Abstract: Drilling mud compositions including a first concentration of powdered latex and a second concentration of SAS are described. The second concentration of SAS can be greater than or equal to the first concentration of latex. In some examples, the second concentration of SAS can be greater than the first concentration of latex. The drilling mud compositions may include an oil-based carrier, or a water-based carrier. An example technique includes dispersing a first predetermined amount of powdered latex and a second predetermined amount of SAS in a water-based carrier to form a water-based mud. Another example technique includes dispersing a first predetermined amount of powdered latex and a second predetermined amount of SAS in an oil-based carrier to form an oil-based mud.
Abstract: A process comprising creating an immiscible mixture by combining (a) a hydrocarbon feedstock containing contaminants and (b) a wash water, to create the immiscible mixture with at least three distinct layers: a hydrocarbon layer, a rag layer, and a brine layer. In this process a portion of the contaminants are removed from the hydrocarbon mixture where are then transferred to the brine layer. The brine layer is then separated from the immiscible mixture. In this process an alkalinity modifier is added in the process to reduce the emulsions in the immiscible mixture to create the at least three distinct layers.
Type:
Grant
Filed:
March 9, 2023
Date of Patent:
July 23, 2024
Assignee:
Phillips 66 Company
Inventors:
Amit B. Patel, Lyda Zambrano, Varadharajan Kailasam
Abstract: Oligomer products are produced by reacting an alpha olefin and a vinylidene compound in the presence of a solid catalyst, such as a solid oxide or a chemically-treated solid oxide. Metallocene compounds, organoaluminum compounds, and BF3 are not needed to perform the reaction. Oligomer products formed by processes disclosed herein have a trimer:tetramer weight ratio of at least 2:1.
Type:
Grant
Filed:
December 12, 2023
Date of Patent:
July 23, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Thomas J. Malinski, Max P. McDaniel, Steven M. Bischof, Graham R. Lief, Holly A. Ramirez
Abstract: A method comprising contacting a silica support with a titanium-containing solution to form a titanated silica support, wherein the titanium-containing solution comprises a solvent; a ligand comprising a glycol, a carboxylate, a peroxide, or a combination thereof, and a titanium compound having the formula Ti(acac)2(OR)2, wherein “acac” is acetylacetonate and wherein each R independently is ethyl, isopropyl, n-propyl, isobutyl, or n-butyl.
Type:
Grant
Filed:
January 19, 2022
Date of Patent:
July 23, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Max P. McDaniel, Kathy S. Clear, William C. Ellis, Deloris R. Gagan
Abstract: A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.
Type:
Grant
Filed:
March 17, 2023
Date of Patent:
July 16, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Youlu Yu, Eric D. Schwerdtfeger, Jeffrey S. Fodor, David A. Soules
Abstract: Methods for preparing metallocene-based catalyst compositions include the steps of contacting an alcohol compound and an organoaluminum compound for a first period of time to form a precontacted mixture, and contacting the precontacted mixture with an activator-support and a metallocene compound for a second period of time to form the catalyst composition. Such catalyst compositions can contain an activator-support, a metallocene compound, an organoaluminum compound, and a dialkyl aluminum alkoxide, and these catalyst compositions have increased catalytic activity for the polymerization of olefins.
Type:
Grant
Filed:
July 24, 2023
Date of Patent:
July 16, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Qing Yang, Ryan N. Rose, Max P. McDaniel, Zhihui Gu
Abstract: Methods for modifying a catalyst system component are disclosed in which a feed mixture containing a fluid and from 1 to 15 wt. % of a catalyst system component is introduced into an inlet of a hydrocyclone, an overflow stream containing from 0.1 to 5 wt. % solids and an underflow stream containing from 10 to 40 wt. % solids are discharged from the hydrocyclone, and the underflow stream is spray dried to form a modified catalyst component. Often, from 4 to 20 wt. % of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 ?m, or less than or equal to 10 ?m.
Type:
Grant
Filed:
July 25, 2023
Date of Patent:
July 16, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Carlos A. Cruz, Mitchell D. Refvik, Max P. McDaniel, Mark Scott
Abstract: Disclosed herein are ethylene-based polymers generally characterized by a melt index of less than 15 g/10 min, a density from 0.91 to 0.945 g/cm3, a CY-a parameter at 190° C. from 0.2 to 0.6, an average number of long chain branches per 1,000,000 total carbon atoms of the polymer in a molecular weight range of 500,000 to 2,000,000 g/mol of less than 5, and a maximum ratio of ?E/3? at an extensional rate of 0.03 sec?1 in a range from 3 to 15. The ethylene polymers have substantially no long chain branching in the high molecular weight fraction of the polymer, but instead have significant long chain branching in the lower molecular weight fraction, such that polymer melt strength and bubble stability are maintained for the fabrication of blown films and other articles of manufacture.
Type:
Grant
Filed:
April 29, 2022
Date of Patent:
July 9, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Errun Ding, Chung Ching Tso, Max P. McDaniel, Ashish M. Sukhadia, Youlu Yu, Randall S. Muninger, Aaron M. Osborn, Christopher E. Wittner
Abstract: A pre-catalyst composition comprising: a) a silica support comprising silica wherein an amount of silica is in a range of from about 70 wt. % to about 95 wt. % based upon a total weight of the silica support; b) a titanium-containing compound wherein an amount of titanium is in a range of from about 0.1 wt. % to about 10 wt. % based upon the total weight of the silica support; c) a chromium-containing compound wherein an amount of chromium is in a range of from about 0.1 wt. % to about 10 wt. % based upon the total weight of the silica support; d) a surfactant wherein the surfactant comprises a non-ionic surfactant, a cationic surfactant, or a combination thereof; e) a carboxylate wherein the carboxylate comprises a multi carboxylate, an alpha-hydroxy carboxylate, or a combination thereof; and f) a solvent.
Type:
Grant
Filed:
June 6, 2022
Date of Patent:
July 9, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Max P. McDaniel, Kathy S. Clear, William C. Ellis, Deloris R. Gagan
Abstract: Disclosed is a process and apparatus for cooling a coolant used in a heat exchange equipment in a plant. The process is performed in a plant having the apparatus disclosed herein. The process and apparatus utilize a geothermal cooling loop for cooling at least a portion of the total amount of coolant circulating in the coolant loop that is used to cool a surface of a heat exchange equipment in the plant.
Abstract: Methods for determining ethylene concentration in an ethylene oligomerization reactor using an ultrasonic flow meter are described, and these methods are integrated into ethylene oligomerization processes and related oligomerization reactor systems.
Type:
Grant
Filed:
June 23, 2023
Date of Patent:
July 2, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Bruce Kreischer, Kendall M. Hurst, Eric D. Schwerdtfeger, Steven M. Bischof, Jared Fern, Kent E. Mitchell, James Hillier
Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.
Type:
Grant
Filed:
September 1, 2023
Date of Patent:
June 25, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Masud M. Monwar, Jared Barr, Carlos A. Cruz, Kathy S. Clear, Max P. McDaniel, William C. Ellis
Abstract: A composition comprising a low density polyethylene (LDPE) and a peroxide-treated metallocene-catalyzed linear low density polyethylene (pmLLDPE), wherein the composition when extruded as a molten resin displays a neck-in value that is (i) decreased when compared to the neck-in value observed when using the LDPE alone, (ii) about equal to the neck-in value observed when using the LDPE alone, or (iii) increased by <10% of the neck-in value observed when using the LDPE alone. The composition when extruded as a molten resin displays a neck-in value that is decreased by ?5% when compared with a neck-in value of an otherwise similar composition comprising the LDPE and a metallocene-catalyzed linear low density polyethylene (mLLDPE) that has not been peroxide-treated. The composition comprises 1-80 wt. % pmLLDPE. The pmLLDPE has a melt index of ?0.9 g/10 min, when tested in accordance with ASTM D1238 under a force of 2.16 kg.
Abstract: A C10 hydrocarbon composition of greater than 55 wt. % C10 mono-olefins contains 1-decene, 2-butyl-1-hexene, 3-propyl-1-heptene, 4-ethyl-1-octene, 4-penten-1-yl-cyclopentane, and 5-methyl-1-nonene. A C12 hydrocarbon composition of greater than 60 wt. % C12 mono-olefins contains 1-dodecene, 6-hepten-1-yl-cyclopentane, heptylcyclopentane and n-dodecane. A C14 hydrocarbon composition of greater than 60 wt. % C14 mono-olefins contains 1-tetradecene, 8-nonen-1-yl-cyclopentane, n-tetradecane, and nonylcyclopentane.
Abstract: A system for processing plastic waste may include a feed line, a feed fractionator, a hydrotreater, a catalytic reforming unit, a heavy oil cracker, and a steam cracker. A pyrolyzed plastics feed is separated into light, medium, and heavy hydrocarbon streams. The hydrotreater removes sulfur, and the catalytic reforming unit produces a circular aromatic-rich stream. The heavy oil cracker generates cracked streams. The steam cracker produces a circular olefin stream from a cracked stream. A system for processing plastic waste may include the feed line, the feed fractionator, the hydrotreater, a medium hydrocarbon fractionator, the catalytic reforming unit, a full-range reforming unit, the heavy oil cracker, and the steam cracker. The medium hydrocarbon fractionator produces two hydrocarbon streams. The full-range naphtha reforming unit produces a second circular aromatic-rich stream.
Type:
Application
Filed:
February 19, 2024
Publication date:
June 13, 2024
Applicant:
Chevron Phillips Chemical Company LP
Inventors:
Bruce D. Murray, Scott G. Morrison, Kenneth Fountain, Steven R. Horlacher, Vincent D. Mcgahee, Reza Khankal, David Dockter
Abstract: A method of preparing a catalyst comprising a) drying a chrominated-silica support followed by contacting with a titanium(IV) alkoxide to form a metalized support, b) drying a metalized support followed by contacting with an aqueous alkaline solution comprising from about 3 wt. % to about 20 wt. % of a nitrogen-containing compound to form a hydrolyzed metalized support, and c) drying the hydrolyzed metalized support followed by calcination at a temperature in a range of from about 400° C. to about 1000° C. and maintaining the temperature in the range of from about 400° C. to about 1000° C. for a time period of from about 1 minute to about 24 hours to form the catalyst.
Type:
Grant
Filed:
June 13, 2022
Date of Patent:
June 11, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Max P. McDaniel, Kathy S. Clear, Eric D. Schwerdtfeger, Jeremy M. Praetorius
Abstract: An auto injector for delivery of a medicament is disclosed. The auto injector comprises a housing, a syringe holder configured to receive a syringe; a first drive module adapted to move the syringe holder relatively to the housing; and a rigid needle shield remover comprising a first part adapted for separating a rigid needle shield from the syringe.
Type:
Grant
Filed:
October 7, 2019
Date of Patent:
June 4, 2024
Assignee:
Phillips-Medisize A/S
Inventors:
Bjarne Sørensen, Esben Weldingh Johansen, Jan Olesen, Jørgen Funder Rasmussen, Emil Wegger Jensen, Søren Koch Bechmann, Lucile Daul
Abstract: Sulfated bentonite compositions are characterized by a total pore volume from 0.4 to 1 mL/g, a total BET surface area from 200 to 400 m2/g, and an average pore diameter from 55 to 100 Angstroms. The sulfated bentonite compositions also can be characterized by a d50 average particle size in a range from 15 to 50 ?m and a ratio of d90/d10 from 3 to 15. The sulfated bentonite compositions can contain a sulfated bentonite and from 10 to 90 wt. % of colloidal particles, or the sulfated bentonite compositions can contain a sulfated bentonite and from 0.2 to 10 mmol/g of zinc and/or phosphorus. These compositions can be utilized in metallocene catalyst systems to produce ethylene based polymers.
Type:
Grant
Filed:
December 13, 2022
Date of Patent:
June 4, 2024
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Max P. McDaniel, Qing Yang, Ryan N. Rose, Kathy S. Clear, Graham R. Lief, Eric D. Schwerdtfeger, Anand Ramanathan, Jeremy M. Praetorius, Connor D. Boxell