Patents Assigned to Sinopec
  • Publication number: 20120083539
    Abstract: The present invention provides a process for preparing methanol, dimethyl ether, and low carbon olefins from syngas, wherein the process comprises the step of contacting syngas with a catalyst under the conditions for converting the syngas into methanol, dimethyl ether, and low carbon olefins, characterized in that, the catalyst contains an amorphous alloy consisting of components M and X wherein the component X represents an element B and/or P, the component M represents two or more elements selected from Group IIIA, IVA, VA, IB, IIB, IVB, VB, VIB, VIIB, VIII and Lanthanide series of the Periodic Table of Elements. According to the present process, the syngas can be converted into methanol, dimethyl ether, and low carbon olefins in a high CO conversion, a high selectivity of the target product, and high carbon availability.
    Type: Application
    Filed: December 15, 2009
    Publication date: April 5, 2012
    Applicants: Research Instutute of Petroleum Procesing, Sinopec, China Petroleum & Chemical Corporation
    Inventors: Qiang Fu, Xiaoxin Zhang, Yibin Luo, Xuhong Mu, Baoning Zong
  • Publication number: 20120077718
    Abstract: A copolymer and preparation method and application thereof are disclosed. The copolymer is random copolymer obtained from monomers consisting of acrylamide, acrylic acid, alkenyl sulfonate, 2-acrylamido-dodecyl sulfonate, p-styrene sulfonate or isoprene sulfonate and so on. The copolymer of present invention can be used as fluid loss additive and has good fluid loss properties, which would not make the drilling fluid thicken at high temperature of 200° C. and high salt conditions of saturated brine. It has a medium-pressure fluid loss after aging and rolling for 16 h at high temperature of 200° C., as measured in accordance with the American Petroleum Institute Standard Test at room temperature, and has good properties of high temperature-resisting and salt-resisting.
    Type: Application
    Filed: September 23, 2011
    Publication date: March 29, 2012
    Applicants: SINOPEC RESEARCH INSTITUTE OF PETROLEUM ENGINEERING, China Petroleum & Chemical Corporation
    Inventors: Xiaohua YANG, Lin Wang, Jiafen Li, Xiaolin Qian, Xianguang Wang, Sheng Li, Liwei Ren, Changming Su, Zhifa Wang, Guichuan Liu, Bingzhong Shi
  • Publication number: 20120053382
    Abstract: The present invention provides a catalyst comprising metallic Pt and/or Pd supported on a binder-free zeolite for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock, wherein the amount of metallic Pt and/or Pd is of 0.01-0.8 wt %, preferably 0.01-0.5 wt % on the basis of the total weight of the catalyst, and the binder-free zeolite is selected from the group consisting of mordenite, beta zeolite, Y zeolite, ZSM-5, ZSM-11 and composite or cocrystal zeolite thereof. The present invention also provides a process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock using said catalyst.
    Type: Application
    Filed: November 7, 2011
    Publication date: March 1, 2012
    Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Deju WANG, Zhongneng LIU, Xueli LI, Minbo HOU, Zheming WANG, Jianqiang WANG
  • Patent number: 8110527
    Abstract: The present invention discloses an alumina support having multiple pore structure, wherein the alumina support has a specific surface area of from 40 to 160 m2/g and a total pore volume of from 0.3 to 1.2 cm3/g; a pore volume of pores having a pore diameter of less than 30 nm comprises 5 to 60% of the total pore volume; a pore volume of pores having a pore diameter of from 30 to 60 nm comprises 20 to 75% of the total pore volume; and a pore volume of pores having a pore diameter of larger than 60 nm comprises 20 to 60% of the total pore volume. The present invention further discloses a catalyst used for selective hydrogenation of a pyrolysis gasoline, comprising: (a) the alumina support according to the invention; and (b) 0.01 to 1.2 wt. % of metal palladium or palladium oxides, based on the weight of the alumina support.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: February 7, 2012
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology Sinopec
    Inventors: Zhongneng Liu, Zaiku Xie, Xinghua Jiang, Xiaoling Wu, Minbo Hou, Hongyuan Zong
  • Patent number: 8088335
    Abstract: A conversion apparatus for catalytic cracking a hydrocarbon feed to light hydrocarbon comprises at least one riser reactor, a dense bed reactor, a disengager, and a stripper. A dense bed reactor which is separated from disengage, is employed to enforce further cracking hydrocarbon to light olefins, with low methane yield. Moreover, the spent catalysts discharged from the outlet of the dense bed reactor can be introduced into the stripper via a specific catalyst transporting channel, to maintain catalyst concentration in the dense bed reactor that can be advantageous to deeper cracking of the intermediate products to produce more light olefins, particularly propylene.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: January 3, 2012
    Assignees: China Petroleum and Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Jun Long, Kejia Xu, Shuandi Hou, Zhijian Da, Chaogang Xie, Jiushun Zhang, Zhanzhu Zhang
  • Patent number: 8084657
    Abstract: A process of making p-xylcne comprising processing a mixed feedstock containing benzene, toluene, C8 aromatic hydrocarbons, C9 and higher aromatic hydrocarbons, and non-aromatic hydrocarbons through a series of operations and various units, including a C9 and higher aromatic hydrocarbon dealkylation unit, a toluene selective disproportionate unit, an adsorption separation unit, an isomerization unit, and a crystallization separation unit.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: December 27, 2011
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology Sinopec
    Inventors: Dejin Kong, Hongli Guo, Luping Zhong, Weisheng Yang, Jian Xiao
  • Patent number: 8083951
    Abstract: The invention provides a method for purifying MTO quench water and scrubbing water via mini-hydrocyclone separation, comprising: removing the entrapped catalyst particles from the MTO quench water via mini-hydrocyclone separation; cooling the quench water purified by mini-hydrocyclone separation so as to effect the recycling of water; removing the entrapped catalyst particles from the MTO quench water to be stripped via mini-hydrocyclone separation, so as to reduce the deposition of the catalyst particles within the stripping tower; removing the entrapped catalyst particles from the MTO scrubbing water via mini-hydrocyclone separation; and cooling the scrubbing water purified via mini-hydrocyclone separation so as to effect the recycling of water. The invention also provides an apparatus for purifying MTO quench water and scrubbing water via mini-hydrocyclone separation.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: December 27, 2011
    Assignees: East China University of Science and Technology, Luoyang Petrochemical Engineering Corporation (LPEC) Sinopec
    Inventors: Hualin Wang, Yanhong Zhang, Qiang Yang, Ji Ma, Zhishan Bai, Yu Liu, Longhu Liang, Lei Shi, Jie Zhang
  • Patent number: 8047821
    Abstract: The Ring Rack Oil Pumping Machine is comprised of: a base, a frame mounted on the base, a roller mounted at the frame top, a sprocket case connects to the middle of the frame; a input shaft having a lower sprocket and a drive shaft having an upper sprocket are installed at the bottom and top of the sprocket case respectively, the upper sprocket and lower sprocket are connected by a chain; a guide wheel, track gear and centralizer wheel are mounted in sequence on the end of the drive shaft extended out of the sprocket case; the track gear meshes with a rack, a slide rail is mounted with the frame, and a sliding base (21) connected with the slide rail (20) moveably. Comparing to currently using pumping units, this invention features simple structure, high safety and reliability, upgraded efficiency, easy maintenance, smooth running and high durability.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: November 1, 2011
    Assignee: Sinopec Group, Shengli Petroleum Administration Transport Corporation
    Inventors: Xinyi Gu, Huanbo Zhou, Yonghai Liu, Zhisheng Tian, Zhengyou Feng
  • Publication number: 20110257424
    Abstract: A process of producing C1-C4 alkyl nitrite, comprising the following steps: a) firstly feeding nitrogen oxide and oxygen into Reactor I, contacting with an aluminosilicate catalyst, and reacting to produce an effluent I containing NO2 and unreacted NO; b) feeding the effluent I and C1-C4 alkanol into Reactor II, and reacting to produce an effluent II containing C1-C4 alkyl nitrite; and c) separating the effluent II containing C1-C4 alkyl nitrite to obtain C1-C4 alkyl nitrite; wherein reactor I is a fixed bed reactor, and Reactor II is a rotating high-gravity reactor; said nitrogen oxide in step a) is NO, or a mixed gas containing NO and one or more of N2O3 and NO2, wherein the molar number of NO is greater than that of NO2, if any; and the molar ratio of NO in nitrogen oxide to oxygen is 4-25:1.
    Type: Application
    Filed: April 14, 2011
    Publication date: October 20, 2011
    Applicants: Shanghai Research Institute of Petrochemical Technology SINOPEC, China Petroleum & Chemical Corporation
    Inventors: Juntao LIU, Weimin YANG, Wanmin WANG, Linna ZHANG
  • Patent number: 8030508
    Abstract: The present invention relates to an organosilicon porous zeolite, preparation of the same, and use of the same. The organosilicon porous zeolite of the invention has the following composition on molar basis: (1/n)Al2O3:SiO(2-m/2):mR:xM, wherein n=5 to 1000, m=0.001 to 1, x=0.005 to 2, R is at least one selected from the group consisting of alkyl, alkenyl and phenyl and connected to a silicon atom in the framework of the zeolite, and M is an organic amine templating agent, wherein a solid Si29NMR spectrum of the zeolite has at least one Si29 nuclear magnetic resonance peak in the range of from ?80 to +50 ppm, and wherein a X-ray diffraction pattern of the zeolite exhibits diffraction peaks corresponding to d-spacing of 12.4±0.2, 11.0±0.3, 9.3±0.3, 6.8±0.2, 6.1±0.2, 5.5±0.2, 4.4±0.2, 4.0±0.2 and 3.4±0.1 ?. The porous zeolite can be used as an adsorbent or as a component of a catalyst for the conversion of an organic compound.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: October 4, 2011
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute Of Petrochemical Technology Sinopec
    Inventors: Huanxin Gao, Bin Zhou, Yilun Wei, Hua Fang, Ruifang Gu, Shufang Ji
  • Publication number: 20110178257
    Abstract: The present invention relates to a new type of oil displacement agent and the process for preparing the same. The oil displacement agent is formed of a polyaclylamide-based polymer characterized by a partly crosslinked and partly branched structure, wherein said polyacrylamide-based polymer is obtained by aqueous copolymerization of acrylamide and N,N-dimethylaminoethyl methacrylate as a functional monomer, in the presence of a redox initiator system.
    Type: Application
    Filed: January 14, 2011
    Publication date: July 21, 2011
    Applicants: Geoscience Research Institute of Shengli Oilfield Branch, SINOPEC, Sichuan University
    Inventors: Huanquan Sun, Zhenquan Li, Xulong Cao, Guangsu Huang, Xinwang Song, Xiaohong Cui, Kun Liu, Jing Zheng, Xiaoyan Chen, Zhiqing Su, Zuming Jiang, Jinrong Wu
  • Publication number: 20110165029
    Abstract: The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system.
    Type: Application
    Filed: March 2, 2011
    Publication date: July 7, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PERTROLEUM PROCESSING. SINOPEC
    Inventors: Zhanzhu ZHANG, Lifeng HU, Xiaojin TANG, Shaobing WANG, Shuandi HOU, Junyi MAO, Hongliang QU
  • Publication number: 20110127193
    Abstract: The present invention relates to a catalyst for catalytic cracking fluidized-bed, and the technical problems to be primarily solved by the present invention are high reaction temperature, low cryogenic activity of catalysts and worse selectivity during the preparation of ethylene-propylene by catalytically cracking naphtha. The present invention uses the composition having the chemical formula (on the basis of the atom ratio): AaBbPcOx, so as to magnificently solve said problems. The present invention therefore can be industrially used to produce ethylene and propylene by catalytically cracking naphtha.
    Type: Application
    Filed: December 23, 2010
    Publication date: June 2, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC
    Inventors: Zaiku Xie, Guangwei Ma, Weimin Yang, Hui Yao, Liang Chen
  • Publication number: 20110127192
    Abstract: The present invention relates to a hydrocracking catalyst comprising an acidic silica-alumina, an optional alumina, an effective quantity of at least one VIII Group metal component(s), an effective quantity of at least one VIB Group metal component(s) and an organic additive, wherein the organic additive is one or more selected from the group consisting of an oxygen-containing or nitrogen-containing organic compound, and the molar ratio of the organic additive to the VIII Group metal component(s) is 0.01-10. The present invention relates further to a process for producing the hydrocracking catalyst and use of the catalyst in a process for hydrocracking hydrocarbon oils. The hydrocracking catalyst provided according to the present invention shows a higher activity for aromatic hydrosaturating and ring-opening reaction, as compared with the prior art hydrocracking catalyst.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 2, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum Processing, Sinopec
    Inventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Yahua Shi, Dadong Li
  • Publication number: 20110100876
    Abstract: The present invention provides a composite solid acid catalyst consisting of from 50%-80% by weight of a porous inorganic support, from 15% to 48% by weight of a heteropoly compound loaded thereon, and from 2% to 6% by weight of an inorganic acid. The present invention further provides a process for preparing said composite solid acid catalyst and a process for conducting an alkylation reaction by using such catalyst. The composite solid acid catalyst of the present invention has the acid sites type of Brönsted acid and has an acid sites density of not less than 1.4×10?3 mol H+/g. Moreover, said composite solid acid catalyst has the homogeneous acid strength distribution, and is a solid acid catalyst having excellent performances.
    Type: Application
    Filed: October 29, 2010
    Publication date: May 5, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum processing, Sinopec
    Inventors: Yigong HE, Zheng MAN, Xuhong MU
  • Patent number: 7923399
    Abstract: A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2??I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.
    Type: Grant
    Filed: March 31, 2005
    Date of Patent: April 12, 2011
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing Sinopec
    Inventors: Jun Long, Zhijian Da, Huiping Tian, Zhenyu Chen, Weilin Zhang, Xingtian Shu, Jiushun Zhang, Yuxia Zhu, Yujian Liu
  • Patent number: 7919536
    Abstract: The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: April 5, 2011
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Zhanzhu Zhang, Lifeng Hu, Xiaojin Tang, Shaobing Wang, Shuandi Hou, Junyi Mao, Hongliang Qu
  • Publication number: 20110073523
    Abstract: The present invention relates to a catalytic conversion process for producing more diesel and propylene, comprising contacting the feedstock oil with a catalyst having a relatively homogeneous activity in a reactor, wherein the reaction temperature, weight hourly space velocity and weight ratio of the catalyst/feedstock oil are sufficient to obtain a reaction product containing from 12 to 60% by weight of a fluid catalytic cracking gas oil relative to the weight of the feedstock oil; the fluid catalytic cracking gas oil is fed into the fluid catalytic cracking gas oil treatment device for further processing. Catalytic cracking, hydrogenation, solvent extraction, hydrocracking and process for producing more diesel are organically combined together, and hydrocarbons such as alkanes, alkyl side chains in the feedstocks for catalysis are selectively cracked and isomerized.
    Type: Application
    Filed: September 23, 2010
    Publication date: March 31, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum Processing, Sinopec
    Inventors: Shouye CUI, Youhao XU, Zhihai HU, Jianhong GONG, Chaogang XIE, Yun CHEN, Zhigang ZHANG, Jianwei DONG
  • Patent number: 7875756
    Abstract: A process for producing lower olefins is disclosed. The technical problem is to overcome the defects presented in the prior art including high reaction pressure, high reaction temperature, low yield and selectivity of lower olefins as the target products, poor stability and short life of catalyst, and limited suitable feedstocks. The disclosed process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock contact with a crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a reaction effluent containing lower olefins; and b) separating lower olefins from the reaction effluent; wherein, the reaction pressure is from ?0.1 MPa to <0 MPa.
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: January 25, 2011
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology Sinopec
    Inventors: Zaiku Xie, Juntao Liu, Siqing Zhong, Wenwei Wu
  • Publication number: 20100326888
    Abstract: The present invention provides a catalytic cracking catalyst, processing method and use thereof. When the catalyst is added into a commercial catalytic cracking unit, it has an initial activity of not higher than 80, preferably not higher than 75, more preferably not higher than 70, a self-balancing time of 0.1-50 h, and an equilibrium activity of 35-60. Said method enables the activity and selectivity of the catalyst in the catalytic cracking unit to be more homogeneous and notably improves the selectivity of the catalytic cracking catalyst, so as to obviously reduce the dry gas and coke yields, to sufficiently use steam and to reduce the energy consumption of the FCC unit.
    Type: Application
    Filed: June 24, 2010
    Publication date: December 30, 2010
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum Processing, Sinopec
    Inventors: Youhao XU, Shouye CUI, Jun LONG, Jianhong GONG, Zhijian DA, Jiushun ZHANG, Yuxia ZHU, Yibin LUO, Jinlian TANG