Abstract: A process for improving the thermal stability of copper alloys having a low stacking fault energy is disclosed which comprises cold working the alloy, heating the alloy at a first temperature of from 100.degree. to 300.degree. C, additionally heating the alloy at a second temperature of from 200.degree. to 360.degree. C and cooling to room temperature. The second temperature must be higher than the first temperature.
Abstract: Hydrogen halide levels of halogenated aliphatic nitriles are unexpectedly reduced by condensing a vapor comprising hydrogen halide and halogenated aliphatic nitrile at selected elevated temperatures, thus producing a product having reduced hydrogen halide levels and improved storage stability.
Type:
Grant
Filed:
February 25, 1976
Date of Patent:
May 24, 1977
Assignee:
Olin Corporation
Inventors:
Sudhir K. Mendiratta, Ronald L. Dotson, George M. Shipley
Abstract: A system is provided for controlling the porosity of a web or film issuing from an electric spark perforating apparatus in accordance with an operator-set reference porosity regardless of variations in web speed, inherent web porosity, spark discharge energy and spark repetition frequency by controlling the frequencies of the electrical sparks applied to the web in accordance with the product of two signals, one a difference signal obtained by comparing the porosity of the web leaving the perforator and the reference porosity and the other signal derived from the speed of the web.
Abstract: Alkali metal salts of dichloroisocyanuric acid are produced by the reaction of a monoalkali metal cyanurate with hypochlorous acid while maintaining the pH of the reaction mixture in the range of from about 6.0 to about 7.5 and recovering the solid alkali metal dichloroisocyanurates produced thereby.The products are useful as bleaching or sanitizing agents.
Abstract: Corrosion inhibiting compositions are described which contain a hydrazine compound, an organometallic complex and a quinone compound. The organometallic complex is the reaction product of a cobaltous, manganous, or cupric inorganic salt and one or more ligands comprising amino derivatives of carboxylic acids or salts. The quinone compound is one which renders the composition compatible with chelating phosphonate scale control agents. The use of these compositions as oxygen scavengers in corrosive environments is also described.
Abstract: Corrosion inhibiting compositions are described which contain a hydrazine compound and an organometallic complex. The organometallic complex is the reaction product of a cobaltous, manganous, or cupric inorganic salt and one or more ligands comprising amino derivatives of carboxylic acids or salts. The use of these compositions as oxygen scavengers in corrosive environments is also described.
Abstract: A method for the manufacture of hollow articles comprising providing a first sheet of metal, placing on said first sheet a weld-inhibiting material in a pattern corresponding to a predetermined configuration of fluid passageways, forming an assembly by superimposing a second sheet of metal upon the surface of said first sheet bearing said pattern, pressure welding said assembly in the areas thereof not separated by weld-inhibiting material, and expanding the areas separated by said weld-inhibiting material, wherein the weld-inhibiting pattern provided is so configured that when said assembly is expanded, a marker structure is formed which is situated so as to guide the determination of the final linear dimensions of said article. The foregoing marker enables the rapid, automated sizing of articles such as heat exchange panels produced by the above process.
Abstract: Superior drying is obtained for coating compositions containing drying or semi-drying oils by incorporating therein an effective amount of 5-methyl-1,10-phenanthroline.
Abstract: The roll formation of polymer coated regenerated cellulose films is substantially improved by incorporating in polymer coatings for such films from 0.25 to 4% by weight, based upon the weight of the polymer coating, of finely divided cellulose fibers having an average particle fiber length within the range of from 10 to 150 microns.
Abstract: High strength oxidation resistant nickel base alloys are disclosed, said alloys consisting essentially of from 2 to 6% aluminum, 1 to 6% chromium, 0.5 to 4% silicon, 5 to 20% cobalt, 0.03 to 0.30% carbon, 0.005 to 0.25% magnesium, balance nickel. The alloys may optionally include 0.002 to 0.05% boron, 0.002 to 0.05% zirconium, up to 15% iron, up to 1% manganese and up to 1% of an element selected from the group consisting of Rare Earth elements. The alloys exhibit a high resistance to oxidation deterioration and good mechanical properties at elevated temperatures.
Abstract: A nitrocellulose-containing lacquer for producing a smokeless powder propellant, which lacquer includes nitrocellulose, a solvent for the nitrocellulose, water, and a surfactant for preventing the water from forming discrete globules in the lacquer.
Type:
Grant
Filed:
February 20, 1975
Date of Patent:
April 19, 1977
Assignee:
Olin Corporation
Inventors:
Earl J. Kimmel, Charles Earnest Silk, deceased
Abstract: An inflating system of the type utilizing a propellant charge and stored fluid under pressure to inflate an inflatable member such as a vehicle safety bag. The propellant chamber in which the propellant burns is separated from the reservoir in which the fluid is stored by a nozzle member. Means is provided for reducing the throat area of the nozzle member upon actuation of the high or fast deployment of the system to increase the burning rate of the propellant charge.
Abstract: Selected Schiff bases of aromatic and alkylsubstituted aromatic ortho diamines are employed as cross-linking agents in the preparation of high resilience polyurethane foam.
Type:
Grant
Filed:
February 17, 1976
Date of Patent:
April 5, 1977
Assignee:
Olin Corporation
Inventors:
Frank J. Preston, John S. Babiec, Jr., Clifford J. Maxwell
Abstract: Spinodal, precipitation hardened copper base alloy is prepared having high strength and favorable strength to ductility characteristics. The alloy consists essentially of from 10 to 30% nickel, 1 to 5% aluminum and the balance essentially copper. The microstructure of the alloy is characterized by including finely dispersed precipitates of Ni.sub.3 Al particles dispersed throughout the alloy matrix.
Abstract: Multiple gauge metal strip is prepared by a process which comprises shaping strip material of rectangular cross section to form regions of at least two variable thicknesses defining a stepped surface configuration in at least one of the broad surfaces of said strip, and drawing the shaped strip through a die which defines said cross sectional configuration to produce a reduction of said strip to final dimension, wherein said drawing step is performed without direct surface-to-surface contact between said strip and said die, such that the width dimension of said strip is unchanged and the ratio of strip surface to strip cross sectional area changes by at least 30%. The drawing method of this invention employs hydrodynamic lubrication and can achieve one-pass cross sectional reductions of from 39 to 55%.
Type:
Grant
Filed:
December 31, 1975
Date of Patent:
April 5, 1977
Assignee:
Olin Corporation
Inventors:
Joseph Winter, Eugene Shapiro, Warren F. Smith
Abstract: A diaphragm cell is provided having a continuous net between the anodes and the diaphragm. The continuous net permits the minimum anode-cathode spacing to be employed while maintaining uniform anode-cathode spacing throughout the cell. In addition, the diaphragm is retained and prevented from adhering to the surface of the anodes.Employing the diaphragm cell of the present invention in the electrolysis of aqueous alkali metal halide brines results in lower electrical energy requirements and reduced operating costs.
Abstract: Improved oxidation resistant nickel base alloys, and processing thereof, consisting essentially of from 2 to 6% aluminum, from 0.5 to 4% silicon, from 0.001 to 0.5% of a material selected from the group consisting of the elements of the lanthanide series of the Periodic Table and mixtures thereof, preferably mischmetal, and the balance essentially nickel.
Abstract: The present invention is directed to a chlorine dioxide generation apparatus and a method of generating chlorine dioxide using the apparatus. The novel apparatus includes a generation vessel having leak-inhibiting solvent weld joints with reducing couplings which form an inlet and outlet. The reducing couplings advantageously have surfaces which form an angle of at least 110.degree. with the vessel walls to create a geometry which prevents chemicals buildup during operation of the apparatus.
Abstract: Corrosion inhibiting compositions are described which contain a hydrazine compound and an organometallic complex. The organometallic complex is the reaction product of a cobaltous, manganous, or cupric inorganic salt and one or more ortho aromatic ligands containing at least two hydroxy or two amino functional groups or at least one amino and one hydroxy group. The use of these compositions as oxygen scavengers in corrosive environments is also described.
Abstract: A method of bonding film-forming metals and their alloys has been developed. The method comprises applying a first coating of a metal, compound, or alloy of the platinum metal group to the film-forming metal. A second coating of copper is then applied to the first coating. A second metal, such as steel, can then be readily soldered to the copper coating to form a strong, durable bond.This bonding method can be used, for example, to solder a titanium screen or mesh to an electroconductive metal in the assembly of electrolytic cells for the production of chlorine or oxychlorine compounds.
Type:
Grant
Filed:
March 27, 1975
Date of Patent:
March 15, 1977
Assignee:
Olin Corporation
Inventors:
Peter A. Danna, Richard A. Holcomb, Richard J. Roethlein