Abstract: Systems and methods for separating a mixture comprising C4 hydrocarbons and a solvent have been disclosed. The mixture is produced as a bottom stream of a rectifier column. The mixture is processed in at least two heating and flash-evaporating cycles to remove at least some C4 hydrocarbons as vapor streams. The resulted liquid stream is further degassed in a degasser column to produce a recycle vapor stream and a lean solvent stream.

Abstract: A fertilizer granule containing a core containing a plant nutrient; and a coat containing 55 wt. % to 90 wt. % of a poly butylene succinate adipate (PBSA), 10 wt. % to 45 wt. % of a second polymer selected from poly lactic acid (PLA), poly butylene succinate (PBS), or a combination or blend of PLA and PBS, and 0 wt. % to 30 wt. % of a wax based on the total weight of the coat, the coat forming a coating on an outer surface of the core and methods of making and using the fertilizer granule. Also a coating composition containing 55 wt. % to 90 wt. % of a PBSA and 10 wt. % to 45 wt. % of a second polymer selected from PLA, PBS, or a combination or a blend of PLA and PBS, and 0 wt. % to 30 wt. % of a wax.

Abstract: The present invention relates to a process for the continuous preparation of a polyolefin from one or more ?-olefin monomers in a reactor system, the process for the continuous preparation of polyolefin comprising the steps of: +feeding a polymerization catalyst to a fluidized bed through an inlet for a polymerization catalyst; +feeding the one or more monomers to the reactor, +polymerizing the one or more monomers in the fluidized bed to prepare the polyolefin; +withdrawing polyolefin formed from the reactor through an outlet for polyolefin; +withdrawing fluids from the reactor through an outlet for fluids and transporting the fluids through first connection means, an heat exchanger to cool the fluids to produce a cooled recycle stream, and through second connection means back into the reactor via an inlet for the recycle stream; wherein a thermal run away reducing agent (TRRA) is added to the reactor in a discontinuous way.

Abstract: A polyethylene composition having increased environmental stress crack resistance (ESCR) is comprised of a polymer blend of a high density polyethylene (HDPE) and polyethylene glycol (PEG). The PEG is present in the polymer blend in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The PEG may have an average molecular weight of from 2000 to 40,000. In a method of forming a polyethylene composition having increased ESCR, a HDPE is modified by combining the HDPE with PEG in a polymer blend, the PEG being present in an amount of from 0.5 wt. % to 15 wt. % by total weight of the polymer blend. The polymer blend can be formed into an article of manufacture, such as a bottle cap.

Abstract: A process for producing light alkanes and creating a flexible distribution system for those alkanes and related systems are disclosed. The process can include supplying a butane feed stream to a butane conversion unit to produce a light alkane output stream including at least methane, ethane, propane, and hydrogen, separating at least part of the light alkane output stream into separate streams of methane, ethane, and propane and distributing the separated streams as desired. The distribution of the separated streams can include sending the separated ethane and propane streams to downstream processing units which use them as feedstock. The butane containing feed and/or unreacted butane feed can include isobutane, which can be converted to n-butane and then further processed.

Abstract: The present invention relates to a semi-crystalline functionalized olefin copolymer composition and a process for the preparation of a semi-crystalline functionalized olefin copolymer composition.

Abstract: A plastic glazing of a window of a vehicle having a light feature includes a first vehicle window glazing component, a second vehicle window glazing component molded onto the first vehicle window glazing component, and a light unit configured to produce light for the light feature. The light unit being integrated with at least one of the following: the first vehicle window glazing component and the second vehicle window glazing component. The light unit further configured to direct the light for the light feature through or from at least one of the following: the first vehicle window glazing component and the second vehicle window glazing component. The plastic glazing is a one-piece molded plastic construction. At least one of the first vehicle window glazing component and the second vehicle window glazing component is translucent or transparent.

Abstract: A multilayer supported oxidative coupling of methane (OCM) catalyst composition (alpha-Al2O3 support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/alpha-Al2O3; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts alpha-Al2O3 support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.

Abstract: Systems and methods for processing crude methanol are disclosed. A crude methanol stream, comprising methanol and paraffin wax, is produced from syngas (carbon monoxide, carbon dioxide, and hydrogen). The crude methanol stream is cooled to form a partially condensed crude methanol stream, which is further separated in a vapor-liquid separator to form a liquid stream and a gas stream. The liquid stream is further cooled in a dewaxing unit to remove paraffin wax. The dewaxing unit includes two or more cooling units arranged in parallel such that when one of the cooling units is offline for cleaning, the methanol system does not need to be shut down.

Abstract: Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is separated to remove propane from C4 hydrocarbons. The resulting C4 hydrocarbons are then processed in an isomerization unit to produce additional isobutane. The isobutane of the isomerization unit effluent is dehydrogenated in a dehydrogenation unit to produce isobutene. The resulting isobutene is reacted with an alkanol to produce an alkyl tert-butyl ether.

Abstract: A multilayer film that includes at least a first polymeric layer comprising a polyolefin-based polymer and a second polymeric layer comprising a blend of a polar polymer and a silicon (Si) containing material comprising a silane having at least one alkyl group having at least 6 carbon atoms (C6) is disclosed. Methods of using and making the multilayer film is also disclosed.

Abstract: A method of reducing color in an alkanolamine is described. The method includes contacting the alkanolamine with a color-reducing amount of a borane complex effective to provide a color-reduced alkanolamine composition having a Platinum-Cobalt Color Value, according to Test Method ASTM D1209, of less than 50.

Abstract: A method for upgrading mixed pyrolysis oil may include contacting the mixed pyrolysis oil with hydrogen in the presence of a mixed metal oxide catalyst at reaction conditions to produce a reaction effluent including light aromatic compounds. The mixed pyrolysis oil includes multi-ring aromatic compounds and is formed from light pyrolysis oil and heavy pyrolysis oil at a ratio of 10:90 to 40:60 with light pyrolysis oil representing a bottom stream of a gas steam cracker and heavy pyrolysis oil representing a bottom stream of a naphtha steam cracker. The mixed metal oxide catalyst includes a plurality of catalyst particles with each catalyst particles including a plurality of metal oxides. An associated system for upgrading mixed pyrolysis oil may include a pyrolysis upgrading unit housing the mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from the reaction effluent.

Abstract: Methods for producing solid acidic fertilizer granules, solid acidic fertilizer granules, and methods for their use in fertigation, are disclosed. The method can include providing a plant nutrient containing nitrogen (N), phosphorus (P) and optionally potassium (K), in a container; feeding an acid solution containing an inorganic acid into the container at a feeding rate comprising an average feed rate of 0.2 to 0.8 metric ton of the inorganic acid (MTacid) per hour per metric ton of the plant nutrient (MTnutrient) (MT acid.h?1.MT nutrient?1) and contacting the inorganic acid and the plant nutrient to obtain acidified granules with average moisture content of 0.5 wt. % to 1.0 wt. %; and drying the acidified granules to obtained dried acidic granules.

Abstract: Systems and methods for producing MTBE without using a catalytic distillation column or a super fractionator have been disclosed. An optimum volume of methanol stream required to maximize MTBE production and reduce slippage of isobutylene to minimum acceptable values together with a crude C4 stream are flowed into a primary reaction unit that comprises a first reactor and a second reactor in parallel configured to produce maximum values of final MTBE volumes under higher or equal established purity commercial quality specifications levels. The combined effluent from the first reactor and the second reactor is split to form a first portion, a second portion and a third portion. The first portion is flowed to a third reactor configured to produce additional MTBE. The second portion is combined with an effluent from the third reactor for further separation. The third portion is recycled to the first reactor and/or second reactor.

Abstract: Systems and methods for recovering cyclopentadiene and/or isoprene from a mixture comprising C5 hydrocarbons are disclosed. A C5 mixture comprising cyclopentadiene and/or isoprene is flowed into a dimerization unit to form dimers. The dimers are then separated from the unreacted C5 hydrocarbons. The separated dimers are monomerized to form a stream comprising cyclopentadiene and/or isoprene, which is subsequently separated to form a first product stream comprising primarily isoprene and a second product stream comprising primarily cyclopentadiene.

Abstract: Catalysts for the hydrogenation of aromatic containing polymers are described. Such a catalyst can include, based on the total weight of the catalyst, 99.1 wt. % to 99.95 wt. % of a metal oxide support, and 0.05 wt. % to 0.9 wt. % of catalytic metal nanoparticles comprising platinum (Pt), palladium (Pd), ruthenium (Ru), any combination thereof, or alloy thereof. The catalyst can have a specific surface area of 5 m2/g to 80 m2/g, a pore volume of 0.01 cm3/g to 0.35 cm3/g, and a catalyst median particle size of less than 300 microns. Processes to produce the catalyst and methods of hydrogenating aromatic containing polymers are also described.

Abstract: Systems and methods for processing a C3 and C4 hydrocarbon mixture have been disclosed. The C3 and C4 hydrocarbon mixture is first processed in an isomerization unit to isomerize n-butane to form isobutane. The resulting effluent stream from the isomerization unit comprising primarily isobutane and C3 hydrocarbons, collectively, is flowed into a separation unit configured to separate the effluent stream to form a C3 stream comprising C1 to C3 hydrocarbons and a C4 stream comprising primarily isobutane. The isobutane in the C4 stream is further dehydrogenated to form isobutene, which is further flowed into an MTBE synthesis unit as a feedstock for producing MTBE.

Abstract: A method for processing pentanes obtained from a DIB unit is disclosed. The process can include separating a first stream containing pentanes obtained from a DIB unit, in a separation column to obtain a second stream comprising iso-pentane and a third stream comprising n-pentane and neo-pentane; and subjecting the third stream to a butane isomerization unit producing a fourth stream containing iso-pentane, n-pentane, and neo-pentane.

Abstract: A composition includes particular amounts of a poly(phenylene ether); a poly(alkylene terephtalate); a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene; a compatibilizing agent; an arc suppressant comprising a nitrogen-containing compound, a phosphorus-containing compound, or a combination thereof; glass fiber, a mineral filler; and poly(tetrafluoroethylene). The composition can be particularly useful for use in molded circuit breakers.