Abstract: Coated articles demonstrating anti-fouling properties are provided, comprising: (a) a substrate comprising sapphire; (b) an adhesion promoting layer applied to the substrate; and (c) a top layer comprising at least an anti-fouling coating applied to the adhesion promoting layer. The adhesion promoting layer is formed from a curable sol-gel composition and has a dry film thickness less than 1000 nm after curing. The present invention also provides a method of forming a coated article comprising: (a) applying a curable film-forming sol-gel composition on a sapphire substrate, to form a coated substrate with a sol-gel adhesion promoting layer having a dry film thickness less than 1000 nm after curing; (b) subjecting the coated substrate to a temperature of at least 500° C. to effect cure of the sol-gel composition; and (c) applying at least an anti-fouling coating on the adhesion promoting layer to form a multi-layer, coated article.

Abstract: The present invention is directed to a method of preparing an alkoxy silane functional ionic liquid comprising reacting a halogenated compound comprising a halogen and an active hydrogen functional group, an isocyanato functional alkoxy silane, and an ionizable compound capable forming an ionic bond with the halogen to form the alkoxy silane functional ionic liquid. The present invention is also directed to alkoxy silane functional ionic liquids.

Abstract: A coating composition comprising a polyester, a mixture of novolak and resole resins and a vinyl chloride polymer, and the use of these compositions to coat metal containers is disclosed.

Abstract: An adhesive composition comprising an epoxy compound and a compound comprising at least one aminimide functional group is disclosed. The compound comprising the at least one aminimide functional group is present in an amount from 2-8% by weight based on total weight of the adhesive composition and reacts with the epoxy compound upon activation by an external energy source. The adhesive composition also may comprise an amidine salt.

Abstract: A system for monitoring performance of an aircraft windshield includes a sensor comprising a sensory contact and an evaluation unit. The sensory contact is in physical contact with one or more components of the windshield, and generates a signal representative of the performance of the component(s) of the windshield. An electrical connector is secured to the surface of the windshield facing the interior of the aircraft. The signal from the sensory contact passes through the connector to the evaluation unit. The evaluation unit acts on the signal to determine the performance of the component(s) of the windshield, wherein the evaluation unit is spaced from and out of physical contact with the windshield and the electrical connector, and is in electrical contact with the electrical connector.

Abstract: A curable film-forming composition is provided, comprising: (a) an acrylic polyol prepared from a monomer mixture comprising a hydroxyl functional monomer, wherein the hydroxyl functional monomer comprises a hydroxyalkyl group with an alkyl chain of at least four carbon atoms; (b) a rheology modifier comprising: (1) a non-aqueous dispersion of an internally crosslinked organic polymer; and (2) a reaction product of an amine and an isocyanate; and (c) a curing agent comprising functional groups that are reactive with hydroxyl functional groups. Also provided are a multi-component composite coating that includes the curable film-forming composition described above and methods for forming a composite coating on a substrate.

Abstract: The present invention is directed to an electrodepositable coating composition comprising a main vehicle comprising a phosphatized epoxy resin, a plasticizer, and a curing agent, wherein the main vehicle comprises a low-VOC main vehicle. The present invention is also directed to coatings and coated substrates.

Abstract: Food or beverage containers coated with polyester coating compositions containing capped polyesters are disclosed.

Abstract: Disclosed herein are methods of preparing an aminimide. An epoxy compound is reacted with a hydrazine compound comprising a trivalent nitrogen, and an anhydride functional material or a cyclic compound containing a carbonyl group and at least one heteroatom alpha to the carbonyl group at a temperature greater than 20° C. to form the aminimide. At least one of the epoxy compound and the anhydride functional material or the cyclic compound is polymeric.

Abstract: The present invention is directed towards an electrodepositable coating composition comprising a polybutylene oxide polymer, an ionic film-forming polymer having functional groups, and a curing agent that is reactive with functional groups on the film-forming polymer. Also disclosed are methods of making the electrodepositable coating composition. Also disclosed are substrates treated with the electrodepositable coating composition.

Abstract: Polyoxazoline-containing compositions cured in the presence of an onium salt catalyst are disclosed.

Abstract: Coated packaging and methods for coating such packaging are disclosed. The coating compositions comprise a polymer comprising acid functionality and a polyoxazoline.

Abstract: Polymeric polyoxazolines of the following structure are disclosed: where X is the residue of a polymeric polyol after reaction with a dicarboxylic acid/anhydride; where R5 is an organic moiety; where Y is an organic moiety containing one or more oxazoline groups; and wherein each R10 is independently hydrogen or an organic moiety. Methods of making such polyoxazolines and using them in a coating, and packages coated therewith, are also within the scope of the present invention.

Abstract: Rubber replacement articles prepared from curable compositions are provided. The curable compositions comprise: (a) an isocyanate-functional prepolymer; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic particles demonstrating a volume average particle size of at least 5 microns. The isocyanate-functional prepolymer is (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol.

Abstract: Methods of printing a three-dimensional object using co-reactive components are disclosed. Thermosetting compositions for three-dimensional printing are also disclosed.

Abstract: Disclosed are particles that have an exterior surface coated with a thin polymeric coating, such as a coating that includes a sulfur-containing polymer. Also disclosed are compositions, such as fuel-resistant sealant and coating compositions, which include such particles. Aerospace vehicles having an aperture at least partially sealed with a sealant deposited from such a sealant composition are also disclosed.

Abstract: An alkoxysilane functionalized polysiloxane polymer can be prepared from a mixture of reactants including: a) a polysiloxane polymer having two or more reactive functional groups selected from -A-NH2, -A-OH, -A-N?C?O, -A-COOH, or combinations thereof; and b) at least one alkoxysilane having a functional group that is reactive with the reactive functional groups on the polysiloxane polymer. The alkoxysilane functionalized polysiloxane polymer can be combined with additional components to form a coating composition.

Abstract: A process for producing an article by three-dimensional printing includes applying a 1,1-di-activated vinyl compound-containing liquid binder over a predetermined area of a layer of solid particles. The liquid binder infiltrates gaps between the solid particles to form a first cross-sectional layer of an article, and the 1,1-di-activated vinyl compound reacts to solidify the liquid binder and bind the solid particles in the first cross-sectional layer of the article. Also provided is an article produced by the three-dimensional printing process, set forth herein.

Abstract: Polyisocyanate-cured coating compositions containing 1,1-di-activated vinyl compounds are described. Also provided are coatings formed from coating compositions comprising 1,1-di-activated vinyl compounds, including multi-layer coatings. Also provided are processes for coating substrates with coating compositions comprising 1,1-di-activated vinyl compounds. Also provided are articles employing the coatings described herein.

Abstract: Acid-catalyzed curable coating compositions containing 1,1-di-activated vinyl compounds are described, including multi-layer coatings. Also provided are processes for coating substrates with coating compositions comprising 1,1-di-activated vinyl compounds, Also provided are coated articles comprising coatings formed from coating compositions comprising 1,1-di-activated vinyl compounds.