Abstract: A process for producing a metallocycle metallocene comprising reacting a reactant metallocene which has a cyclopentadienyl group having an alkenyl group attached which has at least 3 carbon atoms with about 2 molar equivalents of an alkali metal alkyl having at least 4 carbon atoms, catalyst systems resulting from the combination of the metallocycle metallocene and an organic cocatalyst, and polymerization processes using such catalyst systems are disclosed.
Type:
Grant
Filed:
April 26, 1999
Date of Patent:
January 22, 2002
Assignee:
Phillips Petroleum Company
Inventors:
Erik Licht, Helmut G. Alt, M. Bruce Welch
Abstract: Particulate sorbent compositions comprising zinc titanate support having thereon a substantially reduced valence promotor metal selected from the group consisting of cobalt, nickel, iron, manganese, copper, molybdenum, tungsten, silver, tin and vanadium or mixtures thereof provide a system for the desulfurization of a feed stream of cracked-gasolines or diesel fuels in a desulfurization zone by a process which comprises contacting such feed streams in a desulfurization zone with a particulate sorbent composition followed by separation of the resulting low sulfur-containing steam and sulfurized sorbent and thereafter regenerating and activating the separated sorbent before recycle of same to the desulfurization zone.
Abstract: A catalyst system comprising the product resulting from the combination of a metallocene having a monoorganoamide radical attached to the metal of the metallocene and a cocatalyst having alkylaluminum groups and the use of such catalyst systems in the polymerization of olefin.
Abstract: Catalyst activation of a platinum reforming catalyst system contained in a multiple reactor system by simultaneously reducing the catalyst with hydrogen while introducing a nonmetallic chlorine-containing compound into a reactor of the multiple reactor system in an amount to provide from about 0.05 to about 0.3 weight percent chlorine on the catalyst and thereafter purging the system with about 100 to about 50,000 cubic feet of hydrogen per cubic foot of catalyst resulting in a reforming system having increased activity and providing enhanced RON values with reduced cracking of feedstock.
Abstract: Catalyst activation of a platinum reforming catalyst system contained in a multiple reactor system by simultaneously reducing the catalyst with hydrogen while introducing a nonmetallic chlorine-containing compound into a reactor of the multiple reactor system in an amount to provide from about 0.05 to about 0.3 weight percent chlorine on the catalyst and thereafter purging the system with about 100 to about 50,000 cubic feet of hydrogen per cubic foot of catalyst resulting in a reforming system having increased activity and providing enhanced RON values with reduced cracking of feedstock.
Abstract: Metallocenes having a 9-fluorenyl group and another cyclic dienyl group connected by a single carbon having a terminally unsaturated hydrocarbyl substituent wherein the 9-fluorenyl group has a hydrocarbyl substituent in the 4 position, olefin polymerization catalyst systems prepared therefrom, and the use of such catalyst systems are disclosed.
Type:
Application
Filed:
August 7, 2001
Publication date:
December 27, 2001
Applicant:
Phillips Petroleum Company
Inventors:
Alexander Koppl, Helmut G. Alt, M. Bruce Welch
Abstract: Catalyst activation of a platinum reforming catalyst system contained in a multiple reactor system by simultaneously reducing the catalyst with a sustained hydrogen flow through the multiple reactor system while introducing a nonmetallic chlorine-containing compound serially into each reactor of the multiple reactor system in an amount to provide from about 0.05 to about 0.3 weight percent chlorine on the catalyst and thereafter purging the system with about 100 to about 50,000 cubic feet of hydrogen per cubic foot of catalyst prior to commencing use of the treated catalyst system for reforming hydrocarbon feed.
Abstract: A process is provided to recover at least one modifier compound and at least one polar organic compound from a reaction mixture comprising high molecular weight Poly(arylene sulfide) product, low molecular weight P(AS), cyclic and linear P(AS) oligomers, at least one POC, at least one modifier, an alkali metal halide by-product, and water.
Type:
Grant
Filed:
September 13, 1999
Date of Patent:
December 18, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Fernando C. Vidaurri, Jon F. Geibel, James W. Waterman, Jay M. Chaffin, Aubrey South, Jr., Jeffrey S. Fodor, Glenn F. Kile
Abstract: A filtering means containing gelatinous and solid materials is cleaned without dismantling the filtering means by contacting the gelatinous material inside the filtering means with a solvent, thereby physically degrading the gelatinous material such that the degraded gelatinous material can pass through the filtering means.
Abstract: This invention relates to the general subject of seismic exploration and, in particular, to seismic processing and methods for attenuating ground roll in land and ocean bottom seismic surveys. According to a first aspect of the instant invention, there is provided a method of attenuating non-primary reflection events such as ground roll in an unstacked gather. In the preferred embodiment, the collected seismic data will be analyzed to determine the approximate velocity at which the ground roll appears to travel through the section. As a next step, a single-velocity migration is performed on the seismic data at the selected velocity. Those seismic events that are moved by the migration past an “attenuation line” on the section are intentionally discarded or attenuated. Finally, a reverse single velocity migration is performed which places the reflectors—minus those events such as ground roll that have been attenuated—back at their original unmigrated times.
Abstract: An (organo) ((omega-alkenyl) cyclopentacarbyl) (silane-bridged) metallocene compound is provided. Polymerization processes therewith are also provided.
Type:
Grant
Filed:
November 14, 1997
Date of Patent:
December 11, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Michael Jung, Helmut G. Alt, M. Bruce Welch
Abstract: A novel loop/slurry olefin polymerization process is provided which produces ultra high molecular weight ethylene homopolymers and ultra high molecular weight ethylene copolymers. Catalyst systems used are selected from the group consisting of inorganic oxide supported titanium-containing catalyst systems, inorganic oxide supported organo-zirconium catalyst systems and inorganic oxide supported organo-hafnium catalyst systems.
Type:
Grant
Filed:
October 14, 1997
Date of Patent:
December 11, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Joel L. Martin, Joseph J. Bergmeister, Eric T. Hsieh, Max P. McDaniel, Elizabeth A. Benham, Steven J. Secora
Abstract: Metallocycle metallocenes are produced by reacting a first metallocene having an aralkyl group or an aryl dialkyl silyl group attached to a cyclodienyl group with about two molar equivalents of an alkali metal alkyl having at least 4 carbon atoms. The use of the metallocycle metallocenes as components of catalyst for the polymerization of olefins is also disclosed.
Type:
Grant
Filed:
June 17, 1999
Date of Patent:
December 11, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Erik Licht, Helmut G. Alt, M. Bruce Welch
Abstract: A catalyst composition and process for preparing such catalyst composition which can be useful in contacting a hydrocarbon-containing fluid which contains a highly unsaturated hydrocarbon such as 1,3-butadiene, in the presence of hydrogen, with such catalyst composition in a hydrogenation zone under a hydrogenation condition effective to hydrogenate such highly unsaturated hydrocarbon to a less unsaturated hydrocarbon such as n-butene is disclosed. Such process for preparing a catalyst composition includes (1) combining a zeolite, a Group VIB metal, and an inorganic support to form a modified zeolite; (2) calcining such modified zeolite under a calcining condition to produce a calcined, modified zeolite; and (3) contacting such calcined, modified zeolite with a carburizing agent under a carburizing condition to provide such catalyst composition.
Abstract: A process of using a catalyst composition to polymerize at least one monomer to produce a polymer. The process comprising contacting the catalyst composition, at least one monomer in a polymerization zone under polymerization conditions to produce the polymer. The catalyst composition is produced by a process comprising contacting at least one organometal compound, at least one treated solid oxide compound, and at least one organoaluminum compound.
Type:
Grant
Filed:
April 28, 2000
Date of Patent:
November 13, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Max P. McDaniel, Kathy S. Collins, Marvin M. Johnson, James L. Smith, Elizabeth A. Benham, Gil R. Hawley, Christopher E. Wittner, Michael D. Jensen
Abstract: A hydraulic underreamer for enlarging a wellbore includes improved packer, cutting, jet pump, and mill sections. Each of the sections and their associated advantages are described herein in detail. The packer section is designed to minimize wear on its sealing elements, the cutting and jet pump sections are designed to minimize pressure requirements and optimize hydraulic efficiency, and the mill section has a removable center assembly which allows effective well control when pulling the underreamer out of a “live” well filled with a gas, such as methane.
Abstract: The present invention relates to compositions of base oils and automotive engine oils using synthetic poly alpha olefins derived from 1-dodecene or 1-tetradecene to improve engine oil performance as demonstrated by the severe Volkswagen T-4, Volkswagen TDI, and Sequence IIIE tests.
Type:
Grant
Filed:
July 24, 2000
Date of Patent:
November 6, 2001
Assignee:
Phillips Petroleum Company
Inventors:
Frank Stunnenberg, Perla Duchesne, Jurgen H. Raddatz
Abstract: A process for removing sulfone from a liquid hydrocarbon containing a concentration of sulfone by mixing a liquid acid therewith and thereafter separating the resulting admixture into an acid phase and a hydrocarbon phase. The hydrocarbon phase has a concentration of sulfone less than such concentration in the liquid hydrocarbon.