Abstract: This invention relates to novel phosphoramidates of the formula: ##STR1## wherein R.sup.1 is hydrogen, alkyl, cycloalkyl, or optionally substituted aralkyl, aryl, pyridyl, pyridylmethyl, pyridylethyl or pyrazinyl;R.sup.2 is hydrogen provided R.sup.1 is other than optionally substituted aryl; alkyl; cycloalkyl; alkoxyalkyl; alkylthioalkyl; cyanoalkyl; alkenyl; optionally substituted aralylky; or optionally substituted aryl, provided R.sup.1 is other than hydrogen;R.sup.1 and R.sup.2 taken together with the nitrogen to which they are attached form an optionally substituted morpholino or piperidino group;R.sup.3 is hydrogen, alkyl, cycloalkyl, alkenyl, or optionally substituted aralkyl or aryl;R.sup.4 is (C.sub.1 -C.sub.6) alkyl;R.sup.5 is (C.sub.3 -C.sub.4) alkyl; andX, Y and Z are independently oxygen or sulfur;the agronomically acceptable metal salts and metal salt complexes thereof; and to methods of using them to control nematodes.
Type:
Grant
Filed:
March 1, 1976
Date of Patent:
March 31, 1981
Assignee:
Rohm and Haas Company
Inventors:
Harold E. Aller, Edward E. Kilbourn, Ernest D. Weiler, William D. Weir
Abstract: This invention relates to phenoxy, phenylthio, phenylsulfinyl and phenylsulfonyl substituted cyano aralkyl imidazoles and triazoles, their enantiomorphs, acid addition salts and metal salt complexes thereof as well as their methods of preparation and use as broad spectrum systemic fungicides useful in controlling phytopathogenic fungi.
Abstract: A process for preparing trifluoromethylphenyl nitro phenylethers which comprises treating a trifluoromethylhalobenzene with a base in a cosolvent system to afford a trifluoromethyl phenolate which may be isolated as its free phenol or reacted with an appropriately substituted halobenzene to afford a diphenylether herbicide or a precursor thereto.
Abstract: Ambient or low-temperature curable aqueous dispersions of (1) an emulsion polymer containing units polymerized from a monomer mixture of (a) from about 0.25% to about 10% by weight of a polymerizable aldehyde, (b) from about 0.5% to about 10% by weight of an ethylenically unsaturated carboxylic acid, and (c) up to about 99.25% by weight of at least one copolymerizable mono-ethylenically unsaturated monomer, with (2) a curing agent selected from the group of dicarboxylic acid bis-hydrazides and bis-hydrazones are disclosed. The dispersions are useful in leather treating compositions, especially in top coat compositions. A process for producing fully finished leather, or leather substitutes is also disclosed.
Abstract: Process for preparing cation exchange resin having macroreticular structure, high surface area and lowered apparent density from a macroreticulated copolymer produced by copolymerizing a mixture of a monoethylenically unsaturated monomer and a polyethylenically unsaturated monomer dissolved in an organic liquid which is a solvent for said monomers but unable to substantially swell the resulting copolymer, and macroreticulated cation exchange resin beads produced by the process.
Abstract: Stainless steel belts having a thickness of about 0.060 inch used for casting sheet materials such as acrylic plastic sheet are refurbished by first grinding the back surface of the belt until no further distortions can be removed and then grinding the mirrored surface of the belt until said mirrored surface is uniformly dull and thereafter polishing the dulled surface to a mirrored finish. During the grinding and polishing, the belt is cooled to avoid local overheating.
Abstract: Disclosed are inks containing compounds of the formula: ##STR1## where --R.sup.1 is --H or --CH.sub.3--R.sup.2 is an aliphatic, preferably linear hydrocarbyl, radical having 11-23 carbon atoms and containing at least one olefinic double bond, or mixtures thereof, --R.sup.2 being free of terminal double bonds, and--X-- is either (a) --OR.sup.3 O-- in which R.sup.3 is an aliphatic or cycloaliphatic hydrocarbon residue containing from 2 to 10 carbon atoms, or (b) --O(CH.sub.2 CHR.sup.4 O).sub.n -- where R.sup.4 is --H or --CH.sub.3 and n is an integer of from 2-10, or mixtures thereof.Preferably, --X-- is --OR.sup.3 O-- wherein R.sup.3 is --CH.sub.2 CH.sub.2 -- or ##STR2## --R.sup.1 is --CH.sub.3, and --R.sup.2 is a mixture of hydrocarbyl moieties derived from drying oils and is at least in part polyunsaturated, and more preferably, predominantly so.
Type:
Grant
Filed:
February 23, 1979
Date of Patent:
March 10, 1981
Assignee:
Rohm and Haas Company
Inventors:
William D. Emmons, Peter R. Sperry, Fred A. Kaplan
Abstract: Disclosed are inks containing compounds of the formula: ##STR1## where --R.sup.1 is --H or --CH.sub.3--R.sup.2 is an aliphatic, preferably linear hydrocarbyl, radical having 11-23 carbon atoms and containing at least one olefinic double bond, or mixtures thereof, -R.sup.2 being free of terminal double bonds, and--X-- is either (a) --OR.sup.3 O-- in which R.sup.3 is an aliphatic or cycloaliphatic hydrocarbon residue containing from 2 to 10 carbon atoms, or (b) --O(CH.sub.2 CHR.sup.4 O).sub.n -- where R.sup.4 is --H or --CH.sub.3 and n is an integer of from 2-10, or mixtures thereof.Preferably, --X-- is --OR.sup.3 O-- wherein R.sup.3 is --CH.sub.2 CH.sub.2 -- or ##STR2## --R.sup.1 is --CH.sub.3, and --R.sup.2 is a mixture of hydrocarbyl moieties derived from drying oils and is at least in part polyunsaturated, and more preferably, predominantly so.
Type:
Grant
Filed:
October 24, 1979
Date of Patent:
March 3, 1981
Assignee:
Rohm and Haas Company
Inventors:
William D. Emmons, Peter R. Sperry, Fred A. Kaplan
Abstract: Compositions having high notched Izod impact strength and Gardner VHIT impact value are achieved by blending polyglutarimides, multiple stage polymers based on butadiene or acrylates, and polycarbonate in a weight ratio such that the polycarbonate comprises about 12 to 25% of the blend.
Abstract: Disclosed is a process for treating and preserving a vinyl film substrate by applying thereto, followed by drying, a coating film of a polymer latex composition and an article produced thereby. The product article is characterized by an advantageous combination or balance of desirable properties including block resistance, surface tack, solvent resistance, plasticizer migration resistance, abrasion resistance, adhesion, and color stability.
Abstract: Disclosed herein are certain novel compounds which are most properly designated as 3-isothiazolones. These compounds and compositions containing them exhibit a broad spectrum of biocidal properties and are particularly effective for the control of microorganisms.
Type:
Grant
Filed:
December 10, 1979
Date of Patent:
February 24, 1981
Assignee:
Rohm and Haas Company
Inventors:
Sheldon N. Lewis, George A. Miller, Andrew B. Law
Abstract: Insecticidal compositions which comprise an O-ethyl S-n-propyl O-halophenyl phosphorothiolate can be safened by adding to the compositions a safening amount of toxaphene (octochlorocamphene) or DDT. These safened compositions are particularly useful in controlling insects in growing cotton crops.
Abstract: Addition polymers containing a plurality of terminal and/or pendant amine groups in which the nitrogen atom of at least some of such groups is of primary or secondary character, or aldimine or ketimine groups form the main film-forming component in compositions for coating and the like purposes, which also contain a polyfunctional acrylic monomer, such as ethylene glycol diacrylate, with or without monoethylenically unsaturated acrylic ester. Such compositions provide durable films having excellent mechanical and resistance properties even on ambient curing though baking may be used to accelerate the cure. A method of use is also claimed in which the components are mixed in suitable vehicles, e.g.
Abstract: Novel membranes having two or more coatings of polyelectrolytes with at least one oppositely charged adjacent pair of coatings separated by a neutral layer to reduce charge neutralization, their method of preparation, and use for rejecting ionically charged solutes.
Abstract: This invention relates to vinylbenzyl and crosslinking bis-(vinylbenzyl) monomers for use in the preparation of polymers, especially ion exchange resins, and to methods for the preparation of the monomers and polymers. It is particularly concerned with the preparation, polymerization, and use of new nitrogenous monomers as crosslinking agents and/or function-introducing agents.
Abstract: Crosslinked basic polymers useful as anion exchange resins are prepared by reacting a crosslinked vinyl aromatic polymer containing haloalkyl groups with a methylquinoline compound in an alkaline medium.
Abstract: Novel oxazoline-containing monomers represented by the formula ##STR1## wherein: n is an integer of from 1 through 20:R.sub.1 is selected from the group consisting of hydrogen and methyl; andR.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are independently selected from the group consisting of hydrogen and alkyl of from 1 through 20 carbon atoms;polymers thereof, and methods for preparing the same are disclosed.The hydrocurable polymers of the invention, before hydrolysis, contain a plurality of units represented by the following formula: ##STR2## Polymers having such units may be obtained by addition polymerization of monomers of structure I, preferably with other ethylenically unsaturated monomers.
Type:
Grant
Filed:
April 11, 1979
Date of Patent:
January 27, 1981
Assignee:
Rohm and Haas Company
Inventors:
R. Larry Reitz, Thomas W. Hutton, Sheldon N. Lewis
Abstract: Impure sugar solutions containing charged particulate impurities are treated with strongly basic emulsion anion exchange resin particles to form flocs of the charged particulate impurities and the resin particles. These flocs remove dissolved ionic impurities because of their ion exchange functionality, and also remove color-imparting impurities.