from acrylamide and methacrylamide; (b) a second monomer unit selected from dimethylaminoethyl acrylate methyl chloride quaternary salt, 3-(acrylamido)propyltrimethylammonium chloride, 3-(methacrylamido)propyltrimethylammonium chloride, dimethylaminoethyl methacrylate methyl chloride quaternary salt, dimethylaminoethyl acrylate dimethylsulfate quaternary salt, dimethylaminoethyl methacrylate dimethylsulfate quaternary salt, diethylaminoethyl acrylate methyl chloride quaternary salt and diethylaminoethyl acrylate dimethylsulfate quaternary salt; and (c) a third monomer unit selected from benzyl methacrylate, 2,2,2-trifluoroethyl acrylate, acrylamide diacetone, N-phenylacrylamide, 2,2,3,3-tetrafluoropropyl acrylate and poly(propylene glycol)methacrylate. The terpolymer is useful for dewatering a variety of sludges.Type: GrantFiled: October 11, 1999Date of Patent: April 9, 2002Assignee: Nalco Chemical CompanyInventors: Wesley L. Whipple, Ananthasubramanian Sivakumar
-
Patent number: 6369894Abstract: Described and claimed is a modular fluorometer and a method of using same to control an industrial water system, wherein said modular fluorometer comprises: one or more units with each unit comprising: a channel comprising an optically appropriate cell through which a water sample flows; a light source positioned outside said optically appropriate cell; an optional excitation filter positioned between the light source and the optically appropriate cell; a reference detector positioned outside the optically appropriate cell; an emission detector positioned outside the optically appropriate cell; an optional emission filter positioned between said emission detector and said optically appropriate cell; wherein if more than one unit is present in said modular fluorometer, said optically appropriate cells through which said water sample flows are aligned such that only one channel through which a water sample flows exists in said fluorometer.Type: GrantFiled: May 1, 2000Date of Patent: April 9, 2002Assignee: NALCO Chemical CompanyInventors: Jeffrey P. Rasimas, Michael J. Fehr, John E. Hoots
-
Patent number: 6365116Abstract: The present invention comprises a method for reducing the viscosity of the settled mud or underflow of a raked thickener thereby reducing the torque necessary to move the rake blade through the settled mud. The method includes the step of delivering a viscosity modifier to the settled mud and in front of the rake blade by pumping the viscosity modifier down the rake arm to an area in front of the rake blade. The method also includes an improved rake mechanism that includes a means for delivering viscosity modifier to the settled mud and in front of the rake blade. The present invention also includes a method for increasing the rate of consolidation of flocculated solids in a slurry.Type: GrantFiled: April 19, 2000Date of Patent: April 2, 2002Assignee: Nalco Chemical CompanyInventors: Scott Lewis Barham, Raymond Leslie Henderson
-
Patent number: 6365052Abstract: This invention is directed to a method of dewatering animal farm waste water comprising: (1) adding an effective amount of a cationic dispersion polymer having an RSV of at least 24, the dispersion polymer prepared by polymerizing under free radical forming conditions in an aqueous solution of a water-soluble salt in the presence of one or more particle stabilizing polymers (i) from about 20 to about 90 mole percent nonionic monomers and (ii) from about 10 to about 80 mole percent of cationic monomers wherein the cationic monomers are selected from at least one hydrophilic cationic monomer and at least one hydrophobic cationic monomer and wherein less than 50 percent of the cationic monomers on a molar basis are hydrophobic monomers, (2) mixing the waste water and the cationic dispersion polymer to form a mixture of water and flocculated solids and (3) separating the flocculated solids from the water.Type: GrantFiled: March 21, 2000Date of Patent: April 2, 2002Assignee: Nalco Chemical CompanyInventors: Ananthasubramanian Sivakumar, Cathy C. Johnson
-
Patent number: 6361653Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculent and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
-
Patent number: 6361652Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
-
Patent number: 6358364Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 19, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
-
Patent number: 6358746Abstract: Fluorescent compounds of the formula: wherein R1 and R2 are either both SO3M, or one of R1 and R2 is SO3M and the other is COOM, where M is selected from the group consisting of H, Na, K, Rb, Cs, Li or ammonium, are described and claimed. These inert flurorescent compounds have been found to be resistant to oxidizing biocides. One process for making these compounds is described and claimed as the condensation between a 1,8-naphthalic anhydride possessing the desired functionalities and the appropriately substituted o-phenylene diamine. Alternatively, o-amino-nitro-aromatics may be condensed with the various 1,8-naphthalic anhydrides when the in situ reduction of the nitro group is accomplished with a suitable reducing agent such as iron powder. The resulting fluorescent compounds can be used as inert fluorescent tracers in industrial water systems.Type: GrantFiled: November 8, 1999Date of Patent: March 19, 2002Assignee: Nalco Chemical CompanyInventors: Barbara E. Moriarty, Jerry L. Reddinger
-
Patent number: 6352675Abstract: The present invention provides both reagents and a process for removing heavy metals from a caustic fluid stream by the addition of reagents which are not corrosive or deleterious. Specifically, the present invention is directed to removing heavy metals from a Bayer liquor in an aluminum processing plant. The reagents, dithiocarbamate and dithocarbonate groups, are added individually or in combination thereof to the Bayer liquor for the removal of heavy metals, such as zinc. The reagents form a complex with the heavy metal for the precipitation of the metal from the fluid stream. Once a complex is formed, the Bayer liquor is held in a quiescent state for a period of time sufficient for settling out of solution the precipitate. After settling out of solution, the precipitate is separated and removed and the Bayer liquor is then further processed into alumina.Type: GrantFiled: June 7, 1999Date of Patent: March 5, 2002Assignee: Nalco Chemical CompanyInventor: John T. Malito
-
Patent number: 6344531Abstract: Water-soluble polymers of Formula Useful comprising from about 0.001 to about 10.0 mole percent of a Repeating Mer Unit represented by the formula: wherein a is an integer of from 1 to 10, R1 is selected from the group consisting of hydrogen and methyl groups, R2 and R3 are methyl groups, and R9 is selected from the group consisting of NH and O; and TAG is a fluorescing moiety; are described and claimed.Type: GrantFiled: August 31, 1999Date of Patent: February 5, 2002Assignee: Nalco Chemical CompanyInventors: Patrick G. Murray, Wesley L. Whipple
-
Patent number: 6336058Abstract: Described and claimed is a method of controlling a boiler in which control is based on information from a control Matrix applicable to the specific parameters of the boiler. The control matrices include (a) Polymer Based All-in-One Product; (b) Residual Phosphate Polymer Product with Scavenger and Condensate Corrosion Inhibitor Fed Separately; (c) pH/Phosphate Product with Polymer, Scavenger, and Condensate Corrosion Inhibitor Fed Separately; (d) All-Polymer Product with Separate Scavenger and Condensate Corrosion Inhibitor Fed Separately; and (e) pH/Phosphate Polymer Product with Scavenger and Condensate Corrosion Inhibitor Fed Separately.Type: GrantFiled: May 1, 2000Date of Patent: January 1, 2002Assignee: Nalco Chemical CompanyInventor: Roger W. Fowee
-
Patent number: 6331229Abstract: This invention is directed to a method of increasing retention and drainage in a papermaking furnish comprising adding to the furnish an effective flocculating amount of a high molecular weight water-soluble anionic or nonionic dispersion polymer.Type: GrantFiled: September 8, 1999Date of Patent: December 18, 2001Assignee: Nalco Chemical CompanyInventors: Jane B. Wong Shing, Chidambaram Maltesh, John R. Hurlock
-
Patent number: 6329165Abstract: A method for monitoring both the planktonic and sessile microbial populations in an industrial water system by the addition of a fluorogenic dye compound is described and claimed.Type: GrantFiled: December 30, 1999Date of Patent: December 11, 2001Assignee: Nalco Chemical CompanyInventors: Mita Chattoraj, Michael J. Fehr, Steven R. Hatch, Robert W. Shiely
-
Patent number: 6322749Abstract: A synergistic composition and method for inhibiting microbiological growth which comprises a combination of stabilized sodium hypobromite with a mixture of 5-chloro-2-methyl 4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one.Type: GrantFiled: February 24, 1999Date of Patent: November 27, 2001Assignee: Nalco Chemical CompanyInventors: Robert E. McCarthy, Anthony W. Dallmier, William F. McCoy
-
Patent number: 6315909Abstract: Described and claimed is a method of controlling a cooling water system in which control is based on information from a control Matrix applicable to the specific operating parameters of the cooling water system including: (i) providing a suitable fluorometer, sufficient analytical devices and a suitable controller; (ii) programming the suitable fluorometer and controller using planning information from a control Matrix for cooling water systems being treated with treatment programs selected from the group consisting of: (d) stabilized phosphate, (e) zinc, and (f) all organic; (iii) using the fluorometer and sufficient analytical devices to determine the status of system factors; (iv) determining the pattern of changes in the readings from step (iii) over time; (v) comparing the changes in readings in steps (iii) and (iv), with the information listed in the control Matrix to determine what corrective action(s) is recommended; and (vi) using the controller to automatically implement the corrective actiType: GrantFiled: May 1, 2000Date of Patent: November 13, 2001Assignee: Nalco Chemical CompanyInventors: John E. Hoots, Paul R. Young, David P. Workman
-
Patent number: 6315866Abstract: This invention is directed to method for improving the dry strength of a paper product using a single cationic dispersion polymer strength additive, wherein the cationic dispersion polymer is prepared by polymerizing in an aqueous solution of a polyvalent anionic salt in the presence of a dispersant: i. a cationic diallyl-N,N-disubstituted ammonium halide monomer of formula (H2C═CHCH2)2N+R1R2X− wherein R1 and R2 are independently C1-C20 alkyl, aryl or arylalkyl and X is an anionic counterion and ii. an acrylamide monomer of formula wherein R3and R4 are independently hydrogen, C1-C10 alkyl, aryl or arylalkyl; R5 is hydrogen or methyl and R6 and R7 are independently hydrogen or C1-C10 alkyl.Type: GrantFiled: February 29, 2000Date of Patent: November 13, 2001Assignee: Nalco Chemical CompanyInventor: Jordi Roqué Sanchez
-
Patent number: 6313246Abstract: This invention is directed to high molecular weight water-soluble zwitterionic polymers derived from zwitterionic and nonionic monomer units, and to the use of the polymers in papermaking processes.Type: GrantFiled: July 7, 1999Date of Patent: November 6, 2001Assignee: Nalco Chemical CompanyInventors: Phillip W. Carter, Patrick G. Murray, Larry E. Brammer, Jr., Andrew J. Dunham
-
Patent number: 6312644Abstract: Fluorescent monomers of the formula wherein M is selected from the group consisting of hydrogen, sodium, potassium, cesium, rubidium, lithium and ammonium, and n is selected from the group consisting of 1, 2, 3, 4, 6 and 9; are provided which are useful in the production of pyranine-tagged polymers which can be detected using a fluorometer and can be used in industrial water systems as treatment polymers.Type: GrantFiled: December 16, 1999Date of Patent: November 6, 2001Assignee: Nalco Chemical CompanyInventors: Barbara E. Moriarty, Mingli Wei, John E. Hoots, David P. Workman, Jeffrey P. Rasimas
-
Patent number: 6310104Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: November 22, 1999Date of Patent: October 30, 2001Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
-
Patent number: 6306308Abstract: A coagulant which is the reaction product of a trivalent metal salt (eg., FeCl3), excluding chromium salts, an acid phosphorous compound and an aluminum hydroxy chloride, and a process for preparing such coagulant. This coagulant may be effectively used to remove suspended solids and various impurities in most water treatment applications.Type: GrantFiled: April 20, 1999Date of Patent: October 23, 2001Assignee: Nalco Chemical CompanyInventors: Denis E. Hassick, Michael P. Flaherty, Pamela J. Dotter, Robert J. Guerrini