Patents Assigned to Phelps Dodge Corporation
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Publication number: 20060144717Abstract: The present invention relates generally to a process for recovering copper and/or other metal values from a metal-bearing ore, concentrate, or other metal-bearing material using pressure leaching and direct electrowinning. More particularly, the present invention relates to a substantially acid-autogenous process for recovering copper from chalcopyrite-containing ore using pressure leaching and direct electrowinning in combination with a leaching, solvent/solution extraction and electrowinning operation.Type: ApplicationFiled: October 28, 2005Publication date: July 6, 2006Applicant: PHELPS DODGE CORPORATIONInventors: John Marsden, Robert Brewer, Joanna Robertson, David Baughman, Philip Thompson, Wayne Hazen, Christel Bemelmans, Susan Brewer
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Patent number: 7041152Abstract: The present invention relates generally to a process for the production of sulfuric acid and liberation of precious metal values from materials containing sulfur through pressure leaching operations. In accordance with various aspects of the present invention, the sulfur-bearing materials may comprise residues from pressure leaching operations, such as those carried out at medium temperatures. The process of the present invention can be advantageously used to convert such sulfur-bearing materials to sulfuric acid by means of pressure leaching. The sulfuric acid so produced can be used beneficially in other mineral processing operations, for example those at the site where it is produced. Metals, such as precious metals, that are contained within the sulfur-bearing materials advantageously may be recovered from processing products by established precious metals recovery technology.Type: GrantFiled: March 29, 2005Date of Patent: May 9, 2006Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, Wayne W. Hazen, Philip Thompson, David R. Baughman
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Publication number: 20060016696Abstract: This invention relates to a system and method for producing a metal powder product using conventional electrowinning chemistry (i.e., oxygen evolution at an anode) in a flow-through electrowinning cell. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes and/or direct electrowinning.Type: ApplicationFiled: July 14, 2005Publication date: January 26, 2006Applicant: PHELPS DODGE CORPORATIONInventors: Antonioni Stevens, Stanley Gilbert, Scot Sandoval, Timothy Robinson, John Marsden
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Publication number: 20060016684Abstract: This invention relates to an apparatus for producing a metal powder product using either conventional electrowinning or alternative anode reaction chemistries in a flow-through electrowinning cell. A new design for a flow-through electrowinning cell that employs both flow-through anodes and flow-through cathodes is described. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes, direct electrowinning, or alternative anode reaction chemistry.Type: ApplicationFiled: July 14, 2005Publication date: January 26, 2006Applicant: PHELPS DODGE CORPORATIONInventors: John Marsden, Scot Sandoval, Antonioni Stevens, Timothy Robinson, Stanley Gilbert
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Publication number: 20060016697Abstract: This invention relates to a system and method for producing a metal powder product using either conventional electrowinning or alternative anode reaction chemistries in a flow-through electrowinning cell. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes, direct electrowinning, or alternative anode reaction chemistries.Type: ApplicationFiled: July 14, 2005Publication date: January 26, 2006Applicant: PHELPS DODGE CORPORATIONInventors: Stanley Gilbert, Scot Sandoval, Antonioni Stevens, Timothy Robinson, John Marsden
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Publication number: 20050269209Abstract: The present invention relates, generally, to a method for electrowinning copper powder, and more particularly to a method for electrowinning copper powder from a copper-containing solution using the ferrous/ferric anode reaction. In accordance with various embodiments of the present invention, a process for producing copper powder by electrowinning employs alternative anode reaction technology, namely, the ferrous/ferric anode reaction, and enables the efficient and cost-effective production of copper powder at a total cell voltage of less than about 1.5 V and at current densities of greater than 50 A/ft2. A copper powder electrowinning process in accordance with the present invention also reduces or eliminates acid mist generation that is characteristic of electrowinning operations utilizing conventional electrowinning chemistry (e.g., oxygen evolution at the anode), which is advantageous.Type: ApplicationFiled: July 14, 2005Publication date: December 8, 2005Applicant: PHELPS DODGE CORPORATIONInventors: Scot Sandoval, Antonioni Stevens, Timothy Robinson, John Marsden, Stanley Gilbert
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Patent number: 6972107Abstract: A system and process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent extraction techniques or apparatus. A process for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution, without subjecting the copper-containing solution to solvent extraction.Type: GrantFiled: December 15, 2003Date of Patent: December 6, 2005Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Christel M. A. Bemelmans
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Publication number: 20050155459Abstract: The present invention relates generally to a process for the production of sulfuric acid and liberation of precious metal values from materials containing sulfur through pressure leaching operations. In accordance with various aspects of the present invention, the sulfur-bearing materials may comprise residues from pressure leaching operations, such as those carried out at medium temperatures. The process of the present invention can be advantageously used to convert such sulfur-bearing materials to sulfuric acid by means of pressure leaching. The sulfuric acid so produced can be used beneficially in other mineral processing operations, for example those at the site where it is produced. Metals, such as precious metals, that are contained within the sulfur-bearing materials advantageously may be recovered from processing products by established precious metals recovery technology.Type: ApplicationFiled: March 29, 2005Publication date: July 21, 2005Applicant: PHELPS DODGE CORPORATIONInventors: John MARSDEN, Robert BREWER, Joanna ROBERTSON, Wayne HAZEN, Philip THOMPSON, David BAUGHMAN
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Publication number: 20050155458Abstract: The present invention is directed to a system for recovering metal values from metal-bearing materials. During a reactive process, a seeding agent is introduced to provide a nucleation site for the crystallization and/or growth of solid species which otherwise tend to passivate the reactive process or otherwise encapsulate the metal value, thereby reducing the amount of desired metal values partially or completely encapsulated by such material. The seeding agent may be generated in a number of ways, including the recycling of residue or the introduction of foreign substances. Systems embodying aspects of the present invention may be beneficial for recovering a variety of metals such as copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals from any metal-bearing material, such as ores and concentrates.Type: ApplicationFiled: March 29, 2005Publication date: July 21, 2005Applicant: PHELPS DODGE CORPORATIONInventors: John MARSDEN, Robert BREWER, Joanna ROBERTSON, David BAUGHMAN, Philip THOMPSON, Wayne HAZEN, Roland Schmidt
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Patent number: 6893482Abstract: The present invention is directed to a system for recovering metal values from metal-bearing materials. During a reactive process, a seeding agent is introduced to provide a nucleation site for the crystallization and/or growth of solid species which otherwise tend to passivate the reactive process or otherwise encapsulate the metal value, thereby reducing the amount of desired metal values partially or completely encapsulated by such material. The seeding agent may be generated in a number of ways, including the recycling of residue or the introduction of foreign substances. Systems embodying aspects of the present invention may be beneficial for recovering a variety of metals such as copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals from any metal-bearing material, such as ores and concentrates.Type: GrantFiled: August 27, 2003Date of Patent: May 17, 2005Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Roland Schmidt
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Patent number: 6890371Abstract: The present invention relates generally to a process for the production of sulfuric acid and liberation of precious metal values from materials containing sulfur through pressure leaching operations. In accordance with various aspects of the present invention, the sulfur-bearing materials may comprise residues from pressure leaching operations, such as those carried out at medium temperatures. The process of the present invention can be advantageously used to convert such sulfur-bearing materials to sulfuric acid by means of pressure leaching. The sulfuric acid so produced can be used beneficially in other mineral processing operations, for example those at the site where it is produced. Metals, such as precious metals, that are contained within the sulfur-bearing materials advantageously may be recovered from processing products by established precious metals recovery technology.Type: GrantFiled: December 23, 2002Date of Patent: May 10, 2005Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, Wayne W. Hazen, Philip Thompson, David R. Baughman
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Patent number: 6872288Abstract: An electrowinning cell, having a tank with an opened upper end defined by a tank edge, electrolyte within the tank and a plurality of flat, metallic electrode plates disposed within the tank in side-by-side, spaced-apart, parallel relationship. Adjacent electrode plates define an electrode gap therebetween. An injector manifold is disposed at the bottom of the tank for feeding electrolyte into the tank at locations below the electrode plates. A collector grid, comprised of a plurality of collectors having ports, define an upper level of electrolyte by collecting the electrolyte from the tank. The ports are disposed in spaced-apart relationship within the open upper end defined by the tank edge. The collector grid and the injector creating a flow of electrolyte upward between the plates as the electrolyte flows from the manifold locations below the plates to the ports.Type: GrantFiled: June 3, 2002Date of Patent: March 29, 2005Assignee: Phelps Dodge CorporationInventors: Jean-Louis Huens, Peter Peckham
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Publication number: 20040130076Abstract: A system and process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent extraction techniques or apparatus. A process for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution, without subjecting the copper-containing solution to solvent extraction.Type: ApplicationFiled: December 15, 2003Publication date: July 8, 2004Applicant: PHELPS DODGE CORPORATIONInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Christel M. A. Bemelmans
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Patent number: 6680034Abstract: The present invention relates generally to a process for recovering copper and other metal values from metal-containing materials through pressure leaching operations. In accordance with the various aspects of the present invention, metal-containing pregnant leach solutions from pressure leaching operations need not be significantly diluted to facilitate effective metal recovery using solvent extraction and electrowinning.Type: GrantFiled: July 25, 2001Date of Patent: January 20, 2004Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, Wayne W. Hazen, Philip Thompson, David R. Baughman
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Patent number: 6663689Abstract: A system and process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent extraction techniques or apparatus. A process for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution, without subjecting the copper-containing solution to solvent extraction.Type: GrantFiled: September 9, 2002Date of Patent: December 16, 2003Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Christel M. A. Bemelmans
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Patent number: 6626979Abstract: The present invention is directed to a process for recovering metal values from metal-bearing materials. During a reactive process, a seeding agent is introduced to provide a nucleation site for the crystallization and/or growth of solid species which otherwise tend to passivate the reactive process or otherwise encapsulate the metal value, thereby reducing the amount of desired metal values partially or completely encapsulated by such material. The seeding agent may be generated in a number of ways, including the recycling of residue or the introduction of foreign substances. Processes embodying aspects of the present invention may be beneficial for recovering a variety of metals such as copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals from any metal-bearing material, such as ores and concentrates.Type: GrantFiled: September 9, 2002Date of Patent: September 30, 2003Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Roland Schmidt
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Publication number: 20030051996Abstract: An electrowinning cell, having a tank with an opened upper end defined by a tank edge, electrolyte within the tank and a plurality of flat, metallic electrode plates disposed within the tank in side-by-side, spaced-apart, parallel relationship. Adjacent electrode plates define an electrode gap therebetween. An injector manifold is disposed at the bottom of the tank for feeding electrolyte into the tank at locations below the electrode plates. A collector grid, comprised of a plurality of collectors having ports, define an upper level of electrolyte by collecting the electrolyte from the tank. The ports are disposed in spaced-apart relationship within the open upper end defined by the tank edge. The collector grid and the injector creating a flow of electrolyte upward between the plates as the electrolyte flows from the manifold locations below the plates to the ports.Type: ApplicationFiled: June 3, 2002Publication date: March 20, 2003Applicant: Phelps Dodge CorporationInventors: Jean-Louis Huens, Peter Peckham
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Publication number: 20030019331Abstract: A system and process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent extraction techniques or apparatus. A process for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution, without subjecting the copper-containing solution to solvent extraction.Type: ApplicationFiled: September 9, 2002Publication date: January 30, 2003Applicant: PHELPS DODGE CORPORATIONInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Christel M. A. Bemelmans
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Patent number: 6497745Abstract: The present invention relates generally to a process for the production of sulfuric acid and liberation of precious metal values from materials containing sulfur through pressure leaching operations. In accordance with various aspects of the present invention, the sulfur-bearing materials may comprise residues from pressure leaching operations, such as those carried out at medium temperatures. The process of the present invention can be advantageously used to convert such sulfur-bearing materials to sulfuric acid by means of pressure leaching. The sulfuric acid so produced can be used beneficially in other mineral processing operations, for example those at the site where it is produced. Metals, such as precious metals, that are contained within the sulfur-bearing materials advantageously may be recovered from processing products by established precious metals recovery technology.Type: GrantFiled: July 25, 2001Date of Patent: December 24, 2002Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, Wayne W. Hazen, Philip Thompson, David R. Baughman
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Patent number: 6451088Abstract: The present invention is directed to a process for recovering metal values from metal-bearing materials. During a reactive process, a seeding agent is introduced to provide a nucleation site for the crystallization and/or growth of solid species which otherwise tend to passivate the reactive process or otherwise encapsulate the metal value, thereby reducing the amount of desired metal values partially or completely encapsulated by such material. The seeding agent may be generated in a number of ways, including the recycling of residue or the introduction of foreign substances. Processes embodying aspects of the present invention may be beneficial for recovering a variety of metals such as copper, gold, silver, nickel, cobalt, molybdenum, zinc, rhenium, uranium, rare earth metals, and platinum group metals from any metal-bearing material, such as ores and concentrates.Type: GrantFiled: July 25, 2001Date of Patent: September 17, 2002Assignee: Phelps Dodge CorporationInventors: John O. Marsden, Robert E. Brewer, Joanna M. Robertson, David R. Baughman, Philip Thompson, Wayne W. Hazen, Roland Schmidt