Abstract: The invention provides a method of improving the corrosion resistance of a metal substrate. The method comprises: (a) electrophoretically depositing on the substrate a curable electrodepositable coating composition to form a coating over at least a portion of the substrate, and (b) heating the substrate to a temperature and for a time sufficient to cure the coating on the substrate. The electrodepositable coating composition comprises a resinous phase dispersed in an aqueous medium, the resinous phase comprising: (1) an ungelled active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (2) an at least partially blocked polyisocyanate curing agent; and (3) a pigment component comprising an inorganic, platelike pigment having an average equivalent spherical diameter of at least 0.2 microns. The electrodepositable coating composition demonstrates a pigment-to-binder ratio of at least 0.5. The coating composition contains less than 8 percent by weight of a grind vehicle.

Abstract: Disclosed herein is an adhesive composition comprising: an epoxy-containing component; and a blocked polyisocyanate curing agent comprising a blocking group derived from a blocking agent comprising an alpha-hydroxy amide, ester, or thioester, or a combination thereof. Also disclosed are methods for forming a bonded substrate with the adhesive composition. Also disclosed is an article comprising first and second substrates and the adhesive composition.

Abstract: A stain resistant coating composition can include: (a) a polyester polyol; (b) a silicone component having at least one reactive functional group; and (c) a crosslinker reactive with (a) and (b). The polyester polyol can include a reaction product obtained from a mixture of reactants including: an aliphatic diol; a polyol having 3 or more hydroxyl groups; and an aliphatic cyclic polycarboxylic acid, or an anhydride or ester thereof, that is greater than 10 mole % of the total carboxylic acids, or anhydrides or esters thereof, used to prepare the polyester.

Abstract: A transparency includes an additive such that the transparency blocks greater than 50% of light of a wavelength range of 400 nm to 430 nm as measured by ultraviolet-visible spectroscopy from passing through the transparency and the transparency has a total visible light transmittance of greater than 65% as measured by way of ASTM D1003-07. A transparency includes an additive such that the transparency blocks greater than 70% of the light of the wavelength range of 400 nm to 430 nm as measured by ultraviolet-visible spectroscopy from passing through the transparency and the transparency has a total visible light transmittance of greater than 60% as measured by way of ASTM D1003-07.

Abstract: The present invention is directed towards a coating composition comprising a film-forming polymer comprising active hydrogen-containing functional groups; a blocked polyisocyanate curing agent comprising a blocking group derived from a blocking agent comprising an alpha-hydroxy amide, ester or thioester; and a curing catalyst that does not contain tin, lead, iron, zinc or manganese. Also disclosed are coatings, coated substrates, and methods of coating a substrate.

Abstract: A stain resistant, soft touch coating composition can include: (a) a fluoropolymer comprising at least one reactive functional group; (b) a polyester polyol; and (c) a crosslinker reactive with (a) and (b). The polyester polyol can include a reaction product obtained from a mixture of reactants including: an aliphatic diol; a polyol having 3 or more hydroxyl groups; and a cyclic polycarboxylic acid, or an anhydride or ester thereof.

Abstract: Spherically-shaped silica can include a precipitated silica powder having a d50 particle size selected within a range of greater than 20 ?m and up to 80 ?m, a di-octyl adipate oil absorption selected within a range of from 150 ml/100 g to 500 ml/100 g, an average circularity selected within a range of from 0.70 to 1.0, and an angle of repose, of less than 30°. A process of preparing spherically-shaped silica powder is also included.

Abstract: A method that includes obtaining, using a processor, reflectance data from a target coating and calculating, using the processor, pivot-normalized reflectance data. The method also includes generating, using the processor, a coating formulation that is the same or substantially similar in appearance to the target coating.

Abstract: A coating composition comprising (i) a reaction product of two different polyesters, a trimellitic polyanhydride, and a curing agent, for example, an aminoplast; and (ii) an epoxidized polybutadiene polymer. The compositions are useful in coating food and beverage containers, particularly 2-piece cans formed by drawing and redrawing (DRD).

Abstract: There is described an aqueous coating composition, the aqueous coating composition comprising an acrylic polyester resin, obtainable by grafting an acrylic polymer and a polyester material, the polyester material being obtainable by polymerizing: (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality.

Abstract: An adhesive composition comprising an epoxy compound and a compound comprising at least one aminimide functional group is disclosed. The compound comprising the at least one aminimide functional group is present in an amount from 2-8% by weight based on total weight of the adhesive composition and reacts with the epoxy compound upon activation by an external energy source. The adhesive composition also may comprise an amidine salt.

Abstract: A computer system for optimizing a coating formulation through a user interface processes spectrometric data through a probabilistic colorant analysis. The probabilistic colorant analysis generates a set of colorants that are each associated with a calculated probability that the associated colorant is present within a target coating. The system identifies a proposed group of colorants from within the set of colorants that are associated with the highest calculated probabilities of being present within the target coating. The system displays on a graphical user interface an indication of each colorant within the proposed group of colorants. The system receives input through one or more selectable interface elements that define a user-defined group of colorants selected from the proposed group of colorants. The system generates a coating formulation, wherein the coating formulation is generated from the user-defined group of colorants.

Abstract: A computer system for identifying coating texture effects initiates a set of colorant decision points. The colorant decision points identifying a probability that an effect pigment type is present within a target coating. The computer system calculates in parallel each colorant decision point within the set of colorant decision points. Each colorant decision point provides a probability that a different effect pigment type is present within the target coating. The computer system then calculates a set of final colorant probabilities. Each final colorant probability within the set of final colorant probabilities is calculated by combining a unique subset of probabilities calculated by the first set of colorant decision points. Additionally, each final colorant probability indicates a probability that an associated colorant is present within the target coating.

Abstract: A coating composition comprising; a polyester material, and benzoguanamine or a derivative thereof, wherein the coating composition is substantially free of bisphenol A (BPA), bisphenol F (BPF), bisphenol A diglycidyl ether (BADGE) and bisphenol F diglycidyl ether (BFDGE), and wherein the coating composition, when cured, has a flexibility of at least 20 mm as measured according to the draw and re-draw test method with processing in 1% salt (NaCl) solution in tap water at 130° C. for 60 minutes and a scratch resistance of at least 700 g as measured according to ISO Standard 1518-1:2011.

Abstract: A computer system for seeding a formulation engine receives spectrometric data from a target coating. The computer system processes the spectrometric data through a probabilistic colorant analysis. The probabilistic colorant analysis generates a set of colorants. Each colorant within the set of colorants is associated with a calculated probability that the associated colorant is present within the target coating. Additionally, the computer system adds at least a portion of the colorants within the set of colorants to a formulation engine. The portion of the colorants is added to the formulation engine in order of decreasing probability. Further, the computer system generates, from an output of the formulation engine, a coating formulation that is calculated to match the target coating within a predetermined qualitative threshold.

Abstract: A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation of said prepolymer is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coating.

Abstract: There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, including—2,2,4,4-tetraalkyl-cyclobutane-1,3-diol. One of the polyacid component or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.

Abstract: A silicone-containing polyester polyol can include a reaction product prepared from reactants including: a diol; a polyol having at least three hydroxyl groups; a dimer of a fatty acid having two carboxylic acid groups, or an anhydride or ester thereof; and a silicone component having siloxane linkages and at least two reactive functional groups selected from hydroxyl groups, amino groups, thiol groups, carboxylic acid groups, anhydride groups, or combinations thereof. A coating composition for preparing an anti-fingerprinting, soft touch coating can include the silicone-containing polyester polyol and a crosslinker reactive with the silicone-containing polyester polyol.

Abstract: Coating compositions that include a binder formed from a polyester and a phosphorus acid are disclosed. The binder includes a polyester material formed as the reaction product of a polyacid, a polyol, and a phosphorous acid, wherein the polyester material has a number-average molecular weight (Mn) from about 1,000 Da to 25,000 Da and a polydispersity index (Mw/Mn) of from about 1 to 10. The polyester material is present in the binder composition in amounts of more than about 10 weight percent (wt %). The coating compositions are useful for coating food and/or beverage containers.

Abstract: The present invention is directed to a method for treating a surface of a filled microporous membrane. The microporous membrane includes a polyolefinic matrix, inorganic filler distributed throughout the matrix, and a network of interconnecting pores throughout the membrane. The method includes sequentially (1) contacting the membrane with a first treatment composition comprising an epoxy-silane which is in intimate contact with the inorganic filler; (2) subjecting the membrane of (1) to conditions sufficient to effect a first reaction between the inorganic filler and the silane groups of the epoxy-silane compound; (3) contacting the membrane of (2) with a second treatment composition comprising polyalkylene polyamine, an amine functional polysaccharide and/or an amino silane; and (4) subjecting the membrane of (3) to conditions sufficient to effect a second reaction. Treated membranes also are provided.