Patents Assigned to Saint-Gobain Centre de Recherches et d'Etudes
  • Patent number: 11964900
    Abstract: Fused tuckstone defining lower and upper surfaces. The lower surface includes a support surface to rest on metallic structure of a glass furnace, a tank surface intended to face an upper edge of a tank of the furnace, and a lower transition surface connecting the support and tank surfaces. The upper surface includes a superstructure surface to receive a side wall of a superstructure of the furnace and an upper transition surface connecting the superstructure and lower surfaces. At least a part of the lower transition surface has a crystal density of more than four times the crystal density at a depth of 4 centimeters below the lower transition surface, a crystal density being evaluated by the number of crystals having a surface area of more than 12 ?m2 per mm2 of surface after polishing, the crystal density at the depth being evaluated after cutting of the tuckstone.
    Type: Grant
    Filed: December 19, 2018
    Date of Patent: April 23, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Pierrick Vespa
  • Patent number: 11951592
    Abstract: Shot-peening powder that has ceramic particles. The powder having more than 95% by mass of beads. The beads having a median size D50 greater than 50 ?m and less than 1200 ?m, and having a value (D90?D10)/D50, or “S”, such that S??0.126·ln(D50)+0.980.
    Type: Grant
    Filed: May 28, 2019
    Date of Patent: April 9, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Julien Cabrero, Anne-Laure Beaudonnet, Yves Léon Marcel Boussant-Roux, Benjamin Gilbert Robert Levy
  • Patent number: 11932568
    Abstract: An insulated tuckstone that includes a basic tuckstone and an insulating layer exhibiting a thermal conductivity lower than 2.0 W·m 1·K?1 between 20° C. and 500° C., exhibiting enough rigidity to be self-supporting and covering an insulated surface of the basic tuckstone. The insulated surface is included in the lower surface of the basic tuckstone, extending into the lower transition surface and representing more than 20% of the lower transition surface. The insulating layer has a chemical composition, as a percentage by mass on the basis of the oxides, such that Al2O3+SiO2+ZrO2+CaO+Na2O+MgO+K2O+TiO2+Fe2O3+HfO2+P2O5+Y2O3>80%.
    Type: Grant
    Filed: April 10, 2019
    Date of Patent: March 19, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Pierrick Vespa, Franceline Marguerite Louise Villermaux, Christian His
  • Patent number: 11912626
    Abstract: A polycrystalline fused product based on brownmillerite, includes, for more than 95% of its weight, of the elements Ca, Sr, Fe, O, M and M?, the contents of the elements being defined by the formula XyMzFetM?uO2.5, wherein the atomic indices are such that 0.76?y?1.10, z?0.21, 0.48?t?1.15 and u?0.52, 0.95?y+z?1.10, and 0.95?t+u?1.10, X being Ca or Sr or a mixture of Ca and Sr, M being an element chosen from the group formed by La, Ba and mixtures thereof, M? being an element chosen from the group formed by Ti, Cu, Gd, Mn, Al, Sc, Ga, Mg, Ni, Zn, Pr, In, Co, and mixtures thereof, the sum of the atomic indices of Ti and Cu being less than or equal to 0.1.
    Type: Grant
    Filed: September 19, 2019
    Date of Patent: February 27, 2024
    Assignees: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Helena Kaper, Pierre-Alexis Repecaud
  • Patent number: 11905198
    Abstract: A glass furnace including an additive-containing product including an additive selected from: phosphorus compounds other than glasses and vitroceramics, tungsten compounds other than glasses and vitroceramics, molybdenum compounds other than glasses and vitroceramics, iron in the form of metal, aluminum in the form of metal, silicon in the form of metal, and their mixtures, silicon carbide, boron carbide, silicon nitride, boron nitride, glasses including elemental phosphorus and/or iron and/or tungsten and/or molybdenum, vitroceramics including elemental phosphorus and/or iron and/or tungsten and/or molybdenum, and their mixtures, and having the following chemical analysis, exclusively of the additive, as a percentage by weight on the basis of the oxides: Cr2O3?2%, and Cr2O3+Al2O3+CaO+ZrO2+MgO+Fe2O3+SiO2+TiO2?90%, and Cr2O3+Al2O3+MgO?60%, the content by weight of additive being in the range 0.01% to 6%.
    Type: Grant
    Filed: December 20, 2018
    Date of Patent: February 20, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Thibault Champion, Pierrick Vespa, Lionel Moitrier, Olivier Citti, Julien Pierre César Fourcade, Nabil Nahas
  • Patent number: 11878933
    Abstract: A process for treating a fused refractory product including more than 10% by mass of ZrO2, or “base product.” The process includes heating at least a portion of the surface of the product, so as to melt ZrO2 crystals in a superficial region extending to a depth of less than 2000 ?m. The process includes cooling the molten superficial region obtained in the preceding step so as to obtain a protective layer.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: January 23, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Frédéric Hoffmann, Pierrick Fabien Vespa
  • Patent number: 11873257
    Abstract: An antiballistic armor-plating component, includes a ceramic body made of a material including, as percentages by volume, between 20% and 75% of boron carbide, between 5% an d 30% of a metallic silicon phase or of a metallic phase including silicon and between 20% and 70% of silicon carbide and wherein, as percentages by volume: more than 60% of the grains with an equivalent diameter greater than 60 micrometers are boron carbide grains, the boron carbide grains with an equivalent diameter greater than 30 micrometers represent more than 20%, the silicon carbide grains with an equivalent diameter greater than or equal to 10 micrometers represent more than 10%, the silicon carbide grains with an equivalent diameter less than 10 micrometers represent more than 10%.
    Type: Grant
    Filed: July 31, 2020
    Date of Patent: January 16, 2024
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Jérôme Brulin, Jérôme Sant
  • Patent number: 11731883
    Abstract: A powder of melted particles, more than 95% by number of the particles exhibiting a circularity of greater than or equal to 0.85. The powder including more than 99.8% of a rare earth metal oxide and/or of hafnium oxide and/or of an aluminum oxide, as percentage by mass based on the oxides. The powder has a median particle size D50 of less than 15 ?m, a 90 percentile of the particle sizes, D90, of less than 30 ?m, and a size dispersion index (D90?D10)/D10 of less than 2, and a relative density of greater than 90%. The Dn percentiles of the powder are the particle sizes corresponding to the percentages, by number, of n %, on the cumulative distribution curve of the size of the particles in the powder and the particle sizes are classified by increasing order.
    Type: Grant
    Filed: January 31, 2019
    Date of Patent: August 22, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Alain Allimant, Howard Wallar
  • Patent number: 11712818
    Abstract: A method for producing a glass furnace, including a refractory portion, a waveguide with a measurement portion extending into the refractory portion and an interrogator connected to an input of the waveguide to inject an interrogation signal. The measurement portion incorporating a sensor to send a response signal to the interrogator in response to the injection. The interrogator analyzing the response signal and sending a message. Arranging, inside a mold, a temporary part configured to leave space for a compartment for the measurement portion. Preparing a starting feedstock and introducing the starting feedstock into the mold such that the part is embedded therein to obtain a preform. Hardening the preform to form the refractory portion. Removing the temporary part to make the compartment. Assembling the refractory portion with other constituent elements and introducing the measurement portion into the compartment and connecting the interrogator to the input of the waveguide.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: August 1, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Olivier Citti, Jean-Gaël Vuillermet
  • Patent number: 11634362
    Abstract: A process for the manufacture of a refractory block including more than 80% zirconia, in percentage by weight based on the oxides. The process includes the following successive stages: melting, under reducing conditions, of a charge including more than 50% zircon, in percentage by weight, such as to reduce the zircon and obtain a molten material, application of oxidizing conditions to the molten material, casting of the molten material, and cooling until at least partial solidification of the molten material in the form of a block. Also, the process can include heat treatment of the block.
    Type: Grant
    Filed: October 9, 2018
    Date of Patent: April 25, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Pierrick Vespa, Laurent Battu, Olivier Citti
  • Patent number: 11635281
    Abstract: Antiballistic armour plate includes a ceramic body including a hard material, provided, on its inner face, with a back energy-dissipating coating. The ceramic body is monolithic. The constituent material of the ceramic body includes grains of ceramic material having a Vickers hardness that is higher than 15 GPa, and a matrix binding the grains, the matrix including a silicon nitride phase and/or a silicon oxynitride phase, the matrix representing between 5 and 40% by weight of the constituent material of the ceramic body. The maximum equivalent diameter of the grains of ceramic material is smaller than or equal to 800 micrometres. The constituent material of the ceramic body has an open porosity that is higher than 5% and lower than 14%. The metallic silicon content in the material, expressed per mm of thickness of the body, is lower than 0.5% by weight.
    Type: Grant
    Filed: July 7, 2017
    Date of Patent: April 25, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Malte Moeller, Gilles Rossiquet
  • Patent number: 11628404
    Abstract: A monolithic membrane-type filtration structure for filtering liquids, includes a support formed of a porous inorganic material of permeability Ks, the support having a tubular overall shape with a main axis, an upstream base, a downstream base, a peripheral wall delimiting an internal part and a plurality of passages parallel to the main axis of the support, formed in the internal part of the support, a membrane of permeability Km and of mean thickness tm covering the internal surface of the passages; the external hydraulic diameter of the structure satisfying the relationship Øf=?×[A+B×log10 (Ks×tm/Km)]; in which ? is a coefficient between 0.85 and 1.15, and A=?21570×entint2?18.6×Dh+19.0×eint?2.5×eext+0.1244 B=?11760×Dh×eint+9.7×eint+3.1×eext+0.04517. Dh is the mean hydraulic diameter of the passages, eint is the minimum thickness of the internal walls between the passages, eext is the minimum thickness of the peripheral wall of the filter.
    Type: Grant
    Filed: November 29, 2018
    Date of Patent: April 18, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Sébastien Pinson, Paul Leplay, Malte Moeller, Ronald Neufert, Michael Faber
  • Patent number: 11578005
    Abstract: Sintered product having a relative density of greater than 90%, with, to more than 80% of the volume thereof, a stack of flat ceramic platelets, the assembly of the platelets having a mean thickness of less than 3 ?m, having a width of greater than 50 mm, and including more than 20% of alumina, as a percentage on the basis of the weight of the product. The width of the product is the largest dimension measured in the plane in which the length of the product is measured, along a direction perpendicular to the direction of the length. The length of the product is the largest dimension thereof in a plane parallel to the general plane in which the platelets extend.
    Type: Grant
    Filed: January 30, 2018
    Date of Patent: February 14, 2023
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Nassira Benameur, Christian His, Jérôme Leloup
  • Patent number: 11472743
    Abstract: A sintered bead with the following crystal phases, in percentages by mass based on crystal phases: 25%?zircon, or “Z1”, ?94%; 4%?stabilized zirconia+stabilized hafnia, or “Z2”, ?61%; monoclinic zirconia+monoclinic hafnia, or “Z3”?50%; corundum?57%; crystal phases other than Z1, Z2, Z3 and corundum<10%; the following chemical composition, in percentages by mass based on oxides: 33%?ZrO2+HfO2, or “Z4”?83.4%; HfO2?2%; 10.6%?SiO2?34.7%; Al2O3?50%; 0%?Y2O3, or “Z5”; 0%?CeO2, or “Z6”; 0.3%?CeO2+Y2O3?19%, provided that (1) CeO2+3.76*Y2O3?0.128*Z, and (2) CeO2+1.3*Y2O3?0.318*Z, with Z=Z4+Z5+Z6?(0.67*Z1*(Z4+Z5+Z6)/(0.67*Z1+Z2+Z3)); MgO?5%; CaO?2%; oxides other than ZrO2, HfO2, SiO2, Al2O3, MgO, CaO, CeO2 and Y2O3<5.0%.
    Type: Grant
    Filed: July 18, 2018
    Date of Patent: October 18, 2022
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Emmanuel Nonnet
  • Patent number: 11390532
    Abstract: A powder formed of fused particles. More than 95% by number of the feed particles exhibiting a circularity of greater than or equal to 0.85. The powder contains more than 88% of a silicate of one or more elements chosen from Zr, Hf, Y, Ce, Sc, In, La, Gd, Nd, Sm, Dy, Er, Yb, Eu, Pr, Ho and Ta, less than 10% of a dopant, as percentage by weight based on the oxides. The powder has a median particle size D50 of less than 15 ?m, a 90 percentile particle size, D90, of less than 30 ?m, and a size dispersion index (D90-D10)/D10 of less than 2. The powder has a relative density of greater than 90%. The Dn percentiles of the powder are the particle sizes corresponding to the percentages, by number, of n %, on the cumulative distribution curve of the size of the particles of the powder. The particle sizes are classified in increasing order.
    Type: Grant
    Filed: January 31, 2019
    Date of Patent: July 19, 2022
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Alain Allimant, Howard Wallar
  • Patent number: 11390786
    Abstract: A sintered material exhibiting the following chemical composition, as percentages by weight: iron oxide(s), expressed in the Fe2O3 form, ?85%, CaO: 0.1%-6%, SiO2: 0.1%-6%, 0.05% ?TiO2, 0?Al2O3, TiO2+Al2O3?3%, and constituents other than iron oxides, CaO, SiO2, TiO2 and Al2O3: ?5%. The CaO/SiO2 ratio by weight is between 0.2 and 7. The TiO2/CaO ratio by weight is between 0.2 and 1.5.
    Type: Grant
    Filed: April 19, 2017
    Date of Patent: July 19, 2022
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Christian His, Franceline Villermaux
  • Patent number: 11384984
    Abstract: Thermal storage unit including: a receptacle including orifices allowing a heat-transfer fluid to be introduced into and extracted, and a stack of bricks, arranged in the receptacle in superposed strata, each stratum having lower and upper large faces and defining a plurality of ducts opening via lower and upper openings, the stack including a pair of strata of a lower and upper stratum, the upper and lower large faces of the lower and upper stratum being separated to define a passage, placing an upper opening of a lower duct of the lower stratum in fluidic communication with at least one lower opening, entirely offset with respect to the upper opening, of at least one upper duct of the upper stratum, the lower large face of the upper stratum closing off, at least partially, the upper opening, when the upper opening is observed, along its axis, from the lower duct.
    Type: Grant
    Filed: September 29, 2015
    Date of Patent: July 12, 2022
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Benoit Watremetz, Thierry Dupin, Paul Leplay
  • Patent number: 11111183
    Abstract: An unshaped product including, as weight percentages, A) particles (a) of at least one refractory material other than a glass and a glass-ceramic, and the main constituent(s) of which are alumina and/or zirconia and/or silica and/or chromium oxide: B) 2% to 15% of particles (b) of a hot binder chosen from glass-ceramic particles, particles made of a glass, and the mixtures of these particles, a glass being a noncrystalline material exhibiting a glass transition temperature of less than 1100° C., the hot binder not being in the solid state at 1500° C., C) less than 2% of particles (c) of hydraulic cement, D) less than 7% of other constituents, the particles (a) and (b) being distributed, as weight percentages in the following way: fraction<0.5 ?m: ?1%, fraction<2 ?m: ?4%, fraction<10 ?m: ?13%, fraction<40 ?m: 25%-52%.
    Type: Grant
    Filed: March 7, 2016
    Date of Patent: September 7, 2021
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Isabelle Cabodi, Thierry Consales, Michel Gaubil
  • Patent number: 11072563
    Abstract: A fused grain having the following chemical composition in percent by weight in relation to the oxides: ZrO2: 16% to 30%, provided that HfO2<2%, Al2O3: percentage needed to bring the total to 100%, Cr2O3: ?0.2%, TiO2: ?0.5%, Cr2O3+TiO2: <7%, other elements: <3%, provided that SiO2+CaO+MgO<1.5%.
    Type: Grant
    Filed: February 10, 2017
    Date of Patent: July 27, 2021
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Céline Delwaulle, Arnaud Apheceixborde
  • Patent number: 11059752
    Abstract: A sintered concrete having the following mean chemical composition, as mass percentages on the basis of the oxides and for a total of 100%; ZrO2: 55 to 70%, SiO2: 25 to 40%, P2O5: 0.2 to 9.0%, Al2O3: 0.5 to 7.0%, CaO: >0.2%, CaO+MgO+B2O3+Fe2O3: 0.2 to 10.0%, MgO+B2O3+Fe2O3; ?7.5%, B2O3+MgO: ?4.5%, ZrO2+SiO2+P2O5+Al2O3+CaO+MgO+B2O3+Fe2O3: ?95.0%, and containing more than 70% of zircon, as a mass percentage on the basis of the mass of the crystalline phases.
    Type: Grant
    Filed: December 13, 2017
    Date of Patent: July 13, 2021
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Thibault Champion, Michel Bobo