Patents Assigned to Polyplastics Co. Ltd.
  • Patent number: 7648748
    Abstract: The present invention provides a liquid crystalline resin composition capable of readily blow-molding a molded article having uniform thickness, with the addition of good blow-moldability owing to the improved drawdown-resistant property, the improved melt-tension increase rate, and other properties without deteriorating the low gas-permeability which is a characteristic of liquid crystalline resin.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: January 19, 2010
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Mineo Ohtake, Toshio Shiwaku, Masato Suzuki
  • Patent number: 7641833
    Abstract: An object of the present invention is to economically produce a resin composition pellet with the degradation of resin suppressed, by using an ordinary extruder, the resin composition pellet being filled with a desired filling amount of a uniformly compounded fibrous filler, and having a required weight average fiber length, in particular, to produce a resin composition pellet used for a socket of a planar socket pin in which the pitch interval of a lattice area of a semiconductor device is 2.0 mm or less, the thickness of the lattice area is 0.5 mm or less, and the height of the socket is 5.0 mm or less.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: January 5, 2010
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kei Aoki, Masayuki Sakai, Kazufumi Watanabe
  • Patent number: 7638565
    Abstract: A polyacetal resin composition comprises a polyacetal resin and a hetero atom-containing aliphatic carboxylic acid hydrazide. The proportion of the hetero atom-containing aliphatic carboxylic acid hydrazide may be about 0.001 to 20 parts by weight relative to 100 parts by weight of the polyacetal resin. The polyacetal resin composition may further comprise at least one member selected from the group consisting of an antioxidant, a heat stabilizer, a processing stabilizer, a weather (light)-resistant stabilizer, an impact resistance improver, a gloss control agent, an agent for improving sliding property, a coloring agent, and a filler. Such a resin composition improves stability of the polyacetal resin and inhibits formaldehyde emission.
    Type: Grant
    Filed: October 22, 2004
    Date of Patent: December 29, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventor: Hatsuhiko Harashina
  • Patent number: 7619020
    Abstract: The present invention provides a polyacetal resin composition having excellent mechanical characteristics with reduced generation of formaldehyde. To 100 parts by weight of (A1) a polyacetal resin having substantially straight chain molecular structure, there are added 0.1-20 parts by weight of (A2) a polyacetal resin having a branched or cross-linked molecular structure, 3-200 parts by weight of (B) a glass-base inorganic filler, and 0.001 to 3 parts by weight of (C) a boric acid compound.
    Type: Grant
    Filed: August 8, 2007
    Date of Patent: November 17, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventors: Akihide Shimoda, Hiraku Iketani
  • Publication number: 20090197471
    Abstract: Provided is a material capable of forming a molded product which has good mechanical properties with low warpage while being excellent in any of the performance including heat resistance and flowability, even if the molded product is an asymmetric electronic parts. Specifically, the asymmetric electronic parts is prepared by molding a liquid crystalline polymer composition comprising (A) a fibrous filler having an average fiber diameter within the range of 5 to 30 ?m, having a weight average fiber length within the range of 250 to 350 ?m, excluding 10 ?m or shorter fiber length, and having a content of a fibrous filler being 700 ?m or longer within the range of 5% by weight or less; and (B) a plate-like filler having an average particle size within the range of 0.
    Type: Application
    Filed: August 23, 2007
    Publication date: August 6, 2009
    Applicant: Polyplastics Co., Ltd.
    Inventors: Hiroki Fukatsu, Seiji Kayukawa, Hirokazu Ohshiba, Raita Nishikawa
  • Publication number: 20090163632
    Abstract: A novel cycloolefin copolymer that can be employed in the production of molding with fewer defects, for example, fewer gel particles (fish eyes). There is provided a cycloolefin copolymer comprising 80 to 20 mol % of repeating units derived from an ?-olefin monomer and 20 to 80 mol % of repeating units derived from at least one cycloolefin monomer selected from the group consisting of monomer of the general formula (I), monomer of the general formula (II), monomer of the general formula (III), monomer of the general formula (IV) and monomer of the general formula (V), wherein with respect to the repeating units derived from cycloolefin monomer, the proportion thereof being present in the form of dimer (Rd) is 50 mol % or below and the proportion thereof being present in the form of trimer (Rt) 5 mol % or above.
    Type: Application
    Filed: November 24, 2005
    Publication date: June 25, 2009
    Applicants: POLYPLASTICS CO., LTD., TOPAS ADVANCED POLYMERS GMBH
    Inventors: Wilfried Hatke, Matthias Bruch, Anne-Meike Schauwienold, Udo Manfred Stehling, Hiroyuki Kanai, Hajime Serizawa, Hiroshi Hiraike, Takahiko Sawada, Kazunari Yagi, Isao Higuchi, Katsunori Toyoshima, Takeharu Morita
  • Patent number: 7547403
    Abstract: To provide a resin material excellent in electric conductivity and judiciously usable in the manufacture of fuel cell separators and so forth. An electroconductive resin composition which comprises 100 parts by weight of a liquid-crystalline polymer (A) and 200 to 500 parts by weight of at least one species of graphite (B) selected from synthetic graphite, flake graphite and amorphous graphite with a fixed carbon content of not less than 95% by weight and an average particle size of 50 to 200 ?m as incorporated in the polymer, the composition resulting from melt-kneading under such conditions that the ratio Q/N, where Q (kg) is the hourly extrusion throughput rate during kneading and N (rpm) is the screw revolution rate, may amount to 0.1 to 1.5, the composition having a volume resistivity of not more than 2×10?2 ?·cm.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: June 16, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventors: Takayuki Miyashita, Takashi Usami
  • Publication number: 20090137724
    Abstract: The invention provides a thermoplastic resin composition which has high rigidity and high flowability, gives less peeling of molding surface, and provides excellent appearance, and which can be suitably used for mechanical parts of automobile and mechanical parts of electrical and electronic products. Provided is the thermoplastic resin composition comprising: 100 parts by weight of (A) a sole polybenzimidazole resin or a mixed thermoplastic resin composed of 70 to 20% by weight of a polybenzimidazole resin and 30 to 80% by weight of a polyether ketone resin; and 5 to 100 parts by weight of (B) a liquid crystalline polyester amide resin containing one or more types of structuring monomer of 4-aminophenol, 1, 4-phenylenediamine, 4-aminobenzoic acid, and a derivative thereof, and containing 3 to 35% by mole of an amide component in the total bonds.
    Type: Application
    Filed: June 13, 2006
    Publication date: May 28, 2009
    Applicants: POLYPLASTICS CO., LTD., PBI ADVANCED MATERIALS CO., LTD.
    Inventors: Yoshiaki Taguchi, Toru Katsumata, Toshio Shiwaku
  • Patent number: 7498375
    Abstract: A flame-retardant resin composition comprises (A) abase resin; (B) a flame retardant comprising (B1) at least one aromatic resin selected from a polyphenylene oxide-series resin and a polyphenylene sulfide-series resin, (B2) a phosphoric ester, and (B3) a nitrogen-containing cyclic compound; and (C) a styrenic resin having a melt flow rate of not more than 8 g/10 minutes. The base resin may be a polyester-series resin. The styrenic resin (C) may be a styrenic resin having a melt flow rate of 0.1 g/10 minutes to not more than 5 g/10 minutes. The phosphoric ester (B2) may be a condensed phosphoric ester, and the nitrogen-containing cyclic compound (B3) may be a polyphosphate of an amino group-containing triazine compound, a polyphosphoric acid amide, or others. The present invention provides a flame-retardant resin composition which has been flame-retarded without using a halogen-containing flame retardant.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: March 3, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Patent number: 7498368
    Abstract: A flame-retardant resin composition comprises a base resin (e.g., a polyester-series resin), a flame retardant (A) comprising a salt of an amino group-containing triazine compound with a sulfuric acid and/or a sulfonic acid, a flame-retardant auxiliary (B). The flame-retardant auxiliary (B) includes an aromatic resin, acyclic urea-series compound or a derivative thereof [e.g., acetyleneurea, uric acid, a salt of melamine or a condensate thereof (e.g., melam, melem, and melon) with cyanuric acid], an amino group-containing triazine compound (e.g., melamine or a condensate thereof), and/or an inorganic metal-series compound (e.g., a metal salt of an oxygen acid having no sulfur atom, a metal oxide, a metal hydroxide, and a metal sulfide). The present invention provides a flame-retardant resin composition to which flame retardancy is imparted without using a halogen-series flame retardant and an organic phosphorus-series flame retardant.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: March 3, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Publication number: 20090018236
    Abstract: An antihazing agent for noncrystalline cycloolefin resins which can inhibit the hazing of the resins due to fine cracking caused by environmental change, particularly, environmental change from high temperature and humidity atmosphere to ordinary temperature and humidity atmosphere without losing the characteristics inherent in the resins to keep the transparency of the resins and inhibit the light transmittance thereof from lowering; noncrystalline cycloolefin resin compositions containing the agent; and optical elements made from the compositions. A compound component containing a metal rosinate as the main component is used as the antihazing agent for noncrystalline cycloolefin resins. It is particularly preferable that the antihazing agent further contain one or more members selected from the group consisting of alkali metal salts, alkaline earth metal salts, and Group 12 metal salts.
    Type: Application
    Filed: October 30, 2006
    Publication date: January 15, 2009
    Applicant: POLYPLASTICS CO., LTD.
    Inventors: Eiki Kunimoto, Hirotaka Miyazaki, Hajime Serizawa
  • Publication number: 20080286510
    Abstract: A purpose of the present invention is to obtain a hollow extruded article by easy blow molding or extrusion molding to give a draw down resistance and a uniform wall thickness of the article without damaging low gas permeability which is a characteristic property of a liquid-crystalline polymer. A resin composition for extrusion molding which is prepared by melting and kneading 99-70 wt. % of wholly aromatic polyester amide liquid crystal resin (A) having a melting point of 270-370° C. and a melt viscosity at 1000/sec. shear rate of 20-60 Pa·s at Temperature T1 which is higher than 20° C. from said melting point, and containing (I) 1-15 mole % of 6-hydroxy-2-naphthoic acid residue, (II) 40-70 mole % of 4-hydroxybenzoic acid residue, (III) 5-28.5 mole % of aromatic diol residue, (IV) 1-20 mole % of 4-aminophenol residue, and (V) 6-29.5 mole % of aromatic dicarboxylic acid residue; and 1-30 wt. % of epoxy modified polyolefin type resin (B), and has a melt viscosity at 1000/sec.
    Type: Application
    Filed: October 27, 2005
    Publication date: November 20, 2008
    Applicant: POLYPLASTICS CO., LTD.
    Inventors: Toshio Nakane, Mineo Ohtake, Toshio Shiwaku, Masato Suzuki
  • Publication number: 20080271381
    Abstract: The present invention provides an agent to decompose instable terminal group, which is effective in a small adding amount, which sufficiently decreases the quantity of residual instable terminal group, and which generates very little limitation on the treatment method, the apparatus, and the use amount of the agent. Specifically, it provides a method for manufacturing stabilized polyacetal resin having the step of applying heat treatment to a polyacetal resin having an instable terminal group in the presence of an agent to decompose the instable terminal group, which agent is composed of a heterocyclic quaternary ammonium salt, thus decreasing the quantity of the instable terminal group.
    Type: Application
    Filed: June 6, 2007
    Publication date: November 6, 2008
    Applicant: Polyplastics Co., Ltd
    Inventors: Hatsuhiko Harashina, Hiroaki Nakao
  • Patent number: 7442744
    Abstract: The present invention is improved in an enhanced impact resistance of a molded article of a PAS resin and continuous molding (mold release improvement) in mass production and adhesion to coating. The present invention provides a polyarylene sulfide resin composition comprising (A) 100 parts by weight of a polyarylene sulfide resin, (B) 1-20 parts by weight of a graft copolymer formed by the branching or crosslinking chemical bond of an olefin-based copolymer (b-1) and at least one polymer or copolymer (b-2), the olefin copolymer (b-1) composed mainly of an ?-olefin and an ?, ?-unsaturated carboxylic acid ester without a glycidyl group, the polymer or copolymer (b-2) constituted of a specific repeating unit, and (C) 1-20 parts by weight of an olefin copolymer composed mainly of an ?-olefin and a glycidyl ester of an ?,?-unsaturated carboxylic acid.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: October 28, 2008
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kazutomo Tokushige, Sei Wakatsuka
  • Patent number: 7411013
    Abstract: A flame-retardant resin composition comprises a base resin (A), an organic phosphorus compound (B) having a unit represented by the following formula (1a), and a flame-retardant auxiliary (C). Wherein Ar represents an aromatic hydrocarbon ring or a nitrogen-containing aromatic heterocycle; X1 represents an oxygen atom or a sulfur atom; Y1 and Y2 are the same or different and each represents a hydrocarbon group, an alkoxy group, an aryloxy group, or an aralkyloxy group; Z1 represents an alkylene group, or a nitrogen-containing bivalent group corresponding to an alkylamine; Y1 and Y2 may bind to each other, and Y1 and Y2 together with the adjacent phosphorus atom may form a ring; “a” denotes 0 or 1; and “b” denotes an integer of 1 to 6.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: August 12, 2008
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Publication number: 20080139754
    Abstract: A purpose of the invention is to provide a thermoplastic resin composition which enhances crystallization during molding, has high thermal deformation temperature, has high rigidity, induces less pealing on the molding surface, and gives excellent appearance, thus being preferably used as the facility parts of automobiles, and those of electric and electronics products. The (A) 100 parts by weight of a polyamide resin structured by the following monomers (1) and (2) is blended with (B) 5 to 100 parts by weight of a liquid crystalline polyester amide resin: (1) a diamine component containing an aliphatic diamine component unit having 4 to 12 carbon atoms arranged in straight chain and/or an aliphatic diamine component unit having 4 to 12 carbon atoms having side chain, and a derivative thereof; and (2) a dicarboxylic acid component containing 40 to 100% by mole of terephthalic acid component unit and 0 to 60% by mole of isophthalic acid component unit, and a derivative thereof.
    Type: Application
    Filed: August 29, 2005
    Publication date: June 12, 2008
    Applicant: POLYPLASTICS CO., LTD.
    Inventors: Tetsuya Uehara, Akira Hirasawa, Hiroshi Ono, Abdolreza Nezamoleslami, Kazuaki Fujimori
  • Publication number: 20080039567
    Abstract: The present invention provides a polyacetal resin composition having excellent mechanical characteristics with reduced generation of formaldehyde. To 100 parts by weight of (A1) a polyacetal resin having substantially straight chain molecular structure, there are added 0.1-20 parts by weight of (A2) a polyacetal resin having a branched or cross-linked molecular structure, 3-200 parts by weight of (B) a glass-base inorganic filler, and 0.001 to 3 parts by weight of (C) a boric acid compound.
    Type: Application
    Filed: August 8, 2007
    Publication date: February 14, 2008
    Applicant: Polyplastics Co., Ltd.
    Inventors: Akihide Shimoda, Hiraku Iketani
  • Publication number: 20070085056
    Abstract: The present invention provides a liquid crystalline resin composition capable of readily blow-molding a molded article having uniform thickness, with the addition of good blow-moldability owing to the improved drawdown-resistant property, the improved melt-tension increase rate, and other properties without deteriorating the low gas-permeability which is a characteristic of liquid crystalline resin.
    Type: Application
    Filed: October 13, 2006
    Publication date: April 19, 2007
    Applicant: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Mineo Ohtake, Toshio Shiwaku, Masato Suzuki
  • Patent number: 7205346
    Abstract: A flame-retardant resin composition comprises a thermoplastic resin; a flame retardant comprising a phosphorus-containing compound (A), a aromatic resin (B), and at least one flame-retardant auxiliary (C) selected from a nitrogen-containing compound and a metal salt of an inorganic acid; and at least one stabilizer auxiliary (D) selected from a compound having a functional group reactive to an active hydrogen atom and a water-repellent compound. The phosphorus-containing compound may be a phosphoric ester. The aromatic resin may be a polyphenylene sulfide-series resin or a polyphenylene oxide-series resin. The nitrogen-containing compound is a salt of an amino group-containing triazine compound with an oxygen acid, a salt of an amino group-containing triazine compound with a hydroxyl group-containing triazine compound, a polyphosphoric acid amide, a cyclic urea compound, or others.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: April 17, 2007
    Assignee: Polyplastics Co., Ltd.
    Inventor: Hatsuhiko Harashina
  • Patent number: 7205345
    Abstract: A blending of a styrenic resin, and a flame retardant comprising a phenolic resin and a phosphazene compound to a polyalkylene arylate-series resin imparts flame retardancy to a polyalkylene arylate-series resin. The phosphazene compound is a cyclic phenoxyphosphazene compound, a linear phenoxyphosphazene compound, or a crosslinked phenoxyphosphazene compound. The obtained polyalkylene arylate-series resin composition has excellent heat resistance and high flame-retardancy without bleeding out the flame retardant.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: April 17, 2007
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada, Yuji Tada