Patents Assigned to Nippon Petrochemical Company, Limited
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Patent number: 4808454Abstract: An active agent-containing laminated material and the method for producing the same, in which an impermeable film is temporarily adhered to at least one side surface of an active agent-containing film and impermeable film can be peeled off and readhered repeatedly. The laminated material is prepared by directly laminating a molten web of active agent-containing polyolefin composition with an impermeable film at and pressing them together, said active agent-containing polyolefin composition comprising: (A) 10 to 100 parts by weigh to carboxyl group-containing ethylene based copolymer of at least 7% by weight in the content of carboxyl group-containing monomer; (B) 90 parts by weight or less of low density polyethylene having a melt index of at least 30 g/10 min.; and (C) at least 0.005 parts by weight of an active agent or agents relative to 100 parts by weight of said polymers (A) plus (B).Type: GrantFiled: September 16, 1986Date of Patent: February 28, 1989Assignee: Nippon Petrochemicals Company, LimitedInventor: Hachiro Saitoh
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Patent number: 4803238Abstract: A compounding oil for polymers which can be used as a plasticizer, process oil, thinner, softening agent, extender or the like. The compounding oil of the invention comprises a fraction mainly containing triaryldialkanes and having boiling points in the range of 350.degree. to 450.degree. C., which fraction is prepared by disproportionating a by-product oil fraction at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said by-product oil fraction mainly containing diarylalkanes, having boiling points in the range of 260.degree. to 320.degree. C., and being obtained from the process to prepare alkylated monocyclic aromatic hydrocarbons by alkylating monocyclic aromatic hydrocarbons with olefins in the presence of an alkylation catalyst.Type: GrantFiled: October 29, 1987Date of Patent: February 7, 1989Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Eiichi Matsuzaka, Satoshi Narui
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Patent number: 4802058Abstract: The present invention relates to a method for refining an electrical insulating oil by refining a heavy by-product oil obtained in the preparation of ethylbenzene or ethyltoluene. The method comprises distilling off the lighter components from the by-product oil, then dehydrogenating, distilling and hydrogenating.Type: GrantFiled: March 9, 1988Date of Patent: January 31, 1989Assignee: Nippon Petrochemicals Company, LimitedInventors: Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi, Atsushi Sato
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Patent number: 4793956Abstract: A process for preparing a porous film or sheet, which process comprises melt-forming a composition into a film or sheet and then stretching the thus-formed film or sheet at a temperature in the range of 30.degree. to 110.degree. C., said composition containing:(a) 30-90% by weight of a linear low-density polyethylene having a density not smaller than 0.910 g/cm.sup.3 and smaller than 0.940 g/cm.sup.3 ;(b) 10-70% by weight of an ethylene/.alpha.-olefin copolymer having a density not smaller than 0.860 g/cm.sup.3 and smaller than 0.910 g/cm.sup.3, a boiling n-hexane insolubles content not less than 10% by weight and a maximum peak temperature not lower than 100.degree. C. as measured according to a differential scanning calorimetry; and(c) 20-500 parts by weight of a filler based on 100 parts by weight of said resin components.Type: GrantFiled: December 24, 1986Date of Patent: December 27, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Motomi Nogiwa, Shuichi Yoshida, Shigeki Komori, Toshitsune Yoshikawa, Toshio Koutsuka
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Patent number: 4755275Abstract: A process for preparing an electrical insulating oil comprising a reaction product having a boiling range of higher than 260.degree. C. obtained by treating a hydrocarbn feed at a reaction temperature in the range of 0.degree. to 300.degree. C. in liquid phase in the presence of an acid catalyst, said hydrocarbon feed comprising a distillate from a thermal-cracked oil obtained in a thermal cracking process for thermally cracking a petrolic heavy residual oil at a temperature not lower than 400.degree. C. and not exceeding 700.degree. C., said distillate consisting mainly of hydrocarbons boiling in the range of 120.degree. to 290.degree. C. and said distillate containing at least 30 weight percent of paraffins and at least 10 weight percent of aliphatic olefins, and separating said reaction product from the resulting mixture containing at least said reaction product and unreacted hydrocarbons.Type: GrantFiled: February 5, 1985Date of Patent: July 5, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Yoshikazu Murai, Tatsuo Yamaguchi, Kanji Mochizuki, Kunio Sugisawa
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Patent number: 4747902Abstract: A method for producing a laminated material giving higher adhesive strength of laminated layers and the thermal deterioration of polyolefin and the undesirable release of the active agent during the lamination process are avoided. The method is characterized in that the substrate sheet is previously laminated with a polyolefin layer, and a molten web of polyolefin film is laminated to the side of said polyolefin layer of the substrate sheet under pressure at a relatively lower temperature.Type: GrantFiled: September 17, 1986Date of Patent: May 31, 1988Assignee: Nippon Petrochemicals Company, LimitedInventor: Hachiro Saitoh
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Patent number: 4748206Abstract: A polyolefin composition and the same especially used for producing vehicle exterior members which is excellent in softness, impact resistance, moldability, appearance, restorable property and so forth. The composition comprises 20 to 70% by weight of a crystalline propylene polymer (a); 10 to 50% by weight of a substantially amorphous .alpha.-olefin copolymer (b); 5 to 50% by weight of an ethylene-.alpha.-olefin copolymer (c) which is 0.860 to 0.910 g/cm.sup.3 in density, 10% by weight or more in boiling n-hexane insoluble matter and 100.degree. C. or higher in the maximum peak temperature T.sub.m according to the differential scanning calorimetry (DSC); and 5 to 30% by weight of an ethylene polymer (d) of 0.910 to 0.965 g/cm.sup.3 in density, wherein the total of said components (a), (b), (c) and (d) is 100% by weight.Type: GrantFiled: November 7, 1986Date of Patent: May 31, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Motomi Nogiwa, Sachio Akai, Hiroshi Furuhashi, Kenji Tanaka, Toshimasa Takakusaki, Yoichi Kawai, Masaru Abe, Katsumi Sekiguchi
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Patent number: 4742106Abstract: A polyolefin composition having a high rigidity and a high impact resistance, said polyolefin composition comprising:(a) 10-96% by weight of a propylene polymer;(b) 2-30% by weight of an ethylene/.alpha.-olefin copolymer obtained by copolymerizing ethylene with an .alpha.-olefin having 3 to 12 carbon atoms in the presence of a catalyst consisting essentially of a solid material and an organoaluminum compound, said solid material containing magnesium and titanium and/or vanadium, and said ethylene/.alpha.-olefin copolymer having the following properties (i)-(iv):______________________________________ (i) Melt index 0.01-100 g/10 min (ii) Density 0.860-0.910 g/cm.sup.3 (iii) Maximum peak temperature not lower than as measured according to 100.degree. C. a differential scanning calorimetry (DSC) (iv) Insolubles in boiling not less than 10 n-hexane wt. % ______________________________________(c) 20-60% by weight of a mica,provided the toal amount of said components (a), (b) and (c) is 100% by weight.Type: GrantFiled: February 2, 1987Date of Patent: May 3, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Takeshi Kamiya, Noboru Yamaoka
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Patent number: 4735703Abstract: Concentrations of straight chain material are material are increased by treating a thermal-cracked oil distillate boiling in the range of 120.degree. to 290.degree. C. and containing aliphatic olefins, at a temperature of 0.degree. to 330.degree. C. in liquid phase in the presence of an acid catalyst, said thermal-cracked oil distillate being obtained from a thermal cracking process of thermally cracking a petrolic heavy residual oil at a temperature not lower than 400.degree. C. and not exceeding 700.degree. C.; and then separating and removing from the reaction mixture heavy components boiling higher than said distillate.Type: GrantFiled: May 8, 1985Date of Patent: April 5, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Yoshikazu Murai, Tatsuo Yamaguchi, Kanji Mochizuki, Kunio Sugisawa
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Patent number: 4734824Abstract: An electrical insulating oil which is suitable for use in impregnating electrical appliances such as capacitors, cables and transformers, especially those in which plastic materials are used partially or totally as dielectrics or insulating materials, and electrical appliances that are impregnated with the above electrical insulating oil. The electrical insulating oil of the invention contains at least one monoolefin and/or diolefin having three condensed or non-condensed aromatic rings.Type: GrantFiled: June 23, 1986Date of Patent: March 29, 1988Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
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Patent number: 4716084Abstract: An oil-impregnated capacitor made by winding at least one plastic film impregnated with an electrical insulating oil comprising 1-phenyl-1-methylphenylethane in which 1-phenyl-1-(4-methylphenyl)ethane and 1-phenyl-1-(2-methyl)ethane are present in amounts of not less than 70 percent and not more than 15 percent, respectively, based on the total weight of the 1-phenyl-1-methylphenylethane.Type: GrantFiled: April 18, 1986Date of Patent: December 29, 1987Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi
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Patent number: 4709089Abstract: An effective method for refining 2-(aryl substituted)propionic acid or its salt which is characterized in that 2-(aryl substituted)propionic acid or its salt containing halogenated by-products is brought into contact with hydrogen in a liquid phase containing water under a basic condition at temperatures in the range of 20.degree. C. to 170.degree. C. in the presence of a catalyst of transition metal of the group VIII in the periodic table, thereby dehalogenating said halogenated by-product and producing highly pure 2-(aryl substituted)propionic acid or its salt.Type: GrantFiled: February 6, 1987Date of Patent: November 24, 1987Assignee: Nippon Petrochemicals Company, LimitedInventors: Isoo Shimizu, Yasuo Matsumura, Yoshihisa Inomata
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Patent number: 4693844Abstract: A vinylnorbornyl alcohol of 5- or 6-vinyl-2-hydroxymethylbicyclo[2.2.1]heptane which is represented by the following structural formula: ##STR1## The compound has particular fragrance of a mint-like note partaking of camphor tone.Type: GrantFiled: November 22, 1985Date of Patent: September 15, 1987Assignee: Nippon Petrochemicals Company LimitedInventors: Yoshiharu Inoue, Fumio Tanimoto, Hisao Kitano
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Patent number: 4692270Abstract: A surfactant is obtained by treating a mixture of 20 to 95 wt. % of a thermal cracking oil fraction obtained by thermally cracking a petroleum heavy residual oil at 400.degree. to 700.degree. C., for example, by delayed coking and 80 to 5 wt. % of other aromatic source, for example, an aromatic fraction having a comparatively high boiling point with an acid catalyst, and sulfonating and neutralizing the product. This surfactant is used as a dispersing agent for a coal-oil mixture (COM).Type: GrantFiled: September 23, 1985Date of Patent: September 8, 1987Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Yoshikazu Murai, Tatsuo Yamaguchi, Kanji Mochizuki, Kunio Sugisawa
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Patent number: 4686548Abstract: A pressure-sensitive recording material of the type which is prepared by using an electron donating dye-precursor that produces a color when the dye-precursor is brought into contact with an electron accepting color developer. The pressure-sensitive recording material is characterized in that the solvent for said dye-precursor comprises an alkylated fraction which is prepared by alkylating a by-product fraction with at least one alkyl group having 1 to 5 carbon atoms, the by-product fraction containing the components within the boiling range of 255.degree. to 300.degree. C. on the atmospheric pressure basis and being obtained in the process for producing ethylbenzene or ethyltoluene from ethylene and benzene or toluene. The pressure-sensitive recording material of the invention has scarcely offensive odor and can develop a dense color with a higher color developing rate.Type: GrantFiled: June 14, 1985Date of Patent: August 11, 1987Assignee: Nippon Petrochemicals Company, LimitedInventors: Naoya Takahashi, Keiji Endo, Eiichi Matsuzaka, Satoshi Narui, Atsushi Sato
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Patent number: 4681980Abstract: A novel method for improving electrical insulating hydrocarbon. The electrical insulating substance is obtained by dehydrogenating aromatic hydrocarbons having two aromatic nuclei. The electrical insulating substance itself or a mixture of it with other electrical insulating oils is suitable for use in impregnation of electrical appliances.Type: GrantFiled: November 6, 1985Date of Patent: July 21, 1987Assignee: Nippon Petrochemicals Company LimitedInventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
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Patent number: 4661165Abstract: A solvent for the dye of pressure-sensitive recording paper which solvent has no offensive odor and both the color developing rate and the density of developed color are excellent. The solvent is characterized in that it comprises a fraction having boiling points in the range of 270.degree. to 350.degree. C. which is prepared by distilling the heavier products obtained from the process for producing ethyltoluene by alkylating toluene with ethylene in the presence of synthetic zeolite catalyst.Type: GrantFiled: June 18, 1985Date of Patent: April 28, 1987Assignee: Nippon Petrochemicals Company, LimitedInventors: Shigenobu Kawakami, Eiichi Matsuzaka, Satoshi Narui, Naoya Takahashi
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Patent number: 4631632Abstract: Provided is an impregnated capacitor wherein at least part of the capacitor element comprises a metallized polypropylene base film impregnated with an insulating impregnating agent comprising a compound having three condensed or non-condensed aromatic rings, the ratio of the amount of the impregnating agent which penetrates between the base film layers to that of said agent which penetrates into the base film per unit thickness (.mu.) being at least 60.Type: GrantFiled: September 24, 1985Date of Patent: December 23, 1986Assignee: Nippon Petrochemicals Company, LimitedInventors: Masafumi Kano, Megumu Tanaka, Atsushi Sato, Shigenobu Kawakami
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Patent number: 4621302Abstract: An electrical insulating oil which is suitable for use in impregnating electrical appliances such as capacitors, cables and transformers, especially those in which plastic materials are used partially or totally as dielectrics or insulating materials, and electrical appliances that are impregnated with the above electrical insulating oil. The electrical insulating oil of the invention contains at least one monoolefin and/or diolefin having three condensed or non-condensed aromatic rings.Type: GrantFiled: March 13, 1985Date of Patent: November 4, 1986Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
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Patent number: 4618914Abstract: An improved electrical insulating oil which is stable in refining treatment and good electrical properties are maintained under high temperature conditions, and oil-filled electrical appliances impregnated therewith. The electrical insulating oil comprises 1,1,-diarylalkenes which are represented by the following general formula (I): ##STR1## wherein R.sub.1 to R.sub.4 's are the same or different and each of them is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and m and n are integers from 0 to 3, inclusive.Type: GrantFiled: February 28, 1985Date of Patent: October 21, 1986Assignee: Nippon Petrochemicals Company, LimitedInventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi