Patents Assigned to Sinopec
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Patent number: 8609064Abstract: Disclosed are a novel NU-85 molecular sieve having a specific surface area ranging from about 405 m2/g to about 470 m2/g and a pore volume ranging from about 0.27 cm3/g to about 0.35 cm3/g, and processes for preparing the NU-85 molecular sieve.Type: GrantFiled: October 11, 2011Date of Patent: December 17, 2013Assignees: China Petroleum & Chemical Corporation, Fushun Research Institute of Petroleum and Petrochemical, SinopecInventors: Zhizhi Zhang, Xiwen Zhang, Bo Qin
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Patent number: 8609767Abstract: Toughened thermosetting resins comprising thermosetting resins and rubber particles having an average particle size in the range of 20 to 500nm. The toughened resins are obtained by mixing a fully vulcanized powdery rubber having an average particle size in the range of 20 to 500nm with thermosetting resin prepolymers and then curing them. The toughened thermosetting resins comprise rubber phases having a small, uniform and stable particle size, which results in a very significant toughening effect, especially when crazes rapidly grow (as in a standard Izod impact test). The toughened thermosetting resins are excellent in impact resistance, strength, modulus and heat resistance, and when appropriately toughened, the thermosetting resins can be enhanced in terms of impact strength, glass transition temperature and heat distortion temperature.Type: GrantFiled: October 8, 2002Date of Patent: December 17, 2013Assignees: China Petroleum and Chemical Corporation, Sinopec Beijing Research Institute of Chemical IndustryInventors: Fan Huang, Jinliang Qiao, Yiqun Liu, Xiaohong Zhang, Jianming Gao, Zhihai Song
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Publication number: 20130331617Abstract: A process for producing ethylene glycol includes contacting an oxalate with a fluidized bed catalyst under the following conditions: a reaction temperature of from about 170 to about 270° C., a weight space velocity of oxalate of from about 0.2 to about 7 hours?1, a hydrogen/ester molar ratio of about 20˜200:1, a reaction pressure of from about 1.5 to about 10 MPa, and a reaction temperature difference T of from about 1 to about 15° C. The fluidized bed catalyst includes: a) from about 5 to about 80 parts by weight of copper and the oxide thereof, b) from about 10 to about 90 parts by weight of at least one carrier selected from silica, molecular sieve or alumina, c) from about 0.01 to about 30 parts by weight of bismuth and tungsten metallic elements or the oxides thereof, or cerium and niobium metallic elements or the oxides thereof.Type: ApplicationFiled: February 24, 2012Publication date: December 12, 2013Applicants: Shanghai Research Institute of Petrochemical Technology, Sinopec, China Petroleum & Chemical CorporationInventors: Weimin Yang, Juntao Liu, Wanmin Wang, Jun Kuai
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Publication number: 20130331618Abstract: A method for improving the quality of ethylene glycol products, which mainly solves the technical problem of low UV-light transmittance of the ethylene glycol products present in the prior art. The method successfully solves the problem by use of the technical solution wherein the ethylene glycol raw material and hydrogen are passed through a rotating packed bed reactor loaded with solid oxide catalyst at a temperature of about 20 to about 280 ° C., a pressure of about 0.1 to about 4.0 MPa, a space velocity of about 0.2 to about 100.0 hr?1 and a molar ratio of hydrogen to ethylene glycol of from about 0.01 to 40:1, and ethylene glycol is obtained after the reaction. The solid oxide catalyst is at least one of copper-based, nickel-based and palladium-based catalysts, and the rotation rate of the rotating packed bed reactor is about 300 to about 5000 rpm.Type: ApplicationFiled: February 24, 2012Publication date: December 12, 2013Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Juntao Liu, Yuhong Zhang, Wanmin Wang
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Patent number: 8604143Abstract: Disclosed are catalyst compositions for isoprene polymerization formed from components comprising (A) at least one titanium halide; (B) at least one organic aluminum compound comprising at least one alkyl aluminum of formula AlR3, wherein each of the three Rs is independently chosen from linear and branched C1-6 alkyl groups; and (C) at least one electron donor comprising at least one polyether compound of formula (I) and/or at least one tetrahydro-furfuryl ether compound of formula (II). Also disclosed are processes for preparation of the catalyst compositions and processes using the catalyst compositions for isoprene polymerization.Type: GrantFiled: October 28, 2011Date of Patent: December 10, 2013Assignees: China Petroleum & Chemical Corporation, Sinopec Beijing Research Institute of Chemical IndustryInventors: Chao Wang, Chuanqing Li, Guozhu Yu, Aimin Liang, Jie Zhang, Lin Xu, Pengfei Lv, Huiling Liu
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Patent number: 8597500Abstract: A catalytic conversion process to convert inferior feedstock to high quality fuel oil and propylene is disclosed. Inferior feedstock is introduced into first and second reactor zone, wherein first step and second step reactions occur by contacting with catalytic conversion catalyst. Product vapors include fluid catalytic cracking gas oil (FGO) which is introduced into a hydrotreating unit and/or extraction unit to obtain hydrotreated FGO and/or extracted FGO. Hydrotreated FGO and/or extracted FGO returns to the first reactor zone and/or another catalytic cracking unit to obtain propylene and gasoline. The extracted oil of said FGO is rich in double ring aromatics and the raffinate of said FGO is rich in chain alkane and cycloalkane. More particularly, the invention utilizes petroleum oil resources efficiently for decreasing the yield of dry gas and coke significantly.Type: GrantFiled: March 13, 2009Date of Patent: December 3, 2013Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Youhao Xu, Lishun Dai, Zhigang Zhang, Shouye Cui, Jianhong Gong, Chaogang Xie, Jun Long, Hong Nie, Zhijian Da, Jiushun Zhang, Tao Liu, Anguo Mao
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Publication number: 20130317179Abstract: This invention relates to a supported quaternary phosphonium catalyst, preparation thereof and use thereof in producing dialkyl carbonates. The supported quaternary phosphonium catalyst of this invention has the following average molecular structure (I), and is characterized by a relatively high and stable catalyst activity. wherein, each of X, L, n, R1, R2, R3 and is the same as that in the specification.Type: ApplicationFiled: May 15, 2013Publication date: November 28, 2013Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Liangfeng CHEN, Wenjun HE
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Patent number: 8580702Abstract: The present invention discloses a catalyst for toluene shape selective disproportionation, comprising: a) 45 to 95 wt % of ZSM-5 molecular sieve having an average particle size of from 0.3 to 6 ?m and a molar ratio of SiO2 to Al2O3 of from 20 to 120; b) 0.01 to 30 wt % of at least one metal selected from the group consisting of Group IIB metals, Group IIIB metals, rare earth elements and Group VIII metals other than nickel, or oxide(s) thereof; c) 0 to 20 wt % of at least one metal selected from the group consisting of Group VA metals, Group VIB metals and alkaline earth metals, or oxide(s) thereof; d) 1 to 25 wt % of a silica inert surface coating derived from an organopolysiloxane; and e) 1 to 50 wt % of a binder. The present invention further discloses a process for shape selectively disproportionating toluene into p-xylene, comprising contacting a reaction stream containing toluene with the catalyst for toluene shape selective disproportionation under toluene disproportionation conditions.Type: GrantFiled: November 2, 2007Date of Patent: November 12, 2013Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Dejin Kong, Zhirong Zhu, Wei Li, Qingling Chen, Rong Zhang
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Patent number: 8574522Abstract: A process for selective oxidative dehydrogenation of a hydrogen-containing CO mixed gas, comprising contacting a hydrogen-containing CO mixed gas raw material with at least one catalyst entity having an increased activity gradient disposed in a reactor under at least one reaction condition chosen from a reaction temperature ranging from 100 to 300° C., a volume space velocity ranging from 100 to 10000 h?1, and a reaction pressure ranging from ?0.08 to 5.0 MPa, wherein the molar ratio of oxygen to hydrogen in the raw material ranges from 0.5:1 to 5:1.Type: GrantFiled: April 15, 2011Date of Patent: November 5, 2013Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Juntao Liu, Siqin Li, Linna Zhang, Lei Li, Jun Kuai
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Patent number: 8552074Abstract: The present invention provides a process for preparing methanol, dimethyl ether, and low carbon olefins from syngas, wherein the process comprises the step of contacting syngas with a catalyst under the conditions for converting the syngas into methanol, dimethyl ether, and low carbon olefins, characterized in that, the catalyst contains an amorphous alloy consisting of components M and X wherein the component X represents an element B and/or P, the component M represents two or more elements selected from Group IIIA, IVA, VA, IB, IIB, IVB, VB, VIB, VIIB, VIII and Lanthanide series of the Periodic Table of Elements. According to the present process, the syngas can be converted into methanol, dimethyl ether, and low carbon olefins in a high CO conversion, a high selectivity of the target product, and high carbon availability.Type: GrantFiled: December 15, 2009Date of Patent: October 8, 2013Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Qiang Fu, Xiaoxin Zhang, Yibin Luo, Xuhong Mu, Baoning Zong
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Publication number: 20130260324Abstract: A fired heater includes a fired heater body with an air inlet and a flue gas outlet, and a flue gas waste heat recovery system communicated with the fired heater body and including at least two heat exchange chambers. A first port of each of the heat exchange chambers can be communicated with the flue gas outlet or the air inlet, and a second port of each of the heat exchange chambers can be communicated with the outside air or a fume extractor. When the first port of at least one heat exchanger chamber is communicated with the flue gas outlet and the second port thereof is communicated with the fume extractor, the first port of at least another heat exchange chamber is communicated with the air inlet and the second port thereof is communicated with the outside air.Type: ApplicationFiled: March 29, 2013Publication date: October 3, 2013Applicants: LUOYANG PETROCHEMICAL ENGINEERING CORPORATION/SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Derui Wang, Liran Yang, Tiefeng Zhang
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Publication number: 20130253208Abstract: The present invention provides a catalyst and the preparation process thereof and a process of epoxidising olefin using the catalyst. The catalyst contains a binder and a titanium silicate, the binder being an amorphous silica, the titanium silicate having a MFI structure, and the crystal grain of the titanium silicate having a hollow structure, with a radial length of 5-300 nm for the cavity portion of the hollow structure, wherein the adsorption capacity of benzene measured for the titanium silicate under the conditions of 25 degrees C., P/P0=0.Type: ApplicationFiled: October 11, 2011Publication date: September 26, 2013Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum Processing, Sinope Sinopec, Hunan Changling Pertrochemical Science and Technology Development Co. Ltd.Inventors: Min Lin, Hua Li, Wei Wang, Chijian He, Xiaoju Wu, Jizao Gao, Xichun She, Jun Long, Qingling Chen
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Publication number: 20130248415Abstract: The present invention discloses a catalyst for paraffin isomerization, as well as a preparation method and use thereof. The catalyst comprises a TON molecular sieve modified by rare earth, an inorganic refractory oxide modified by zirconium oxide and a noble metal of group VIII. The weight ratio of the TON molecular sieve modified by rare earth to the inorganic refractory oxides modified by zirconium oxide is 10:90 to 90:10, and the content of the metal of group VIII is 0.1 to 10 wt % based on the metal. When used in the process of isomerization dewaxing of various raw materials containing paraffins, the catalyst can not only decrease the solidifying points of raw oil containing paraffins, but also increase the yield of liquid products. Particularly, when used in the process of isomerization dewaxing of lubricating oil distillates, the catalyst is advantageous in producing base oil for lubricating oil with a high a higher yield, a lower pour point (solidifying point) and a higher viscosity index.Type: ApplicationFiled: October 13, 2011Publication date: September 26, 2013Applicants: FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Huiqing Xu, Quanjie Liu, Liming Jia, Xiwen Zhang, Wei Wang
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Patent number: 8541630Abstract: Disclosed is a process for producing dimethyl ether from methanol, which is characterized in that the absorbing liquid used in said absorbing column is the bottom liquid of DME-fractionating column and/or bottom waste water of the methanol-recovering column. Said process can significantly reduce energy consumption of the apparatus.Type: GrantFiled: March 26, 2008Date of Patent: September 24, 2013Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Xiangbo Guo, Zheng Li, Qiang Li, Chaogang Xie, Keyong Yang, Anguo Mao, Xueliang Chang, Genquan Zhu
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Patent number: 8536286Abstract: A composite catalyst useful in the production of polyethylene, which comprises at least a first catalyst and a second catalyst separated by a polymer layer, with the first catalyst and the second catalyst being identical or different, is described. A composite catalyst useful in the production of polyethylene with a broad molecular weight distribution in a single polymerization reactor, which comprises at least a first catalyst and a second catalyst separated by a polymer layer, with the first catalyst and the second catalyst being different, is also described. A process for preparing said catalysts and a process for the production of a polyethylene by using said catalysts are also described.Type: GrantFiled: March 28, 2008Date of Patent: September 17, 2013Assignees: China Petroleum & Chemical Corporation, Zhejiang University, Sinopec Engineering IncorporationInventors: Wenqing Wu, Yongrong Yang, Jingdai Wang, Binbo Jiang, Guanghai Luo, Shufang Wang, Yi Wang, Xianfong Zhang, Guodong Han
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Publication number: 20130236933Abstract: The present invention provides a method for producing a fermentation product from lignocellulose-containing material, a method for converting lignocellulose-containing material into a hydrolyzate comprising mono- and oligo-saccharides, and a method for treating lignocellulose-containing material, all of which comprise the step of mixing an acid pre-treated lignocellulose-containing material and an alkaline pre-treated lignocellulose-containing material. The present invention further provides a fermentation product made according to the method for producing a fermentation product.Type: ApplicationFiled: December 9, 2011Publication date: September 12, 2013Applicants: Novozymes A/S, Sinopec, CofcoInventors: Hongzhi Huang, Yun Wang, Haiyu Ren, Ye Chen, Feng Xu
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Publication number: 20130237730Abstract: A process of producing isopropyl benzene which solves the problem of high amount of n-propyl benzene according to the prior art. The process separates the polyisopropyl benzene through a suitable rectification into two streams of relatively lighter and heavier components, wherein the content of diisopropylbenzene in the stream of relatively lighter components is controlled to be at least greater than 95 wt %, and the content of tri-isopropyl benzene in the stream of relatively heavier components is controlled to be at least greater than 0.5 wt %. Such a technical solution subjecting the two streams respectively to the transalkylation solves the problem raised from the prior art, and is useful for the industrial production of isopropyl benzene.Type: ApplicationFiled: November 15, 2011Publication date: September 12, 2013Applicants: Shanghai Research Institute of Petrochemical Technology, SINOPEC, China Petroleum & Chemical CorporationInventors: Huanxin Gao, Bin Zhou, Yilun Wei, Ruifang Gu, Hua Fang, Shufang Ji, Hui Yao
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Patent number: 8532969Abstract: A numerical simulation method for characterizing fluid channeling along large-aperture fractures of reservoirs relates to the field of petroleum reservoir development research and computational fluid dynamics. The conventional method can not effectively represent the rapid fluid channeling along large-aperture fractures. Aiming at solving the above technical problem, an advanced method is provided in the present invention. In the invented method, the geometric similarity and hydraulic similarity treatments of large-aperture fractures can be made simultaneously, moreover, the traditional numerical simulation software was improved to be an unstructured grid simulator. Therefore, the method of the present invention can effectively simulate the rapid fluid channeling along large-aperture fractures, consequently it can ensure the reliability of the simulation results and provide reasonable reference for the adjustment and optimization of oil field development plans.Type: GrantFiled: March 4, 2011Date of Patent: September 10, 2013Assignee: Geo-science Research Institute of Shengli Oil Field Co. Ltd. of SinopecInventors: Yang Li, Yongyi Zhou, Duanping Wang, Xiantai Liu, Shuling Sui, Shiming Zhang, Yong Wang, Haibo Su, Yajuan Dong, Yanhu Chen, Yong Song
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Patent number: 8529753Abstract: Disclosed is a combined process for hydrotreating and catalytic cracking of residue, wherein the residue, catalytic cracking heavy cycle oil with acidic solid impurity being removed, optional distillate oil and adistillate of catalytic cracking slurry oil from which the acidic solid impurity is removed are fed into residue hydrotreating unit, the hydrogenated residue obtained and optional vacuum gas oil are fed into catalytic cracking unit to obtain various products; the catalytic cracking heavy cycle oil from which the acidic solid impurity is removed is circulated to the residue hydrotreating unit; the catalytic cracking slurry oil is separated by distilling, the distillate of the catalytic cracking slurry oil after removing off the acidic solid impurity is circulated to the residue hydrotreating unit.Type: GrantFiled: December 27, 2007Date of Patent: September 10, 2013Assignees: Research Institute of Petroleum Processing, Sinopec, China Petroleum & Chemical CorporationInventors: Chuanfeng Niu, Lishun Dai, Yongcan Gao, Dadong Li, Yahua Shi, Hong Nie, Qinghe Yang
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Publication number: 20130225397Abstract: The present invention relate to a binderless molecular sieve catalyst and a process for preparing the same, which are mainly useful for solving the problems of the current catalysts, such as lower activity, less pore volume and worse diffusivity. The present invention relates to a novel binderless molecular sieve catalyst, comprising, based on the weight of the catalyst, 90-100 wt. % of a molecular sieve, 0-10 wt. % of a binder, and 0-10 wt. % of an anti-wear agent, wherein said catalyst has a pore volume of 0.1-0.5 ml/g, an average pore diameter of 50-100 nm, and a porosity of 20-40%; the anti-wear agent is selected from the rod or needle-like inorganic materials having a length/diameter ratio of 2-20. Said catalyst has the advantages of higher activity, greater pore volume, larger average pore diameter and porosity, and better diffusivity, and well solves said problems and can be used for the industrial preparation of binderless molecular sieve catalysts.Type: ApplicationFiled: August 23, 2011Publication date: August 29, 2013Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Guangwei Ma, Huiming Zhang, Jingxian Xiao, Liang Chen, Xiqiang Chen