Abstract: Aromatic polyester resins having improved color characteristics obtained incorporating in the resins in the preparation phase of the resin by polycondensation of a diol with an aromatic bicarboxylic acid a violet toner formed of 9,10 anthraquinone -2-hydroxy-4-p-toluidine or having an absorption spectrum comparable to that of the above anthraquinone compound.
Abstract: Process for the purification of an inert gas recycled from a solid state polycondensation (SSP) reactor of aromatic polyester resins, comprising the step of adding the gas with oxygen or gas containing oxygen in stoichiometric quantity or in such an excess that the gas at the outlet of the catalytic bed contains no more than 250 ppm of oxygen, circulating the gas on a catalytic bed comprising Pt or Pt and Pd heated at temperatures from 250.degree. to 600.degree. C. and recycling the gas to SSP reactor with previous drying to eliminate the water formed in the oxidation stage.
Type:
Grant
Filed:
November 16, 1995
Date of Patent:
March 18, 1997
Assignee:
Sinco Engineering S.p.A.
Inventors:
Guido Ghisolfi, Dario Giordano, Giuseppina Boveri, Hussain A. K. Al Ghatta
Abstract: Process for the production of polyester resins suitable for the manufacture of fibers including a phase of esterification of an aromatic dicarboxylic acid with an alkylenic glycol or of transesterification of a diester of the dicarboxylic acid with the alkylenic glycol, of polycondensation of diester obtained to form a prepolymer with intrinsic viscosity between 0.2 and 0.5 dl/g and, lastly, of polycondensation of the melt polymeric mass added with a dianhydride of a tetracarboxylic acid kept in agitation and on which an inert gas current is circulated.
Type:
Grant
Filed:
April 11, 1994
Date of Patent:
October 29, 1996
Assignee:
Sinco Engineering S.p.A.
Inventors:
Hussain A. K. Al Ghatta, Mario Pizzetti
Abstract: Process for the purification of inert gases containing impurities of organic nature particularly of gas (nitrogen) coming from solid state polycondensation reactors or polyester resins including the gas treatment with the stoichiometric quantity (or slightly higher) of oxygen as regards the present impurities at a temperature between 250.degree. and 600.degree. C. by using Pt or Pt/Pd catalysts supported on a porous solid and the gas recycling directly to the polycondensation reactor before drying to eliminate the water produced during the reaction of impurities oxidation.