Abstract: A multimetallic reforming catalyst and the preparation process thereof are disclosed. Said catalyst comprises the following components on the basis of mass percent: 0.01-2.0 of a Group VIII metal, 0.01-5.0 of a Group IVA metal, 0.01-10.0 of Eu, 0.01-10.0 of Ce, 0.10-10.0 of a halogen, and 63.00-99.86 of a refractory inorganic oxide. This catalyst has relatively high activity and selectivity, low carbon deposition rate and long lifetime for reformation of naphthas.

Abstract: The present invention relates to a process for carrying our gas-liquid countercurrent processing comprising passing the liquid material and the gas reactant in countercurrent flow through the fixed bed of catalyst in a reactor, characterized in that the fixed bed of catalyst includes two or more catalyst layers, with the difference of voidage between the adjacent catalyst layers being at least 0.05. The voidages of the catalyst layers can be increased or decreased in the direction of the flow of the liquid phase. The process of the invention can be effected with an increased range of gas-liquid ratio and an improved stability and flexibility.

Abstract: A catalyst for olefin polymerization having the following structural formula (I): wherein R1 is selected from the group consisting of hydrogen, C1-C12 alkyl, C1-C12 alkoxy, or C6-C12 aryl, R2 and R2′ are respectively selected from hydrogen and C1-C4 alkyl, R3 is selected from the group consisting of hydrogen, C1-C12 alkyl, C1-C12 alkoxy and C6-C12 aryl, and M is selected from Ti, Zr, and Hf The catalyst is suitable for olefin polymerization to yield polymerized products with high molecular weight and high insertion rate of comonomers.

Abstract: A silicon-containing alumina support, a process for preparing the support, and a catalyst containing the support are provided. The alumina support includes an additive silicon enriched on its surface, with the difference between the atomic ratio of silicon to aluminum on the surface of alumina support and that of the alumina support is at least 0.10. The process for preparing the silicon-containing alumina support comprises adding a nanometer silicon compound. The inventive alumina support can be used in manufacturing a catalyst for hydrotreating hydrocarbons with good physico-chemical properties and performance.

Abstract: The present invention discloses a process for hydroconverting a heavy hydrocarbon chargestock, wherein said chargestock oil is first contacted with a highly active homogeneous hydrogenation catalyst to effect the hydrogenation reaction so that macromolecular radicals of the residue (the precursor of coke) form as less as possible, thereby decreasing the output of coke in the hydrocracking of the residue; when the reaction proceeds to a certain extent, a solid powder is added to adsorb the macromolecular radicals of the residue formed during the reaction and lower their reaction activity, thereby preventing them from further condensing to coke and/or depositing due to polymerization. The synergetic action of the two sorts of substances makes it possible to produce substantively no coke or less coke during the hydrogenation of residue in a suspension bed and prolong the operation lifetime of the unit.

Abstract: An acidic amorphous silica-alumina having large specific surface area and a large pore volume, a carrier complex and a hydrotreating catalyst containing said acidic amorphous silica-alumina, in particular a hydrocracking catalyst containing said acidic amorphous silica-alumina in combination with a modified zeolite-Y for treating petroleum hydrocarbon materials to produce middle distillates, and processes for the preparation thereof. Said amorphous silica-alumina has a SiO2 content of 10-50 wt %, a specific surface area of 300-600 m2/g, a pore volume of 0.8-1.5 ml/g and an IR acidity of 0.25-0.60 mmol/g. The catalyst according to the present invention shows a relatively high activity and mid-distillate selectivity and can be particularly used in hydrocracking process for producing mid-distillates in a higher yield.

Abstract: A process for removing unreacted ammonia from an effluent of a catalyst bed used in a hydrocarbon ammoxidation reaction is provided. The process includes a step of providing a fluidized bed reactor. The reactor includes the catalyst bed for reacting ammonia and hydrocarbons therein. The reactor also includes a dilute phase of the catalyst bed disposed above the catalyst bed. The reactor further includes a set of internals disposed at least partially within the dilute phase of the catalyst bed. The reactor additionally includes an inlet of a first-stage cyclone separator disposed above the set of internals. The process also includes a step of removing the unreacted ammonia from the effluent of the catalyst bed by passing the effluent through the set of internals. The ammonia and hydrocarbons present in the effluent contact the dilute phase of the catalyst bed and react therein.

Abstract: A storage-stable modified asphalt composition, which comprises: 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatibilizer, 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound, and the softening point difference of its product determined by the stability test is lower than 2.5° C. The process for preparing said modified asphalt composition is mixing 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatibilizer 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound under certain conditions. The modified asphalt provided by the present invention has good storage-stability. The preparation process provided by the present invention is simple, and there is no need for special apparatus.

Abstract: A catalyst component for the (co)polymerization of olefins is provided. The catalyst comprises titanium, magnesium halogen and a mixed electron-donor and a catalyst for the (co)polymerization of olefins comprising:(A) the catalyst component; (B) an organic aluminum compound; and (C) an organic silicon compound. A polymer with high and adjustable stereospecificity and broad molecular weight distribution can be prepared by using the catalyst.

Abstract: Disclosed is a catalytic promoter for fluid catalytic cracking of hydrocarbons, comprising a HZSM-5 zeolite in an amount of 5-65 wt % based on the total weight of the catalytic promoter, said zeolite being modified with Zn and at least one element selected from the group consisting of P, Ga, Al, Ni and rare earth elements, the combined amount of said modifying elements being 0.01-10.37 wt % based on total weight of said modified HZSM-5 zeolite. A reduced olefin content in gasoline from catalytic cracking process, an increased gasoline octane number and an increased lower olefin yield can be obtained using said catalytic promoter.

Abstract: A downflow catalytic cracking reactor, comprising: one or more catalyst delivery pipes, reactor top cover, one or more feed nozzles, reactor vessel, downflow reaction pipe, the upper end of the reaction vessel is close connected with top cover along the direction of circumference; the bottom of the reactor vessel is close connected with the outer wall of the downflow reaction pipe; the upper section of the downflow reaction pipe locates inside the reactor vessel, while the lower section extends from the bottom of the reactor vessel; feed nozzle locates on the top cover and/or side wall of the reactor vessel with the outlet of the feed nozzle being above the inlet of downflow reaction pipe; catalyst delivery pipe is fixedly jointed with the reactor vessel and communicated with catalyst lifting zone formed by the reactor vessel and the downflow reaction pipe. Besides, the present invention also provides the use of the reactor.

Abstract: A combined process of low degree solvent deasphalting and delayed coking, which comprises feeding a deasphalting stock and a solvent into an extractor and making the yield of the deasphalted oil 70 wt %-95 wt %, and introducing a part or all of the deasphalted oil and optionally a conventional coking stock into a delayed coker. This process increases the yield of liquid products, removes the heavy asphaltene which is prone to coke, extends the run length of the delayed coker, and at the same time, lowers the content of impurities in coke, enlarges the sources of the stocks for producing the needle coke.

Abstract: A guard catalyst, comprising an alumina support and molybdenum and/or tungsten and nickel and/or cobalt supported on the alumina support, wherein the total ammonia integral adsorption heat of said alumina support does not exceed 25 J/g, the percentage taken up by the ammonia integral adsorption heat of the ammonia differential adsorption heat greater than 100 kJ/mol does not exceed 10% of the total ammonia integral adsorption heat. Compared to the catalysts of the prior art, the guard catalyst has higher catalytic activity, less coke deposit, lower reduction rate of pore volume, better stability of activity, and higher strength.

Abstract: The present invention relates to a highly active midbarrel hydrocracking catalyst and a process for the preparation thereof. The support of the catalyst comprises a modified zeolite-Y, a modified zeolite-&bgr;, alumina, etc. The composite of the modified zeolite-Y and zeolite-&bgr; exhibits a good synergistically catalytic effect. The catalyst prepared by supporting Group VIB and/or Group VIII metal components is useful in the hydrocacking of heavy oils with high content of sulfur and nitrogen to produce high quality middle distillates with maximum output. The activity of and selectivity to middle distillates of the catalyst are remarkably raised simultaneously. Moreover, the solidifying point of the produced diesel is remarkably lowered.

Abstract: A method of producing polyester filaments by heat drawing with hot tubes comprising shaping by lateral blowing of air the polyester melt extruded through the spinneret; passing the cooled as-spun fibers into hot tubes and heat drawing them; obtaining polyester filaments after the procedures of bundling, oiling, entangling, winding and the like, wherein the hot tube temperature is 80-200° C. and the winding speed is 2500-5300 m/min. The heated hot tube for drawing consists of an internal tube assembly and an electromagnetic induction heating element. The latter is a coil of high temperature resistant metal wire wound on the external wall of the internal tube. In the coil a current is passed, which is controlled by a temperature control circuit of a single return circuit.

Abstract: The present invention discloses a process for regenerating titanium-containing catalysts, characterized in that a deactivated catalyst is treated in an acidic solution having a pH value of ≦3, and then dried and calcined. The process is simple in procedure and can make the catalytic activity, selectivity and stability of the regenerated catalyst be recovered to the level of its fresh catalyst.

Abstract: The present invention provides an improved selective hydrogenation process for removing C10-C16 diolefins in the product from dehydrogenation of C10-C16 paraffins to mono-olefins, which process includes bringing the mixture stream of paraffins and olefins containing C10-C16 mono-olefins and C10-C16 diolefins into contact with a specific hydrogenation catalyst in a plurality of hydrogenation reactors connected in series under the reaction conditions for hydrogenation. Hydrogen is injected into each reactor respectively. To convert the diolefins in the mixture stream of paraffins and olefins into mono-olefins, &ggr;-alumina having a specific surface area of 50-300 m2/g and a pore volume of 0.2-2.0 cm3/g is used as the supporter of the hydrogenation catalyst, palladium is supported on the supporter as the main catalyst element and an element selected from silver, gold, tin, lead or potassium is supported on the supporter as the promoter.

Abstract: A SAPO-11 silicoaluminopihosphate molecular sieve, its preparation method, and a catalyst containing the same are disclosed. The X-ray diffraction data of the molecular sieve before removing the template by calcination are as listed in Table 1. The molar composition of this molecular sieve after removing the template by calcination expressed in anhydrous oxides is Al2O3: yP2O5: zSiO2, in which y has a value of 0.60-1.20, and z has a value of 0.05-1.3, characterized in that after removing the template by calcination, its X-ray diffraction data are as listed in Table 3, and that the crystal structures of the molecular sieve before and after removing the template by calcination are substantially the same. The catalyst is composed of 10-85% by weight of said SAPO-11 molecular sieve, 0.05-1.5% by weight of Pd or Pt, and the balance is alumina.

Abstract: The present invention relates to a highly active titanium based supported catalyst suitable for olefin (co)polymerization, preparation and use of the same. The catalyst according to the present invention is obtained by supporting a titanium based catalyst component containing a halide promoter on spherical silica. The resultant catalyst is excellent in its particle morphology and flowability, has highly catalytic activity, has excellent hydrogen response and has superior comonomer incorporation, the polymer prepared by using such a catalyst has its particle morphology further improved.

Abstract: A catalyst for hydrofining fraction oils, comprises an alumina carrier and at least one metal and/or thereof oxide of Group VIB and at least one metal and/or thereof oxide of Group VIII supported on said alumina carrier. The pore volume of said alumina carrier is not less than 0.35 ml/g, in which the pore volume of the pores having a diameter of 40-100 angstrom accounts for more than 80% of the total pore volume, the alumina carrier is prepared by a special process. The catalyst possesses relatively high hydrogenation activity.