Patents Assigned to Sakai Chemical Industry Co. Ltd.
  • Patent number: 5002920
    Abstract: A catalyst for ozone decomposition which comprises: at least one oxide of a metal selected from the group consisting of Cu, Mn, Co, Fe and Ni; and at least one oxide of a metal selected from the group consisting of Ti and Ag, and/or Au.A further catalyst freed from deterioration in activity even when it is used under severe conditions, which comprises: a ternary metal oxide represented by the formula of xMnO.sub.z.yAg.sub.z O.zTiO.sub.z wherein weight proportion coordinates (x, y, z) of the oxide on a triangular diagram are either on sides of a triangle formed by connecting three points (20, 10, 70), (80, 10, 10) and (20, 70, 10) with straight lines or within the traingle, as seen in FIG. 1.
    Type: Grant
    Filed: October 31, 1989
    Date of Patent: March 26, 1991
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Masafumi Yoshimoto, Tadao Nakatsuji, Kazuhiko Nagano
  • Patent number: 4996015
    Abstract: A method of producing ceramic honeycomb structures which comprises: the first step of preparing a ceramic plastic composition which comprises admixing and kneading a ceramic material with water, a polyalkylene glycol monoether and an organic binder; the second step of extruding the ceramic plastic composition into a wet green mold of a honeycomb structure having openings extending therethrough; the third step of passing a high humidity air through the openings to evaporate the substantial amount of the water in the green mold; the fourth step of passing heated air to evaporate the substantial amount of the polyalkylene glycol monoether from the green mold; and the fifth step of calcining the mold.The method is suitably applicable to the production of ceramic honeycomb structures as a catalyst structure or a catalyst carrier structure therefor which contains a material acting as an oxidation catalyst.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: February 26, 1991
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Masafumi Yoshimoto, Tadao Nakatsuji, Noriaki Sato
  • Patent number: 4977127
    Abstract: A catalyst for denitrizing nitrogen oxides contained in waste gases in the presence of arsenic compounds, which comprises: titanium and vanadium therein in weight ratios of oxides of titanium to oxides of vanadium ranging from 99.9:0.1 to 92.0:8.0, the vanadium being concentratedly contained in the surface layer of the catalyst up to 200 .mu.m in depth from the surface of the catalyst in concentrations of at least about 1.5 times as much as the concentrations of vanadium throughout the catalyst.The catalyst may further contain therein at least one of tungsten and zirconium.The catalyst preferably has micropores of about not less than about 50 .ANG. in amounts of 0.25-0.40 ml/g, and micropores of about 50-100 .ANG. in radius in amounts of about 10-40% by volume and micropores of about 1000-60000 .ANG. in radius in amounts of not less than about 10% by volume, respectively, based on the total volume of the micropores of not less than about 50.ANG. in radius.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: December 11, 1990
    Assignees: Sakai Chemical Industry Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Hiroaki Rikimaru, Tadao Nakatsuji, Toshikatsu Umaba, Kazuhiko Nagano, Kazuya Mishina, Hiromitsu Shimizu
  • Patent number: 4960582
    Abstract: A process of producing a spinel structure Ni/Zn ferrite-modified, Co/Ti-substituted microcrystalline barium ferrite platelets having an average particle size of 0.03-0.15 .mu.m, a temperature coefficient of coercive force of not more than +1 Oe/.degree. C., including small absolute values in negative region, and a saturated magnetization of not less than 56 emu/g, which comprises: forming substantially amorphous preecursors of Co/Ti-substituted barium ferrites; adding an aqueous solution of nickel salts to the dispersion of the precursors of Co/Ti-substituted barium ferrites, and subjecting the slurry to hydrothermal reaction, thereby to provide precursors of spinel structure nickel ferrite-modified, Co/Ti-substituted barium ferrites; depositing a water insoluble zinc compound on the precursors; and calcining the precursors in the presence of barium chloride, washing the calcined products to remove therefrom the barium chloride, and drying.
    Type: Grant
    Filed: August 1, 1989
    Date of Patent: October 2, 1990
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Susumu Iwasaki, Shigefumi Kamisaka, Iwao Yamazaki, Tutomu Hatanaka
  • Patent number: 4952381
    Abstract: A catalyst for denitrizing nitrogen oxides contained in waste gas which contains a substantial amount of arsenic compounds therein, which comprises:(a) titanium, and(b) at least one element selected from the group consisting of arsenic and manganese. The catalyst is resistant to deactivation by arsenic compounds and retains high denitrizing activity over a long period of time. The catalyst may further contain at least one base metal selected from the group consisting of V, W, Mo, Cu, Fe, Cr, Co, Ni, Zn and Sn.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: August 28, 1990
    Assignees: Sakai Chemical Industry Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha, Mitsubishi Petrochemical Co., Ltd., Mitsubishi Petrochemical Engineering Co., Ltd., Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Horiaki Rikimaru, Tadao Nakatsuji, Toshikatsu Umaba, Kazuhiko Nagano, Kazuya Mishina, Hiromitsu Shimizu, Shigeru Nojima, Kozo Iida, Yoshiaki Obayashi, Touru Seto, Shigeaki Mitsuoka, Masayuki Hanada, Morio Fukuda, Kiyoshi Nagano, Makoto Imanari, Takeo Koshikawa, Akihiro Yamauchi
  • Patent number: 4892716
    Abstract: A molded catalyst for fitting into a reactor vessel having an inlet and an outlet for a reactant gas, the catalyst having openings therethrough parallel to the direction of a reactant gas which is introduced into the reactor vessel from the inlet, the catalyst comprising: a wear-resistant front surface facing the inlet of the reactor vessel and a continuation of the front surface extending therefrom, the both being the front portion of the catalyst, and the remaining part of the catalyst made so wear-susceptible as to have either:(a) a wearability of 2-10% in a shaking abrasion test wherein grinding particles having an average particle size of 100 .mu.m and a Mohs scale of 9 are placed in the openings of the catalyst in an amount of 50% by volume based on the total volume of the openings, and the catalyst is shaked for three hours with an amplitude of 77 mm and a frequency of 320 per minute; or(b) a wearability of 7.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: January 9, 1990
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kazunobu Abe, Toshikatsu Umaba
  • Patent number: 4891348
    Abstract: A catalyst for removing nitrogen oxides in an exhaust gas, said catalyst containing a first group of many pores having a diameter of 1.times.10.sup.2 .ANG. to less than 1.times.10.sup.3 .ANG. and a second group of many pores having a diameter of 1.times.10.sup.3 .ANG. to 1.2.times.10.sup.5 .ANG., the pore volume of the first group being at least 10% based on the total pore volume of the first group and the second group, and said catalyst comprising titanium and at least one metal selected from molybdenum, tungsten and vanadium as metal elements of catalytically active ingredients.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: January 2, 1990
    Assignees: Mitsubishi Petrochemical Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha, Sakai Chemical Industry Co., Ltd., Catalysts & Chemicals Industries, Co., Ltd., Mitsubishi Petrochemical Engineering Co., Ltd.
    Inventors: Makoto Imanari, Takeo Koshikawa, Akihiro Yamauchi, Masayuki Hanada, Morio Fukuda, Kiyoshi Nagano
  • Patent number: 4873351
    Abstract: Antimony trioxide is reached with an organic mercaptan R.sup.1 --SH or R.sup.2 --OCO--(CH.sub.2).sub.n --SH (where R.sup.1 is an alkyl, alkenyl, aryl, aralkyl, cycloalkyl or heterocyclic group having from 1 to 18 carbon atoms, which optionally has sulfide bond or ether bond or a hydroxyl or carboxyl group as a substituent, R.sup.2 is a hydrogen atom or an alkyl, alkenyl, aryol, aralkyl, cycloalkyl or heterochclic group having from 1 to 18 carbon atoms, which optionally has sulfide bond or ether bond or a hydroxyl or carboxyl group as a substituent, and n is 1 to 3) in the presence of a lower aliphatic carboxylic acid to give an antimony mercaptide Sb(--SR.sup.1).sub.3 or Sb(--S--(CH.sub.2).sub.n --COOR.sup.2).sub.3 of high purity with high yield. The products are excellent in the time-dependent stability and the effect as a passivator for catalysts for catalytic cracking of hydrocarbons.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: October 10, 1989
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kohtaroh Fujita, Toshio Wachi, Yoshiaki Ikeda
  • Patent number: 4859439
    Abstract: A catalyst for denitrizing nitrogen oxides contained in waste gases, which comprises:(a) titanium, and(b) at least one base metal selected from the group consisting of V, W, Mo, Mn, Cu, Fe, Cr, Co, Ni, Zn and Sn, the catalyst containing titanium and the base metals in amounts of at least about 50% by weight in terms of oxides based on the catalyst, and titanium in amounts of about 80-99% by weight in terms of oxides and the base metals in amounts of about 20-1% by weight in terms of oxides, respectively, based on the total weight in terms of oxides of titanium and the base metals, and the catalyst having micropores of about 50-75000 .ANG. in radius in amounts of about 0.25-0.45 ml/g, and micropores of about 50-100 .ANG. in radius in amounts of about 10-40% by volume and micropores of about 500-60000 .ANG. in radius in amounts of not less than about 10% by volume, respectively, based on the total volume of the micropores of about 50-75000 .ANG.
    Type: Grant
    Filed: September 30, 1987
    Date of Patent: August 22, 1989
    Assignees: Sakai Chemical Industry Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha, Mitsubishi Petrochemical Co., Ltd., Mitsubishi Petrochemical Engineering Co., Ltd., Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Hiroaki Rikimaru, Tadao Nakatsuji, Toshikatsu Umaba, Kuzuhiko Nagano, Kazuya Mishina, Hiromitsu Shimizu
  • Patent number: 4830731
    Abstract: A passivator of detrimental metals such as nickel, vanadium or iron that are contained in hydrocarbons and deteriorate catalysts in catalytic cracking of hydrocarbons, which has the general formula ofSb(--S--R.sup.1).sub.3wherein R.sup.1 represents as alkyl of 4-14 carbons.A further passivator which has the general formula ofSb(--S--(CH.sub.2).sub.n --COOR.sup.2).sub.3wherein R.sup.2 represents an alkyl of 4-14 carbons, and n is an integer of 1 or 2.
    Type: Grant
    Filed: April 1, 1988
    Date of Patent: May 16, 1989
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Fujita Kohtaroh, Wachi Toshio, Nakano Hitomi
  • Patent number: 4755500
    Abstract: A molded catalyst for fitting into a reactor vessel having an inlet and an outlet for a reactant gas, the catalyst having openings therethrough parallel to the direction of a reactant gas which is introduced into the reactor vessel from the inlet, the catalyst comprising: a wear-resistant front portion facing the inlet of the reactor vessel, and the remaining portion of the catalyst made so wear-susceptible as to have either:(a) a wearability of 2-10% in a shaking abrasion test wherein grinding particles having an average particle size of 1000 .mu.m and a Mohs scale of 9 are placed in the openings of the catalyst in an amount of 50% by volume based on the total volume of the openings, and the catalyst is shaken for three hours with an amplitude of 77 mm and a frequency of 320 per minute; or(b) a wearability of 7.5-35% in an air abrasion test wherein an air which contains silica particles having an average particle size of 40 .mu.m in amounts of 70 g/m.sup.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: July 5, 1988
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kazunobu Abe, Toshikatsu Umaba
  • Patent number: 4693931
    Abstract: A magnetic recording medium comprising a nonmagnetic support and a magnetic layer provided thereon is disclosed. The magnetic layer comprises a magnetic recording element and a binder, wherein the magnetic recording element mainly comprises acicular gamma-Fe.sub.2 O.sub.3 particles having an average porosity of not more than 5% by volume, a specific surface area of 24 to 30 m.sup.2 /g and the X-ray diffraction intensity at the face (210) to that at the face (311) of not more than 5%. The magnetic recording medium has improved electromagnetic conversion characteristics such as sensitivity and noise.
    Type: Grant
    Filed: August 17, 1984
    Date of Patent: September 15, 1987
    Assignees: Hitachi Maxell, Ltd., Sakai Chemical Industry Co., Ltd.
    Inventors: Haruo Andoh, Seiji Matsumoto
  • Patent number: 4643984
    Abstract: A process for producing a composition which includes a perovskite compound, the process comprising:(a) subjecting a mixture of a hydroxide of at least one A group element selected from the group consisting of Mg, Ca, Sr, Ba, Pb and rare earth elements and a hydroxide of at least one B group element selected from the group consisting of Ti, Zr, Hf and Sn, to the hydrothermal reaction in an aqueous reaction medium;(b) adding an insolubilizing agent to the resultant reaction mixture to insolubilize water-soluble compounds of the unreacted A group element dissolved in the aqueous medium so as to adjust the ratio of the group A element to the group B element in a resulting composition to a desired A/B ratio; or(c) filtering, washing with water and drying the resultant reaction mixture to provide a solid reaction product, dispersing the reaction product in an aqueous medium to form a slurry, adding to the slurry a water-soluble compound of the A group element, and then adding to the slurry an insolubilizing agent t
    Type: Grant
    Filed: July 23, 1985
    Date of Patent: February 17, 1987
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kazunobu Abe, Masashi Aoki, Hiroaki Rikimaru, Takeshi Ito, Kazuhisa Hidaka, Kayoko Segawa
  • Patent number: 4608361
    Abstract: A process is disclosed for producing a sheet for a catalyst carrier for vapor-phase reactions which comprises mixing highly heat resistant ceramic fibers, organic fibers and an organic binder to form a slurry, forming the slurry into a paper sheet, impregnating the paper sheet with a silicon compound, converting the silicon compound to silica gel and heating the impregnated sheet to burn up the organic fibers and organic binder. The process produces an improved catalyst carrier for vapor-phase reactions having high porosity and good strength properties.
    Type: Grant
    Filed: December 8, 1983
    Date of Patent: August 26, 1986
    Assignees: Nichias Corporation, Honshu Paper Mfg. Co., Ltd., Sakai Chemical Industry Co., Ltd.
    Inventors: Nobutaka Kanamori, Masaji Kurosawa
  • Patent number: 4520124
    Abstract: A method is provided for producing a catalytic structure in the form of sheet or honeycomb for the gas phase reduction of nitrogen oxides. The method comprises: beating an inorganic fiber in water to form a slurry; forming the slurry into a sheet by paper-making means and drying the sheet; impregnating the sheet or a honeycomb structure manufactured therefrom which has a porosity of 60-85% with an impregnating slurry which contains titanium dioxide or its precursor in a concentration at least of 100 g/l and has a viscosity of 5-250 cps. at normal temperatures, drying, and when necessary calcining the structure; and then immersing the structure in a solution containing a catalytically active agent or its precursor, drying and calcining the structure, thereby to provide a porous catalytic structure having titanium dioxide and the catalytically active agent substantially uniformly dispersed and supported therein.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: May 28, 1985
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kazunobu Abe, Tadao Nakatsuji
  • Patent number: 4508571
    Abstract: A mold additive for use in the continuous casting is disclosed, which comprises a base material for slag having a chemical composition of CaO--SiO.sub.2 --Al.sub.2 O.sub.3 system, a flux and a carbonaceous aggregate. The mold additive contains 0.5-2.0% by weight of carbon black and 1-4% by weight of activated carbon with an average particle size of not more than 10 .mu.m as the carbonaceous aggregate, and has a bulk density of not more than 0.9 g/cm.sup.3.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: April 2, 1985
    Assignees: Kawasaki Steel Corporation, Sakai Chemical Industry Co., Ltd
    Inventors: Hakaru Nakato, Toshikazu Sakuraya, Yasuhiro Habu, Toshihiko Emi, Masanori Kodama, Takao Koshikawa, Yoshimitsu Yoshida, Fumitaka Shimokawa
  • Patent number: 4416800
    Abstract: A method is provided for producing a catalyst and a carrier therefor in the form of sheet or honeycomb. The method comprises: beating a heat-resistant fiber such as asbesto fiber in water to form a slurry; mixing the slurry with a catalytically active agent, a carrier material therefor and/or their precursors to fix such materials in the fiber, thus forming a stock; and forming the stock into a sheet and drying the same. The sheet thus obtained may be formed into a honeycomb structure with an improved adhesive.
    Type: Grant
    Filed: March 19, 1981
    Date of Patent: November 22, 1983
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Kazunobu Abe, Tadao Nakatsuji
  • Patent number: 4414196
    Abstract: A method of producing single crystalline, acicular .alpha.-ferric oxide particles of narrow particle size distribution is provided. The method comprises heating an aqueous suspension of ferric hydroxide at temperatures of 100.degree.-250.degree. C. at an alkaline pH in the presence both a water soluble organic or inorganic compound capable of forming complexes with iron as a growth regulating agent and .alpha.-ferric oxide seed crystals of minor axes not larger than 0.4 microns in average in amounts of 0.1-25 mole % in terms of the Fe content thereof in relation to the ferric hydroxide.
    Type: Grant
    Filed: November 18, 1981
    Date of Patent: November 8, 1983
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Seiji Matsumoto, Tadashi Koga, Kiyoshi Fukai, Hideji Yamamoto
  • Patent number: 4379183
    Abstract: A method of producing cobalt-modified magnetic particles is provided. The method comprises heating an aqueous suspension of ferric hydroxide at temperatures of 100.degree.-250.degree. C. at an alkaline pH in the presence of a water soluble organic or inorganic compound capable of forming complexes with iron as a growth regulating agent, and preferably also in the presence of .alpha.-ferric oxide seed crystals of minor axes not larger than 0.4 microns in average in amounts of 0.1-25 mole % in terms of the Fe content thereof in relation to the ferric hydroxide, converting the obtained .alpha.-ferric oxide into .gamma.-ferric oxide by reduction thereof followed by oxidation, maintaining an aqueous suspension of the .gamma.-ferric oxide at temperatures of 30.degree.-50.degree. C. at an alkaline pH in the presence of ferrous hydroxide and cobaltous hydroxide in amounts of 0.5-50 mole %, respectively, in relation to the Fe content of the .gamma.
    Type: Grant
    Filed: November 18, 1981
    Date of Patent: April 5, 1983
    Assignee: Sakai Chemical Industry Co., Ltd.
    Inventors: Yasuo Araki, Hajime Uno, Shigeharu Higuchi, Seiji Matsumoto
  • Patent number: 4352899
    Abstract: A coating composition for a metal substrate having excellent adhesion, corrosion resistance and welding property which comprises (A) an epoxy resin, (B) an organic phosphorus compound, (C) zinc powder, of which a portion being replaceable by (E) a solid electroconductive material, and (D) a magnesium compound dispersed in a liquid medium, the weight proportion of the components (A) and (B) being from 45:55 to 95:5, the content of the component (C) corresponding to from 30 to 95% by weight based on the total weight of the non-volatile components in the composition and the content of the component (D) being from 0.1 to 5% by weight based on the total weight of the non-volatile components in the composition.
    Type: Grant
    Filed: April 3, 1981
    Date of Patent: October 5, 1982
    Assignees: Sakai Chemical Industry Co., Ltd., Nippon Steel Corporation
    Inventors: Fusao Tada, Takeshi Itoh, Joji Oka, Akira Okamoto