Patents Assigned to Rice University
  • Patent number: 9095876
    Abstract: In some embodiments, the present invention provides methods of immobilizing carbon nanotubes on a surface, wherein the method comprises: (1) mixing carbon nanotubes with a superacid to form a carbon nanotube solution; and (2) exposing the carbon nanotube solution to the surface. The exposing results in the immobilization of the carbon nanotubes on the surface. In some embodiments, the method occurs without the utilization of carbon nanotube wrapping molecules. Other embodiments of the present invention pertain to systems that comprise immobilized carbon nanotubes on a surface, as developed by the aforementioned methods.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: August 4, 2015
    Assignee: William Marsh Rice University
    Inventors: Angel A. Marti-Arbona, Avishek Saha, Matteo Pasquali
  • Publication number: 20150206314
    Abstract: Provided is an image processing apparatus including an image generation unit that, from photographic images that are captured using multiple photographic parameters, generates an image of which values of the multiple photographic parameters are different from values of the photographic image.
    Type: Application
    Filed: January 12, 2015
    Publication date: July 23, 2015
    Applicants: SONY CORPORATION, WILLIAM MARSH RICE UNIVERSITY
    Inventors: Atsushi ITO, Ashok VEERARAGHAVAN, Kaushik MITRA, Salil TAMBE
  • Publication number: 20150195088
    Abstract: Mechanisms for operating a prover device and a verifier device so that the verifier device can verify the authenticity of the prover device. The prover device generates a data string by: (a) submitting a challenge to a physical unclonable function (PUF) to obtain a response string, (b) selecting a substring from the response string, (c) injecting the selected substring into the data string, and (d) injecting random bits into bit positions of the data string not assigned to the selected substring. The verifier: (e) generates an estimated response string by evaluating a computational model of the PUF based on the challenge; (f) performs a search process to identify the selected substring within the data string using the estimated response string; and (g) determines whether the prover device is authentic based on a measure of similarity between the identified substring and a corresponding substring of the estimated response string.
    Type: Application
    Filed: January 3, 2014
    Publication date: July 9, 2015
    Applicant: WILLIAM MARSH RICE UNIVERSITY
    Inventors: Masoud Rostami, Mehrdad Majzoobi, Farinaz Koushanfar, Daniel S. Wallach, Srinivas Devadas
  • Publication number: 20150184232
    Abstract: In some embodiments, the present disclosure pertains to methods of monitoring dioxane biodegradation in an environment by: (1) exposing a sample from the environment to an oligonucleotide probe that targets at least one bacterial nucleotide sequence; (2) detecting the presence of the at least one bacterial nucleotide sequence in the sample from the environment; and (3) correlating the presence of the at least one bacterial nucleotide sequence to dioxane biodegradation in the environment. In some embodiments, the methods of the present disclosure can be used to determine whether monitored natural attenuation (MNA) of dioxane will occur in the environment. In some embodiments, the methods of the present disclosure can be used to determine whether dioxane decontamination is needed. Additional embodiments of the present disclosure pertain to oligonucleotide probes for monitoring dioxane biodegradation in an environment.
    Type: Application
    Filed: December 5, 2014
    Publication date: July 2, 2015
    Applicant: William Marsh Rice University
    Inventors: Mengyan Li, Jacques Mathieu, Pedro J. Alvarez
  • Patent number: 9067791
    Abstract: According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.
    Type: Grant
    Filed: April 23, 2007
    Date of Patent: June 30, 2015
    Assignee: WILLIAM MARSH RICE UNIVERSITY
    Inventors: Myung Jong Kim, Nolan Walker Nicholas, W. Carter Kittrell, Howard K. Schmidt
  • Patent number: 9068109
    Abstract: A method for the encapsulation and triggered-release of water-soluble or water-dispersible materials. The method comprises a) providing an amount of electrolyte having a charge, b) providing an amount of counterion having a valence of at least 2, c) combining the polyelectrolyte and the counterion in a solution such that the polyelectrolyte self-assembles to form aggregates, d) adding a compound to be encapsulated, and e) adding nanoparticles to the solution such that nanoparticles arrange themselves around the aggregates. Release of the encapsulated species is triggered by disassembly or deformation of the microcapsules though disruption of the charge interactions. This method is specifically useful for the controlled viscosity reduction of the fracturing fluids commonly utilized in the oil field.
    Type: Grant
    Filed: June 24, 2013
    Date of Patent: June 30, 2015
    Assignees: William Marsh Rice University, Halliburton Energy Services, Inc.
    Inventors: Rohit K. Rana, Vinit S. Murthy, Michael S. Wong, Lewis R. Norman
  • Patent number: 9061268
    Abstract: The invention generally relates to the ultrasmall MOx nanoparticles that are made in a solvothermal method using water soluble inorganic ammonium salt precursors of the MOx and organic amines, and slow heating to generate uniform ultrasmall MOx nanoparticles of 5 nm or less, as well as methods to make and use same.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: June 23, 2015
    Assignee: William Marsh Rice University
    Inventors: Nikolaos Soultanidis, Michael S. Wong
  • Publication number: 20150162381
    Abstract: Various embodiments of the resistive memory cells and arrays discussed herein comprise: (1) a first electrode; (2) a second electrode; (3) resistive memory material; and (4) a diode. The resistive memory material is selected from the group consisting of SiOx, SiOxH, SiOxNy, SiOxNyH, SiOxCz, SiOxCzH, and combinations thereof, wherein each of x, y and z are equal or greater than 1 or equal or less than 2. The diode may be any suitable diode, such as n-p diodes, p-n diodes, and Schottky diodes.
    Type: Application
    Filed: August 27, 2012
    Publication date: June 11, 2015
    Applicants: Nanyang Technological University, William Marsh Rice University
    Inventors: James M. Tour, Jun Yao, Jian Lin, Gunuk Wang, Krishna Palem
  • Publication number: 20150153472
    Abstract: Magnetic nanoparticles are utilized for magnetically detecting hydrocarbons in a geological structure. The magnetic nanoparticles generally include a core particle and a temperature responsive polymer associated with the core particle. The temperature responsive polymer may include polyacrylamides, polyethylene glycols, or combinations thereof. The temperature responsive polymer facilitates an agglomeration of the nanoparticles in a fluid at an organic/aqueous interface of the fluid, an organic phase of the fluid, or combinations thereof. The agglomeration may occur at a specific temperature or temperature range.
    Type: Application
    Filed: June 24, 2013
    Publication date: June 4, 2015
    Applicant: William Marsh Rice University
    Inventors: James M. Tour, Wei Lu, Chih-Chau Hwang
  • Patent number: 9045527
    Abstract: Methods for targeting a protein by providing an inhibitor covalently linked to a rhodium(II) complex, introducing the inhibitor to the target protein and allowing the inhibitor and protein to interact. The rhodium(II) complex covalently linked to the inhibitor binds the target protein both inorganically and organically and forms stabilizing secondary contacts between the rhodium(II) complex and the protein.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: June 2, 2015
    Assignees: WILLIAM MARSH RICE UNIVERSITY, TRUSTEES OF DARTMOUTH COLLEGE
    Inventors: Zachary T. Ball, Rituparna Kundu, Brian V. Popp, Dean R. Madden, Patrick R. Cushing
  • Publication number: 20150138549
    Abstract: A method of adjusting a resolution of a multidimensional imaging system includes taking a first hyperspectral snapshot by the multidimensional imaging system comprising a light processor comprising a plurality of optical fibers having a first end with an input spacing and a second end with an adjustable output spacing; adjusting the adjustable output spacing of the light processor to a new output spacing; and taking a second hyperspectral snapshot after adjusting the adjustable spacing of the multidimensional imagining system.
    Type: Application
    Filed: November 21, 2014
    Publication date: May 21, 2015
    Applicant: WILLIAM MARSH RICE UNIVERSITY
    Inventor: Tomasz S. Tkaczyk
  • Patent number: 9034085
    Abstract: A composition of matter, and method to make same, for a nano-based material including a nanocarbon support to which is attached an aliphatic amine. In particular, the composition of matter is an aliphatic amine-nanocarbon material that includes a nanocarbon (NC) support, such as C60, nano-graphite, graphene, nanocarbon ribbons, graphite intercalation compounds, graphite oxide, nano-coal, nanohorns, and combinations thereof, and further includes an aliphatic amine, such as polyethyleneimine (PEI).
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: May 19, 2015
    Assignee: WILLIAM MARSH RICE UNIVERSITY
    Inventors: Andrew R. Barron, Eoghan Dillon
  • Patent number: 9032731
    Abstract: A method for powering a cooling unit. The method including applying electromagnetic (EM) radiation to a complex, where the complex absorbs the EM radiation to generate heat, transforming, using the heat generated by the complex, a fluid to vapor, and sending the vapor from the vessel to a turbine coupled to a generator by a shaft, where the vapor causes the turbine to rotate, which turns the shaft and causes the generator to generate the electric power, wherein the electric powers supplements the power needed to power the cooling unit.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: May 19, 2015
    Assignee: William Marsh Rice University
    Inventors: Nancy J. Halas, Peter Nordlander, Oara Neumann
  • Publication number: 20150115159
    Abstract: In some embodiments, the present invention provides methods of detecting strain associated with an object by: (1) irradiating a composition that has been applied to the object, where the composition comprises semiconducting single-walled carbon nanotubes; (2) measuring an emission from the irradiated composition, where the emission comprises near infrared emission; and (3) correlating the near infrared emission to the presence or absence of strain associated with the object. In some embodiments, the aforementioned steps occur without physically contacting the object or the composition. In some embodiments, the aforementioned steps occur without utilizing Raman spectroscopy. Further embodiments of the present invention also include a step of applying the composition to the object.
    Type: Application
    Filed: March 14, 2013
    Publication date: April 30, 2015
    Applicant: William Marsh Rice University
    Inventors: R. Bruce Weisman, Paul A. Withey, Sergei M. Bachilo, Satish Nagarajaiah, Venkata Srivishnu M. Vemuru
  • Publication number: 20150108391
    Abstract: Various embodiments of the present disclosure pertain to methods of making magnetic carbon nanoribbons. Such methods generally include: (1) forming carbon nanoribbons by splitting carbon nanomaterials; and (2) associating graphene nanoribbons with magnetic materials, precursors of magnetic materials, or combinations thereof. Further embodiments of the present disclosure also include a step of reducing the precursors of magnetic materials to magnetic materials. In various embodiments, the associating occurs before, during or after the splitting of the carbon nanomaterials. In some embodiments, the methods of the present disclosure further comprise a step of (3) functionalizing the carbon nanoribbons with functionalizing agents. In more specific embodiments, the functionalizing occurs in situ during the splitting of carbon nanomaterials. In further embodiments, the carbon nanoribbons are edge-functionalized.
    Type: Application
    Filed: January 28, 2013
    Publication date: April 23, 2015
    Applicants: M-I L.L.C., William Marsh Rice University
    Inventors: James M. Tour, Bostjan Genorio, Wei Lu, Brandi Katherine Price-Hoelscher
  • Publication number: 20150111024
    Abstract: In some embodiments, the present disclosure pertains to methods of capturing a gas from an environment by associating the environment (e.g., a pressurized environment) with a porous carbon material that comprises a plurality of pores and a plurality of nucleophilic moieties. In some embodiments, the associating results in sorption of gas components (e.g., CO2 or H2S) to the porous carbon materials. In some embodiments, the methods of the present disclosure also include a step of releasing captured gas components from porous carbon materials. In some embodiments, the releasing occurs without any heating steps by decreasing environmental pressure. In some embodiments, the methods of the present disclosure also include a step of disposing released gas components and reusing porous carbon materials. Additional embodiments of the present disclosure pertain to porous carbon materials that are used for gas capture.
    Type: Application
    Filed: August 13, 2014
    Publication date: April 23, 2015
    Applicant: William Marsh Rice University
    Inventors: James M. Tour, Chih-Chau Hwang, Desmond E. Schipper
  • Publication number: 20150111018
    Abstract: In some embodiments, the present disclosure pertains to methods of capturing a gas from an environment by associating the environment with a porous carbon material that includes, without limitation, protein-derived porous carbon materials, carbohydrate-derived porous carbon materials, cotton-derived porous carbon materials, fat-derived porous carbon materials, waste-derived porous carbon materials, asphalt-derived porous carbon materials, coal-derived porous carbon materials, coke-derived porous carbon materials, asphaltene-derived porous carbon materials, oil product-derived porous carbon materials, bitumen-derived porous carbon materials, tar-derived porous carbon materials, pitch-derived porous carbon materials, anthracite-derived porous carbon materials, melamine-derived porous carbon materials, and combinations thereof. In some embodiments, the associating results in sorption of gas components (e.g., CO2, H2S, and combinations thereof) to the porous carbon material.
    Type: Application
    Filed: August 13, 2014
    Publication date: April 23, 2015
    Applicant: William Marsh Rice University
    Inventors: James M. Tour, Desmond E. Schipper, Chih-Chau Hwang, Josiah Tour, Almaz S. Jalilov, Gedeng Ruan
  • Patent number: 9005460
    Abstract: The present invention provides methods of selectively removing one or more graphene layers from a graphene material by: (1) applying a metal to a surface of the graphene material; and (2) applying a hydrogen containing solution to the surface of the graphene material that is associated with the metal. The hydrogen containing solution dissolves the metal along with one or more layers of graphene associated with the metal, thereby removing the layer(s) of graphene from the graphene material. In some embodiments, the hydrogen containing solution is an acidic solution, such as hydrochloric acid. In some embodiments, the metal is zinc. In some embodiments, the methods of the present invention are utilized to selectively remove one or more layers of graphene from one or more targeted sites on the surface of a graphene material.
    Type: Grant
    Filed: October 11, 2011
    Date of Patent: April 14, 2015
    Assignee: William Marsh Rice University
    Inventors: James M. Tour, Ayrat M. Dimiev, Dmitry V. Kosynkin
  • Patent number: 8992881
    Abstract: In various embodiments, the present disclosure describes processes for preparing functionalized graphene nanoribbons from carbon nanotubes. In general, the processes include exposing a plurality of carbon nanotubes to an alkali metal source in the absence of a solvent and thereafter adding an electrophile to form functionalized graphene nanoribbons. Exposing the carbon nanotubes to an alkali metal source in the absence of a solvent, generally while being heated, results in opening of the carbon nanotubes substantially parallel to their longitudinal axis, which may occur in a spiralwise manner in an embodiment. The graphene nanoribbons of the present disclosure are functionalized on at least their edges and are substantially defect free. As a result, the functionalized graphene nanoribbons described herein display a very high electrical conductivity that is comparable to that of mechanically exfoliated graphene.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: March 31, 2015
    Assignee: William Marsh Rice University
    Inventors: James M. Tour, Dmitry Kosynkin
  • Patent number: 8986737
    Abstract: A method of treating or preventing infection at a surgical site comprising a bony defect and an implanted metal device is disclosed. Biodegradable microspheres are placed at the site and are capable of near-linear controlled release of an antibiotic agent for a predetermined period of time. The microspheres are configured to be large enough to avoid being phagocytosed and removed from the body, and small enough in diameter to not physically inhibit bone growth at said bony defect site. The microspheres are formed of polylactic-co-glycolic acid (PLGA), with or without polyethylene glycol (PEG), and sufficient antibiotic agent to produce bactericidal levels in body tissues. The microspheres exhibit near-linear delivery of the antibiotic agent for at least 4 weeks at levels exceeding the minimum inhibitory concentration (MIC) for organisms commonly found to be the cause of infections, and facilitate bone ingrowth or regrowth at the site.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: March 24, 2015
    Assignees: Wm. Marsh Rice University, Board of Regents of the Univeristy of Texas System
    Inventors: Catherine G. Ambrose, Terry A. Clyburn, Antonio G. Mikos