Patents Assigned to Petroleum Energy Center
  • Patent number: 7776784
    Abstract: A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: August 17, 2010
    Assignees: Nippon Oil Corporation, Petroleum Energy Center
    Inventors: Hideshi Iki, Shigeto Hatanaka, Eitaro Morita, Shinya Takahashi
  • Publication number: 20100147238
    Abstract: The invention provides lubricant compositions for diesel engines having a regenerative DPF, which prolong life of the DPF by inhibiting accumulation of components depositable on DPF inner walls, diesel engine systems having a regenerative DPF with prolonged life, and a method for inhibiting accumulation of components depositing on the DPF in the system. The present composition is for diesel engines having a regenerative DPF and running on diesel fuel with <10 mass ppm sulfur, contains a base oil and additives including (A) metal detergent, (B) ashless dispersant, and (C) phosphorus-based anti-wear agent, and satisfies the conditions of a sulfated ash content of 0.4-2 mass %, an atomic ratio of metal from component (A) to the total phosphorus of 0.2-3, an atomic ratio of the total boron to metal from component (A) of 0.2-2, and an atomic ratio of the total sulfur to metal from component (A) of 0-4.
    Type: Application
    Filed: February 19, 2010
    Publication date: June 17, 2010
    Applicants: NIPPON OIL CORPORATION, JAPAN PETROLEUM ENERGY CENTER
    Inventors: Isao KURIHARA, Mineo Kagaya
  • Patent number: 7707816
    Abstract: A gas turbine system burning heavy-oil modified fuel and a method of operating the gas turbine system, which covers from a stage of modifying heavy oil and producing gas turbine fuel to a stage of operating a gas turbine, including startup, ordinary shutdown and emergency shutdown of the gas turbine. The gas turbine system burning heavy-oil modified fuel comprises a reactor for mixing heavy oil and water to cause reaction, thereby separating and removing a heavy component from the heavy oil, a gas-liquid separator for separating hydrocarbon gas and modified oil obtained in the reactor from each other, a gas turbine combustor for burning the hydrocarbon gas supplied from the gas-liquid separator, and a gas turbine driven by combustion gas produced in the gas turbine combustor. The system further comprises another line for extracting the hydrocarbon gas externally of a relevant system region.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: May 4, 2010
    Assignees: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Hirokazu Takahashi, Shinichi Inage, Kouji Nishida, Nobuyuki Hokari, Osami Yokota, Akinori Hayashi, Shinsuke Kokubo
  • Patent number: 7691774
    Abstract: A process for producing a catalyst for hydrodesulfurization and isomerization of a sulfur-containing hydrocarbon oil, which comprises supporting palladium on a composition comprising a platinum-supported sulfated zirconia and alumina.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: April 6, 2010
    Assignees: Petroleum Energy Center, Cosmo Oil Co., Ltd.
    Inventors: Katsuya Watanabe, Takao Kimura, Takahito Kawakami, Kouji Baba
  • Patent number: 7658078
    Abstract: A heavy oil reforming system includes a reforming preheater raising the temperature of a mixed fluid comprising a high pressure heavy oil and high pressure steam up to a temperature for reforming reaction. The mixed fluid having been heated up to the temperature for reforming reaction is introduced into a reformer kept at the temperature for reforming reaction and thereby the heavy oil is reformed. This reforming system allows the attainment of a residence time of 1 to 10 min necessary for reforming in a uniform or nearly uniform temperature field, thereby implementing the manufacturing of reformed fuels from a large volume of heavy oil.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: February 9, 2010
    Assignees: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Koji Nishida, Nobuyuki Hokari, Shin-ichi Inage, Osami Yokota, Hirokazu Takahashi, Masahiko Yamagishi, Akinori Hayashi
  • Publication number: 20090283443
    Abstract: A catalytic composition for hydrotreating of hydrocarbons in which a metallic component for hydrogenation is carried on a carrier comprising zeolite Y with aluminum and titanium inserted therein and a porous inorganic oxide, the zeolite Y having the following characteristics: (a) unit cell dimension (UD) in a range from 24.25 to 24.60 ?, (b) crystallinity of 95% or more, (c) specific surface area (SA) of 500 m2/g or more, (d) total pore volume (PVt) of a group of pores each having a diameter of 600 ? or below in a range from 0.45 to 0.70 ml/g, (e) pore volume (PVm) of a group of pores each having a diameter in a range from 100 to 600 ? in a range from 0.10 to 0.40 ml/g, (f) pore volume (PVs) of a group of pores each having a diameter in a range from 35 to 50 ? in a range 0.03 to 0.15 ml/g, and (g) percentage of 4-coordinate aluminum atoms against total aluminum atoms in the zeolite of 60 atom % or more.
    Type: Application
    Filed: September 6, 2006
    Publication date: November 19, 2009
    Applicants: CATALYSTS & CHEMICALS INDUSTRIES CO., LTD., PETROLEUM ENERGY CENTER
    Inventors: Ryuzo Kuroda, Masaru Ushio
  • Patent number: 7611676
    Abstract: In a method for producing gas turbine fuel through the step of modifying heavy fuel oil with the use of an asphaltene-insoluble solvent, the utilization factor of the heavy fuel oil usable as gas turbine fuel is increased by making asphaltene selectively removable. A solvent having a specific inductive capacity in the range of 1.4 to 2.0 is used as the asphaltene-insoluble solvent. In particular, water controlled in temperature and pressure so as to have a specific inductive capacity in the above range is used as the asphaltene-insoluble solvent. By using such a solvent, an asphaltene component contained in the heavy fuel oil can be selectively removed and power generation can be performed while utilizing 95% or more of the heavy fuel oil.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: November 3, 2009
    Assignees: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Shinichi Inage, Hirokazu Takahashi, Koji Nishida, Akinori Hayashi, Nobuyuki Hokari, Osami Yokota, Shinsuke Kokubo, Tetsuo Sasada, Tsunemasa Nishijima, Toshifumi Sasao
  • Patent number: 7594387
    Abstract: A gas turbine which can be easily employed in an area where it is hard to obtain a sufficient amount of water, such as an isolated island. Heated and pressurized heavy oil and water in a supercritical state are mixed with each other in a modifying unit to produce fuel-purpose modified oil. The fuel-purpose modified oil is depressurized by a depressurizing valve. Due to a temperature fall caused by adiabatic expansion with the depressurization, the fuel-purpose modified oil is brought into a two-phase state where moisture is in a gas phase (steam) and modified oil is in a liquid phase. The fuel-purpose modified oil is separated into the steam and the modified oil by a gas-liquid separator. The separated steam is condensed to water in a condenser and returned to a water supply line. The modified oil in the liquid phase is supplied to a combustor, thereby driving a gas turbine.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: September 29, 2009
    Assignees: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Shinichi Inage, Nobuyuki Hokari, Osami Yokota, Hirokazu Takahashi, Masahiko Yamagishi
  • Patent number: 7591983
    Abstract: The invention is intended to produce high-pressure light fuel gas with good combustibility by contacting and reacting high-temperature, high-pressure water and heavy oil with each other in a contact-reaction unit to extract light oil components from the heavy oil and to remove metals. The high-temperature, high-pressure water and the heavy oil are introduced to the contact-reaction unit for contact and reaction with each other therein. Heavy oil components not dissolved in the high-temperature, high-pressure water are separated by precipitation from hydrocarbon gases and light oil components which are dissolved in the high-temperature, high-pressure water. The separated heavy oil components are burnt or incinerated without any further modification.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: September 22, 2009
    Assignees: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Hirokazu Takahashi, Shinichi Inage, Nobuyuki Hokari, Masahiko Yamagishi, Akinori Hayashi, Osami Yokota, Youji Ishibashi
  • Publication number: 20090230023
    Abstract: The present invention 1, 2 or 3 provides a desulfurization function-added FCC catalyst which can efficiently reduce the sulfur content of FCC gasoline while maintaining the yield of FCC gasoline in a process of producing FCC gasoline by cracking of heavy oil.
    Type: Application
    Filed: June 25, 2007
    Publication date: September 17, 2009
    Applicants: IDEMITSU KOSAN CO., LTD., PETROLEUM ENERGY CENTER, A JURIDICAL INC. FOUND.
    Inventors: Akira Iino, Toshio Itoh, Shinji Akashi
  • Patent number: 7585677
    Abstract: It is an object to establish a test method that enables a high-concentration ammonium bisulfide environment to be reproduced at a laboratory level, and enables the corrosivity of a material to be evaluated easily and highly accurately. According to the test method, when evaluating the corrosion resistance of a material under an ammonium bisulfide environment, the corrosion resistance of the material is evaluated by simulating the relationship between the ammonium bisulfide concentration of a test solution and the pressure in advance, and then determining the ammonium bisulfide concentration from the pressure.
    Type: Grant
    Filed: October 11, 2005
    Date of Patent: September 8, 2009
    Assignees: Petroleum Energy Center, Toyo Engineering Corp.
    Inventor: Hirohito Iwawaki
  • Publication number: 20070283701
    Abstract: The present invention provides a reformed-fuel-burning gas turbine system that constantly generates good-quality reformed fuel even when heavy fuel has a different composition. The reformed-fuel-burning gas turbine system according to the present invention comprises a heavy oil heater; a water heater; a reformer vessel for mixing high-temperature, high-pressure water with high-temperature, high-pressure heavy oil to cause a hydrothermal reaction and producing reformed fuel from heavy oil; and a gas turbine which operates on the reformed fuel.
    Type: Application
    Filed: June 8, 2007
    Publication date: December 13, 2007
    Applicants: Hitachi, Ltd., Petroleum Energy Center
    Inventors: Osami Yokota, Shinichi Inage, Koji Nishida, Akinori Hayashi, Hirokazu Takahashi, Shinsuke Kokubo
  • Patent number: 7235312
    Abstract: A novel aromatic compound represented by following general formula (I): among X1 to X20 in general formula (I), (1) at least four each independently represent a linear or branched alkoxyl group having 1 to 6 carbon atoms, and others each represent hydrogen atom; (2) at least one represents a linear or branched alkyl group having 1 to 6 carbon atoms, at least one represents a linear or branched alkoxyl group having 1 to 6 carbon atoms, a total of a number of the alkyl group and a number of the alkoxyl group being 4 or greater, and others each represent hydrogen atom; (3) at least six each independently represent a linear or branched alkyl group having 1 to 6 carbon atoms, and others each represent hydrogen atom; or (4) at least four each independently represent a linear or branched alkyl group having 1 to 6 carbon atoms, two among said alkyl groups having 3 to 6 carbon atoms, and others each represent hydrogen atom; and an organic electroluminescence device using the aromatic compound, are provided.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: June 26, 2007
    Assignees: Petroleum Energy Center, A Juridical Incorporated Foundation, Idemitsu Kosan Co., Ltd.
    Inventors: Toshihiro Iwakuma, Takashi Arakane, Tadashi Kusumoto
  • Patent number: 7026439
    Abstract: There is disclosed a process for continuously producing a polyarylene sulfide which comprises reacting a sulfur source with a dihalogenated aromatic compound in an aprotic organic solvent, characterized by maintaining the content of the dihalogenated aromatic compound in the polymerization liquid after the substantial completion of the polymerization reaction at 5 mg/g or higher. It is made possible by the process according to the present invention to efficiently produce the polyarylene sulfide which has a high molecular weight and is excellent in thermal stability.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: April 11, 2006
    Assignees: Petroleum Energy Center, Idemitsu Kosan Co., Ltd.
    Inventors: Minoru Senga, Masaya Okamoto, Mikiya Hayashi
  • Patent number: 7018574
    Abstract: There is disclosed a process for removing volatile components in a polyarylene sulfide resin which is produced by subjecting a sulfur source and a dihalogenated aromatic compound to polymerization reaction in an aprotic organic solvent, comprising using an extruder which is equipped with front vent having an opening length in the range of 4D to 11D (D: screw diameter) and which has a distance between a terminal position of a screw in a kneading portion and the opening portion of the front vent being in the range of 4D to 15D. The process is capable of steadily and economically removing volatile components in the polyarylene sulfide resin without necessitating expensive machinery or equipment such as a dryer without plugging up the opening portion of a vent even in the case of degassing a PAS resin having a low molecular weight and further, thus enabling a long-term continuous stable running.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: March 28, 2006
    Assignees: Idemitsu Kosan Co., Ltd., Petroleum Energy Center, a Juridical Incorporated Foundation
    Inventor: Yoshinari Koyama
  • Patent number: 6982312
    Abstract: There is disclosed a process for producing a polyarylene sulfide (PAS) which comprises reacting a sulfur source with a dihalogenated aromatic compound in the presence of an aprotic organic solvent, characterized in that the process comprises at least one polymerization reaction step wherein a polymer phase as a dispersed phase is in the form of spherical droplets. It is made possible by the continuous polymerization process to discharge the polymer phase and solvent phase from a polymerization vessel at a constant ratio and as a result, to maintain PAS composition (concentration) at a constant level at all times, and thus to provide a continuous PAS production process which is effective for enhancing its molecular weight and stabilizing the same.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: January 3, 2006
    Assignees: Idemitsu Kosan Co., Ltd., Petroleum Energy Center, A Jurdical Incorporated Foundation
    Inventors: Minoru Senga, Masaya Okamoto, Mikiya Hayashi
  • Patent number: 6939942
    Abstract: There is disclosed a process for treating a by-product salt of a polyarylene sulfide which comprises subjecting solid matter containing an aprotic organic solvent and the by-product salt that is formed in the case of producing a polyarylene sulfide by polymerization condensation reaction of an alkali metal sulfide and a dihalogenated aromatic compound in the aprotic organic solvent to a drying treatment followed by a firing treatment of the resultant dryingly treated matter at a temperature in the range of 500 to 1000° C. The above process is capable of enhancing the solubility in water, of the by-product salt comprising sodium chloride as the principal component in the production of polyarylene sulfide, and affording waste water which is lowered in SS and COD in the case where the by-product salt is dissolved in water and is discharged as waste water.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: September 6, 2005
    Assignees: Petroleum Energy Center, A Jurdical Incorporated Foundation, Idemitsu Kosan Co., Ltd.
    Inventor: Daigo Shirota
  • Patent number: 6916762
    Abstract: An FCC catalyst which not only deactivates catalyst poison metals, such as nickel, vanadium and the like, in feedstock oils, inhibits the generation of hydrogen or coke, has excellent cracking activity and bottom oil-treating ability, and can yield a gasoline and LCO fraction in high yields, but also retains the performances on a high level over long and has an improved catalyst life; and an FCC method using the catalyst. The FCC catalyst has a compound of a bivalent metal or of bivalent and trivalent metals showing an XRD pattern of a carbonate of the bivalent metal; an inorganic oxide matrix and the compound dispersed therein; or an inorganic oxide matrix and the compound dispersed therein together with a crystalline aluminosilicate zeolite, and relates to an FCC method in which at least one of the catalysts are used in combination with an FCC catalyst obtained by evenly dispersing a crystalline aluminosilicate zeolite in an inorganic oxide matrix.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: July 12, 2005
    Assignees: Petroleum Energy Center, Cosmo Oil Co., Ltd.
    Inventors: Tadashi Shibuya, Junko Naito, Hidenori Yamada, Nobuki Sekine
  • Patent number: 6797153
    Abstract: A catalyst for the hydrocracking of heavy oils contains iron and active carbon having an MCH conversion rate of 40-80%, a specific surface area of 600-1000 m2/g of, a pore volume of 0.5 to 1.4 cm3/g, 2-50 nanometers' mesopore volume of not less than 60% and an average pore diameter of 3-6 nanometers, the iron being carried on the active carbon in an amount of 1 to 20 wt. % to the active carbon. The hydrocracking process using the catalyst includes a first step of conducting hydrocracking at a temperature within the range of 360-450° C. at a hydrogen partial pressure of 2-14 MPaG and a second step of conducting hydrocracking at a temperature within the range of 400-480° C. at a hydrogen partial pressure of 2-18 MPaG, which can suppress the generation of coke and remove, in a high efficiency, heavy metals such as Ni and V, asphaltene, residual carbon, sulfur and nitrogen from the heavy oils.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: September 28, 2004
    Assignees: Petroleum Energy Center, Toyo Engineering Corporation
    Inventors: Hidetsugu Fukuyama, Koji Ohtsuka, Satoshi Terai, Shuhei Sawamoto
  • Publication number: 20040164443
    Abstract: There is disclosed a process for granulating a polyarylene sulfide-based resin which comprises extruding a molten polyarylene sulfide-based resin with an extruder through a die nozzle, thereafter taking off the resin in cooling water at a temperature in the range of 5 to 60° C. which flows down on a prescribed inclined surface, and cutting off the resin and pelletizing the same at a prescribed position on the downstream region. It is made possible by the above process to efficiently steadily produce micro-pellets and amorphous pellets of the polyarylene sulfide-based resin. Furthermore, in the case of preparing the compound of the pellets by compositing with a filler such as calcium carbonate, the stability of an extruder can be assured by the specific resin pellets.
    Type: Application
    Filed: February 20, 2003
    Publication date: August 26, 2004
    Applicants: IDEMITSU PETROCHEMICAL CO., LTD., PETROLEUM ENERGY CENTER
    Inventor: Yoshinari Koyama