Patents Assigned to Sinco Engineering S.p.A.
  • Patent number: 6245863
    Abstract: Process for the production of aromatic polyester resins starting from resins with an IV from 0.1 to 0.4 dl/g comprising the steps of blending the resin with a dianhydride of a tetracarboxylic acid, extruding the resin under the form of a strand, cooling the strand or the chips obtainable by cutting the strand, at a temperature between 150° C. and 210° C. and maintaining the same temperature for sufficient time to obtain a crystalline product wherein the DSC curves of the same do not show presence of premelt peaks or only so in a negligible amount.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: June 12, 2001
    Assignee: Sinco Engineering S.p.A.
    Inventor: Hussain Al Ghatta
  • Patent number: 6228302
    Abstract: Process for the crystallization of aromatic polyester resins having IV between 0,5 and 0.7 dl/g wherein the resin is extruded in the form of a strand at extruder exit or the chips obtained by cutting the strand are crystallized maintaining them at temperature between 160° C. and 220° C. for sufficient time to obtain a crystallized product wherein the DSC curves do not show the presence of practically any premelt peaks.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: May 8, 2001
    Assignee: Sinco Engineering S.p.A.
    Inventor: Hussain Al Ghatta
  • Patent number: 6150475
    Abstract: Aromatic polyester resins, having improved mechanical and hydrolysis resistant properties, by mixing said aromatic polyester resin with a phenoxy resin, a dianhydride of a tetracarboxylic acid and liquid crystals.
    Type: Grant
    Filed: April 27, 1998
    Date of Patent: November 21, 2000
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Al Ghatta, Sandro Cobror
  • Patent number: 5976654
    Abstract: Polyester resins containing up to 5% by weight of a polymeric liquid crystal and an upgrading agent capable of increasing the I.V. of the resin by polyaddition reaction in the solid state with the end groups of the resin. Fibers, films and biaxially oriented articles obtained from the resins.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: November 2, 1999
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Tonino Severini, Sandro Cobror
  • Patent number: 5902864
    Abstract: Process for the production of aromatic polyester resins starting from resins with an IV from 0.1 to 0.4 dl/g comprising the steps of blending the resin with a dianhydride of a tetracarboxylic acid, extruding the resin under the form of a strand, cooling the strand or the chips obtainable by cutting the strand, at a temperature between 150.degree. C. and 210.degree. C. and maintaining the same temperature for sufficient time to obtain a crystalline product wherein the DSC curves of the same do not show presence of premelt peaks or only in a negligible amount.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: May 11, 1999
    Assignee: Sinco Engineering S.p.A.
    Inventor: Hussain Al Ghatta
  • Patent number: 5869561
    Abstract: Articles from a polyester resin reinforced with glass fiber obtained by melt-shaping of the resin mixed with the glass fiber and a polyfunctional compound capable of increasing the intrinsic viscosity of the resin by addition reactions with the end groups of the rein using melt residence times during the shaping phase lower than 120 sec. and temperatures lower than 300.degree. C.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: February 9, 1999
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Tonino Severini, Sandro Cobror
  • Patent number: 5859180
    Abstract: Process for the solid state polycondensation of polyamide resins by the use in the polycondensation reactor of a quantity of an inert gas such that the ratio by weight between the solid capacity/h at the reactor outlet and that one of gas fed into the reactor is lower than 0.5.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: January 12, 1999
    Assignee: Sinco Engineering S.p.A.
    Inventors: Dario Giordano, Riccardo Bianchi
  • Patent number: 5852134
    Abstract: A process for the preparation of polymeric alloys from polyester resins and polymers containing groups capable of giving addition reaction with functional compounds containing at least two reactive groups comprising the melt state mixture stage of polyester resin, reactive polymer and functional compound of mixture pelletizing and following polyaddition reaction in the solid state at temperatures between 150.degree. and 220.degree. C. to obtain an increase of the polymer intrinsic viscosity of 0.1 dl/g in comparison with the starting polyester resin.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 22, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventor: Hussain Ali Kashif Al Ghatta
  • Patent number: 5817747
    Abstract: Cooling process for polyester and/or polyamide resins downstream of solid-state polycondensation plants in which the cooling is carried out by passing the solid material through two types of equipment in series, of which one is a fluid-bed, the other is a solid/wall cooling equipment. The fluid bed equipment is fed with a stream of inert-gas coming from the solid-state polycondensation reactor, previously subjected to by-products purification, drying and cooling.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: October 6, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventors: Dario Giordano, Giuseppina Boveri
  • Patent number: 5776994
    Abstract: Concentrates of dianhydrides of tetracarboxylic acids in polycarbonate resins containing up to about 50% by weight of dianhydride. The concentrates can be added to aromatic polyester resins in the melt in quantities equivalent to contents of dianhydride from 0.05 to 2% by weight of the resin.
    Type: Grant
    Filed: March 25, 1997
    Date of Patent: July 7, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Al Ghatta, Sandro Cobror
  • Patent number: 5714571
    Abstract: Aromatic polyester resins are continuously crystallized in a fluid bed crystallizer, where the fluidizing gas (nitrogen) enters at a temperature not lower than 195.degree. C. and the average residence time is higher than 5 minutes.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: February 3, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Dario Giordano
  • Patent number: 5708124
    Abstract: Process for the solid state polycondensation of polyester resins, where an inert gas is circulating in a moving bed of polymer at a temperature between 180.degree. and 230.degree. C., characterized by the fact that the ratio by weight between the gas rate of flow per hour and that one of the discharged polymer is lower than 0.6.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 13, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Dario Giordano
  • Patent number: 5696208
    Abstract: Polyamide resins characterized in melt state by high sensitivity to shear forces and high visco-elasticity, obtained by polycondensation/polyaddition in the solid state in presence of polyfunctional compounds capable of reacting with resin terminal groups and/or in presence of polyester resins employed in quantity up to about 40% by weight of the resin mixtures.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: December 9, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Sandro Cobror
  • Patent number: 5681655
    Abstract: Filaments from a polyester resin having an elastic modulus higher than 30 GPa and stress at break greater than 300 MPa. The filaments are obtained by upgrading under stretch filaments prepared from polyester resin mixed in the melt with a polyfunctional compound able to increase the polymer intrinsic viscosity by addition reaction in the solid state with the terminal groups of the resin.
    Type: Grant
    Filed: January 2, 1996
    Date of Patent: October 28, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Tonino Severini, Sandro Cobror
  • Patent number: 5670584
    Abstract: Polyester resins containing up to 5% by weight of a polymeric liquid crystal and an upgrading agent capable of increasing the I. V. of the resin by polyaddition reaction in the solid state with the end groups of the resin. Fibres, films and biaxially oriented articles obtained from the resins.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: September 23, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Ali Kashif Al Ghatta, Tonino Severini, Sandro Cobror
  • Patent number: 5667691
    Abstract: A new process has been developed for separating the water and acetic acid present in the aqueous phase contained in cellulose acetate flakes precipitated from esterification solutions of cellulose. The process includes the step of simultaneously extracting water and acetic acid from the aqueous phase with supercritical carbon dioxide until the content of water and acetic acid in the flakes is substantially reduced.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: September 16, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain Al Ghatta, Arianna Giovannini
  • Patent number: 5618908
    Abstract: Aromatic polyester resins having improved color characteristics obtained incorporating in the resins in the preparation phase of the resin by polycondensation of a diol with an aromatic bicarboxylic acid a violet toner formed of 9,10 anthraquinone -2-hydroxy-4-p-toluidine or having an absorption spectrum comparable to that of the above anthraquinone compound.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: April 8, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventor: Renato Vosa
  • Patent number: 5612011
    Abstract: Process for the purification of an inert gas recycled from a solid state polycondensation (SSP) reactor of aromatic polyester resins, comprising the step of adding the gas with oxygen or gas containing oxygen in stoichiometric quantity or in such an excess that the gas at the outlet of the catalytic bed contains no more than 250 ppm of oxygen, circulating the gas on a catalytic bed comprising Pt or Pt and Pd heated at temperatures from 250.degree. to 600.degree. C. and recycling the gas to SSP reactor with previous drying to eliminate the water formed in the oxidation stage.
    Type: Grant
    Filed: November 16, 1995
    Date of Patent: March 18, 1997
    Assignee: Sinco Engineering S.p.A.
    Inventors: Guido Ghisolfi, Dario Giordano, Giuseppina Boveri, Hussain A. K. Al Ghatta
  • Patent number: 5569510
    Abstract: Process for the production of polyester resins suitable for the manufacture of fibers including a phase of esterification of an aromatic dicarboxylic acid with an alkylenic glycol or of transesterification of a diester of the dicarboxylic acid with the alkylenic glycol, of polycondensation of diester obtained to form a prepolymer with intrinsic viscosity between 0.2 and 0.5 dl/g and, lastly, of polycondensation of the melt polymeric mass added with a dianhydride of a tetracarboxylic acid kept in agitation and on which an inert gas current is circulated.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: October 29, 1996
    Assignee: Sinco Engineering S.p.A.
    Inventors: Hussain A. K. Al Ghatta, Mario Pizzetti
  • Patent number: 5547652
    Abstract: Process for the purification of inert gases containing impurities of organic nature particularly of gas (nitrogen) coming from solid state polycondensation reactors or polyester resins including the gas treatment with the stoichiometric quantity (or slightly higher) of oxygen as regards the present impurities at a temperature between 250.degree. and 600.degree. C. by using Pt or Pt/Pd catalysts supported on a porous solid and the gas recycling directly to the polycondensation reactor before drying to eliminate the water produced during the reaction of impurities oxidation.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: August 20, 1996
    Assignee: Sinco Engineering S.p.A.
    Inventors: Guido Ghisolfi, Dario Giordano, Giuseppina Boveri