Patents Assigned to Shikoku Chemicals Corporation
  • Patent number: 7661577
    Abstract: A water-based composition for treating copper or copper alloy surface for lead-free soldering, the composition comprising a compound represented by general formula (1): wherein R1 is hydrogen or methyl, and either R2 and R3 represent chlorine and R4 and R5 represent hydrogen, or R2 and R3 represent hydrogen and R4 and R5 represent chlorine.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: February 16, 2010
    Assignee: Shikoku Chemicals Corporation
    Inventors: Takayuki Murai, Yoshimasa Kikukawa, Hirohiko Hirao
  • Patent number: 7651628
    Abstract: A compression molded product of effervescent chlorinated isocyanuric acid, comprising (a) chlorinated isocyanuric acid, (b) organic acid, (c) carbonate salt and (d) sodium sulfate.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: January 26, 2010
    Assignee: Shikoku Chemicals Corporation
    Inventors: Shigeru Morioka, Yoshiya Iwasaki, Yasufumi Seo
  • Publication number: 20080318070
    Abstract: It is an object to provide a water-soluble preflux containing a low-volatile solubilizing agent excellent in performance to dissolve an imidazole compound in water and capable of bringing out an excellent film-forming property of the imidazole compound and also to provide a treating method for the surface of a metal conductive part which comprises bringing the surface into contact with the above water-soluble preflux. Another object is to provide a printed wiring board wherein the surface of a metal conductive part has been brought into contact with the above water-soluble preflux and a soldering method which comprises bringing the surface of a metal conductive part into contact with the above water-soluble preflux and subsequently soldering the surface.
    Type: Application
    Filed: May 23, 2006
    Publication date: December 25, 2008
    Applicant: SHIKOKU CHEMICALS CORPORATION
    Inventors: Hirohiko Hirao, Yoshimasa Kikukawa, Takayuki Murai
  • Publication number: 20070246134
    Abstract: A surface treating agent containing a novel phenylnaphthylimidazole compound represented by the following formula is brought into contact with the surface of copper or a copper alloy. In the formula, when A1 is a phenyl group, then A2 represents a 1-naphthyl group or a 2-naphthyl group, and when A1 is a 1-naphthyl group or a 2-naphthyl group, then A2 represents a phenyl group; and R represents a hydrogen atom or a methyl group.
    Type: Application
    Filed: June 8, 2005
    Publication date: October 25, 2007
    Applicant: Shikoku Chemicals Corporation
    Inventors: Hirohiko Hirao, Yoshimasa Kikukawa, Takayuki Murai
  • Patent number: 6025457
    Abstract: Novel molten-salt type polyelectrolytes are disclosed which contain as an essential ingredient a molten salt polymer obtained by reacting an imidazolium derivative, such as a 1,3-dialkylimidazolium halide, 1,2,3-trialkylimidazolium halide, 1-vinyl-3-alkylimidazolium halide, or 1-vinyl-2,3-alkylimidazolium halide, with an acid monomer, a poly(vinylsulfonamide), trifluoromethanesulfonimide, or the like. The electrolytes show high ionic conductivity at room temperature and have excellent stability to temperature fluctuations and excellent mechanical properties.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: February 15, 2000
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hiroyuki Ohno, Kaori Ito
  • Patent number: 5795409
    Abstract: A surface treating agent for copper and a copper alloy, comprising an aqueous solution containing an imidazole compound or a benzimidazole compound, a complexon, and iron ions. The agent forms a chemical film selectively on the surface of copper while forming no film on other metals.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: August 18, 1998
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hirohiko Hirao, Yoshimasa Kikukawa
  • Patent number: 5599864
    Abstract: A polyarylene sulfide resin composition having an excellent fluidability and a good moldability is disclosed. The resin composition is useful as a material for an optical pick-up part which has a high reliability and a high tenacity and does not generate deviation of an optical axis with changes in environmental conditions such as temperature and humidity. The polyarylene sulfide resin composition comprises, as main components, a polyarylene sulfide resin, a fibrous filler and a particulate filler, and, optionally, a silane coupling agent and an alicyclic hydrocarbon.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: February 4, 1997
    Assignees: Kabushiki Kaisha Sankyo Seiki Seisakusho, Shikoku Chemicals Corporation
    Inventors: Shogo Ogawa, Hajime Hata, Ikuo Kasuga, Hiromasa Marumo, Masamichi Hayakawa
  • Patent number: 5560785
    Abstract: A water-based surface treatment agent is used to provide a chemical layer on a copper or copper alloy printing wiring board (PWB). The chemical layer shows excellent heat-resistance and moisture-resistance. The treated PWB maintains excellent solderability for extended lengths of time. The water-based surface treatment agent contains as an active ingredient 2,4-diphenylimidazole, 2,4-diphenyl-5-methylimidazole or 2-phenyl-4-benzyl-5-methylimidazole. The treating compositions with a lower carboxylic acid of up to 4 carbon atoms are soluble in water, and have improved solder wetting properties and improved solder paste spreading property. A copper compound may be included in the aqueous solution to increase the rate at which the chemical layer is formed.
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: October 1, 1996
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hirohiko Hirao, Yoshimasa Kikukawa, Toshihiro Okamoto, Takayuki Murai, Seiji Sogabe, Miya Tanioka, Rie Nakayama, Takashi Yoshioka
  • Patent number: 5514811
    Abstract: A process for preparing, on an industrial scale, 4-halo-5-(hydroxymethyl) imidazole compounds that are useful as intermediates for medicines. A 4-chloro-5-(hydroxymethyl) imidazole compound, a 4-bromo-5-(hydroxymethyl) imidazole compound or a like compound is synthesized by reacting a 4,5-bis(hydroxymethyl) imidazole compound with a halogenating agent such as an N-chlorosuccinimide, an N-bromosuccinimide, a chlorinated isocyanuric acid compound or the like compound.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: May 7, 1996
    Assignee: Shikoku Chemicals Corporation
    Inventors: Takayuki Murai, Tokuichi Saeki, Suzuko Satou, Shozo Miura, Tomoko Takashige, Naoki Kano
  • Patent number: 5498301
    Abstract: An water-based surface treatment agent used for the copper on a printed wiring board (PWB). Chemical layer formed on PWB shows excellent heat-resistance and moisture-resistance; therefore, the treated PWB preserves excellent soldability for a long time. The water-based surface treatment agent contains, as an active ingredient, a 2-arylimidazole compound represented by the following formula, ##STR1## wherein R is a hydrogen atom or a methyl group, R1 and R2 are hydrogen atoms, lower alkyl groups or halogen atoms, and R3 and R4 are hydrogen atoms, lower alkyl groups, halogen atoms, lower alkoxy groups, di-lower alkylamino groups, cyano groups or nitro groups, ##STR2## wherein R is a hydrogen atom or a methyl group, and R1 and R2 are hydrogen atoms, lower alkyl groups or halogen atoms, but excluding the case where R, R1 and R2 are all hydrogen atoms.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: March 12, 1996
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hirohiko Hirao, Yoshimasa Kikukawa, Toshihiro Okamoto, Takayuki Murai, Seiji Sogabe, Miya Tanioka, Rie Nakayama, Takashi Yoshioka
  • Patent number: 5464910
    Abstract: An epoxy resin composition having high epoxy curing property and sufficient storage stability, and an epoxy curing agent therefor. The curing agent or the cure accelerating agent obtained by treating the surfaces of (1) an epoxy adduct obtained by adding a nitrogen-containing heterocyclic compound, an aliphatic amine or an aromatic amine to an epoxy compound having one, two or more epoxy groups in one molecule, with (2) a boric acid compound or (3) a boric acid compound and a phenolic compound, exhibits high curing property and storage stability, and can be favorably used as a curing agent for the epoxy resin composition. The epoxy resin composition prepared by mixing the epoxy resin with (1) and (2) or (1) and (3), exhibits excellent curing property and storage stability.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: November 7, 1995
    Assignee: Shikoku Chemicals Corporation
    Inventors: Takuo Nakatsuka, Tsuyoshi Toyota, Mie Tanimoto, Akiko Matsumoto
  • Patent number: 5290321
    Abstract: An organic solvent alone or together with a rubber process oil is added to a powder of .mu.-sulfur, the mixture is granulated, and the granulation product is heated at a temperature lower than 120.degree. C. to evaporate the organic solvent, whereby granular .mu.-sulfur having an improved flowability is obtained. This granular .mu.-sulfur is valuable as a rubber-vulcanizing agent.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: March 1, 1994
    Assignee: Shikoku Chemicals Corporation
    Inventors: Yukihiro Koga, Tadahiko Matsuoka, Masatoshi Sasa
  • Patent number: 5173130
    Abstract: Disclosed is a process for the surface treatment of copper or a copper alloy, which comprises immersing the surface of copper or a copper alloy in an aqueous solution containing a benzimidazole compound having an alkyl group of at least 3 carbon atoms at the 2-position and an organic acid.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: December 22, 1992
    Assignee: Shikoku Chemicals Corporation
    Inventors: Masashi Kinoshita, Takayuki Murai, Takashi Yoshioka
  • Patent number: 5080707
    Abstract: A cut flower is immersed in an aqueous solution containing chloroisocyanuric acid or its salt. By this treatment, freshness of the color and gloss of the cut flower is maintained over a long period and a high life-prolonging effect is attained.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: January 14, 1992
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hisao Ide, Kazuo Kamagata
  • Patent number: 5064631
    Abstract: A mixture comprising (i) an oxide, hydroxide or oxyhydroxide of aluminum, (ii) an aluminum-containing sulfate, (iii) an oxide or oxyacid of boron or an alkali metal salt thereof and (iv) an alkali metal sulfate is heated at a temperature of 900 to 1200.degree. C. to grow an aluminum borate whisker. In this process, the reaction is advanced apparently in the solid phase, and this process is advantageous over the conventional processes in that the yield is high and the isolation and purification of the reaction product is facilitated.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: November 12, 1991
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hajime Hata, Hajime Kambara, Seiji Sogabe, Keizo Oka
  • Patent number: 5061468
    Abstract: An aluminum borate whisker is prepared by heating and reacting aluminum sulfate and an oxide of boron, an oxyacid of boron or an alkali metal salt thereof in the presence of an alkali metal sulfate and an alkali metal carbonate. In this process, the reaction is advanced apparently in the solid phase, and this process is advantageous over the conventional processes in that the yield is high and the withdrawal of the reaction product is facilitated.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: October 29, 1991
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hajime Hata, Seiji Sogabe, Keizo Oka
  • Patent number: 5021584
    Abstract: Disclosed is a process for the preparation of a 1-benzylimidazole compound represented by the following general formula: ##STR1## wherein R.sub.2 represents a lower alkyl group or phenyl group, and R.sub.4 represents a hydrogen atom or a methyl group,which comprises heating and to react a 1-unsubstituted imidazole compound represented by the following general formula: ##STR2## wherein R.sub.2 and R.sub.4 are as defined above, with benzyl alcohol in the presence of a carboxylic acid, a carboxylic anhydride, a benzyl ester thereof or a lower alkyl ester thereof, and neutralizing the reaction product with an alkali.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: June 4, 1991
    Assignee: Shikoku Chemicals Corporation
    Inventors: Natsuo Sawa, Takeshi Masuda, Shozo Miura, Naoki Kano, Kazuo Kamagata, Masayuki Ito
  • Patent number: 5013523
    Abstract: Disclosed is a metal-based composite material comprising aluminum or an aluminum alloy combined with a whisker of aluminum borate represented by the chemical formula of 9Al.sub.2 O.sub.3.2B.sub.2 O.sub.3 or 2Al.sub.2 O.sub.3.B.sub.2 O.sub.3. This composite material has excellent mechanical properties such as high tensile strength and high hardness.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: May 7, 1991
    Assignees: Agency of Industrial Science & Technology, Shikoku Chemicals Corporation
    Inventors: Hajime Hata, Takao Kitamura, Kohji Sakane, Hideo Wada, Seiji Sogabe
  • Patent number: 4985222
    Abstract: Disclosed is a process for the preparation of an aluminum borate whisker, which comprises mixing a trialkali aluminum trisulfate represented by the following general formula:M.sub.3 Al(SO.sub.4).sub.3wherein M represents an alkali metal, with at least one boric anhydride source component selected from the group consisting of boron oxides, boron oxyacids and alkali metal salts thereof, and carrying out reaction and growth at a temperature of from 700.degree. to 1200.degree. C.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: January 15, 1991
    Assignee: Shikoku Chemicals Corporation
    Inventors: Hajime Hata, Hajime Kanbara
  • Patent number: 4983485
    Abstract: Disclosed is a positively chargeable toner comprising, as a charge-controlling agent, an acid adduct, metal complex or derivative of a 2-alkylimidazole represented by the following formula: ##STR1## wherein R.sub.2 stands for an alkyl group having 11 through 17 carbon atoms, and R.sub.4 stands for a hydrogen atom or a methyl group.In this toner, a high charge-controlling effect is attained with a small amount of the charge-controlling agent, and since the charge-controlling agent has a white color or light color, this toner is advantageously used as an electrostatic photographic toner for the color printing.
    Type: Grant
    Filed: April 11, 1989
    Date of Patent: January 8, 1991
    Assignee: Shikoku Chemicals Corporation
    Inventors: Takeshi Nagaoka, Takashi Yoshioka, Kazuo Kamagata, Natsuo Sawa, Takayuki Murai