Patents Assigned to Research Institute of Petroleum Processing, Sinopec
  • Patent number: 10144680
    Abstract: Disclosed is a process for producing light olefins. In the process for producing light olefins by continuously bringing an alkane feedstock and a catalyst into contact to subject to a dehydrogenation reaction, the reaction pressure P of the dehydrogenation reaction is made 0.6-2 MPa and the volume space velocity H of the dehydrogenation reaction is made 500-1000 h?1. The light olefins production process of the present invention is simple and continuous in operation and has the characteristics of low investment, significant increase in yield of light olefins and high safety.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: December 4, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Xin Wang, Jingchuan Yu, Minggang Li, Jianhong Gong, Baoning Zong, Youhao Xu
  • Patent number: 10130944
    Abstract: The present invention provides a rare earth-containing Y zeolite and a preparation process thereof, said rare earth-containing Y zeolite has a rare earth content as rare earth oxide of 10-25 wt %, a unit cell size of 2.440-2.472 nm, a crystallinity of 35-65%, a Si/Al atom ratio in the skeleton of 2.5-5.0; and a product of the ratio of the strength I1 of the peak at 2?=11.8±0.1° to the strength I2 of the peak at 2?=12.3±0.1° in the X-ray diffraction spectrogram of the zeolite and the weight percent of rare earth as rare earth oxide in the zeolite of higher than 48.
    Type: Grant
    Filed: June 27, 2013
    Date of Patent: November 20, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jinyu Zheng, Yibin Luo, Xingtian Shu
  • Patent number: 9993811
    Abstract: A process for preparing a catalytic cracking catalyst, which process comprises: a molecular sieve is introduced into a gas-phase ultra-stabilization reactor, the molecular sieve is moved without the conveying of carrier gas from a molecular sieve inlet of the gas-phase ultra-stabilization reactor to a molecular sieve outlet of the gas-phase ultra-stabilization reactor, and the molecular sieve is contacted and reacted with a gaseous SiCl4 in the gas-phase ultra-stabilization reactor, the molecular sieve resulting from the contacting and the reacting is optionally washed, then mixed with a matrix and water into slurry, and shaped into particles.
    Type: Grant
    Filed: October 25, 2013
    Date of Patent: June 12, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Ziyang Liu, Jiexiao Zhang, Mingde Xu, Weilin Zhang, Huiping Tian, Yuxia Zhu
  • Patent number: 9926243
    Abstract: The present invention relates to a process for separating isomers by simulated moving bed (SMB) adsorption, comprising separating the raw materials comprising isomers by SMB adsorption, said SMB comprising many adsorption beds each of which is equipped with grids, each of the grids being equipped with the feedstock inlet and outlet pipeline of the bed, the feedstock charged into and discharged from SMB at least comprising feedstocks, desorbent, extract, and raffinate, the extract being enriched with the target product, characterized in that the extract is used as a flushing liquid and respectively charged to first or second bed at the upstream of the feedstock charging position and to one of second to fourth beds at the downstream of the extract withdrawing position. Such process is used for separation of C8 aromatic isomers by adsorption, and can improve the capacity of the device while effectively increasing the purity of the target product separated by adsorption.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: March 27, 2018
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Dehua Wang, Zhuo Yu, Huiguo Wang, Jianfeng Ma
  • Patent number: 9895681
    Abstract: A process for preparing a catalytic cracking catalyst, which process comprises: a molecular sieve is introduced into a gas-phase ultra-stabilization reactor, the molecular sieve is moved without the conveying of carrier gas from a molecular sieve inlet of the gas-phase ultra-stabilization reactor to a molecular sieve outlet of the gas-phase ultra-stabilization reactor, and the molecular sieve is contacted and reacted with a gaseous SiCl4 in the gas-phase ultra-stabilization reactor, the molecular sieve resulting from the contacting and the reacting is optionally washed, then mixed with a matrix and water into slurry, and shaped into particles.
    Type: Grant
    Filed: October 25, 2013
    Date of Patent: February 20, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Mingde Xu, Jiexiao Zhang, Lingping Zhou, Weilin Zhang, Huiping Tian, Yuxia Zhu
  • Patent number: 9896343
    Abstract: The present invention relates to a titanium silicalite molecular sieve, wherein the crystal grain of the titanium silicalite molecular sieve has a ratio of (surface Si/Ti ratio):(bulk Si/Ti ratio) being larger than 1.1 and less than 5.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: February 20, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Changjiu Xia, Bin Zhu, Min Lin, Xinxin Peng, Xingtian Shu, Chunfeng Shi
  • Patent number: 9855552
    Abstract: The present invention relates to a metal modified Y zeolite, its preparation and use. Said zeolite contains 1-15 wt % of IVB group metal as oxide and is characterized in that the ratio of the zeolite surface's IVB group metal content to the zeolite interior's IVB group metal content is not higher than 0.2; and/or the ratio of the distorted tetrahedral-coordinated framework aluminum to the tetrahedral-coordinated framework aluminum in the zeolite lattice structure is (0.1-0.8):1.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: January 2, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Huiping Tian, Shanqing Yu, Zhenbo Wang
  • Patent number: 9782757
    Abstract: A modified Y-type molecular sieve has a unit cell size of 2.420-2.440 nm. It contains a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%, and a specific hydroxyl nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g. The modified Y-type molecular sieve is used as the active component in a catalytic cracking catalyst. The catalytic cracking catalyst maintains a stable activity for a long time, effectively controls the coke yield and increases the heavy oil utilization.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: October 10, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yibin Luo, Li Zhuang, Minggang Li, Ying Ouyang, Xingtian Shu
  • Patent number: 9771529
    Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock by contacting with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone among the reaction zones downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone, separating the spent catalyst from the reaction product vapor, regenerating the separated spent catalyst and returning the regenerated catalyst to the reactor, and separating the reaction product vapor to obtain the desired products, light olefins and aromatics. This process produces maximum light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.
    Type: Grant
    Filed: June 2, 2014
    Date of Patent: September 26, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jun Long, Zhijian Da, Dadong Li, Xieqing Wang, Xingtian Shu, Jiushun Zhang, Hong Nie, Chaogang Xie, Zhigang Zhang, Wei Wang
  • Patent number: 9694356
    Abstract: This disclosure describes a method for regenerating a semi-regenerated reforming catalyst. The method comprises adjusting the reaction temperature to 250-480° C., introducing a sulfur-containing naphtha into the reforming reactor, or stopping introducing a feedstock into the reforming reactor, and introducing a sulfur-containing hydrogen into a recycle gas, until the sulfur content in the catalyst is 0.32-0.8 mass %, then the catalyst is subject to coke-burning, oxychlorination and reduction. Alternatively, the method first subjects the spent catalyst to coke-burning followed by introducing sulfate ions thereinto; and then performing oxychlorination and reduction. Disclosed is still another method for regenerating a platinum-rhenium reforming catalyst, which comprises coke-burning the spent catalyst; introducing sulfur and chlorine in the catalyst by impregnation; and then drying, calcinating and reducing.
    Type: Grant
    Filed: March 25, 2016
    Date of Patent: July 4, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Daqing Zhang, Gaoshan Zang, Yuhong Zhang, Jiaxin Wang, Tao Wang
  • Patent number: 9656251
    Abstract: The present invention relates to a full-Si molecular sieve, wherein the full-Si molecular sieve has a Q4/Q3 of (10-90):1 wherein Q4 is the peak strength at the chemical shift of ?112±2 ppm in the 29Si NMR spectrum of the full-Si molecular sieve, expressed as the peak height relative to the base line; and Q3 is the peak strength at the chemical shift of ?103±2 ppm in the 29Si NMR spectrum of the full-Si molecular sieve, expressed as the peak height relative to the base line.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: May 23, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Xingtian Shu, Changjiu Xia, Min Lin, Bin Zhu, Xinxin Peng, Aiguo Zheng, Mudi Xin, Yanjuan Xiang, Chunfeng Shi
  • Patent number: 9656255
    Abstract: The present invention relates to a catalytic cracking catalyst and a preparation process thereof, the catalytic cracking catalyst has a cracking active component, an optional mesoporous aluminosilicate material, a clay and a binder, wherein said cracking active component comprises, substantially consists of or consists of: a rare earth-containing Y zeolite, an optional other Y zeolite, and an optional MFI-structured zeolite, said rare earth-containing Y zeolite has a rare earth content as rare earth oxide of 10-25 wt %, e.g. 11-23 wt %; a unit cell size of 2.440-2.472 nm, e.g. 2.450-2.470 nm; a crystallinity of 35-65%, e.g. 40-60%; a Si/Al atom ratio in the skeleton of 2.5-5.0; and a product of the ratio of the strength I1 of the peak at 2?=11.8±0.1° to the strength I2 of the peak at 2?=12.3±0.1° in the X-ray diffraction spectrogram of the zeolite and the weight percent of rare earth as rare earth oxide in the zeolite of higher than 48, e.g. higher than 55.
    Type: Grant
    Filed: June 27, 2013
    Date of Patent: May 23, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jun Long, Yuxia Zhu, Yibin Luo, Jinghui Deng, Jinyu Zheng, Fei Ren, Xue Yang, Ying Ouyang
  • Patent number: 9630171
    Abstract: The present invention discloses a catalytic cracking catalyst and a preparation process therefor. The catalytic cracking catalyst comprises a cracking active component, 10 wt %-70 wt % of a clay on the dry basis, and 10 wt %-40 wt % of an inorganic oxide binder (as oxide), relative to the weight of the catalytic cracking catalyst, wherein said cracking active component contains, relative to the weight of the catalytic cracking catalyst, 10 wt %-50 wt % of a modified Y-type zeolite on the dry basis and 0-40 wt % of other zeolite on the dry basis, wherein said modified Y-type zeolite is characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type zeolite, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxy nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g.
    Type: Grant
    Filed: June 27, 2013
    Date of Patent: April 25, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jun Long, Fei Ren, Yuxia Zhu, Yibin Luo, Jiasong Yan, Xue Yang, Huiping Tian, Li Zhuang, Beiyan Chen, Minggang Li, Ying Ouyang, Xiangtian Shu
  • Patent number: 9623403
    Abstract: A naphtha reforming catalyst, comprising an alumina support and following components with the content calculated on the basis of the support: VIII group metal 0.1-2.0% by weight, VIIB group metal 0.1-3.0% by weight, sulfate ion 0.45-3.0% by weight, and halogen 0.5-3.0% by weight. The catalyst is used in a naphtha reforming reaction without presulfurization and has a high aromatization activity and a selectivity.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: April 18, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Daqing Zhang, Gaoshan Zang, Yuhong Zhang, Jiaxin Wang, Tao Wang
  • Patent number: 9611432
    Abstract: The present invention provides a catalytic cracking catalyst, processing method and use thereof. When the catalyst is added into a commercial catalytic cracking unit, it has an initial activity of not higher than 80, preferably not higher than 75, more preferably not higher than 70, a self-balancing time of 0.1-50 h, and an equilibrium activity of 35-60. Said method enables the activity and selectivity of the catalyst in the catalytic cracking unit to be more homogeneous and notably improves the selectivity of the catalytic cracking catalyst, so as to obviously reduce the dry gas and coke yields, to sufficiently use steam and to reduce the energy consumption of the FCC unit.
    Type: Grant
    Filed: June 24, 2010
    Date of Patent: April 4, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Shouye Cui, Jun Long, Jianhong Gong, Zhijian Da, Jiushun Zhang, Yuxia Zhu, Yibin Luo, Jinlian Tang
  • Patent number: 9593290
    Abstract: This invention relates to a lubricating oil composition and production thereof. The lubricating oil composition comprises a Mannich base represented by the following formula (III) (wherein A and R2 are as defined in the specification) and a lubricant base oil. The lubricating oil composition according to this invention exhibits excellent cleansing and dispersing performance and excellent anticorrosion performance.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: March 14, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING SINOPEC
    Inventors: Shihao Xin, Xin Xie, Zuoxin Huang, Qinghua Duan, Zhiqiang Wu, Lihua Wang
  • Patent number: 9587198
    Abstract: This invention relates to a Mannich base, production and use thereof in producing a detergent. The Mannich base is represented by the following formula (III), wherein A and R2 are as defined in the specification. The Mannich base can be used to produce a detergent and a fuel oil composition exhibiting excellent deposit formation suppressing performance and excellent anticorrosion performance.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: March 7, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Shihao Xin, Qinghua Duan, Zuoxin Huang
  • Patent number: 9586895
    Abstract: A process for producing dimethyl sulfoxide, wherein said process comprises the following steps: (1) contacting hydrogen sulfide with methanol to produce a mixture containing dimethyl sulfide, and separating dimethyl sulfide from the mixture; and (2) in the presence or absence of a solvent, contacting dimethyl sulfide obtained in step (1) with at least one oxidant and a catalyst to produce a mixture containing dimethyl sulfoxide, said catalyst comprises at least one Ti—Si molecular sieve.
    Type: Grant
    Filed: October 29, 2013
    Date of Patent: March 7, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Chunfeng Shi, Min Lin, Xingtian Shu, Xuhong Mu, Bin Zhu
  • Patent number: 9580664
    Abstract: The present invention relates to a catalytic conversion process for improving the product distribution, characterized in that a feedstock oil of good quality is contacted with a hot regenerated catalyst having a lower activity in a reactor to carry out a cracking reaction, the reaction product is separated from the spent catalyst to be regenerated, then the reaction product is fed into a separation system, and the spent catalyst to be regenerated is stripped, regenerated and recycled in the process. The isobutene content in the liquefied petroleum gas (LPG) produced by the process is increased by a factor of more than 30%, and the olefin content in the gasoline composition may be increased to more than 30 wt. %. The product distribution is optimized, and the yields of dry gas and coke are decreased, so as to sufficiently utilize the petroleum resources.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: February 28, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Shouye Cui, Siwei Liu, Nan Jiang, Yinliang Liu
  • Patent number: 9561991
    Abstract: This invention relates to a process for co-producing cyclohexanol and alkanol, including a cyclohexene esterification step and a cyclohexyl ester hydrogenation step. This invention further relates to a process for further producing cyclohexanone or caprolactam, starting from the co-producing process, and an apparatus for co-producing cyclohexanol and alkanol. The process for co-producing cyclohexanol and alkanol of this invention is environment-friendly, with low production cost and highly improved atom economy.
    Type: Grant
    Filed: September 17, 2013
    Date of Patent: February 7, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Baoning Zong, Dongqiang Ma, Langyou Wen, Bin Sun, Keyong Yang