Abstract: Polymers of esters of acrylic acid having an average chain length of about 6 to about 30 mers are prepared by an anionic polymerization reaction, carried out in the presence of a catalytic amount of an alkoxide anion. These polymers, their hydrolysis products, and their derivatives have a wide variety of applications, including among others use as components in films, coatings, fibers, impregnants, adhesives, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.
Abstract: Polymers containing imide units and a process of imidizing acrylic polymers to any desired degree of imidization without the use of added water or solvent.
Abstract: Hard, infusible, discrete beads of crosslinked copolymer are prepared by free-radical catalyzed polymerization of a monomer mixture in aqueous dispersion wherein a minor amount of a modifier, specifically an organic compound containing acetylenic or allylic unsaturation having the ability to moderate the rate of polymerization, is incorporated in the monomer mixture. Ion exchange resins having improved mechanical strength are obtained by attaching functional groups to the copolymer.
Type:
Grant
Filed:
May 8, 1978
Date of Patent:
January 20, 1981
Assignee:
Rohm and Haas Company
Inventors:
Thomas J. Howell, William G. Paterson, Ian Pattison
Abstract: The method of modifying latex paints for maintenance paint applications, primarily on iron or steel industrial and transportation structures, in order to provide both short term and long term corrosion resistance, and the resulting composition, are described. Two types of corrosion encountered in painting ferrous surfaces with latex paint are: (1) flash rusting which occurs as a result of contact with the water from the latex and results in rust bleed-through at the time the paint is drying, and (2) rust bleeding, which may occur over a period of months or years. It has now been found that the benefits of both water soluble corrosion inhibitors, for preventing flash rusting, and water insoluble corrosion inhibitors, for minimizing blistering and rust bleeding, are achieved by utilizing a soluble complex of a polyvalent metal, a volatile complexing agent, and a corrosion inhibiting anion. This complex may be represented by the formulaM(Z).sub.
Abstract: The method of modifying latex paints for maintenance paint applications, primarily on iron or steel industrial and transportation structures, in order to provide both short term and long term corrosion resistance, and the resulting composition, are described. Two types of corrosion encountered in painting ferrous surfaces with latex paint are: (1) flash rusting which occurs as a result of contact with the water from the latex and results in rust bleed-through at the time the paint is drying, and (2) rust bleeding, which may occur over a period of months or years. It has now been found that the benefits of both water soluble corrosion inhibitors, for preventing flash rusting, and water insoluble corrosion inhibitors, for minimizing blistering and rust bleeding, are achieved by utilizing a soluble complex of a polyvalent metal, a volatile complexing agent, and a corrosion inhibiting anion. This complex may be represented by the formulaM(Z).sub.
Abstract: Described herein is a pigment paste for use in an aqueous paint comprising a film-forming latex polymer, a pigment and a dispersant copolymer. Also described is the dispersant copolymer which serves the function of dispersing the pigment in the preparation of the paste and maintaining the dispersion in the paste and paint made therefrom. The dispersant copolymer is such that its complex salt formed with Zn++ and ammonia is water-soluble at a pH of 9.6. The dispersant is a copolymer of an .alpha.,.beta.-unsaturated monovinylidene carboxylic acid and at least one other ethylenically unsaturated monomer. The dispersant is particularly adapted to preparing paste for difficult-to-formulate paints such as paints with reactive pigments and paints requiring high levels of dispersant.
Abstract: Disclosed herein are certain novel compounds which are most properly designated as 3-isothiazolones. These compounds and compositions containing them exhibit a broad spectrum of biocidal properties and are particularly effective for the control of microorganisms.
Type:
Grant
Filed:
May 30, 1978
Date of Patent:
January 6, 1981
Assignee:
Rohm and Haas Company
Inventors:
Sheldon N. Lewis, George A. Miller, Andrew B. Law
Abstract: 2-Imino substituted isothioureidobenzene products useful as anthelmintics and fungicides are disclosed. The products may be prepared by several different methods including treating a 2-iminothioureidobenzene with a base and either an organic halide, a diester of sulfuric acid or a diester of sulfurous acid or treating a 2-aminoisothioureidobenzene with an appropriately substituted aldehyde.
Abstract: Metal salt complexes of 3-isothiazolones and compositions containing them exhibit useful biocidal properties, including bactericidal, fungicidal, and algaecidal properties.
Abstract: This invention relates to solid nonionic crosslinked resins containing amine or phosphine borane adducts and their use as reducing agents for metal ions.
Abstract: A method for removing cumene vapor from a cumene-containing vapor stream comprises passing the vapor stream through a bed of a substantially dry hydrophobic, macroreticular, water-insoluble, crosslinked polymer containing from 20% to 100% by weight of the polymer, of divinylbenzene or a copolymer of divinylbenzene, the balance being ethylvinylbenzene or styrene or mixtures thereof but not more than 50% of either ethylvinylbenzene or styrene, until the capacity of the polymer or copolymer to remove cumene is substantially exhausted. Thereafter, the cumene is desorbed from the mass or bed of the polymer or copolymer by passing steam through said mass or bed. Without drying, the mass or bed is then ready for reuse.
Abstract: This invention relates to a novel process for the preparation of 4H-substituted-1,2,4-triazoles. In this process, 4H-substituted-1,2,4-triazoles are prepared by the reaction of an amine with hydrazine and a nitrile.
Abstract: Compounds of the formula ##STR1## wherein R.sup.1 is alkyl,R.sup.2 is carboxy, carboxylate, or carbalkoxyR.sup.3 is hydrogen or alkyl,R.sup.4 is hydrogen, alkyl, or halogen andR.sup.5 is optionally substituted aryl,are active as plant growth regulators, and particularly as chemical gametocides.
Abstract: This application discloses a composition and a method for catalyzing and crosslinking of a polyepoxy compound and an acrylic resin containing carboxylic acid groups, the catalyst being in the form of a metal chelate, particularly of manganese, zinc or chromium. The compositions, when substantially freed of volatile solvent and adjusted to a viscosity resembling that of gunnable caulking compositions, are particularly well adapted as a replacement for the metallic body solder used in automobile manufacture to fill out imperfections, welded joints and the like, when applied thereto and cured.
Abstract: This disclosure describes novel aralkyl imidazoles, their acid addition salts, their metal complex salts and processes for their preparation. These compounds possess biological activity and in particular are useful as systemic protectant/eradicant fungicidal agents for controlling plant diseases caused by fungi and as plant growth regulators. The metal complex salts of these compounds are particularly useful in their ability to reduce undesirable plant growth regulatory activity and phytotoxicity while retaining their ability for controlling plant diseases caused by fungi.
Abstract: An effective amount of a vinylbenzyltrialkylammonium salt, prepared from a vinylbenzyl halide and a tertiary amine, is polymerized with various other monomers to afford stable latex polymers which have the latex stabilizing surfactant incorporated into the polymer backbone. The use of a vinylbenzyltrialkylammonium salt lessens or avoids the usual problems associated with the conventional anionic, nonionic or cationic emulsifiers employed in aqueous polymerizations. The copolymers prepared with the quaternary ammonium compounds are useful as sizing agents, as extender/binders for cationic water repellents; in addition, the polymers are depositable on pulp without requiring any deposition aids or defoamers.
Abstract: This invention relates to liquid adhesive and/or sealing compositions capable of hardening or curing under exclusion of oxygen comprising dicyclopentenyloxyethyl acrylate and/or methacrylate and an organic peroxy compound having 3 to 18 carbon atoms selected from the group consisting of organic peroxides and organic hydroperoxides, preferably the latter, and an imide or amine accelerator.
Abstract: This invention relates to novel anthelmintic compounds containing an arylene or divalent heterocyclic ring whose free valences are satisfied by(1) a disubstituted phosphoryl ureido or thioureido group and(2) an amino group or a substituted amido or thioamido group,to compositions containing them, and to methods of using them for the treatment of intestinal parasites in mammals and birds.
Abstract: Novel 3-pyridylmethyl N-(4-substituted-phenyl)thiocarbamates are disclosed. These compounds are useful as single-dose rodenticides, which have high baitacceptance.
Type:
Grant
Filed:
January 31, 1979
Date of Patent:
November 11, 1980
Assignee:
Rohm and Haas Company
Inventors:
Edward E. Kilbourn, Ernest D. Weiler, William D. Weir
Abstract: The specification discloses a polymer and the method of using the same to prepare articles of manufacture, the composition comprising a water-soluble salt of a polymer containing pendant groups derived from an unsaturated drying oil fatty acid hydroxyamide, carboxy groups, carboxy ester groups and optionally the residues of other unsaturated addition polymerizable monomers, the carboxy units being present in a critical amount and the polymer having a critical glass transition temperature, molecular weight and the like. Aqueous coating compositions are disclosed in which the soluble polymer is either the sole polymeric vehicle or is combined with a water-insoluble polymer latex.