Patents Assigned to Sinopec
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Patent number: 9339801Abstract: The present invention relates to a catalyst for the conversion of methanol to aromatics and the preparation of the same. The catalyst comprising 85 to 99 parts by weight of a ZSM-5 zeolite, 0.1 to 15 parts by weight of element M1, which is at least one selected from the group consisted of Ag, Zn and Ga, and 0 to 5 parts by weight of element M2, which is at least one selected from the group consisted of Mo, Cu, La, P, Ce and Co, wherein the total specific surface area of the catalyst ranges from 350 to 500 m2/g, and the micropore specific surface area ranges from 200 to 350 m2/g. The catalyst has high total specific surface area, micropore specific surface area and micropore volume. Good catalytic activity can be shown from the results of the reaction of aromatics preparation from methanol using the catalyst provided by the present invention.Type: GrantFiled: July 11, 2013Date of Patent: May 17, 2016Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Xiqiang Chen, Zheming Wang, Jingxian Xiao, Feng Xu
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Patent number: 9334339Abstract: Disclosed is a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst is characterized by a high catalyst activity for olefin polymerization and a significant monomer effect. Further disclosed is use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization. The polymer produced therewith is characterized by superior particle morphology, a high bulk density, and/or a narrow molecular weight distribution.Type: GrantFiled: June 9, 2014Date of Patent: May 10, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SINOPEC YANGZI PETROCHEMICAL COMPANY LTD.Inventors: Chuanfeng Li, Hongping Ren, Lin Kan, Feng Guo, Wenrui Wang, Yuming Yi, Shaohui Chen, Jiye Bai
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Publication number: 20160122256Abstract: A method for producing an aromatic hydrocarbon with an oxygenate as raw material, includes: i) reacting an oxygenate in at least one aromatization reactor to obtain an aromatization reaction product; ii) separating the aromatization reaction product to obtain a gas phase hydrocarbons flow X and a liquid phase hydrocarbons flow Y; iii) after removing gas and/or a part of the oxygenate from the gas phase hydrocarbons flow X, a hydrocarbons flow X1 containing a non-aromatic hydrocarbon is obtained; or after removing gas and/or a part of the oxygenate from the gas phase hydrocarbons flow X, a reaction is conducted in another aromatization reactor and a separation is conducted to obtain a flow X2 containing a non-aromatic hydrocarbon and a flow X3 containing an aromatic hydrocarbon. The flows are further treated.Type: ApplicationFiled: October 30, 2014Publication date: May 5, 2016Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Zheming WANG, Weimin Yang, Xiqiang Chen, Jingxian Xiao, Feng Xu
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Patent number: 9327277Abstract: The present invention provides a fibrous IM-5 molecular sieve and the preparation process thereof. According to the process according to the present invention, by adding an appropriate amount of a quaternary ammonium salt with a long carbon chain to the preparation system so as to occur a synergistic action with the organic templet agent, an IM-5 molecular sieve which would be otherwise a rodlike form is converted into the fibrous form. The IM-5 molecular sieve according to the present invention has an aspect ratio greater than that of the rodlike IM-5 molecular sieve obtained according to the prior art, such that the proportion of the exposed periphery crystal face is higher, which benefit to increasing the selectivity of the catalytic reaction for the corresponding crystal face.Type: GrantFiled: October 30, 2012Date of Patent: May 3, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPECInventors: Weiya Yang, Fengxiang Ling, Shaojun Wang, Zhiqi Shen
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Publication number: 20160115783Abstract: Disclosed is a data transmission system and a method for transmission of downhole measurement data to the ground. The system includes a drill string mounted with a logging while drilling measurement tool, and a throw while drilling section, which accommodates a micromemory. The throw while drilling section includes a housing which is mounted outside of the drill string as a sleeve to form a clearance space therebetween; a control circuit; and a wireless transceiver. The throw while drilling section releases, under function of a micromemory release instruction transmitted by the control circuit, the micromemory loaded with the downhole measurement data to the ground.Type: ApplicationFiled: May 22, 2014Publication date: April 28, 2016Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SINOPEC RESEARCH INSTITUTE OF PETROLEUM ENGINEERINGInventors: Yijin Zeng, Wei Zhang, Jibo Li, Weining Ni, Huangsheng Lu, Sanguo Li, Dawei Deng, Zuyang Zhu, Yiting Zheng, Xin Li, Yongjie Li
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Patent number: 9321705Abstract: A process of producing isopropyl benzene which solves the problem of high amount of n-propyl benzene according to the prior art. The process separates the polyisopropyl benzene through a suitable rectification into two streams of relatively lighter and heavier components, wherein the content of diisopropylbenzene in the stream of relatively lighter components is controlled to be at least greater than 95 wt %, and the content of tri-isopropyl benzene in the stream of relatively heavier components is controlled to be at least greater than 0.5 wt %. Such a technical solution subjecting the two streams respectively to the transalkylation solves the problem raised from the prior art, and is useful for the industrial production of isopropyl benzene.Type: GrantFiled: November 15, 2011Date of Patent: April 26, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Huanxin Gao, Bin Zhou, Yilun Wei, Ruifang Gu, Hua Fang, Shufang Ji, Hui Yao
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Patent number: 9314781Abstract: The present invention discloses a catalyst for paraffin isomerization, as well as a preparation method and use thereof. The catalyst comprises a TON molecular sieve modified by rare earth, an inorganic refractory oxide modified by zirconium oxide and a noble metal of group VIII. The weight ratio of the TON molecular sieve modified by rare earth to the inorganic refractory oxides modified by zirconium oxide is 10:90 to 90:10, and the content of the metal of group VIII is 0.1 to 10 wt % based on the metal. When used in the process of isomerization dewaxing of various raw materials containing paraffins, the catalyst can not only decrease the solidifying points of raw oil containing paraffins, but also increase the yield of liquid products. Particularly, when used in the process of isomerization dewaxing of lubricating oil distillates, the catalyst is advantageous in producing base oil for lubricating oil with a high a higher yield, a lower pour point (solidifying point) and a higher viscosity index.Type: GrantFiled: October 13, 2011Date of Patent: April 19, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPECInventors: Huiqing Xu, Quanjie Liu, Liming Jia, Xiwen Zhang, Wei Wang
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Patent number: 9314776Abstract: This invention relates to a composite oxide, production and use thereof as a methane selective oxidizing catalyst. The composite oxide has a composition as illustrated by the formula RhRxMoyVzO?-?, wherein the symbols are as defined in the specification. When used as a methane selective oxidizing catalyst, the present composite oxide provides a high methane conversion and a high selectivity to the aimed products.Type: GrantFiled: October 10, 2013Date of Patent: April 19, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPECInventors: Shudong Zhang, Yingjie Jin, Xiangqian Ni, Jie Li, Xiwen Zhang, Xinwei Zhang
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Publication number: 20160102033Abstract: A fluidized bed reactor is provided, comprising an inlet zone at a lower position, an outlet zone at an upper position, and a reaction zone between the inlet zone and the outlet zone. A guide plate with through holes is disposed in the reaction zone, comprising a dense channel region in an intermediate region thereof and a sparse channel region disposed on a periphery thereof and encompassing the dense channel region. Catalysts in said fluidized bed reactor can be homogeneously distributed in the reaction zone thereof, whereby the reaction efficiency can be improved. A reaction regeneration apparatus comprising said fluidized bed reactor, and a process for preparing olefins from oxygenates and a process for preparing aromatic hydrocarbons from oxygenates using the reaction regeneration apparatus.Type: ApplicationFiled: October 13, 2015Publication date: April 14, 2016Applicants: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPECInventors: Weimin YANG, Xiaohong LI, Siqing ZHONG, Guozhen QI, Jun XU, Zhinan YU
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Publication number: 20160101396Abstract: Device for use in a fluidized bed reactor includes a gas-solid separator communicated with an outlet of the fluidized bed reactor; a vertically arranged damper, a solid outlet of the gas-solid separator communicated with a lower region of the damper, a gas outlet of the gas-solid separator communicated with an upper region of the damper; a fine gas-solid separator, an inlet of the fine gas-solid separator communicated with the upper region of the damper, and a solid outlet of the fine gas-solid separator communicated with the lower region of the damper. Product from the fluidized bed reactor is fed into the preliminary gas-solid separator, most solid catalysts separated and fed into the lower region; the product entraining the rest catalysts is fed into the upper region, and into the fine gas-solid separator, the rest catalysts fed into the lower region; and final product is obtained from the fine gas-solid separator.Type: ApplicationFiled: October 13, 2015Publication date: April 14, 2016Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Shanghai Research Institute Of Petrochemical Technology, SINOPECInventors: Jun XU, Songyuan GU, Siqing ZHONG, Yongming JIN, Zhinan YU, Guozhen QI, Xiaohong LI
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Patent number: 9309467Abstract: Disclosed is a combination process for improved hydrotreating and catalytic cracking of hydrocarbon oils, including: contacting residual oil, catalytic cracking cycle oil, and optional distillate oil with a hydrotreating catalyst under hydrotreating conditions in the presence of hydrogen followed by separation of the reaction products to obtain gas, hydrogenated naphtha, hydrogenated diesel oil, and hydrogenated tail oil; contacting the hydrogenated tail oil and optional normal catalytic cracking feedstock oil with a cracking catalyst under catalytic cracking conditions followed by separation of the reaction products to obtain dry gas, hydrogenated naphtha, liquefied petroleum gas, catalytic cracked gasoline, catalytic cracked diesel oil, and catalytic cracking cycle oil; wherein the hydrogenated tail oil and/or normal catalytic cracking feedstock oil are separated into at least two fractions, the light and the heavy fractions or normal catalytic cracking heavy feedstock oil and normal catalytic cracking lighType: GrantFiled: December 19, 2008Date of Patent: April 12, 2016Assignees: China Petroleum and Chemical Corp., Research Institute of Petroleum Processing, SinopecInventors: Yongcan Gao, Chaogang Xie, Chuanfeng Niu, Jiushun Zhang, Lishun Dai, Hong Nie, Dadong Li, Jun Long, Jianguo Ma, Yan Cui
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Patent number: 9302910Abstract: The invention relates to a short-flow process for desulfurization of circulating hydrogen and a device for the same. A short-flow process for desulfurization of circulating hydrogen is provided, comprising: (a) removing hydrocarbons from the circulating hydrogen mixture, so that the liquid drops of the heavy hydrocarbons in the dispersion phase are separated from the circulating hydrogen in the continuous phase, and a heavy hydrocarbon phase and a mixture phase of circulating hydrogen containing sulfur are obtained; (b) further separating the resultant mixture phase to remove the sulfides therein, so that circulating hydrogen without sulfur is obtained; (c) further separating the resultant circulating hydrogen without sulfur to remove the amine solution therein, so that purified circulating hydrogen is obtained. The invention also provides a device for desulfurization of circulating hydrogen.Type: GrantFiled: September 10, 2009Date of Patent: April 5, 2016Assignees: SHANGHAI HUACHANG ENVIRONMENT PROTECTION CO., LTD., LUOYANG PETROCHEMICAL ENGINEERING CORPORATION (LPEC)/SINOPECInventors: Hualin Wang, Ji Ma, Zhuoqun Qian, Yanhong Zhang, Liquan Li, Qian Zeng, Chonggang Chen, Qiang Yang, Xiaomei Xu, Xin Cui
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Patent number: 9303217Abstract: Disclosed herein is a process for catalytically reforming naphtha, comprising, in the presence of hydrogen gas, contacting naphtha with at least one reforming catalyst under the conditions of a pressure ranging from 0.15 to 3.0 MPa, a temperature ranging from 300 to 540° C., a volume space velocity ranging from 2.1 to 50 h?1, to carry out a shallow catalytic reforming reaction so as to achieve a naphthene conversion ratio of greater than 85 mass %, and a conversion ratio of paraffins to arenes and C4? hydrocarbons of less than 30 mass %.Type: GrantFiled: May 25, 2012Date of Patent: April 5, 2016Assignees: China Petroleum & Chemical Corporation, China Research Institute of Petroleum Processing, SinopecInventors: Aizeng Ma, Jieguang Wang, Jincheng Pan
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Patent number: 9295963Abstract: A process for producing light olefins is provided. A feedstock enters a pre-reaction zone and contacts a catalyst comprising at least one silicon-aluminophosphate molecular sieve and produces a gas-phase stream; the gas-phase stream and the catalyst enter at least one riser, and the gas-phase stream and the catalyst pass from an outlet of the at least one riser and enter a gas-solid rapid separation zone; the separated gas-phase stream enters a separation section; a first portion of the separated catalyst returns to the pre-reaction zone, and a second portion is regenerated in a regenerator; wherein an inlet of the at least one riser extends into the pre-reaction zone, about 60% to about 90% of the height of the at least one riser passes through a heat exchange zone, and the outlet extends into the gas-solid rapid separation zone.Type: GrantFiled: March 5, 2014Date of Patent: March 29, 2016Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SinopecInventors: Guozhen Qi, Siqing Zhong, Wei Chen, Zhinan Yu
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Patent number: 9259711Abstract: The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.Type: GrantFiled: January 9, 2009Date of Patent: February 16, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING SINOPECInventors: Jun Long, Jiushun Zhang, Huiping Tian, Yuxia Zhu
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Patent number: 9260667Abstract: Disclosed is a combination process for improved hydrotreating and catalytic cracking of hydrocarbon oils, including: contacting residual oil, catalytic cracking cycle oil, and optional distillate oil with a hydrotreating catalyst under hydrotreating conditions in the presence of hydrogen followed by separation of the reaction products to obtain hydrogenated tail oil and other products; contacting the hydrogenated tail oil and optional normal catalytic cracking feedstock oil with a cracking catalyst under catalytic cracking conditions followed by separation of the reaction products; wherein the hydrogenated tail oil and/or normal catalytic cracking feedstock oil are separated into at least two fractions prior to contacting the hydrogenated tail oil and/or normal catalytic cracking feedstock oil with the cracking catalyst.Type: GrantFiled: September 14, 2012Date of Patent: February 16, 2016Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Yongcan Gao, Chaogang Xie, Chuanfeng Niu, Jiushun Zhang, Lishun Dai, Hong Nie, Dadong Li, Jun Long, Jianguo Ma, Yan Cui
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Patent number: 9248437Abstract: The present invention provides a hollow IM-5 molecular sieve sphere and the preparation process thereof. The process according to the present invention adds a relatively great amount of the surfactant of a cationic quaternary ammonium salt in the IM-5 molecular sieve system, to form a hollow IM-5 molecular sieve sphere via the micelle action by the surfactant, which structure benefits the mass transfer of the reaction process.Type: GrantFiled: October 30, 2012Date of Patent: February 2, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPECInventors: Fengxiang Ling, Weiya Yang, Shaojun Wang, Zhiqi Shen
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Publication number: 20160023965Abstract: An apparatus for recycling propylene includes a first propylene recovery column, a flash tank, a second propylene recovery column, and a depropanizing column. The apparatus can effectively solve the problem of high power consumption in the prior art, and can be used for the industrial manufacturing of propylene recovery from a propylene oxide apparatus. A process for recycling and refining propylene also is described.Type: ApplicationFiled: July 22, 2015Publication date: January 28, 2016Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPECInventors: Weisheng YANG, Mujin LI, De SHI, Zhi HE
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Patent number: 9243180Abstract: The present invention provides a filtration control agent and a drilling fluid containing the same. The filtration control agent comprises the product obtained from the reaction of water, lignite, aldehyde and sulfonate polymer at 180-220° C. and the units containing sulfonate groups in the molecular chains of sulfonate polymer are at least 30 wt %. The filtration control agent provided by the present invention features a good filtration loss reduction effect and a low viscosity effect and can improve the rheological behavior of the drilling fluid, thereby meeting the requirements of the drilling of deep wells, ultra-deep wells and ultra high pressure formations.Type: GrantFiled: September 26, 2012Date of Patent: January 26, 2016Assignees: China Petroleum & Chemical Corporation, SINOPEC Research Institute of Petroleum EngineeringInventors: Xiaohua Yang, Lin Wang, Yongxue Lin, Sheng Li, Long Chai, Xiaoqiang Dong
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Patent number: 9242236Abstract: A catalyst composition comprising on weight basis the following components: a) 30 to 99.5% of at least one intergrowth molecular sieve; b) 0 to 20% of a rare earth element or oxides thereof; c) 0 to 10% of at least one element from Group VA of the Periodic Table or oxides thereof; d) 0 to 10% of at least one element from Group IIIA of the Periodic Table or oxides thereof; e) 0 to 20% of at least one element from Group IB or IIB of the Periodic Table or oxides thereof; f) 0 to 20% of at least one element from Group IA or IIA of the Periodic Table or oxides thereof; and g) 0 to 65% of a binder, wherein the components b), c), d), e) and f) are supported on the component a), and contents of at least two of the components b), c), d), e) and f) are larger than zero, is described. A process for preparing said catalyst composition and a process for the production of olefins via catalytic cracking by using said catalyst composition are also described.Type: GrantFiled: April 3, 2008Date of Patent: January 26, 2016Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Guangwei Ma, Weimin Yang, Hui Yao, Xiaqin Yang