Patents Assigned to NL Industries, Inc.
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Patent number: 3977894Abstract: A self-activating organoclay rheological additive for non-aqueous fluid systems has been produced comprising a homogeneous mixture of an organically modified montmorillonite clay and two solid waxes, the waxes being the activators for the organic clay. The two waxes are finely divided particles of glyceryl tri-12-hydroxystearate and an amide wax having the formula ##EQU1## where n is from 2 to 18, HSA is the acyl radical of 12-hydroxystearic acid, R is hydrogen or the acyl radical of 12-hydroxystearic acid.The montmorillonite clay is modified with a quaternary ammonium compound.Type: GrantFiled: September 19, 1975Date of Patent: August 31, 1976Assignee: NL Industries, Inc.Inventors: Robert Winslow White, Armando Franco
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Patent number: 3976744Abstract: Laminar 2 : 1 layer-lattice aluminosilicate minerals containing intra-lattice multivalent ions such as nickel, copper, cobalt and others. The minerals are particularly useful in catalytic operations. Procedures for preparing the inventive minerals are given.Type: GrantFiled: September 23, 1974Date of Patent: August 24, 1976Assignee: NL Industries, Inc.Inventor: William T. Granquist
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Patent number: 3975283Abstract: A gelling agent is added to a brine containing magnesium chloride to convert the brine into a gel which is spray dried to produce dried magnesium chloride comprising substantially solid discrete particles of magnesium chloride having bulk densities in the range from about 12 to 45 pounds per cubic foot.Type: GrantFiled: March 21, 1975Date of Patent: August 17, 1976Assignee: NL Industries, Inc.Inventors: David G. Braithwaite, William P. Hettinger, Jr.
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Patent number: 3975063Abstract: A progressive slide assembly comprising three nested channel members or slides, the outer one of which is adapted to be fixed, has a rack and pinion gear assembly for effecting positive sliding movement of the intermediate slide, progressively, with the inner slide and uniformly throughout the entire length of travel of the intermediate and inner slides.Type: GrantFiled: May 12, 1975Date of Patent: August 17, 1976Assignee: NL Industries, Inc.Inventors: Hans Mahotka, Manfred Glastetter
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Patent number: 3973991Abstract: A light-weight lead-acid battery has been prepared which contains a novel light weight electrode assembly. The electrode assembly comprises a laminated electrode having at least three plies, the center ply being a conductive sheet and the outer two plies being sheets of porous, compressed and sintered homogeneous composite of synthetic fibers and lead oxide powder material.Type: GrantFiled: March 5, 1975Date of Patent: August 10, 1976Assignee: NL Industries, Inc.Inventors: John P. Cestaro, Uriel Sokolov
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Patent number: 3973061Abstract: A composition of matter comprising a mass of ferrous scrap pieces compressed together in random orientation forming a network of interlocking pieces has been prepared. The ferrous metal network has a density of 1.2 to 4.0 g/cc, a porosity of 50% to 85% and a short transverse tensile strength (S.T.T.S.) of at least 2 psi, preferably at least 2.5 psi.This ferrous metal network may be impregnated with magnesium in amount from 18 to 55% by weight of the impregnated body. The magnesium impregnated body is useful for treating high melting metals such as ferrous metal to reduce the sulphur content or to produce nodular iron.Type: GrantFiled: March 25, 1975Date of Patent: August 3, 1976Assignee: NL Industries, Inc.Inventors: Jairaj Easwaran, George S. Foerster
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Patent number: 3971734Abstract: The invention provides compositions and aqueous solutions containing a sulfite compound chosen from alkali metal and ammonium sulfites and bisulfites and at least one water soluble stabilizing compound which is an organic phosphonate containing at least two phosphonic acid groups per molecule. Also provided is a method of reducing the oxidation rate of aqueous sulfite solutions caused by oxygen in the atmosphere and a method of decreasing the corrosiveness to ferrous metals of aqueous systems containing dissolved oxygen and at least one divalent cation derived from iron, cobalt, copper, manganese, and nickel.Type: GrantFiled: March 3, 1975Date of Patent: July 27, 1976Assignee: NL Industries, Inc.Inventor: Harley E. Bush
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Patent number: 3969293Abstract: Novel basic zinc phosphites are described for use as tannin stain inhibitors which can be represented by the formula;X ZnO.sup.. ZnHPO.sub.3wherein X is a number from 1/2 to 10.The basic zinc phosphites are prepared by admixing zinc oxide and phosphorous acid in the presence of water.Type: GrantFiled: March 24, 1975Date of Patent: July 13, 1976Assignee: NL Industries, Inc.Inventors: Edward Louis White, William Ernest Robertson, William Heng-Sen Yu
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Patent number: 3965043Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.Type: GrantFiled: September 6, 1974Date of Patent: June 22, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3963602Abstract: Catalysts of wide utility, e.g., for hydrocarbon conversion, are prepared by calcining at 500.degree.C. to 800.degree.C. a septechlorite precursor prepared by hydrothermal synthesis, and which may be characterized as a charge-balanced 1:1 trioctahedral phyllosilicate in which the divalent metal ions may be nickel, magnesium, cobalt, iron, copper, manganese, zinc, or mixtures thereof, and the trivalent metal ions may be aluminum, chromium, iron, or mixtures thereof, in relative proportions as set forth in the specification and claims.Type: GrantFiled: July 7, 1975Date of Patent: June 15, 1976Assignee: NL Industries, Inc.Inventors: Alan C. Wright, Hsien-Dao Chang
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Patent number: 3962361Abstract: Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged synthetic saponite-type catalyst in which the central octahedral layer contains one or more divalent cations selected from the group consisting of Mg, Ni, Co, Zn, Mn, Cu, and mixtures thereof, provided that the octahedral layer contains less than 95 mole % Mg, and in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of a nickeliferous saponite-type clay.Type: GrantFiled: December 6, 1974Date of Patent: June 8, 1976Assignee: NL Industries, Inc.Inventor: George E. Stridde
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Patent number: 3952085Abstract: Minute amounts of boron present in naturally occurring brines found in oceans, inland seas, salt lakes and the like are removed by treating the brine with an oxide of aluminum.Type: GrantFiled: February 21, 1975Date of Patent: April 20, 1976Assignee: NL Industries, Inc.Inventors: David G. Braithwaite, R. Keith Darlington
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Patent number: 3948670Abstract: An improved alumina-chrome refractory composition having increased strength at both ambient and high temperatures has been prepared comprising the following ingredients:Tabular Alumina 70-96% Calcined Alumina -325 mesh 0-10% Milled Zircon -325 mesh 1-10% Chromic Oxide Refractory Grains Ground to -10 mesh with at Least 70% +200 mesh 3-10% Bentonite 0-4% Water 0-10% Phosphate Compound 0-18%Type: GrantFiled: October 24, 1974Date of Patent: April 6, 1976Assignee: NL Industries, Inc.Inventor: Edward L. Manigault
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Patent number: 3945272Abstract: A thread-rolling method as well as thread-rolling dies and method for manufacturing the dies. The shank on which the thread is rolled has a tapered free end region, and the dies which are used for rolling the thread are initially made up of a pair of individual sections having flat and inclined die faces with these sections subsequently joined to each other to form the complete die. The threads may be of lobular configuration, and during the rolling of the thread itself the lobes are simultaneously formed. The lobes for the threads are achieved directly from the thread-rolling dies by pressing across the ridges thereof tools which form in the ridges indentations having a predetermined pattern of distribution which will achieve the required distribution of the lobes on the thread which is rolled.Type: GrantFiled: June 11, 1974Date of Patent: March 23, 1976Assignee: NL Industries Inc.Inventor: Leon Simons
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Patent number: 3934444Abstract: A vibration-resistant, thread-forming screw. The screw has an elongated shank made of a solid, one-piece body and provided with an interior core portion which, in any plane normal to the shank axis, has a circular configuration. Integral with and projecting radially from this core portion are a plurality of lobes uniformly distributed circumferentially about the shank axis and extending along spirals which progress angularly about the shank axis in a direction opposite to the thread. Each lobe has, in the direction in which the screw is turned into a body, an elongated leading leg which progresses gradually away from the shank axis in the latter direction of turning and a relatively short trailing leg which returns abruptly toward the shank axis before joining the leading leg of the next lobe. A specially shaped die for forming the screw.Type: GrantFiled: August 29, 1974Date of Patent: January 27, 1976Assignee: NL Industries, Inc.Inventor: Leon Simons
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Patent number: 3935170Abstract: A novel antimony catalyst for polyester condensation reactions is described comprising trivalent antimony having its valences occupied by dianion radicals of 1,2-diols and anion radicals or organic carboxylic acids. The molar ratio of antimony to dianion radical of 1,2-diol to anion radical of organic carboxylic acid is 1:1:1. The antimony compound is prepared by reacting a mixture of a 1,2-diol and a trivalent antimony reactant represented by the formula; ##EQU1## wherein Sb is antimony, R.sub.1 is an anion radical of an organic carboxylic acid; and R.sub.2 is selected from the group consisting of anions of alcohols, anions of organic carboxylic acids and mixtures thereof.Type: GrantFiled: February 3, 1975Date of Patent: January 27, 1976Assignee: NL Industries, Inc.Inventor: Otto Ernest Loeffler
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Patent number: 3930881Abstract: A lead acid storage battery is produced wherein the electrolyte is an immobilized paste. The immobilized electrolyte paste comprises 1.5 to 4 parts sulfuric acid having a specific gravity from 1.050 to 1.350 and 1 part organic microparticles being inert to sulfuric acid and having a particle diameter of 0.1 to 3 .mu..Type: GrantFiled: July 22, 1974Date of Patent: January 6, 1976Assignee: NL Industries, Inc.Inventors: John P. Cestaro, Linda J. Crosby