Patents Assigned to Saint-Gobain Centre de Recherches et d'Etudes
  • Patent number: 10167233
    Abstract: A sintered refractory product having the form of a block and consisting of a granulate formed by all the grains having a size larger than 100 ?m, referred to as “coarse grains”, and a matrix binding the coarse grains and consisting of the grains having a size smaller than or equal to 100 ?m, the granulate representing between 45% and 90% by mass of the product, the product having a composition such that, in a mass percentage based on the oxides: Al2O3>80%, SiO2<15%, Na2O<0.15%, Fe2O3<0.05%, CaO<0.1%, the other oxides forming the remainder up to 100%, and the Na2O content in the matrix being greater than 0.010%, in a mass percentage based on the mass of the product.
    Type: Grant
    Filed: July 18, 2014
    Date of Patent: January 1, 2019
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Laurie San-Miguel, Fabiano Rodrigues, Christian His, Thibault Champion
  • Patent number: 10071502
    Abstract: Process for the manufacture of a mesoporous product comprising the following successive steps: a) preparation of a slip comprising: a solvent, an additive, more than 4%, as percentage by volume based on the slip, of a powder formed of ceramic particles, b) oriented freezing of the slip, so as to form a block comprising ice crystals separated by walls, c) removal of the ice crystals from said frozen slip block, optionally removed from the mold, so as to obtain a porous preform, d) removal of the additive, so as to obtain a preformed mesoporous product, the additive and the amount of additive being chosen so that the additive is present in a mesopore-forming micellar phase in said walls, more than 25% by volume of said ceramic particles exhibiting a size less than twice the size of the micelles of said mesopore-forming micellar phase.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: September 11, 2018
    Assignees: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Michaela Klotz, Idris Amirouche, Sylvain Deville, Christian Gilbert Guizard
  • Publication number: 20180230058
    Abstract: Sintered product having a chemical analysis such that, in percentages by mass based on the oxides, —ZrO2 partially stabilised with CeO2 and Y2O3: remainder up to 100%, —Al2O3: >10% and <19%—of an additive selected from CaO, the oxides of manganese, ZnO, the oxides of praseodymium, SrO, the oxides of copper, Nd2O3, BaO, the oxides of iron, and mixtures thereof: 0.2-6%, —impurities: <2%, CeO2 and Y2O3 being present in quantities such that, in molar percent based on the sum of ZrO2, CeO2 and Y2O3, —CeO2: 2.5 mol % and <5.5 mol %, and —Y2O3: 0.5-2 mol %.
    Type: Application
    Filed: July 13, 2016
    Publication date: August 16, 2018
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Thomas PERIE
  • Publication number: 20180231316
    Abstract: Thermal storage unit including: a receptacle including orifices allowing a heat-transfer fluid to be introduced into and extracted, and a stack of bricks, arranged in the receptacle in superposed strata, each stratum having lower and upper large faces and defining a plurality of ducts opening via lower and upper openings, the stack including a pair of strata of a lower and upper stratum, the upper and lower large faces of the lower and upper stratum being separated to define a passage, placing an upper opening of a lower duct of the lower stratum in fluidic communication with at least one lower opening, entirely offset with respect to the upper opening, of at least one upper duct of the upper stratum, the lower large face of the upper stratum closing off, at least partially, the upper opening, when the upper opening is observed, along its axis, from the lower duct.
    Type: Application
    Filed: September 29, 2015
    Publication date: August 16, 2018
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Benoit WATREMETZ, Thierry DUPIN, Paul LEPLAY
  • Patent number: 10017427
    Abstract: Preparation of a slip including more than 4% and less than 50% of ceramic particles and including more than 1% of orientable ceramic particles made of a material including an oriented function, as volume percentage on the basis of the set of ceramic particles, wherein the fraction of non-orientable ceramic particles has a median length less than ten times the median length of the orientable ceramic particles if the set of ceramic particles includes less than 80%, as volume percentage, of orientable ceramic particles, oriented freezing of the slip by movement of a solidification front at a speed less than the speed of encapsulation of the ceramic particles; elimination of the crystals of solidified liquid phase of said block, optionally, sintering.
    Type: Grant
    Filed: December 6, 2013
    Date of Patent: July 10, 2018
    Assignees: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Sylvain Deville, Florian Bouville
  • Patent number: 9932681
    Abstract: The present disclosure relates to an electrolytic cell for the production of aluminium by reducing alumina. The cell may comprise a sidewall including at least one side block. The side block may comprise an aluminous material having an apparent porosity of less than about 10% and a composition, as a weight percentage on the basis of the aluminous material and for a total of about 100%, such that: Al2O3>about 50%, beta-alumina being less than about 20% of the weight of the aluminous material, oxides that are less reducible than alumina at 1000° C.<about 50%, Na2O<about 3.9%, and other components<about 5%.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: April 3, 2018
    Assignee: Saint-Gobain Centre De Recherches Et D'Etudes Europeen
    Inventors: Eric Jorge, Olivier Francy, Olivier Panagiotis
  • Patent number: 9908816
    Abstract: A powder is disclosed having a coarse fraction representing more than 60% and less than 85% of the powder, as a weight percentage on the basis of the oxides, and that is constituted of particles having a size greater than or equal to 50 ?m, referred to as “coarse particles”, the powder comprising at least 5% of coated grains having a size greater than or equal to 50 ?m, as a weight percentage on the basis of the oxides of the powder, and a fine fraction, forming the balance to 100% as a weight percentage on the basis of the oxides, constituted of particles having a size of less than 50 ?m, referred to as “matrix particles”. The powder can be applied in combustion chambers in which the temperature may reach 1400° C.
    Type: Grant
    Filed: July 13, 2015
    Date of Patent: March 6, 2018
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Thibault Champion, Christian His
  • Patent number: 9845266
    Abstract: A fused grain is essentially composed of a matrix of a magnesium aluminum oxide of spinel structure MgAl2O4 and/or of the MgO—MgAl2O4 eutectic, the matrix including inclusions essentially composed of magnesium oxide, the grain exhibiting the following overall chemical composition, as percentages by weight, expressed in the form of oxides: more than 20.0% and less than 50.0% of Al2O3, Al2O3 and MgO together represent more than 95.0% of the weight of the grain, wherein the cumulative content of CaO and ZrO2 is less than 4000 ppm by weight.
    Type: Grant
    Filed: March 17, 2015
    Date of Patent: December 19, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Stéphane Raffy
  • Publication number: 20170284741
    Abstract: A method for testing the internal structure of a refractory part, has the following steps: a) by a transmission antenna, sending at least one electromagnetic wave, termed a “pulse”, into the refractory part to be tested; b) by a reception antenna, receiving the pulse after reflection thereof by a reflecting zone of the refractory part; c) analyzing the time offset between the two preceding steps in order to deduce the position, in the refractory part, of the reflecting zone, the pulse having a duration less than or equal to 0.5 nanoseconds.
    Type: Application
    Filed: September 14, 2015
    Publication date: October 5, 2017
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Olivier BORIES
  • Patent number: 9748579
    Abstract: The present invention provides a fused product comprising LTM perovskite, L designating lanthanum, T being an element selected from strontium, calcium, magnesium, barium, yttrium, ytterbium, cerium, and mixtures of these elements, and M designating manganese.
    Type: Grant
    Filed: April 28, 2014
    Date of Patent: August 29, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Samuel Marlin, Caroline Levy
  • Patent number: 9695060
    Abstract: A fused product including lithium-manganese spinel, which is optionally doped, having a spinel structure AB2O4, where the site A is occupied by lithium and the site B is occupied by manganese, it being possible for the site B to be doped with an element B? and it being possible for the site A to exert a substoichiometry or a superstoichiometry with respect to the site B, so that the product observes the formula Li(1+x)Mn(2?y)B?yO4, with ?0.20?x?0.4 and 0?y?1, the element B? being chosen from aluminum, cobalt, nickel, chromium, iron, magnesium, titanium, vanadium, copper, zinc, gallium, calcium, niobium, yttrium, barium, silicon, boron, zirconium and their mixtures.
    Type: Grant
    Filed: December 22, 2011
    Date of Patent: July 4, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Caroline Levy, Samuel Marlin, Yves Boussant-Roux
  • Patent number: 9688581
    Abstract: Molten grains include titanium suboxides of the formulation TinO2n-1, in which the phases are principally Ti5O9 or Ti6O11 or a mixture of these two phases, the phases Ti5O9 and/or Ti6O11 representing, in total, more than 60% of the weight of the grains, the grains further including less than 30% by weight of Ti4O7.
    Type: Grant
    Filed: September 27, 2013
    Date of Patent: June 27, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Stéphane Raffy
  • Publication number: 20170129816
    Abstract: A method includes the following steps: a) the production of a slip including more than 4% and less than 50% of ceramic particles and including: b) a first particulate fraction including of orientable particles having a median length L?50 and representing more than 1% of the ceramic particles, and c) a second particulate fraction having a median length D50 at least ten times shorter than L?50 and representing more than 1% of the ceramic particles, the first and second particulate fractions together representing more than 80% of all of the ceramic particles, in volume percentages based on the total quantity of ceramic particles; d) oriented freezing of the slip by moving a solidification front at a lower speed than the speed of encapsulation of the ceramic particles; e) elimination of the crystals of the solidified liquid phase of the block; and f) optionally sintering.
    Type: Application
    Filed: June 11, 2014
    Publication date: May 11, 2017
    Applicants: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Sylvain DEVILLE, Florian BOUVILLE, Adam STEVENSON
  • Patent number: 9620778
    Abstract: A method for manufacturing a molten material (the crystallized portion of which consists of a single crystalline phase), includes a) mixing raw materials so as to form a feedstock; b) melting the feedstock until a liquid mass reaches a temperature higher than the melting temperature Tf of the molten material obtained at the end of step e); c) cooling until the liquid mass is completely solidified to obtain a molten material, the amorphous phase of which is constitutes less than 80 wt % thereof; d) optionally crushing/grinding and/or performing selection by particle size on the molten material; e) optionally, heat-treating the molten material at a temperature which is an increment lower than the melting temperature of the molten material and is between Tf?800° C. (or 500° C.) and Tf?50° C., for a period of time in a reducing environment; and f) optionally, crushing/grinding and/or performing selection by particle size on said molten material.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: April 11, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Caroline Levy, Arnaud Apheceixborde
  • Patent number: 9593048
    Abstract: The invention relates to a melted and cast refractory product having a chemical composition such that, in mass percentages on the basis of the oxides: AI2O3: complement up to 100%; MgO: 26% to 50%; ZrO2: 0.5% to 10.0%; B2O3: <1.5%; SiO2: ?0.5%; Na2O+K2O: ?0.3%; CaO: ?1.0%; Fe2O3+TiO2: <0.55%; other oxide species: <1.0%. In said product, the elementary mass ratio R of the zirconium content to the total boron, fluorine and silicon content is between 2 and 80.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: March 14, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Eric Jorge, Olivier Francy
  • Patent number: 9573850
    Abstract: A sintered product made from a starting batch containing 5 to 50% zircon and having the following average chemical composition, in weight percentages on the basis of the oxides and for a total of 100%: silica and zirconia, the zirconia content (ZrO2) being at least 64%, at least 0.2% of a dopant selected from V2O5, Nb2O5, Ta2O5, and mixtures thereof, optionally, a stabilizer selected from Y2O3, MgO, CaO, CeO2, and mixtures thereof, at a content of 6% or less, “other oxides” at a content of 6.7% or less.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: February 21, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Olivier Citti, Julien Fourcade, Michel Gaubil, Charles Nicholas McGarry, Michael J. Seaborne
  • Patent number: 9550692
    Abstract: Feeder channel for molten glass including an infrastructure including a block self-cast and sintered in situ. Furthermore, a method for manufacturing a block of such an infrastructure and a supply channel for a glassmaking furnace are claimed.
    Type: Grant
    Filed: July 12, 2012
    Date of Patent: January 24, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES
    Inventors: Cyril Linnot, Michel Bobo
  • Patent number: 9546115
    Abstract: A monolithic honeycomb element includes a collection of adjacent ducts of mutually parallel axes separated by walls made of a porous material, the element having, in transverse cross section, a polygonal, notably quadratic cross section delimited by exterior wall elements, wherein at least one corner of the polygon, has, along the bisector of the angle at the corner, an additional thickness, such that the total thickness of the external wall, likewise measured along the bisector of the angle at the corner, is greater than the mean thickness of the exterior walls by a factor of at least 1.43, the additional thickness being obtained at least in part by an additional quantity of porous material on the external face of the corner.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: January 17, 2017
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventor: Bernard Bouteiller
  • Patent number: 9505663
    Abstract: A method for manufacturing sintered refractory grains containing Cr2CO3 from an initial refractory product including one or more chromium that includes: A) optionally, \crushing the starting refractory material; B) grinding a filler, comprising said starting refractory material in a liquid medium to obtain a suspension of particles of said starting refractory material; C) preparing a starting mixture including at least 1 wt % of particles of the suspension obtained during the preceding step; D) shaping the starting mixture into the shape of a preform; E) optionally drying the preform obtained in step D); F) sintering the preform so as to obtain a sintered body; G) optionally grinding the sintered body; and H) the optional selection by particle size.
    Type: Grant
    Filed: February 14, 2012
    Date of Patent: November 29, 2016
    Assignee: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Cyril Linnot, Olivier Citti
  • Publication number: 20160340220
    Abstract: An unshaped product including a particulate mixture containing: a coarse fraction, representing >50%<91% of particulate mixture, in mass percentage, and containing particles size ?50 ?m, “coarse particles”, and matrix fraction, forming remainder up to 100% of particulate mixture, and containing particles sizes <50 ?m, product having chemical analysis, in mass percentage based on oxides of product, such: ?45%<Al2O3, ?7.5%<SiO2<35%, ?0%?ZrO2<33%, providing 10%<SiO2+ZrO2<54%, ?0.15%<B2O3<8%, other oxides: <6%, Al2O3 forming remainder up to 100%, coarse fraction including more than 15% coarse particles having size >1 mm, in mass percentage based on particulate mixture, matrix fraction having a chemical analysis, in mass percentage based on oxides of matrix fraction, such: Al2O3+SiO2+ZrO2>86%, providing 35%<Al2O3.
    Type: Application
    Filed: December 18, 2014
    Publication date: November 24, 2016
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Thibault CHAMPION, Olivier CITTI, Michel BOBO