Patents Assigned to Saudi Basic Industries Corporation
  • Patent number: 9926240
    Abstract: The present invention relates to a process for producing chemical grade BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a catalyst having hydrocracking/hydrodesulphurization activity. Particularly, a process for producing BTX from a feedstream comprising C5-C12 hydrocarbons is provided comprising the steps of: (a) contacting said feedstream in the presence of hydrogen with a combined hydrocracking/hydrodesulphurization catalyst to produce a hydrocracking product stream comprising BTX; and (b) separating the BTX from the hydrocracking product stream. The hydrocracking/hydrodesulphurization catalyst comprises 0.1-1 wt-% hydrogenation metal in relation to the total catalyst weight. The hydrocracking/hydrodesulphurization catalyst further comprises a zeolite having a pore size of 5-8 ? and a silica (SiO2) to alumina (Al2O3) molar ratio of 5-200. The hydrocracking/hydrodesulphurization conditions include a temperature of 450-580° C.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: March 27, 2018
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventor: Andrew Mark Ward
  • Patent number: 9926391
    Abstract: The invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization. The invention also relates to a procatalyst obtained or obtainable by the process. The invention further relates to the use of a benzamide as an activator in the preparation of a Ziegler-Natta procatalyst. The invention also relates to a process for the preparation of polyolefins. The invention also relates to a polyolefin. The invention further relates to a shaped article.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: March 27, 2018
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Martin Alexander Zuideveld, Aurora Alexandra Batinas-Geurts, Gennadii Dimitrievich Bukatov, Sergei Andreevich Sergeev, Vladimir Aleksandrovich Zakharov
  • Patent number: 9919298
    Abstract: A catalyst composition comprises an inert hydrocarbon solvent, having dissolved therein a titanate of the formula Ti(OR)4 wherein each R is the same or different, and is a hydrocarbon residue, and an organic aluminum compound, wherein a molar ratio of the organic aluminum compound and any alkene present in the catalyst composition is greater than one.
    Type: Grant
    Filed: December 12, 2014
    Date of Patent: March 20, 2018
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Roland Schmidt, Mohammed H. Al-Hazmi, Mohammed F. Al-Anazi, DevRanjan J. Pradhan
  • Patent number: 9910410
    Abstract: The invention provides a multi-input multi-output (MIMO) control system comprising a controller adapted for receiving an input set of at least two control input parameters and a set of at least two control output parameters, said control system arranged for effecting a modified deadbeat control, in which said modified deadbeat control comprises a robust deadbeat control for an n-th order, linear time invariant (LTI) system based upon a series of cascade proportional integrating-differentiating (PID) controls, each PID control comprising a system transfer function having a nominator and a denominator, wherein for the nominator a constant gain (K) is selected for each PID control. The invention further provides a method for controlling a continuous process using this control system.
    Type: Grant
    Filed: February 6, 2015
    Date of Patent: March 6, 2018
    Assignees: SABIC GLOBAL TECHNOLOGIES B.V., SAUDI BASIC INDUSTRIES CORPORATION
    Inventor: Yousof Mustafa Ghazzawi
  • Patent number: 9902668
    Abstract: A reactor and process for removing unsaturated alkynes and diolefinic impurities from olefins and oxygenates.
    Type: Grant
    Filed: August 29, 2014
    Date of Patent: February 27, 2018
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Zeeshan Nawaz, Faisal Baksh
  • Patent number: 9902678
    Abstract: The present disclosure relates to a method for purifying an acid, wherein the method comprises: a) producing a crude product mixture by a partial oxidation reaction, wherein the crude product mixture comprises acrylic acid and acetic acid; b) purifying the crude product mixture by distillation using a high-boiling solvent to purify the acrylic acid; and c) purifying the crude product mixture by distillation using a low-boiling solvent to purify the acetic acid.
    Type: Grant
    Filed: May 19, 2014
    Date of Patent: February 27, 2018
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Mustapha N. Karime, Faisal Baksh, Mubarik Bashir, Zeeshan Nawaz
  • Patent number: 9902845
    Abstract: The invention relates to linear low density polyethylene having a density in the range from about 900 kg/m3 to less than about 940 kg/m3 as determined using IS01872-2, having a molecular weight distribution (Mw/Mn) in the range from 2.5 to 3.5, having an area under the peak in the temperature range from 20 to 40° C. determined using an analytical temperature rising elution fractionation analysis using 1,2-dichlorobenzene and a heating rate of 1° C./min, wherein the area is in the range from 5 to 20% of the sum of the areas under all peaks determined with the analytical temperature rising elution fractionation analysis.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: February 27, 2018
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Bart Albertus Hubertus van den Esschert, Maria Johanna Willems, Abdulaziz Hamad Al-Humydi, Yahya Banat, Said Fellahi
  • Patent number: 9896392
    Abstract: The present invention relates to a method for oligomerization of ethylene, comprising the steps: a) feeding ethylene, solvent and a catalyst composition comprising catalyst and cocatalyst into a reactor, b) oligomerizing ethylene in the reactor, c) discharging a reactor effluent comprising linear alpha-olefins including 1-butene, solvent, unconsumed ethylene dissolved in the reactor effluent, and catalyst composition from the reactor, d) separating ethylene and 1-butene collectively from the remaining reactor effluent, and e) recycling at least a part of the ethylene and the 1-butene separated in step d) into the reactor.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: February 20, 2018
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, LINDE AG
    Inventors: Andreas Meiswinkel, Wolfgang Mueller, Anina Woehl, Marco Harff, Heinz Bolt, Karl-Heinz Hofmann, Hans-Jorg Zander, Anton Wellenhofer, Abduljelil Iliyas, Shehzada Khurram, Shahid Azam, Abdullah Al-Qahtani
  • Patent number: 9873753
    Abstract: A catalyst system including a procatalyst, a co-catalyst and an external electron donor of Formula I?: Si(L)n(OR11)4-n-m(R12)m??Formula I? wherein, Si has a valency 4+; O has a valency 2? and O is bonded to Si via a silicon-oxygen bond; n is 1-4; m is 0-3; n+m?4; each R11 and R12 group is independently an alkyl or aromatic substituted or unsubstituted hydrocarbyl; each L group is independently of Formula II: wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently a hydrogen atom; a heteroatom of Groups 13-17; an alkyl, optionally containing a heteroatom of Groups 13-17 or an aromatic substituted and unsubstituted hydrocarbyl, optionally containing a heteroatom of Groups 13-17.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: January 23, 2018
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Martin Alexander Zuideveld, Erik Zuidema
  • Patent number: 9868797
    Abstract: A metallocene complex according to formula 1 wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5, or 6, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, X is a cyclic bridging group that is bonded to a carbon atom of the cyclopentadienyl ligand and to nitrogen, Z1, and Z4 are hydrogen or a hydrocarbon radical with 1-20 carbon atoms; adjacent substituents Z2 and Z3 and are connected to form an indenyl or tetrahydroindenyl ring system and R is hydrogen or a hydrocarbon radical with 1-20 carbon atoms. Also described is a composition comprising the metallocene complex, a process for the preparation of the complex, and a process for the polymerization of olefin polymers in the presence of the metallocene complex.
    Type: Grant
    Filed: July 29, 2014
    Date of Patent: January 16, 2018
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Nedumbamana Sankaran, Prashant Sukumar Shinge, Sharankumar Shetty, Girish Chandra, Haif Al-Shammari, Abdulaziz Hamad Al-Humydi, Edward Joseph Nesakumar
  • Patent number: 9868799
    Abstract: The invention relates to a procatalyst for polymerization of olefins. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of preparing polyolefins by contacting an olefin with said catalyst system and to polyolefins obtained or obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: January 16, 2018
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Inaamul Haq Siddiqui, Khalid Abdullah Al-Bahily, Khalid Mohammed Al-Gahtani
  • Patent number: 9862898
    Abstract: The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, reforming, dearomatization, fluid catalytic cracking and aromatic ring opening, which process comprises: subjecting crude oil to crude oil distillation to produce naphtha and one or more of kerosene and gasoil; subjecting naphtha to reforming to produce reformer gasoline; subjecting kerosene and/or gasoil to dearomatization to produce a first stream enriched for alkanes and naphthenes and a second stream enriched for aromatics; subjecting the stream enriched for alkanes and naphthenes to pyrolysis to produce a pyrolysis gasoline or to fluid catalytic cracking to produce a FCC gasoline; subjecting the stream enriched for aromatics to aromatic ring opening to produce a ARO gasoline; and subjecting one or more of reformer gasoline, FCC gasoline and ARO gasoline to gasoline treatment to produce BTX.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: January 9, 2018
    Assignees: Saudi Basic Industries Corporation, Sabic Global Technologies B.V.
    Inventors: Andrew Mark Ward, Ravichander Narayanaswamy, Vijayanand Rajagopalan, Arno Johannes Maria Oprins, Egidius Jacoba Maria Schaerlaeckens, Raul Velasco Pelaez
  • Patent number: 9856425
    Abstract: The present invention relates to method of producing aromatics and light olefins from a hydrocarbon feedstock comprising the steps of: (a) subjecting the hydrocarbon feedstock to a solvent extraction process in a solvent extraction unit; (b) separating from the solvent extracted hydrocarbon feedstock obtained in step (a) a raffinate fraction comprising paraffins and a fraction comprising aromatics and naphtenes; (c) converting said fraction comprising aromatics and naphtenes in a hydrocracking unit and separating into a high content aromatics fraction and a stream high in light paraffins; (d) converting said raffinate fraction in a steam cracking unit into light olefins.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: January 2, 2018
    Assignees: Saudi Basic Industries Corporation, Sabic Global Technologies B.V.
    Inventors: Andrew Mark Ward, Thomas Hubertus Maria Housmans, Arno Johannes Maria Oprins
  • Patent number: 9856200
    Abstract: The present disclosures and inventions relate to a supported catalyst composition for the catalytic oxidation of a hydrocarbon such as propane with oxygen or air, in the presence of a catalyst composition comprising a support material and a mixed metal composition comprising metals in the molar ratios described by the formula MoaVbGacPddNbeZf, wherein the support material is neutral or oxidative.
    Type: Grant
    Filed: April 22, 2014
    Date of Patent: January 2, 2018
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, Abdulaziz Al Jodai
  • Patent number: 9856424
    Abstract: The present invention relates to an integrated hydrocracking process for production of olefinic and aromatic petro-chemicals from crude oil. An object of the present invention is to provide an integrated hydrocracking process for production of olefinic and aromatic petrochemicals from a hydrocarbon feedstock comprising crude oil wherein the portion of the crude oil converted to LPG is increased significantly.
    Type: Grant
    Filed: December 23, 2014
    Date of Patent: January 2, 2018
    Assignees: Saudi Basic Industries Corporation, Sabic Global Technologies B.V.
    Inventor: Arno Johannes Maria Oprins
  • Patent number: 9850136
    Abstract: A process for the purification of CO2 from chlorinated hydrocarbons and non-chlorinated hydrocarbons, comprising: contacting a CO2 stream with a chromium oxide catalyst, wherein the stream comprises the CO2, and impurities, wherein the impurities comprise the non-chlorinated hydrocarbons and the chlorinated hydrocarbons; forming a purified CO2 stream by interacting the impurities with the chromium oxide catalyst to form additional CO2 and chromium chloride; and regenerating the chromium oxide catalyst by contacting the chromium chloride with an oxygen containing gas stream.
    Type: Grant
    Filed: October 15, 2014
    Date of Patent: December 26, 2017
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Aghaddin Kh. Mammadov, Clark David Rea
  • Patent number: 9850438
    Abstract: An integrated hydrocracking process for production of olefinic and aromatic petrochemicals from a hydrocarbon feedstock having crude oil. An object of the present invention is to provide an integrated hydrocracking process for the production of olefinic and aromatic petrochemicals from a hydrocarbon feedstock comprising crude oil in which the portion of crude oil converted to LPG is increased significantly.
    Type: Grant
    Filed: December 23, 2014
    Date of Patent: December 26, 2017
    Assignees: SABIC GLOBAL TECHNOLOGIES B.V., SAUDI BASIC INDUSTRIES CORPORATION
    Inventor: Arno Johannes Maria Oprins
  • Patent number: 9834624
    Abstract: Systems and processes for generating polyethylene are provided. A process includes performing a first reaction with methane and oxygen to produce a first product; performing a second reaction with the first product to produce a second product; separating components from the second product; returning ethane from the second product and performing a reaction simultaneous to the first reaction; performing a third reaction to produce a third product including polyethylene and vented methane; and returning the vented methane to a feed to the first reaction.
    Type: Grant
    Filed: October 7, 2014
    Date of Patent: December 5, 2017
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Aghaddin Mamedov, Mohamed Sabri Abdelghani
  • Patent number: 9827555
    Abstract: The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMnaSibXcYdOx wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.
    Type: Grant
    Filed: July 28, 2014
    Date of Patent: November 28, 2017
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, Mohammad Abdur Rakib, Asad Ahmad Khan, Mohammed Al-Semahi
  • Patent number: 9828447
    Abstract: The invention relates to a novel process for the preparation of 2,2?-bis indenyl biphenyl ligands of following formula (3): The invention also relates to metallocene complexes prepared using the novel process for the preparation of 2,2-bis indenyl biphenyl ligands. The invention also relates to novel intermediates used in the process for the preparation of 2,2?-bis indenyl biphenyl ligands.
    Type: Grant
    Filed: August 19, 2014
    Date of Patent: November 28, 2017
    Assignees: SAUDI BASIC INDUSTRIES CORPORATION, SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mudubagilu Udaya Kumar, Paresh Bhagvanbhai Rasadiya, Bharatkumar Ravjibhai Paghadar, Sambhaji Nanasaheb Chougule