Patents Assigned to Research Institute of Petroleum Processing, Sinopec
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Patent number: 11898118Abstract: A silole derivative is of formula (I): each of the groups in the above formula is defined as those in the description. The silole derivative of formula (I) has aggregation-induced emission performance, and is particularly applicable in luminescent parts and devices, fluorescent probes, biological imaging, lubricating oils and greases. A lubricating grease composition has photoluminescence performance, as well as one or more of advantageous anti-oxidation properties, anti-wear properties, extreme pressure properties and anti-rust properties. It is applicable in many mechanical equipment in electrical industry, metallurgical industry, food industry, paper industry, automobile industry and aircraft industry.Type: GrantFiled: October 17, 2019Date of Patent: February 13, 2024Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Xinyang Liu, Yifeng He, Minyang Zhuang, Hui Zheng, Hongwei Sun
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Patent number: 11890589Abstract: An alkylation reaction apparatus has n reactors. In the n reactors, there are m reactors including the first reactor that have three reaction zones as defined below. According to the flow direction order of alkylation reaction streams, the three reaction zones are an x reaction zone, a y reaction zone and a z reaction zone respectively; based on the mixing intensity, the mixing intensity of the y reaction zone>the mixing intensity of the x reaction zone>the mixing intensity of the z reaction zone, wherein n?1 and n?m. An alkylation reaction system includes the aforementioned alkylation reaction apparatus, and a liquid acid catalyzed alkylation reaction process by using the aforementioned alkylation reaction apparatus or the aforementioned alkylation reaction system.Type: GrantFiled: February 21, 2020Date of Patent: February 6, 2024Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Minghui Dong, Baoning Zong, Xuhong Mu, Yibin Luo, Hua Chen, Jinyu Zheng, Langyou Wen
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Patent number: 11891578Abstract: A process for catalytic cracking of hydrocarbon oils includes the step of contacting a hydrocarbon oil feedstock with a catalytic cracking catalyst in a reactor comprising a dilute-phase transport fluidized bed and a fast fluidized bed connected in series for reaction. In the fast fluidized bed, the axial solid fraction ? of the catalyst is controlled within the range of about 0.1 to about 0.2. When used for catalytic cracking of hydrocarbon oil feedstocks, particularly heavy feedstock oils, the process and system show lower yields of dry gas and coke, and good product distribution.Type: GrantFiled: July 15, 2019Date of Patent: February 6, 2024Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Jianhong Gong, Zhigang Zhang, Xiaoli Wei
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Patent number: 11873457Abstract: A catalytic conversion process for producing gasoline and propylene includes the steps of 1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product; 2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction and a fraction comprising C4 olefin; 3) carrying out an oligomerization reaction on the fraction comprising C4 olefin in an oligomerization reactor to obtain an oligomerization product comprising C12 olefin, and optionally separating the oligomerization product to obtain a fraction comprising C12 olefin; 4) recycling the C12 olefin-containing oligomerization product or fraction to the first catalytic conversion reaction device, and/or sending the C12 olefin-containing oligomerization product or fraction to a second catalytic conversion reaction device for a second catalytic conversion reaction to obtain a second reaction product comprising propylene.Type: GrantFiled: March 17, 2020Date of Patent: January 16, 2024Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Xuhui Bai, Yanfen Zuo, Youhao Xu, Yibin Luo, Xingtian Shu, Xieqing Wang, Xin Wang
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Patent number: 11845718Abstract: A process for producing para-xylene and ethylbenzene from C8 aromatics containing ethylbenzene includes the steps of sending C8 aromatics containing ethylbenzene to an ethylbenzene liquid-phase adsorption separation device, wherein a suction liquid containing ethylbenzene and a suction residual liquid are obtained after the adsorption separation, and the desorbents in the suction liquid and the suction residual liquid are removed to obtain ethylbenzene and a suction residual oil; sending the suction residual oil to a para-xylene adsorption separation device, and unadsorbed components are discharged as a raffinate from the adsorbent bed; the adsorbent bed is rinsed with a desorbent to desorb the para-xylene therein and obtain an extract; the desorbents in the extract and the raffinate are respectively removed to obtain para-xylene and a raffinate oil; sending the raffinate oil to a xylene isomerization device to carry out xylene isomerization, and the isomerization product is fractionated.Type: GrantFiled: September 28, 2020Date of Patent: December 19, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Yanqiang Yang, Dehua Wang, Huiguo Wang, Jianfeng Ma, Hongchao Wang, Ben Li, Yusi Liu, Xiaofei Qiao, Ningning Gao
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Patent number: 11787757Abstract: A phenol derivative of the present invention has a structure as represented by the formula (I): The functional groups are defined in the description. The phenol derivative can be used as the antioxidant in lubricating oil, lubricating grease, plastic, rubber, or can be used as the base oil of the lubricating oil and the lubricating grease and the antiwear additive of the lubricating oil and the lubricating grease.Type: GrantFiled: October 16, 2019Date of Patent: October 17, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Xiaowei Chen, Kecheng Wei, Yuxiang Liang
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Patent number: 11759726Abstract: A liquid phase alkylation product from an alkylation reaction unit is introduced into a first heat-exchanger directly or after being pressurized with a pressure pump and heat-exchanged with a vapor phase stream from the column top of a high-pressure fractionating column n, then introduced into a second heat-exchanger and further heated to 100° C.-150° C., then introduced into the high-pressure fractionating column and subjected to fractionation at 2.0 MPa-4.0 MPa, the vapor phase stream from the column top of the high-pressure fractionating column is heat-exchanged with the liquid phase alkylation product to be separated, a liquid phase stream from the column bottom of the high-pressure fractionating column is introduced into a low-pressure fractionating column and subjected to fractionation under at 0.2 MPa-1.Type: GrantFiled: September 6, 2019Date of Patent: September 19, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Qing Yuan, Junyi Mao, Zhenxing Zhu, Tao Huang, Zhihai Zhao, Yongxiang Li, Lifeng Hu, Xiaojin Tang
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Patent number: 11731922Abstract: A method for separating aromatic hydrocarbons by an extractive distillation, comprising introducing a hydrocarbon mixture containing aromatic hydrocarbons into the middle of an extractive distillation column (8); introducing an extraction solvent into the upper part of the extractive distillation column; after an extractive distillation, a raffinate containing benzene is discharged from the top of the column, wherein the benzene content is 3-40% by mass, and sent to the lower part of the extraction column (10); the extraction solvent is introduced to the upper part of the extraction column for a liquid-liquid extraction; a raffinate liquid free of aromatic hydrocarbons is discharged from the top of the extraction column; a rich solvent containing benzene is discharged from the bottom of the column and enters the upper-middle part of the extractive distillation column; the rich solvent obtained at the bottom of the extractive distillation column is sent to the solvent recovery column to separate the aromatic hType: GrantFiled: January 30, 2019Date of Patent: August 22, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Longsheng Tian, Ming Zhao, Wencheng Tang, Siliang Gao, Nan Yang, Zhifeng Bian, Siyuan Qie
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Patent number: 11691132Abstract: A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of P2O5, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, a gallium content of about 0.1% to about 2.5% by weight on the basis of gallium oxide, and a zirconium content of about 0.1% to about 2.5% by weight on the basis of zirconia; and the modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20% to about 40%.Type: GrantFiled: August 15, 2019Date of Patent: July 4, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Lingping Zhou, Qiuqiao Jiang, Shuai Yuan, Hao Sha, Mingde Xu, Zhenyu Chen, Weilin Zhang, Huiping Tian
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Patent number: 11655423Abstract: A process for separating an alkylation product includes introducing a liquid phase alkylation product from an alkylation reaction unit into a first heat-exchanger directly or after being pressurized with a pressure pump and heat-exchanged with a vapor phase stream from the column top of a high-pressure fractionating column, then into a second heat-exchanger and subsequently into the high-pressure fractionating column. The vapor phase stream from the column top of the high-pressure fractionating column is heat-exchanged with the liquid phase alkylation product to be separated, a liquid phase stream from the column bottom of the high-pressure fractionating column is introduced into a low-pressure fractionating column and subjected to fractionation under a condition of 0.2 MPa-1.0 MPa, a low-carbon alkane is obtained from the column top of the low-pressure fractionating column, and a liquid phase stream obtained from the column bottom of the low-pressure fractionating column is an alkylation oil product.Type: GrantFiled: September 6, 2019Date of Patent: May 23, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Qing Yuan, Junyi Mao, Zhenxing Zhu, Tao Huang, Zhihai Zhao, Yongxiang Li, Lifeng Hu, Xiaojin Tang
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Patent number: 11639474Abstract: A catalytic cracking process includes a step of contacting a cracking feedstock with a catalytic cracking catalyst in the presence of a radical initiator for reaction under catalytic cracking conditions. The radical initiator contains a dendritic polymer and/or a hyperbranched polymer. The dendritic polymer and the hyperbranched polymer each independently has a degree of branching of about 0.3-1, and each independently has a weight average molecular weight of greater than about 1000. The catalytic cracking process is beneficial to enhancing and accelerating the free radical cracking of petroleum hydrocarbon and promoting the regulation of cracking activity and product distribution; by using the process disclosed herein, the conversion of catalytic cracking can be improved, the yields of ethylene and propylene can be increased, and the yield of coke can be reduced.Type: GrantFiled: October 25, 2019Date of Patent: May 2, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Yibin Luo, Ying Ouyang, Enhui Xing, Xingtian Shu, Xiaojie Cheng, Genquan Zhu
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Patent number: 11624033Abstract: A process for the catalytic cracking of hydrocarbon oils includes the step of contacting a hydrocarbon oil feedstock with a catalytic cracking catalyst in a reactor having one or more fast fluidized reaction zones for reaction. At least one of the fast fluidized reaction zones of the reactor is a full dense-phase reaction zone, and the axial solid fraction ? of the catalyst is controlled within a range of about 0.1 to about 0.2 throughout the full dense-phase reaction zone. When used for catalytic cracking of hydrocarbon oils, particularly heavy feedstock oils, the process, reactor and system show a high contact efficiency between oil and catalyst, a selectivity of the catalytic reaction, an effectively reduced yield of dry gas and coke, and an improved yield of high value-added products such as ethylene and propylene.Type: GrantFiled: July 15, 2019Date of Patent: April 11, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Jianhong Gong, Zhigang Zhang, Xiaoli Wei
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Patent number: 11572283Abstract: A molecular sieve has a silica/alumina molar ratio of 100-300, and has a mesopore structure. One closed hysteresis loop appears in the range of P/P0=0.4-0.99 in the low temperature nitrogen gas adsorption-desorption curve, and the starting location of the closed hysteresis loop is in the range of P/P0=0.4-0.7. The catalyst formed from the molecular sieve as a solid acid not only has a good capacity of isomerization to reduce the freezing point, but also can produce a high yield of the product with a lower pour point. The process for preparing the catalyst involves steps including crystallization, filtration, calcination, and hydrothermal treatment.Type: GrantFiled: October 26, 2018Date of Patent: February 7, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Yunfei Bi, Guofu Xia, Mingfeng Li, Qinghe Yang, Weiguo Huang, Qingzhou Guo, Wenxiu Fang, Luqiang Wang, Hongbao Li, Honghui Li, Jie Gao
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Patent number: 11541377Abstract: A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.5 wt % by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO2/Al2O3 molar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%. The modified Y-type molecular sieve has a high crystallinity and a high thermal and hydrothermal stability, and is rich in secondary pores.Type: GrantFiled: August 20, 2019Date of Patent: January 3, 2023Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Hao Sha, Lingping Zhou, Shuai Yuan, Weilin Zhang, Zhenyu Chen, Mingde Xu, Huiping Tian
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Publication number: 20220403263Abstract: Described are a process and a system for processing aromatics-rich fraction oil. The process includes: (1) introducing an aromatics-rich fraction oil into a fifth reaction unit for hydrosaturation, followed by fractionation, to provide a first light component and a first heavy component; (2) introducing a deoiled asphalt and an aromatics-comprising stream including the first heavy component into a hydrogen dissolving unit to be mixed with hydrogen, and introducing the mixed material into a first reaction unit for a hydrogenation reaction; (3) fractionating a liquid-phase product from the first reaction unit to provide a second light component and a second heavy component; (41) introducing the second light component into a second reaction unit for reaction; and (42) introducing the second heavy component into a delayed coking unit for reaction; or using the second heavy component as a component of low sulfur ship fuel oil.Type: ApplicationFiled: October 30, 2020Publication date: December 22, 2022Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Qinghe YANG, Yanzi JIA, Dawei HU, Chuanfeng NIU, Shuling SUN, Lishun DAI, Zhen WANG, Anpeng HU, Liang REN, Dadong LI
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Patent number: 11529612Abstract: The present invention relates to the field of catalytic cracking, and discloses a composition capable of reducing CO and NOx emissions, the preparation method and use thereof, and a fluidized catalytic cracking method. The inventive composition capable of reducing CO and NOx emissions comprises an inorganic oxide carrier, and a first metal element, optionally a second metal element, optionally a third metal element and optionally a fourth metal element supported on the inorganic oxide carrier, wherein the first metal element includes Fe and Co, and wherein the weight ratio of Fe to Co is 1:(0.1-10) on an oxide basis. The inventive composition has better hydrothermal stability and higher activity of reducing CO and NOx emissions in the flue gas from the regeneration.Type: GrantFiled: July 5, 2018Date of Patent: December 20, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Haitao Song, Qiuqiao Jiang, Huiping Tian, Wei Lin, Peng Wang, Yan Sun, Xue Yang, Jiushun Zhang, Zhijian Da
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Patent number: 11524281Abstract: A phosphorus-containing molecular sieve has a phosphorus content of about 0.3-5 wt %, a pore volume of about 0.2-0.95 ml/g, and a ratio of B acid content to L acid content of about 2-10. The molecular sieve has a specific combination of characteristics, including a high ratio of B acid content to L acid content, thereby exhibiting higher hydrocracking activity and ring-opening selectivity when used in the preparation of a hydrocracking catalyst.Type: GrantFiled: October 22, 2018Date of Patent: December 13, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Yichao Mao, Mingfeng Li, Xiangyun Long, Runqiang Zhang, Yang Zhao
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Patent number: 11517887Abstract: A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of P2O5, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, and an active element content of about 0.1% to about 5% by weight on the basis of the oxide, with the active element being gallium and/or boron. The modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm of about 20% to about 40%; a lattice constant of about 2.440 nm to about 2.455 nm, and a lattice collapse temperature of not lower than about 1060° C.Type: GrantFiled: August 15, 2019Date of Patent: December 6, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Lingping Zhou, Hao Sha, Mingde Xu, Weilin Zhang, Shuai Yuan, Zhenyu Chen, Qiuqiao Jiang, Huiping Tian
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Patent number: 11518949Abstract: A process for producing propylene and a low-sulfur fuel oil component, comprising the steps of contacting a heavy feedstock oil with a solvent for extraction separation to obtain a deasphalted oil and a deoiled asphalt; contacting the deasphalted oil and optionally a light feedstock oil with a catalytic conversion catalyst for reaction to obtain a reaction product comprising propylene; separating the reaction product to obtain a catalytic cracking distillate oil, and subjecting the catalytic cracking distillate oil to hydrodesulfurization to obtain a low-sulfur hydrogenated distillate oil, wherein the low-sulfur hydrogenated distillate oil and/or the deoiled asphalt is suitable for use as a fuel oil component. The process allows the conversion of saturated hydrocarbons in the heavy feedstock into propylene, eliminates the use of saturated hydrocarbons in the fuel oil component, and thus has better economic and social benefits.Type: GrantFiled: October 26, 2020Date of Patent: December 6, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Youhao Xu, Xuhui Bai, Xinyu Xie, Shouye Cui, Xin Wang, Yanfen Zuo
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Patent number: 11517886Abstract: A modified Y-type molecular sieve has a modifying metal content of about 0.5-6.3 wt % calculated on the basis of an oxide of the modifying metal and a sodium content of no more than about 0.5 wt % calculated on the basis of sodium oxide. The modifying metal is magnesium and/or calcium. The modified Y-type molecular sieve has a proportion of non-framework aluminum content to the total aluminum content of no more than about 20%, a total pore volume of about 0.33-0.39 ml/g, a proportion of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 10-25%, a lattice constant of about 2.440-2.455 nm, a lattice collapse temperature of not lower than about 1040° C., and a ratio of B acid to L acid in the total acid content of no less than about 2.30.Type: GrantFiled: June 27, 2019Date of Patent: December 6, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Shuai Yuan, Lingping Zhou, Huiping Tian, Zhenyu Chen, Weilin Zhang, Hao Sha