Abstract: A gas seal for rotary shaft applications in which at least a portion of a contact surface of one member of the seal that has relative motion with and in contact with a second member of the seal is coated with a chromium carbide-age hardenable nickel base alloy. The process for depositing and heating the coating is also claimed.
Type:
Grant
Filed:
July 21, 1992
Date of Patent:
May 25, 1999
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
John Eric Jackson, Marianne O'Connor Price
Abstract: Coating a structure such as a brazed joint with a powdered wicking agent, preferably mixed with a fugitive liquid binder to form an adherent slurry, then heating the joint to allow the brazing alloy to melt and be drawn into the powdered wicking agent by capillary action. After cooling, the powder and braze alloy are mixed together to form a loosely consolidated mass which can be readily removed by mechanical and/or chemical means so that the components can then be separated for repair or reuse.
Abstract: A boron-nitride-silicate-containing sealant having good resistance to attack by molten metal such as molten zinc and a method for coating the sealant on a substrate.
Abstract: A sleeve adapted to be mounted on a mandrel to form a liquid transfer roll or the like comprises a radially expandable inner skin defining a radially inner surface of the sleeve, at least one radially compressible intermediate layer of resilient plastic material; and a rigid, self-supporting metal outer tube. Further methods for producing such a sleeve are described.
Abstract: A TiB.sub.2 -M coating which consists of greater than 50 vol % TiB.sub.2 hard phase particles in a metal or metal alloy (M) matrix that is produced by a thermal spray process using sintered TiB.sub.2 -M powders. The TiB.sub.2 -M powders were fabricated by sintering TiB.sub.2 powders and elemental metals or metal alloys which were selected to form a desired matrix for the TiB.sub.2 particles.
Type:
Grant
Filed:
January 10, 1997
Date of Patent:
November 17, 1998
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
Jiinjen Albert Sue, Robert Clark Tucker, Jr., Antony John Stavros
Abstract: A method of producing a coating on a substrate by electrolytically co-depositing a metal matrix M.sub.1 and particles of CrAlM.sub.2, where M.sub.1 is Ni, Co or Fe or two or all of these elements and M.sub.2 is Y, Si, Ti, Hf, Ga, Nb, Mn, Pt, a rare earth element or two or more of these elements. The co-deposition is carried out at a current density of less than 5mA per square centimeter. Preferably, the co-deposition forms a layer less than 50 microns thick, and occurs at a bath loading of less than 40 grams per liter of the particles. In a preferred embodiment, the particle size distribution in the plating bath is 25 percent between 15 and 12 microns, 45 percent between 12 and 10 microns and 30 percent less than 10 microns. The method is particularly useful for coating a gas turbine part.
Abstract: A method producing a coating on a substrate by aluminizing, chromizing or siliconizing the substrate, and depositing on the coated substrate by electrolytic or electroless deposition a metal matrix M.sub.1 from a bath containing particles of CrAlM.sub.2 to co-deposit the particles with the matrix as M.sub.1 CrAlM.sub.2, where M.sub.1 is Ni, Co or Fe or two or all of these elements and M.sub.2 is Y, Si, Ti, Hf, Ga, Nb, Mn, Pt, a rare earth element or two or more of these elements. Preferably, the method includes platinum aluminizing of the substrate. Heat treatments may be incorporated before and after deposition of the M.sub.1 CrAlM.sub.2. The deposition of the M.sub.1 CrAlM.sub.2 is carried out at a current density of less than 5 mA per square centimeter. Preferably, the deposition forms a M.sub.1 CrAlM.sub.2 layer less than 50 microns thick, and occurs at a bath loading of less than 40 grams per liter of the particles.
Abstract: A compressor or turbine blade having its tip coated with a zirconium-based oxide having a plurality of macrocracks extending at least 100 microns through the coating and the process used to produce such a coating.
Abstract: A thermal spray process for producing a MCrAlY-based coating wherein M is selected from the group consisting of iron, cobalt, nickel and mixtures thereof and wherein the oxygen in the fuel-oxidant mixture of the thermal spray process converts a substantial portion of the yttrium component to Y.sub.2 O.sub.3, a minor portion of the aluminum component to Al.sub.2 O.sub.3, and the Y.sub.2 O.sub.3 and Al.sub.2 O.sub.3 are present in an amount of less than 15 volume percent of the coating.
Abstract: A sealing material having excellent resistance to attack by molten metals, such as molten zinc, comprising aluminum phosphate/silicon dioxide-based material. The invention also relates to a method for coating articles with such sealing material.
Abstract: A method of and apparatus for producing abrasive tips on compressor or turbine rotor blades by electrolytic or electroless deposition in which the blades are mounted in a hollow jig with the tips of the blades extending through sealed openings in the jig and abrasive tips are formed on the tips. The parts of the blades within the hollow jig are isolated from the electrolyte without the need for wax masking. Preferably the jig is cylindrical with the blades extending radially through at least one circumferential row of apertures. The jig may comprise two end discs and at least one ring in which a circumferential row of apertures is formed. The ring is positioned between the end discs and means are provided for securing the discs and ring together.
Type:
Grant
Filed:
May 3, 1996
Date of Patent:
December 30, 1997
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
John Foster, Alan Taylor, Martin Patrick Chatterley
Abstract: A hearth roll with a cermet thermal spray coating on the roll surface which is composed of a heat resistant MCrA1Y (M: Fe, Ni, Co) alloy where the amount of A1 is below 10 at. % and the combined (Al+Cr) amount is between 13-31 at. % and at least one oxide ceramic from the group consisting of MgO, MgAl.sub.2 O.sub.4, and Y.sub.2 O.sub.3.
Abstract: A thermal spray process for producing a MCrAlY-based coating wherein M is selected from the group consisting of iron, cobalt, nickel and mixtures thereof and wherein the carbon in the fuel of the thermal spray process converts between 30 to 80 percent by weight of the chromium component in the coating to chromium carbide.
Abstract: A corona electrode, such as a roller electrode, having an outer dielectric layer and an undercoat of a copper layer that permits the electrode to operate at a lower temperature for a specific power input over a similar electrode without the copper undercoat.
Type:
Grant
Filed:
January 18, 1996
Date of Patent:
July 15, 1997
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
Russell Bruce Hatch, Keith Edward Bowen
Abstract: An electrodeposited composite coating comprises, as deposited, a matrix of cobalt and particles of chromium carbide, at least 50% and preferably at least 80% or 90% by weight of the particles lying within the size range of 4 .mu.m to 8 .mu.m.
Abstract: A compressor or turbine blade having its tip coated with a zirconium-based oxide having a plurality of macrocracks extending at least 100 microns through the coating and the process used to produce such a coating.
Abstract: A process of coating the internal surface of a hollow body by depositing a coating on a substrate having an external surface similar to the internal surface of the hollow body; inserting the coated substrate to mate within and contact the internal surface of the hollow body; and then removing the substrate while leaving the coating secured to the internal surface of the hollow body.
Abstract: A process of providing a thermal spray powder feed coating composition composed of stabilized zirconia mixed with zircon and a selected oxide, such as yttria, to form a refractory oxide coating ideally suited for hearth rolls for annealing steel.
Type:
Grant
Filed:
December 10, 1993
Date of Patent:
November 14, 1995
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
John E. Jackson, Hideo Nitta, Katoh Shoichi, Masahiko Amano, Yasushi Kurisu, Keiichiro Ohno
Abstract: An alloy of 3 to 9 weight percent boron with the balance molybdenum for use as a thermal spray coating for articles intended to be exposed to molten zinc.
Type:
Grant
Filed:
May 25, 1994
Date of Patent:
October 10, 1995
Assignee:
Praxair S.T. Technology, Inc.
Inventors:
John C. Wood, Shoichi Katoh, Hideo Nitta
Abstract: A coating composition comprising an alloy having the formula RCrAlR'R" wherein R is nickel, cobalt or the like; R' is yttrium or hafnium and R" is tantalum, rhenium and/or platinum, preferably mixed with an oxide dispersion such as alumina, to provide an improved class of coatings suitable for operating in high temperature oxidizing environments.