Patents Assigned to Sinopec
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Publication number: 20150158961Abstract: The present disclosure provides a suspension of a solid catalyst component used in propylene polymerization and a method for preparing the same. The suspension includes the solid catalyst component and a liquid medium containing propylene and an alkane, and is preferably prepared by mixing the solid catalyst component and the alkane to obtain a mixed slurry, which is further mixed with liquid propylene. Using of a proper liquid dispersing agent at a proper proportion and amount enables the solid catalyst component to be more homogeneously dispersed, thus preventing the phenomenon of agglomeration in the polymerization process without using a large amount of the dispersing agent or any additional mixer. The present disclosure further provides a method of propylene polymerization, including feeding the suspension into a reaction system of propylene polymerization, wherein propylene polymerization is initiated under polymerization conditions.Type: ApplicationFiled: December 5, 2014Publication date: June 11, 2015Applicants: China Petroleum & Chemical Corporation, Sinopec Catalyst Co., Ltd., Beijing Research Institute of Chemical Industry, China Petroleum & Chemical CorporationInventors: Jinlai QIN, Haixiang CUI, Xiaodong WANG, Mingzhi GAO, Cuiling XIAO, Yanju SUN, Liang PAN, Xin CHEN, Ziqiang WANG
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Patent number: 9051236Abstract: A method for improving the quality of ethylene glycol products, which mainly solves the technical problem of low UV-light transmittance of the ethylene glycol products present in the prior art. The method successfully solves the problem by use of the technical solution wherein the ethylene glycol raw material and hydrogen are passed through a rotating packed bed reactor loaded with solid oxide catalyst at a temperature of about 20 to about 280° C., a pressure of about 0.1 to about 4.0 MPa, a space velocity of about 0.2 to about 100.0 hr?1 and a molar ratio of hydrogen to ethylene glycol of from about 0.01 to 40:1, and ethylene glycol is obtained after the reaction. The solid oxide catalyst is at least one of copper-based, nickel-based and palladium-based catalysts, and the rotation rate of the rotating packed bed reactor is about 300 to about 5000 rpm.Type: GrantFiled: February 24, 2012Date of Patent: June 9, 2015Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPECInventors: Juntao Liu, Yuhong Zhang, Wanmin Wang
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Publication number: 20150126420Abstract: This invention relates to a lubricating oil composition and production thereof. The lubricating oil composition comprises a Mannich base represented by the following formula (III) (wherein A and R2 are as defined in the specification) and a lubricant base oil. The lubricating oil composition according to this invention exhibits excellent cleansing and dispersing performance and excellent anticorrosion performance.Type: ApplicationFiled: April 25, 2013Publication date: May 7, 2015Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING SINOPECInventors: Shihao Xin, Xin Xie, Zuoxin Huang, Qinghua Duan, Zhiqiang Wu, Lihua Wang
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Publication number: 20150119619Abstract: A method for producing isopropyl benzene includes the following steps. Step A: feeding a first stream containing benzene and a first stream containing propylene into a first reaction zone to contact a first catalyst for alkylation, and obtaining a first stream containing isopropyl benzene from the first reaction zone, dividing the first stream containing isopropyl benzene into a stream Ia and a stream IIa, the stream Ia circulating back into the first reaction zone and the stream IIa entering into a second reaction zone, having the stream entering the second reaction zone to contact a second catalyst for alkylation, and obtaining a second stream containing isopropyl benzene from the second reaction zone, and purifying at least a partial stream IIIa of the second stream containing isopropyl benzene, and obtaining a product isopropyl benzene.Type: ApplicationFiled: October 28, 2014Publication date: April 30, 2015Applicants: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPECInventors: Huanxin GAO, Hongyuan ZONG, Yilun WEI, Hui YAO, Ruifang GU, Hua FANG, Shufang JI
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Patent number: 9017545Abstract: Disclosed is a process for hydrotreating inferior naphtha fraction, comprising: (1) warming a recycle oil in a heating device; (2) mixing the inferior naphtha fraction with the recycle oil before and/or after the heating device; and (3) feeding the mixture of the inferior naphtha fraction and the recycle oil into a separating unit, wherein the gas-liquid separation is realized at least to obtain a gas phase and a liquid phase, wherein the gas phase comprises gasified inferior naphtha, wherein the gas phase enters a hydrotreating reactor to undergo hydrotreating, and wherein part of the liquid phase circulates to the heating device as the recycle oil; wherein warming of the recycle oil is controlled to ensure the temperature of gas phase from the separator at least reaches the inlet temperature of the hydrotreating reactor. Comparing with the prior art, the inventive process effectively solves the coking problem of the hydrogenating unit for inferior naphtha fraction.Type: GrantFiled: October 26, 2012Date of Patent: April 28, 2015Assignees: China Petroleum & Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemicals, SinopecInventors: Ying Zhang, Baozhong Li, Ronghui Zeng, Youliang Shi
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Patent number: 8981023Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: March 17, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co. Ltd.Inventors: Hongping Ren, Chuanfeng Li, Xiaoli Yao, Feng Guo, Zhonglin Ma, Haibin Chen, Kaixiu Wang, Jingwei Liu, Yaming Wang
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Patent number: 8975208Abstract: The present invention provides an adsorbent for removing sulfur from cracking gasoline or diesel fuel. The adsorbent has excellent abrasion-resistance and desulfurization activity. The adsorbent comprises from about 5 to about 35 wt % of alumina, from about 3 to about 30 wt % of silica, from about 10 to about 80 wt % of at least one oxide of metal selected from Groups IIB and VB, from about 3 to about 30 wt % of at least one metal accelerant selected from Groups VIIB and VIII, and from about 0.5 to about 10 wt % of at least one oxide of metal selected from Groups IA and IIA, based on the total weight of the adsorbent.Type: GrantFiled: December 30, 2009Date of Patent: March 10, 2015Assignees: China Petroleum Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Jun Long, Huiping Tian, Wei Lin
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Patent number: 8962895Abstract: The present invention relates to a method for the production of ethylene glycol using a feedstock comprising an oxalate and a catalyst containing copper and/or a copper oxide, comprising contacting the feedstock with the catalyst in a reactor under the conditions of a temperature in the range from about 170 to about 270° C., a weight hourly space velocity of the oxalate in the range from about 0.2 to about 5 h?1, a molar ratio of hydrogen to the oxalate in the range from about 40:1 to about 200:1 and a reaction pressure in the range from about 1.5 to about 10 MPa, to produce an effluent containing ethylene glycol, in which the reactor is a tube-array reactor using partitioned heat exchange and adopting outer and inner tubes configured in a double-tube structure to facilitate the heat exchange of the catalyst.Type: GrantFiled: February 24, 2012Date of Patent: February 24, 2015Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SinopecInventors: Juntao Liu, Weimin Yang, Lei Li, Wanmin Wang, Linna Zhang, Haifeng Song
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Patent number: 8957135Abstract: The present invention relates to a composite powder, preparation and use thereof. The composite powder according to the present invention is prepared by intimately mixing an irradiated or non-irradiated rubber latex with a slurry of inorganic particles in a ratio corresponding to that of rubber particles to inorganic particles in the composite powder according to the present invention, and then drying the resultant mixture. The composite powder according to the present invention comprises agglomerates composed of powdery rubber particles and inorganic particles, with inorganic particles being uniformly distributed either inside the agglomerats or both inside the agglomerates and on the surfaces thereof. The composite powder according to the present invention can be easily dispersed in plastic matrixes and thus can be compounded with plastics to produce toughened plastics and thermoplastic elastomers.Type: GrantFiled: December 31, 2012Date of Patent: February 17, 2015Assignees: China Petroleum & Chemical Corporation, Sinopec Beijing Research Institute of Chemical IndustryInventors: Yiqun Liu, Jinliang Qiao, Xiaohong Zhang, Fan Huang, Jianming Gao, Banghui Tan, Genshuan Wei, Zhihai Song, Zhida Chen
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Patent number: 8957169Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 17, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co. Ltd.Inventors: Xiaoli Yao, Chuanfeng Li, Hongping Ren, Zhonglin Ma, Feng Guo, Kaixiu Wang, Jingwei Liu, Yaming Wang
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Publication number: 20150041366Abstract: This disclosures provides an adsorbent which, on the basis of the total weight of the adsorbent, comprises: 1) a Si—Al molecular sieve having an A-FAU structure, wherein A represents a monovalent cation, in an amount of 1-20 wt %, 2) at least one binder selected from the group consisting of titanium dioxide, stannic oxide, zirconium oxide and alumina, in an amount of 3-35 wt %, 3) a silica source, in an amount of 5-40 wt %, 4) zinc oxide, in an amount of 10-80 wt %, and 5) at least one promoter metal selected from the group consisting of cobalt, nickel, iron and manganese, based on the metal, in an amount of 5-30 wt %, wherein at least 10 wt % of the promoter metal is present in a reduced valence state. This adsorbent exhibits improved activity and stability, and at the same time, is capable of significantly improving the octane number of the product gasoline.Type: ApplicationFiled: July 27, 2012Publication date: February 12, 2015Applicants: RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Wei Lin, Huiping Tian, Zhenbo Wang
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Patent number: 8952112Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 10, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Company Ltd.Inventors: Chuanfeng Li, Hongping Ren, Xiaoli Yao, Zhonglin Ma, Feng Guo, Kaixiu Wang, Jingwei Liu, Yaming Wang, Lijuan Yang
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Patent number: 8952113Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.Type: GrantFiled: October 13, 2010Date of Patent: February 10, 2015Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Company Ltd.Inventors: Chuanfeng Li, Hongping Ren, Xiaoli Yao, Lin Kan, Bo Liu, Zhonglin Ma, Feng Guo, Kaixiu Wang, Yaming Wang, Lijuan Yang
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Patent number: 8940939Abstract: A process of oxidizing cyclohexane, comprising feeding cyclohexane, an aqueous hydrogen peroxide solution and optionally an organic solvent into a reaction zone through a feed inlet thereof under the oxidation reaction conditions for contact, and providing all or most of the oxidation product at the reaction zone bottom, wherein a part or all of the packing in the reaction zone is a titanium silicate molecular sieve-containing catalyst. The process of oxidizing cyclohexane according to the present invention carries out the oxidation in the reaction zone, which, firstly, utilizes the latent heat from reaction sufficiently so as to achieve energy-saving; secondly, increases the yield of target product and the availability of oxidizer; and thirdly, allows the separation of the oxidation product from the raw material cyclohexane as the reaction proceeds, such that the cost for subsequent separations can be saved.Type: GrantFiled: May 2, 2012Date of Patent: January 27, 2015Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Min Lin, Chunfeng Shi, Bin Zhu, Yingchun Ru
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Patent number: 8932457Abstract: A catalytic conversion process uses a catalytic cracking catalyst having a relatively homogeneous activity containing mainly large pore zeolites in a catalytic conversion reactor. The reaction temperature, residence time of oil vapors and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from about 12 to about 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feed stock oil and containing a diesel. The reaction temperature ranges from about 420° C. to about 550° C. The residence time of oil vapors ranges from about 0.1 to about 5 seconds. The weight ratio of the catalytic cracking catalyst/feedstock is about 1-about 10.Type: GrantFiled: October 20, 2010Date of Patent: January 13, 2015Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Youhao Xu, Jianhong Gong, Congli Cheng, Shouye Cui, Zhihai Hu, Yun Chen
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Patent number: 8921592Abstract: A process of producing oxalate by CO gas phase method includes the following steps: a) introducing nitrite salt, water and an inorganic acid first into a reactor I to produce a NO containing effluent I; and separating the resultant effluent to obtain the effluent II of NO; b) introducing the effluent II of NO, a C1-C4 alkanol and oxygen into a reactor II to be subjected to the reaction, and separating the resultant effluent to obtain the effluent IV of C1-C4 alkyl nitrites; c) introducing the effluent IV of C1-C4 alkyl nitrites and a CO gas stream into a coupling reactor where they are reacted to produce a NO containing effluent VI. The reactor I and/or the reactor II are preferably rotating supergravity reactors. Therefore, the process is applicable to the industrial production of oxalate by CO gas phase method.Type: GrantFiled: June 9, 2011Date of Patent: December 30, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SINOPECInventors: Weimin Yang, Juntao Liu, Wanmin Wang, Lei Li
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Method for selective hydrogenation of phenylacetylene using composite bed in the presence of styrene
Patent number: 8916736Abstract: The present invention discloses a process for the selective hydrogenation of phenylacetylene in the presence of styrene conducted in a combined bed, which process comprises under hydrogenation reaction conditions, passing a hydrocarbon fraction feedstock containing phenylacetylene and styrene through a combined bed reactor containing a catalyst A and a catalyst B to contact the feedstock with the catalyst A and the catalyst B in turn, wherein the catalyst A is a nickel-based catalyst, the catalyst B is at least one selected from the group consisting of palladium-based catalysts and copper-based catalysts, and a weight ratio of the catalyst A loaded to the catalyst B loaded is from 0.5:1 to 5:1.Type: GrantFiled: December 17, 2009Date of Patent: December 23, 2014Assignees: Shanghai Research Institute of Petrochemical Technology, Sinopec, China Petroleum & Chemical CorporationInventors: Siqin Li, Juntao Liu, Zhiyan Zhu, Junhua Zhu, Jun Kuai -
Publication number: 20140364576Abstract: Disclosed is a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst is characterized by a high catalyst activity for olefin polymerization and a significant monomer effect. Further disclosed is use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization. The polymer produced therewith is characterized by superior particle morphology, a high bulk density, and/or a narrow molecular weight distribution.Type: ApplicationFiled: June 9, 2014Publication date: December 11, 2014Applicants: SINOPEC YANGZI PETROCHEMICAL COMPANY LTD., CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Chuanfeng LI, Hongping REN, Lin KAN, Feng GUO, Wenrui WANG, Yuming YI, Shaohui CHEN, Jiye BAI
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Patent number: 8906205Abstract: A process for separating ethylene glycol and 1,2-butanediol. A material flow containing ethylene glycol and 1,2-butanediol gets into the lower-middle part of the azeotropic rectification column C3 after the light components are removed by the separating columns C1 and C2, wherein the ethylene glycol and the azeotropic agent added from the top of the column form azeotrope which is distilled out from the top of the column and gets into the phase separator D1 after being condensed, the upper phase enriched with azeotropic agent after the phase was separated returns to the top of the column to continue to participate in azeotropy, and the lower phase enriched with ethylene glycol gets into the fourth separating column C4 to be refined to obtain the ethylene glycol product.Type: GrantFiled: January 8, 2013Date of Patent: December 9, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SINOPECInventors: Jian Xiao, Yanzi Guo
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Patent number: 8900522Abstract: The invention relates to an ethylene cracking furnace having a multi-pass radiant coil, comprising at least one radiant section. In the radiant section there are provided with bottom burners and/or sidewall burners, and at least one set of multi-pass radiant coil longitudinally arranged in the radiant section. The multi-pass radiant coil is a four- to ten-pass type radiant coil. At least one tube of the multi-pass radiant coil is arranged to be spatially adjacent to a tube which is not consecutive to said at least one tube. With this arrangement, the thermal radiation influence between tubes with high temperature can be reduced, so that the tubes with low temperature can absorb the radiation heat from the tubes with high temperature. Therefore, the surface temperature of the tubes with high temperature can be reduced, thus extending the lifetime of the radiant coil and the operational cycle of the cracking furnace.Type: GrantFiled: October 26, 2010Date of Patent: December 2, 2014Assignees: China Petroleum & Chemical Corporation, SINOPEC Engineering Incorporation, China Petroleum & Chemical Corporation, Beijing Institute of Chemical IndustryInventors: Xiou He, Changli Li, Zhaobin Zhang, Jingkun Liu, Mujun Yuan, Cong Zhou, Yuping Guo, Yonghua Zhao, Hainü Shen