Patents Assigned to Nihon Bayer Agrochem K.K.
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Patent number: 5366976Abstract: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic group containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.Type: GrantFiled: September 27, 1993Date of Patent: November 22, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shoko Sasaki, Koichi Moriya, Yumi Hattori, Katsuhiko Shibuya
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Patent number: 5362704Abstract: Herbicidal novel tetrazolinones of the formula ##STR1## wherein Y represents hydrogen, chlorine, or methyl,R.sup.1 represents ethyl or n-propyl, andR.sup.2 represents cyclopentyl or cyclohexyl, with the proviso that the total of the carbon atoms of R.sup.1 and R.sup.2 is 7 or 8. They may be mixed with other herbicides.Type: GrantFiled: February 24, 1994Date of Patent: November 8, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Seishi Ito, Yukiyoshi Watanabe, Shin-ichi Narabu, Akihiko Yanagi
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Patent number: 5360935Abstract: A novel process for the preparation of 3-pheny-2-propenones of the formula ##STR1## which process comprises reacting phenylmethanesulphonyl fluorides of the formula ##STR2## with ketones of the formula ##STR3## in which A, R, Z and M have the meanings given in the specification,in the presence of a phase transfer catalyst and in the presence of acid binders and inert solvents.The products are known intermediates for the preparation of pesticides and pharmaceuticals.Type: GrantFiled: September 14, 1992Date of Patent: November 1, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Shinzo Kagabu, Katsuaki Wada
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Patent number: 5346880Abstract: This invention relates to novel pyrimidinylthioalkane derivatives of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are defined in the specification and A represents hydroxy, and B represents hydrogen or A and B together form a carbonyl group, a process for their production and a method of using said derivatives to combat unwanted plant growth.Type: GrantFiled: April 6, 1993Date of Patent: September 13, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Yoshinori Kitagawa, Hidenori Hayakawa, Katsuhiko Shibuya, Ryo Watanabe
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Patent number: 5347009Abstract: Herbicidal 1-(3-halo-4-trifluoromethylphenyl) tetrazolinones of the formula ##STR1## wherein X represents halogen,R.sup.1 represents C.sub.1-3 alkyl, andR.sup.2 represents C.sub.1-3 alkyl.Type: GrantFiled: May 26, 1993Date of Patent: September 13, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Hidenori Hayakawa, Yukiyoshi Watanabe, Akihiko Yanagi
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Patent number: 5347010Abstract: Novel tetrazolinones of the formula (I) ##STR1## wherein X is chlorine or bromine,Y is hydrogen, chlorine, bromine, methyl or ethyl, andR.sup.1 and R.sup.2 are the same or different C.sub.2-4 alkyl, a process for their preparation, and the use of the new compounds as herbicides, especially against paddy-weeds.Type: GrantFiled: July 1, 1993Date of Patent: September 13, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Hidenori Hayakawa, Yukiyoshi Watanabe, Shin-ichi Narabu, Akihiko Yanagi
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Patent number: 5344814Abstract: Herbicidal 1-(3,4-disubstituted phenyl)tetrazolinones of the formula ##STR1## wherein X represents halogen,Y represents trifluoromethoxy or trifluoromethylthio,R.sup.1 represents propyl, isopropyl or allyl, andR.sup.2 represents propyl, isopropyl or allyl.Type: GrantFiled: May 26, 1993Date of Patent: September 6, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Hidenori Hayakawa, Yukiyoshi Watanabe, Akihiko Yanagi
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Patent number: 5342938Abstract: Novel benzoxazines of the formula (I) ##STR1## the use of the new compounds as herbicides, and novel compounds of the formula (IX) as intermediates ##STR2## are disclosed.Type: GrantFiled: February 5, 1993Date of Patent: August 30, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toyohiko Kume, Toshio Goto, Atsumi Kamochi, Hidenori Hayakawa, Akihiko Yanagi, Tadao Asami
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Patent number: 5342954Abstract: Herbicidal 1-(3-halo-4-substituted phenyl)tetrazolinones of the formula ##STR1## wherein X represents halogen,Y represents isopropyl or isopropoxy,R.sup.1 represents ethyl, propyl, isopropyl or allyl, andR.sup.2 represents ethyl, propyl, isopropyl or allyl.Type: GrantFiled: May 26, 1993Date of Patent: August 30, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Hidenori Hayakawa, Yukiyoshi Watanabe, Akihiko Yanagi
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Patent number: 5314897Abstract: Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,m represents 0 or 1,n represents 0 or 1,R.sup.2 represents hydrogen or C.sub.1-4 alkyl,R.sup.3 represents hydrogen, C.sub.1-6 alkyl optionally substituted substituted by cyano, halogen or C.sub.1-4 alkoxy, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl or optionally substituted heterocyclic-methyl,T represents an optionally substituted two- or three-membered divalent or trivalent chain comprising hetero atoms and/or carbon atom, andA represents optionally substituted phenyl or an optionally substituted five- or six-membered heterocyclic radical comprising at least one hetero atom selected from the group consisting of N, O and S.Type: GrantFiled: July 12, 1993Date of Patent: May 24, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Koichi Moriya, Yumi Hattori, Ikuro Honda, Katsuhiko Shibuya
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Patent number: 5304564Abstract: Novel guanidine derivatives of the formula (I) ##STR1## wherein Z is 2-chloro-5-pyridyl, 2-chloro-5-thiazolyl, or 3-chloro-5-isoxazolyl,R.sup.1 is hydrogen or C.sub.1-4 alkyl,R.sup.2 is hydrogen, C.sub.1-4 alkyl, C.sub.3-4 alkynyl, C.sub.3-4 alkenyl or 2-chloro-5-pyridylmethyl,R.sup.3 and R.sup.4 each represent hydrogen, halogen, C.sub.1-4 alkyl, C.sub.3-1 alkynyl, C.sub.3-4 alkenyl, benzyl which may be substituted, or Z--C(R.sup.1)H--,n is 2 or 3, andY is nitro or cyano,and pesticidal compositions comprising the compound of the formula (I) as active components.Type: GrantFiled: December 7, 1992Date of Patent: April 19, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Shin-ichi Tsuboi, Koichi Moriya, Yumi Hattori, Shinzaburo Sone, Katsuhiko Shibuya
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Patent number: 5298507Abstract: Novel insecticides of the formula ##STR1## in which n is 1,X is ##STR2## Y is N or ##STR3## Z is a 5- or 6-membered nitrogen-containing heterocyclic ring, and R to R.sup.9 variously represent hydrogen or specified organic radicals.Type: GrantFiled: February 6, 1992Date of Patent: March 29, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shinzo Kagabu, Koichi Moriya
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Patent number: 5296454Abstract: The invention relates to novel acetanilides of the formula (I) ##STR1## wherein Ar represents phenyl, furyl or thienyl,R.sup.1 represents hydrogen, C.sub.1-5 -alkyl, C.sub.3-6 -cycloalkyl, C.sub.3-6 -cycloalkyl-methyl, C.sub.3-5 alkenyl, C.sub.3-5 -alkynyl, C.sub.1-3 -haloalkyl, C.sub.3-5 -epoxyalkyl, C.sub.1-3 -alkoxy-C.sub.1-4 -alkyl, C.sub.1-3 -alkylthio-C.sub.1-4 -alkyl, C.sub.1-3 -alkoxycarbonyl-C.sub.1-2 -alkyl, cyano-C.sub.1-3 -alkyl, or aralkylR.sup.2 represents hydrogen or C.sub.1-3 -alkyl,R.sup.3 represents hydrogen or C.sub.1-3 -alkyl,X represents halogen, andY represents iso-propyl, tert-butyl, C.sub.1-2 -haloalkyl, C.sub.1-2 -haloalkoxy, C.sub.1-2 -haloalkylthio or C.sub.1-2 -alkylsulfonyl,to processes for their preparation and to their use as herbicides. The invention also relates to novel intermediates and to processes for their preparation.Type: GrantFiled: June 26, 1992Date of Patent: March 22, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Hidenori Hayakawa, Itsuko Manabe, Akihiko Yanagi
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Patent number: 5290779Abstract: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a xeto group. Such compounds being useful as insecticides.Type: GrantFiled: December 30, 1992Date of Patent: March 1, 1994Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shoko Sasaki, Koichi Moriya, Yumi Hattori, Katsuhiko Shibuya
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Patent number: 5260312Abstract: Compositions which contain, as the active ingredients, a combination of heterocyclic compounds of the general formula (I) and organophosphorous compounds, in addition to one or more compounds having a polyethyleneglycol or polypropyleneglycol chain or an ethyleneglycol-propyleneglycol copolymeric chain, or a mixture of these compounds which results in a stabilization of the active ingredients without any adverse influences on the physical properties of the formulations.Type: GrantFiled: May 13, 1992Date of Patent: November 9, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Yuzuru Wada, Shigeharu Koyama
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Patent number: 5254713Abstract: Novel 2- or 3-chloropyrroles represented by the general formula: ##STR1## wherein R.sup.1 represents hydrogen atom, chlorine atom, alkyl group, or aryl group which may optionally be substituted, with the proviso that any one of the two groups represented by R.sup.1 is chlorine atom,R.sup.2 represents alkyl group or aryl group which may optionally be substituted, andR.sup.3 represents tertiary alkyl group which may be substituted by phenyl, or phenyl which may optionally be substituted, andprocesses for preparing the same.Type: GrantFiled: February 10, 1993Date of Patent: October 19, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Shinzo Kagabu, Itsumi Kawai, Katsuaki Wada
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Patent number: 5238949Abstract: Insecticidal novel nitro compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or C.sub.1-4 alkyl,R.sup.3 is -S-R.sup.4 or ##STR2## in which R.sup.4 is C.sub.1-4 alkyl, R.sup.5 and R.sup.6 are hydrogen or C.sub.1-4 alkyl,Y is CH or N, andZ is a five- or six-membered heterocyclic group having at least one nitrogen atom which may be substituted by halogen or C.sub.1-4 alkyl, provided that where Y is CH, then R.sup.1 is C.sub.1-4 alkyl.Type: GrantFiled: May 22, 1990Date of Patent: August 24, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Koichi Moriya, Yumi Hattori, Ikuro Honda, Katsuhiko Shibuya
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Patent number: 5237100Abstract: Substituted benzylcycloalkenylurea derivatives of the formula (I) ##STR1## wherein X represents a halogen atom or a lower alkyl group, Y represents an oxygen atom or a sulfur atom,R.sup.1 represents a cycloalkenyl group andR.sup.2 represents a lower alkyl group, a cycloalkyl group, a benzyl group or a phenyl group optionally substituted by 1 to 5 substituents selected from the group consisting of a hydroxyl group or a lower alkoxy groupand their use as fungicides. They can be synthesized, for example, by reacting of a substituted benzyl-cycloalkenylamine with an isocyanate or by reacting of a carbamoyl halide with an amine. The starting material, the substituted benzyl-cycloalkenyl amines, are also new.Type: GrantFiled: April 23, 1992Date of Patent: August 17, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Yasuo Yamada, Junichi Saito, Tatsuo Tamura, Shinji Sakawa
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Patent number: 5231098Abstract: Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally substituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-atom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.Type: GrantFiled: January 21, 1992Date of Patent: July 27, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shoko Sasaki, Koichi Moriya, Yumi Hattori, Katsuhiko Shibuya
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Patent number: 5219869Abstract: Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,m represents 0 or 1,n represents 0 or 1,R.sup.2 represents hydrogen or C.sub.1-4 alkyl,R.sup.3 represents hydrogen, C.sub.1-6 alkyl optionally substituted substituted by cyano, halogen or C.sub.1-4 alkoxy, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl or optionally substituted heterocyclic-methyl,T represents an optionally substituted two- or three-membered divalent or trivalent chain comprising hetero atoms and/or carbon atom, andA represents optionally substituted phenyl or an optionally substituted five- or six-membered heterocyclic radical comprising at least one hetero atom selected from the group consisting of N, O and S.Type: GrantFiled: September 11, 1992Date of Patent: June 15, 1993Assignee: Nihon Bayer Agrochem K.K.Inventors: Kozo Shiokawa, Shinichi Tsuboi, Koichi Moriya, Yumi Hattori, Ikuro Honda, Katsuhiko Shibuya