Patents Assigned to Research Institute of Petroleum Processing, Sinopec
  • Patent number: 11053129
    Abstract: A magnesium modified Y-type molecular sieve has a rare earth oxide content of about 4% to about 11% by weight, a magnesium oxide content of about 0.1% to about 4% by weight, a sodium oxide content of about 0.3% to about 0.8% by weight, a total pore volume of about 0.33 mL/g to about 0.39 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of the modified Y-type molecular sieve of about 10% to about 30%, a lattice constant of about 2.440 nm to about 2.455 nm, a percentage of non-framework aluminum content to the total aluminum content of the modified Y-type molecular sieve of no more than about 20%, and a lattice collapse temperature of not lower than about 1045° C.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: July 6, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
  • Patent number: 11052381
    Abstract: A modified Y-type molecular sieve has a rare earth oxide content of about 4% to about 12% by weight, a phosphorus content of about 0% to about 10% by weight, a sodium oxide content of no more than about 1.0% by weight, a total pore volume of about 0.36 to 0.48 mL/g, a percentage of the pore volume of secondary pores to the total pore volume of about 20% to about 40%, a lattice constant of about 2.440 nm to about 2.455 nm, a percentage of the non-framework aluminum content to the total aluminum content of no more than about 10%, a lattice collapse temperature of not lower than about 1060° C., and a ratio of Brønsted acid to Lewis acid of no less than about 3.50. The preparation of the molecular sieve includes ion-exchange with rare earth, hydrothermal roasting, gas phase ultra-stabilization, acid treatment, and an optional phosphorus modification.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: July 6, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
  • Patent number: 11041131
    Abstract: The present application relates to a process for treating gasoline, comprising the steps of: splitting a gasoline feedstock into a light gasoline fraction and a heavy gasoline fraction; optionally, subjecting the resulting light gasoline fraction to etherification to obtain an etherified oil; contacting the heavy gasoline fraction with a mixed catalyst and subjecting it to desulfurization and aromatization in the presence of hydrogen to obtain a heavy gasoline product; wherein the mixed catalyst comprises an adsorption desulfurization catalyst and an aromatization catalyst. The process of the present application is capable of reducing the sulfur and olefin content of gasoline and at the same time increasing the octane number of the gasoline while maintaining a high yield of gasoline.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: June 22, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Junyi Mao, Xin Wang, Qing Yuan, Jingchuan Yu, Hong Nie, Dadong Li
  • Patent number: 11028334
    Abstract: A gradient copolymer comprises or consists of n polymer components. The n polymer components each independently represents an addition polymer of a monomer of the formula (I), and/or a mixture thereof, or the n polymer components each independently comprises or consists essential of one or more structural units represented by the formula (I-1), The symbol n represents an integer within the closed interval [5, ?]. The average side chain carbon number of the i-th polymer component as determined according to the nuclear magnetic resonance method is expressed as Xi, with the symbol i representing an arbitrary integer from 1 to n, the relationship X1<X2< . . . <Xn?1<Xn holds.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: June 8, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yao Zhang, Qinghua Duan, Kecheng Wei, Yinong Liu, Hongwei Sun
  • Patent number: 10968313
    Abstract: The present invention relates to an amino polymer, its main chain is attached via a —O— group to a structure represented by the following formula (I). The present invention also relates to a process for producing said amino polymer and to its use as fuel oil detergent. Compared with the prior art, the fuel oil detergent of the present invention has the advantages such as a lower manufacturing cost and an improved deposit formation inhibition performance. In formula (I), groups and values are defined as described in the description.
    Type: Grant
    Filed: November 28, 2016
    Date of Patent: April 6, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Xin Cheng, Jianrong Zhang, Zuoxin Huang, Qinghua Duan
  • Patent number: 10961471
    Abstract: A process for producing catalytic cracking gasoline includes the following steps: i) subjecting a heavy feedstock oil to a catalytic cracking reaction in the presence of a first catalytic cracking catalyst to obtain a first reaction product; ii) subjecting a hydrogenated cycle oil to a catalytic cracking reaction in the presence of a second catalytic cracking catalyst to obtain a second reaction product; iii) separating a mixture of the first reaction product and the second reaction product to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iv) subjecting the catalytic cracking light cycle oil or a fraction thereof to hydrogenation to obtain a hydrogenated product; and v) recycling the hydrogenated product to the step ii) as the hydrogenated cycle oil.
    Type: Grant
    Filed: October 24, 2018
    Date of Patent: March 30, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jianhong Gong, Zekun Li, Jinlian Tang, Anguo Mao, Jiushun Zhang, Yuying Zhang, Jun Long
  • Patent number: 10907110
    Abstract: The present application relates to a process for treating gasoline, comprising the steps of: contacting a gasoline feedstock with a mixed catalyst and subjecting it to desulfurization and aromatization in the presence of hydrogen to obtain a desulfurization-aromatization product; optionally, splitting the resulting desulfurization-aromatization product into a light gasoline fraction and a heavy gasoline fraction; and, optionally, subjecting the resulting light gasoline fraction to etherification to obtain an etherified oil; wherein the mixed catalyst comprises an adsorption desulfurization catalyst and an aromatization catalyst. The process of the present application is capable of reducing the sulfur and olefin content of gasoline and at the same time increasing the octane number of the gasoline while maintaining a high yield of gasoline.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: February 2, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Youhao Xu, Yibin Luo, Xin Wang, Ying Ouyang, Zhijian Da, Xingtian Shu, Xieqing Wang
  • Patent number: 10888848
    Abstract: A catalytic cracking catalyst has a rare earth modified Y-type molecular sieve, an additive-containing alumina binder, and a clay. The rare earth modified Y-type molecular sieve has a rare earth oxide content of about 4-12 wt %, a phosphorus content of about 0-10 wt %, a sodium oxide content of no more than about 1.0 wt %, a total pore volume of about 0.36-0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%, a lattice constant of about 2.440-2.455 nm, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, a lattice collapse temperature of not lower than about 1060° C., and a ratio of B acid to L acid in the total acid content of the modified Y-type molecular sieve of no less than about 3.50.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: January 12, 2021
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
  • Patent number: 10822359
    Abstract: The present invention relates to a benzotriazole derivative, a preparation process thereof and the use thereof in preparation of the lubricating oil composition. The structure of the benzotriazole derivative of the present invention is shown by general formula (I). The benzotriazole derivative of the present invention, as the anti-wear additive for lubricating oil, not only has an excellent extreme pressure anti-wear property, but also has one or more excellent properties of thermal oxidation stability, corrosion resistance, rust resistance and anti-friction performance. In the general formula (I), each of the group(s) and the number(s) are defined as in the description.
    Type: Grant
    Filed: April 25, 2017
    Date of Patent: November 3, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Shuo Su, Jun Long, Qinghua Duan, Hui Zhang
  • Patent number: 10808188
    Abstract: A catalytic cracking process includes the following steps: i) subjecting a heavy feedstock oil to flail catalytic cracking; ii) separating the catalytic cracking reaction product obtained from step i) to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iii) splitting the catalytic cracking gasoline to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; iv) subjecting the catalytic cracking light cycle oil to hydrogenation to obtain a hydrogenated light cycle oil); v) mixing a portion of the light gasoline fraction with at least a portion of the hydrogenated light cycle oil to obtain a mixed fraction; vi) subjecting the mixed fraction to catalytic cracking; and vii) subjecting a portion of the medium gasoline fraction to flail catalytic cracking. The process is capable of producing more catalytic cracking gasoline, reducing the olefin content of the catalytic cracking gasoline, and increasing its octane number.
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: October 20, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jianhong Gong, Zekun Li, Jinlian Tang, Anguo Mao, Jiushun Zhang, Yuying Zhang, Jun Long
  • Patent number: 10737945
    Abstract: The present invention relates to a molecular sieve, particularly to an ultra-macroporous molecular sieve. The present invention also relates to a process for the preparation of the molecular sieve and to its application as an adsorbent, a catalyst, or the like. The molecular sieve has a unique X-ray diffraction pattern and a unique crystal particle morphology. The molecular sieve can be produced by using a compound represented by the following formula (I), wherein the definition of each group and value is the same as that provided in the specification, as an organic template. The molecular sieve is capable of adsorbing more/larger molecules, thereby exhibiting excellent adsorptive/catalytic properties.
    Type: Grant
    Filed: April 26, 2017
    Date of Patent: August 11, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yongrui Wang, Jincheng Zhu, Mingyi Sun, Xuhong Mu, Xingtian Shu
  • Patent number: 10737991
    Abstract: Disclosed is a process for producing light olefins, the process comprising: continuously contacting an oxygen-containing compound raw material with catalyst to have a dehydration reaction so as to prepare low-carbon alkene, the reaction pressure P of the dehydration reaction being 1-2 MPa, and the weight hourly space velocity H of the dehydration reaction being 15-50 h?1. The process of preparing light olefins has a simple and continuous operation process, reduces investment, greatly increases production of light olefins and has a high safety.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: August 11, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Shouye Cui, Youhao Xu, Jingchuan Yu, Minggang Li, Baoning Zong, Jinlian Tang, Xin Wang
  • Patent number: 10717939
    Abstract: Disclosed is a desulfurization catalyst for hydrocarbon oils, comprising a support and at least one metal promoter selected from the group consisting of cobalt, nickel, iron and manganese, the support comprising at least one metal oxide selected from the group consisting of oxides of Group IIB, Group VB and Group VIB metals and a refractory inorganic oxide, wherein the support further comprises at least about 5% by weight of vanadium carbide, based on the total weight of the desulfurization catalyst for hydrocarbon oils. The desulfurization catalyst for hydrocarbon oils shows a good stability, a high desulfurization activity, an excellent abrasion resistance, and a long service life. Also disclosed is a process for preparing the desulfurization catalyst for hydrocarbon oils, and use of the catalyst in the desulfurization of sulfur-containing hydrocarbon oils.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: July 21, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Wei Lin, Ye Song, Huiping Tian, Lei Wang, Jun Liu
  • Patent number: 10544372
    Abstract: The present invention relates to a method for obtaining a fraction oil yield from petroleum hydrocarbons in a distillation column, wherein said distillation column comprises a fractionation stage, a vaporization section and a stripping stage from the top to the bottom of the distillation column. The method comprises preheating and sending a feedstock oil of petroleum hydrocarbons through a pressure-feeding system at a pressure of 100-1000 kPa higher than the vaporization section pressure of the distillation column, wherein said preheating is conducted in a heating furnace, wherein said heating furnace has an outlet pressure of 100-1000 kPa higher than the vaporization section absolute pressure, and an outlet temperature of 360-460° C.
    Type: Grant
    Filed: April 15, 2011
    Date of Patent: January 28, 2020
    Assignees: RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Zhanzhu Zhang, Junyi Mao, Shuandi Hou, Ya Qin, Qing Yuan, Kejia Xu, Tongwang Zhang, Shaobing Wang, Hongliang Qu, Xiaojin Tang, Zhenxing Zhu, Tao Huang
  • Patent number: 10537882
    Abstract: A heteroatom-containing nano-carbon material, based on the total weight of said heteroatom-containing nano-carbon material and calculated as the elements, has an oxygen content of 1-6 wt %, a nitrogen content of 0-2 wt %, a carbon content of 92-99 wt %. In its XPS, the ratio of the oxygen content as determined with the peak(s) in the range of 531.0-532.5 eV to the oxygen content as determined with the peak(s) in the range of 532.6-533.5 eV is 0.2-0.8; the ratio of the carbon content as determined with the peak(s) in the range of 288.6-288.8 eV to the carbon content as determined with the peak(s) in the range of 286.0-286.2 eV is 0.2-1; the ratio of the nitrogen content as determined with the peak(s) in the range of 398.5-400.1 eV to the total nitrogen content is 0.7-1. The heteroatom-containing nano-carbon material shows a good catalytic capability in dehydrogenation of hydrocarbons.
    Type: Grant
    Filed: January 27, 2016
    Date of Patent: January 21, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Chunfeng Shi, Junfeng Rong, Peng Yu, Jingxin Xie, Mingsheng Zong, Weiguo Lin
  • Patent number: 10537878
    Abstract: A carbonaceous material, based on the total weight of the carbonaceous material, contains 1-99 wt % of a carbon element, 0.2-60 wt % of a magnesium element, 0.5-60 wt % of an oxygen element and 0.1-40 wt % of a chlorine element. The process for preparing the carbonaceous material include (1) Mixing a solid carbon source, a precursor and water to produce a mixture; wherein said precursor contains a magnesium source and a chlorine source; (2) Drying the resulting mixture obtained in Step (1) to produce a dried mixture; and (3) Calcining the dried mixture obtained in Step (2). The carbonaceous material can be used in catalytic oxidation of hydrocarbons.
    Type: Grant
    Filed: January 27, 2016
    Date of Patent: January 21, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Junfeng Rong, Chunfeng Shi, Jingxin Xie, Peng Yu, Mingsheng Zong, Weiguo Lin
  • Patent number: 10533154
    Abstract: The present invention provides a joint method of cultivating microalgae combined with denitrating an industrial waste gas and a system useful for the same. The joint method comprises the steps of: (1) a step of cultivating microalgae; (2) a separation step of separating a microalgae suspension obtained from step (1) into a wet microalgae (microalgae biomass) and a residual cultivation solution; (3) a NOx absorbing/immobilizing step of denitrating an industrial waste gas with the residual cultivation solution obtained from step (2); wherein the nutrient stream absorbed with NOx obtained from step (3) is used to provide nitrogen source to the microalgae cultivation of step (1). During the microalgae cultivation, EM bacteria is added into the microalgae suspension. The microalgae is preferably Chlorella sp., Scenedesmus sp., Monoraphidium sp. or Spirulina sp.
    Type: Grant
    Filed: March 17, 2015
    Date of Patent: January 14, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Junfeng Rong, Xuhua Zhou, Lin Cheng, Junying Zhu, Xugeng Huang, Baoning Zong
  • Patent number: 10526211
    Abstract: A method of producing a highly-pure aluminum hydroxide, comprising the following steps: (1) reacting alcohol with metal aluminum to produce aluminum alkoxide, then hydrolyzing the aluminum alkoxide with water to produce an aluminum hydroxide slurry and an alcohol, filtering the aluminum hydroxide slurry, washing a resulting filter cake with water to remove the alcohol trapped therein, and drying the filter cake after the water washing to produce an aluminum hydroxide powder, (2) sending the alcohol-containing water produced in step (1) to an alcohol extraction unit for separating water and alcohol through extraction, and sending the separated water back to step (1) for recycling, (3) dehydrating the hydrous alcohol produced by hydrolyzing the aluminum alkoxide in step (1) before using it as the raw materials for reacting metal aluminum with alcohol to produce aluminum alkoxide in step (1).
    Type: Grant
    Filed: July 21, 2017
    Date of Patent: January 7, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Yanpeng Yang, Aizeng Ma
  • Patent number: 10518219
    Abstract: A process for ion-exchanging an exchangeable-ion containing solid material, characterized in that said process include a bipolar membrane electrodialysis step, which comprises subjecting an aqueous ion-containing solution to a bipolar membrane electrodialysis to produce an acid liquid; an ion-exchange step, which comprises contacting the exchangeable-ion containing solid material with the acid liquid and conducting the ion-exchange to produce a slurry containing the ion-exchanged solid material; a solid-liquid separation step, which comprises subjecting the slurry containing the ion-exchanged solid material to a solid-liquid separation to produce a solid phase and a liquid phase, adjusting the liquid phase to a pH of 4-6.5, and subjecting the pH-adjusted liquid phase to a solid-liquid separation to produce a treatment liquid. Oxalic acid is used in at least one of the bipolar membrane electrodialysis step, the ion-exchange step, and the solid-liquid separation step.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: December 31, 2019
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Zhongqing Liu, Lina Zhou, Yibin Luo, Xingtian Shu
  • Patent number: 10399068
    Abstract: The present invention relates to an SCM-10 molecular sieve, a process for producing same and use thereof. The molecular sieve has an empirical chemical composition as illustrated by the formula “the first oxide·the second oxide”, wherein the ratio by molar of the first oxide to the second oxide is less than 40, the first oxide is at least one selected from the group consisting of silica and germanium dioxide, the second oxide is at least one selected from the group consisting of alumina, boron oxide, iron oxide, gallium oxide, titanium oxide, rare earth oxides, indium oxide and vanadium oxide. The molecular sieve has specific XRD pattern and can be used as an adsorbent or a catalyst for converting an organic compound.
    Type: Grant
    Filed: November 9, 2016
    Date of Patent: September 3, 2019
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Weimin Yang, Zhendong Wang, Hongmin Sun, Bin Zhang, Yi Luo