Abstract: A composition of a packer fluid which comprises biodiesel glycerin to be used in deep and ultra-deep wells in environments containing CO2 and a process of using the same. This fluid presents a specific mass of at least 1.15 g/cm3, adequate viscosity for pumping at less than 2,000 cP and corrosive potential of up to 3 mm in 30 years. In addition to this, the composition of this packer fluid is compatible with the elastomers normally employed and does not degrade when exposed to temperatures lower than 100° C. The packer fluid is injected into an oil well as part of a well packer process.

Abstract: A process for API GRAVITY enrichment and the reduction of naphthenic acidity of petroleum, heavy petroleum, extra-heavy oil and oil mixtures and their fractions in the presence of microwave-absorbing materials, preferentially those which absorb radiation in localized sites forming nanoreactors, pure or in mixtures such as spent hydrotreatment catalysts. The process is characterized by causing an increase in the API GRAVITY of the petroleum or its mixtures, performing the cracking of the heavier fractions present in the petroleum and reducing the concentration of naphthenic acids present in the processed petroleum. This process is also characterized by operating at a relatively low temperature and pressure with an operating range that enables a simplified union of the microwave source with a petroleum enrichment industrial reactor.

Abstract: The present invention relates to a system for the separation of suspensions of spent catalysts and hydrocarbons formed in an FCC unit with multiple ascending flow reaction tubes, comprising interconnections between each of the ascending flow reaction tubes and the separator vessel, each interconnection also comprises two sections. The outside sections of the separator vessel are inclined and are connected to a single vertical section, which penetrates into the interior of the separator vessel, and which has at its lower end an open device for draining the spent catalyst from the suspensions separated in this sector. In the same vertical section, at the end of its internal part at the separator vessel, a series of two sets of cyclones are installed, the first set containing cyclones without sealing legs, and the second set containing conventional cyclones of the first stage.

Abstract: A system for sealing the legs of two stages of cyclones in series used in fluid catalytic cracking (FCC) processes, comprising a terminal leg configuration, which is devoid of moving parts and makes use of a long-radius curve, and which changes the flow direction of the descending mass flow of catalyst in dense phase into a plane orthogonal to the ascending gaseous flow. This prevents the entry of gaseous phase inside the leg, and promotes efficient sealing and preventing the “packing-down” of the dense bed of particulates.

Abstract: A method to exploit the glycerin obtained as a by-product of the industrial process to produce biodiesel inside or out of the industrial production unit, providing a reduction in the environmental liability that may be caused by an excess in the production of glycerin that cannot be exploited for industrial use. The referenced method uses recycling of the glycerin obtained through industrial process to produce biodiesel, using a process basically consisting of four stages: a) extracting glycerin produced as a by-product of the industrial process for producing biodiesel; b) hydrogenation of said n-propanol glycerin, c) recycling of the n-propanol thus obtained to be added to a mixture of alcohols; and d) transesterfication of the n-propanol mixture added to the alcohol mixture, together with raw material triglycerides from renewable sources in order to obtain biodiesel.

Abstract: This invention relates to a device for cooling and distributing mixed charges on fixed catalyst beds for use in the cooling zone of descending flow reactors which comprises a flat tray fitted with collector and distributor tubes for liquid superimposed upon and connected to another flat tray of similar design to the upper tray. The device, which is of smaller size in comparison with other commercially available devices, is extremely simple to install industrially and compact, and has as its main characteristic the efficiency with which it promotes reduction of the temperature of the reaction medium when it receives the cooling fluid within the catalytic reactor.

Abstract: A free standing riser system includes a riser, a subsea intervention unit, and an umbilical line. The riser includes interconnected joints linked to one another, a lower-end of the riser being coupled to a wellhead and an upper-end of the riser enclosed in a buoy assembly, including a terminal, the riser being maintained in an erect, substantially vertical position. The subsea intervention unit is provided above the riser, and includes three connections: one connection to the terminal of the riser, one connection to a flexible jumper that is connected to a FPU, and one connection that provides a vertical conveyance to an intervention rig.

Abstract: A process is described for the purification of estolides for subsequent use as lubricants. This purification process comprises the removal of free fatty acids present in the estolide by liquid-liquid extraction using an alcohol, preferably ethanol or methanol, as solvent, where the total acid number of the estolide after purification is less than 1 mg KOH/g of sample, which endows it with characteristics of oxidation stability suitable for its use as a lubricant.

Abstract: An aviation gasoline (Avgas) formulation free from tetraethyl lead (TEL) for piston driven aircraft is described, the formulation comprising, in volume percent, between 0 and 65.2 base alkylate, between 0 and 50 super-alkylate, between 0 and 25 toluene, between 2 and 10 of a toluidine isomer blend, between 0 and 5 ethyl alcohol, between 0 and 25 C5 cut and between 0 and 10 triptane. The formulations are prepared by admixing the components, with the order of mixing being from the denser to the less dense, except in the case of the toluidine isomer blend, which in spite of being the denser product is the latest to be added to the other streams in order to by-pass homogenization problems.

Abstract: This invention relates to equipment and a subsea pumping system using a subsea module installed on the sea bed, preferably away from a production well and intended to pump hydrocarbons having a high associated gas fraction produced by one or more subsea production wells to the surface. One object of this invention is achieved by means of the design of a pumping module (PM) which is linked to pumping equipment already present in a production well and which basically comprises: an inlet pipe (2), separator equipment (3), a first pump (4) and a second pump (8). In the subsea pumping system for the production of hydrocarbons with a high gas fraction, the other object of this invention, when oil is pumped from the production well (P) the well pump (13) increases the energy of the fluid in the form of pressure and transmits this increase in energy in the form of an increase in suction pressure in the second pump (8) of the subsea module (PM).

Abstract: This invention relates to a restrictive seal of the labyrinth type of reduced external size. The invention has an inner deflector which is capable of retaining the lubricating oil within the bearing housing with great efficiency, and a highly accurate system for adjusting and aligning the elements of the labyrinths, ensuring an infinite service life. Because it has very much smaller external dimensions it can be applied as a replacement to the lip seals commonly in use without causing problems to accessory equipment connected to a pump.

Abstract: A Torpedo Pile (100) is described for the anchoring of floating structures used for drilling and production wells for oil and gas, the pile (100) comprising a tapering body (1) provided with fins (20) and a point (30) for embedding in the seabed, its upper end being provided with at least two plates (2) provided with flaps (3), said flaps being capable of inducing a rotation of the articulation elements (4) when a dragging force is exerted on the system. With the continuation of the dragging force, the plates (2) continue to rotate as far as a final configuration, when the points of contact (6) of stops (5) are reached. The pile (100) comprises one embodiment for permanent anchorage and another for temporary anchorage. The method of installation/withdrawal of the two embodiments is also described.

Abstract: An improved cyclone system for disengaging solid and gaseous particles in fluid catalytic cracking (FCC) processes with reduced coke formation in disengager vessels, without favoring release of the disengaged catalyst into cyclones in subsequent stages, said system comprising legless cyclones 42 fitted with external collector pipes 43, is described. The collector pipes 43 optimize the purge of gases coming from the disengager vessel 49, reducing the time the hydrocarbons remain inside the disengager vessel 49, thus preventing overcracking and subsequent coke formation. Positioning of the external collector pipes 43 prevents release of the disengaged catalyst into cyclones in subsequent stages.

Abstract: A method is described for co-processing of ethanol and hydrocarbons from petroleum refining, which are introduced separately in two reaction zones of a reactor of a fluidized catalytic cracking unit. The process combines conversion of ethanol into ethene and conversion of hydrocarbons into other lighter hydrocarbon fractions, to produce ethene in quantities of 15 to 90 wt % in the fuel gas fraction obtained during the process.

Abstract: Fiber optic position transducer that includes a magnetic or electromagnetic element, one or more segments of magnetostrictive material, Fiber Bragg Grating Sensors, a rod of material that is impenetrable to magnetic fields, optical fiber. One or more of the sensors is fixed upon a segment of magnetostrictive material, which is fixed to a rod, and may only be displaced longitudinally. The Fiber Bragg Grating Sensors have different wave lengths and are made of the same optical fiber. The magnetic or electromagnetic element included may be made of NdFeB (Neodymium Iron Boron) or metal alloys of TbDyFe (Terbium, Dysprosium and Iron), such as TX, Terphenol-D and others. It is applied to a control flow valve in an oil well, and it also refers to the calibration process of the position of the transducer.

Abstract: This invention relates to a platform of the FPSO type in the form of a mono-column, of circular or polygonal horizontal section or of a combination of circular and polygonal sections, comprising one or more central load tanks (12), which can be single or compartmented, surrounded, in an alternately and uniformly distributed manner, by permanent-ballast tanks (13) and by ballast tanks open to the sea (“moonpools”) (14).

Abstract: A method is described for controlling instability of operation in a de-ethanizer tower (13) in the gas recovery unit in fluid catalytic cracking units and delayed coking units. The method comprises the step of intervening in the de-ethanizer tower (13) when instability occurs in it, and adjusting the material balance of water in such a way that the excess of water in the feed load stream (9) is removed only as an azeotrope. The intervention is performed by introducing into the feed load stream (9) of the de-ethanizer tower (13) a volume fraction (18) of a flow of hydrocarbon, which may be either dry hydrocarbons or hydrocarbons with a low level of water content.

Abstract: The invention relates to a continuous process for the preparation of sodium titanate nanotubes and their derivatives obtained by ion exchange and/or thermal treatment, by reacting titanium oxides with sodium hydroxide under suitable hydrothermal conditions to obtain or control the morphology of nanostructural titanates. The method is carried out continuously in one or more reactors connected in series, where the reaction mixture is introduced continuously into the reactor at a feed rate that is the same as the rate of discharge of the product. When more than one reactor is used, the material leaving the first reactor is used to feed the next reactor, and preferably a temperature differential is applied between the reactors in such a way as to obtain a mean temperature of between 60 and 180° C., and the overall reaction time is short, being about 90 minutes or less.

Abstract: The present invention refers to the process of determination of light elements, i.e., molar mass lower than 23, within inorganic materials, by means of spectra analysis between 5 keV and 22 keV, obtained from these materials when exposed to X radiation. Particularly, the invention refers to the direct determination of carbon content in steel and alloys. According to the invention process, the inorganic materials are exposed to X radiation and the spectra are organized as a matrix and mathematically processed using chemometric tools properly selected.

Abstract: The reaction of N-alkylimidazol with alkyl sulfonates, at room temperature, favors the production of 1,3-dialkylimidazolium alkane-sulfonates as crystalline solids at high yields. The alkane-sulfonate anions may be easily substituted by a series of other anions [BF4, PF6, PF3(CF2CF3)3, CF3SO3 and (CF3SO2)2N] through simple anion, salt, or acid reactions in water at room temperature. The extraction with dichloromethane, filtration, and evaporation of the solvent, allows the production of the desired ionic liquids at a yield of 80-95%. The purity of these ionic liquids (in some cases >99.4%) is performed using the intensity of 13C satellite signals from the magnetic resonance spectrums of the N-methyl imidazolium group as an internal standard.