Patents Assigned to Societe Anonyme
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Publication number: 20240066493Abstract: A hydrogen production facility having equipment with a nitridation protective layer is provided. The hydrogen production facility can include a reformer configured to catalytically convert a feed stream into a product stream comprising hydrogen, the reformer having a plurality of catalyst tubes and a plurality of burners configured to provide heat to the catalyst tubes; means for providing the feed stream to the reformer from an ammonia source, wherein the feed stream comprises at least 90% of ammonia, wherein the plurality of catalyst tubes comprise a nitridation protective layer on an inner surface of the catalyst tubes.Type: ApplicationFiled: August 25, 2022Publication date: February 29, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Christoph BEYER, Robert BREINING, Dieter ULBER
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Publication number: 20240068744Abstract: In a method for liquefying a gas rich in carbon dioxide, the gas is compressed to a first pressure greater than its critical pressure in a compressor to form a compressed gas, the compressed gas is cooled through heat exchange with a refrigerant to a variable temperature to form a cooled compressed gas with a density between 370 and 900 kg/m3, the cooled compressed gas is cooled at supercritical pressure in a first heat exchanger to a temperature below the critical temperature, the gas cooled below the critical temperature is expanded to a second pressure between 45 and 60 bara to form a diphasic fluid which is separated in a phase separator to form a liquid and a gas, and a liquid portion originating from the phase separator provides cold to the first heat exchanger.Type: ApplicationFiled: March 2, 2022Publication date: February 29, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Michael TRAN, Mathieu LECLERC
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Publication number: 20240068081Abstract: A method for converting an existing steam methane reformer (SMR) to produce hydrogen via ammonia cracking is provided. The method can include the steps of: providing the existing SMR, wherein the SMR was formerly used to produce hydrogen from a hydrocarbon feedstock; and improving the nitridation resistance of the inner surface of the equipment by adding a protective layer to an inner surface of equipment to be used in the existing SMR, wherein the equipment is selected from the group consisting of a catalyst tube, feed piping, a feed preheater, process gas heat exchangers, and combination thereof.Type: ApplicationFiled: August 25, 2022Publication date: February 29, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Christoph BEYER, Robert BREINING, Dieter ULBER
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Publication number: 20240068746Abstract: A method and apparatus for restarting an air separation unit comprising a system of columns including at least a first distillation column and a heat exchanger positioned below the first column with its main axis vertical and with its cold end adjacent to the bottom of the first column, in which, during the restart, air is sent to the exchanger and at least one portion of the cooled air is sent in gaseous form to the atmosphere.Type: ApplicationFiled: December 16, 2021Publication date: February 29, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Benoit DAVIDIAN, Jean-Marc PEYRON
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Patent number: 11916267Abstract: An installation for supplying a fuel cell with hydrogen comprising a fuel cell, a liquefied hydrogen storage facility and a supply circuit that includes at least one upstream end connected to the storage facility and one downstream end connected to a fuel inlet of the fuel cell, the supply circuit including at least one system for heating hydrogen by heat exchange with a heat source and a set of control valves, the liquefied hydrogen storage facility being configured to keep the liquefied hydrogen in equilibrium with a gaseous phase at a determined nominal storage pressure of between 1.5 and 4.5 bar, the supply circuit including a buffer tank for pressurized gaseous hydrogen which is configured to store the hydrogen withdrawn from the storage facility and heated by the heating system, the set of valves being configured to accumulate pressurized gas in the buffer tank at a determined storage pressure of between 4 and 100 bar, for example between 6 and 8 bar.Type: GrantFiled: March 25, 2021Date of Patent: February 27, 2024Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Laurent Allidieres
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Patent number: 11912651Abstract: A method and apparatus for producing methanol from a synthesis gas is provided. The method includes (i) producing, in a partial oxidation chamber, the synthesis gas having a stoichiometric number of less than 1.8 by performing a partial oxidation process with a hydrocarbon stream and an oxygen stream, (ii) passing, in a water-gas shift reactor, the synthesis gas over a water-gas shift catalyst to convert at least a portion of carbon monoxide and water into hydrogen and carbon dioxide, (iii) producing a dry, shifted synthesis gas by separating liquid condensate from shifted synthesis gas, (iv) combining, in a recycle compressor, the dry, shifted synthesis gas with a recycle synthesis gas comprised of unreacted synthesis gas and a hydrogen rich product to form a mixed synthesis gas stream, and (v) converting, in a cooled methanol synthesis reactor, at least a portion of the mixed synthesis gas stream into methanol.Type: GrantFiled: March 11, 2022Date of Patent: February 27, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Karsten Covella, Hans Kopetsch, Bryce Williams, Julien Aoun
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Patent number: 11912576Abstract: An integrated process for producing a purified and converted synthesis gas and a corresponding plant including initially converting in a synthesis gas generation stage a carbon-containing input material into a raw synthesis gas which in a subsequent CO conversion zone is altered in respect of its H2/CO ratio and finally sent to a gas scrubbing zone operating according to a physical gas scrubbing process with methanol as the absorption medium in which the content of unwanted gas constituents, in particular of acidic gas constituents, in the synthesis gas is reduced.Type: GrantFiled: October 30, 2019Date of Patent: February 27, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Stefan Walter
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Patent number: 11913720Abstract: A supply quantity adjustment device 500 comprises: a total demand quantity calculation unit 502 that calculates a total demand quantity used at a supply destination, based on plant information; an excess/deficit information setting unit 503 that compares the total demand quantity and a flow rate set value and sets a first calculated pressure value; a backup coefficient setting unit that sets a backup coefficient set value based on a reference gasholder pressure, the first calculated pressure value, a reference backup pressure set value, and a measured gasholder pressure value; and a production coefficient setting unit that compares a production pressure set value obtained by adding the reference gasholder pressure and a first pressure output value with the measured gasholder pressure value, and sets a production coefficient so as to modify a variation in the quantity of product gas produced by the air separation apparatus.Type: GrantFiled: March 22, 2021Date of Patent: February 27, 2024Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Takuya Kaneda, Shigenobu Kuwada
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Patent number: 11913719Abstract: A liquefaction apparatus that automatically adjusts the load on the liquefaction apparatus correspondingly with an upper limit value of contracted power in different time slots, and which is capable of maximizing the amount of liquefied product produced and of achieving optimum operating efficiency is provided.Type: GrantFiled: January 22, 2021Date of Patent: February 27, 2024Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Takuya Kaneda
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Patent number: 11913718Abstract: A method for producing power and argon is provided by providing a residual gas stream, purifying the residual gas stream in a front-end purification unit to remove carbon dioxide, thereby forming a purified residual gas stream, and introducing the purified residual gas stream to a cold box, wherein the purified residual gas stream is cooled and expanded within the cold box to produce power and then fed to a distillation column system for separation therein, thereby forming an argon-enriched stream and optionally a nitrogen-enriched stream and/or an oxygen-enriched stream, wherein the residual gas stream is sourced from a retentate stream of a cold membrane having oxygen, nitrogen, carbon dioxide, and argon.Type: GrantFiled: November 27, 2019Date of Patent: February 27, 2024Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Guillard, Michael A. Turney, Abigail Bonifacio
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Publication number: 20240060715Abstract: A liquefaction system comprises: a temperature setting unit for setting an inlet gas temperature on entry to a cold turbine; a control valve for controlling an amount of gas fed to the cold turbine, correspondingly with an inlet gas temperature measured by the temperature measuring unit; and a control unit which compares the inlet gas temperature measured by the temperature measuring unit with a warning temperature set value plus a margin, and sets a first operating state when the inlet gas temperature is equal to or less than the warning temperature set value plus the margin and also sets an emergency stoppage temperature set value at the warning temperature set value plus the margin, and sets a second operating state when the inlet gas temperature is greater than the warning temperature set value plus the margin, the control unit performing control in response to the second operating state to make a degree of opening of the control valve greater than a degree of opening during the first operating state in oType: ApplicationFiled: August 22, 2023Publication date: February 22, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventor: Takuya KANEDA
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Publication number: 20240058762Abstract: A hollow fiber membrane bundle useful for manufacturing a wide variety of hollow fiber membrane modules having different flow configurations includes hollow fiber membranes arranged around a porous support tube, a cured resin tubesheet formed at first end of the bundle, and either a cured resin nub or a cured resin tubesheet formed at a second end of the bundle. The bore(s) of the hollow fiber membranes are open at a face of the tubesheet adjacent the first end of the bundle. The tubesheet has an annular structure that encapsulates the hollow fiber membranes and the porous support tube at the first end of the bundle but which does not completely block a bore of the porous support tube, wherein the collection tube has a plurality of orifices formed therein at least at positions adjacent the nub.Type: ApplicationFiled: August 16, 2022Publication date: February 22, 2024Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Sandeep K. KARODE, Karl BEERS, Sudhir S. KULKARNI, Tim POLUDNIAK, Fan Z. WORLEY, Ed SANDERS, JR.
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Publication number: 20240058763Abstract: A hollow fiber membrane bundle useful for manufacturing a wide variety of hollow fiber membrane modules having different flow configurations includes hollow fiber membranes arranged around a porous support tube, a cured resin tubesheet formed at first end of the bundle, and either a cured resin nub or a cured resin tubesheet formed at a second end of the bundle. The bore(s) of the hollow fiber membranes are open at a face of the tubesheet adjacent the first end of the bundle. The tubesheet has an annular structure that encapsulates the hollow fiber membranes and the porous support tube at the first end of the bundle but which does not completely block a bore of the porous support tube, wherein the collection tube has a plurality of orifices formed therein at least at positions adjacent the nub.Type: ApplicationFiled: August 16, 2022Publication date: February 22, 2024Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Sandeep K. KARODE, Karl BEERS, Sudhir S. KULKARNI, Tim POLUDNIAK, Fan Z. WORLEY, Ed SANDERS, JR.
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Patent number: 11904343Abstract: The invention relates to a device for injecting a fluid, in particular a cryogenic fluid, the device comprising a fluid feed head and a fluid dispenser body, detachably mounted on said feed head, said feed head comprising a groove for circulating the fluid fed to said body, said groove being closed when the body is mounted on the feed head and said groove being open when the feed head and the body are detached from one another.Type: GrantFiled: November 30, 2017Date of Patent: February 20, 2024Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide France IndustrieInventors: Jo Algoet, Alain Brangeon, Michel Pichou, Christian Reymond
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Patent number: 11906247Abstract: A reformer furnace having a reaction space formed with reaction tubes, a firing space fitted with burners and a flue gas channel in fluid connection with the firing space. The burners are arranged at a first end face of the reformer furnace and produce flames oriented towards a second end face to fire the reaction tubes. The flue gas channel has a transition region and a withdrawal region, wherein the flue gas channel is connected to the second end face of the firing space via the transition region and the transition region of the flue gas channel has a reduced channel diameter compared to the withdrawal region of the flue gas channel. The transition region has a constriction relative to the withdrawal region which results in a hydraulic decoupling between the firing space and the withdrawal region of the flue gas channel.Type: GrantFiled: November 13, 2020Date of Patent: February 20, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Expoitation des Procédés Georges ClaudeInventor: Antonio Coscia
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Publication number: 20240053094Abstract: In a hydrogen liquefaction process, a hydrogen-rich gas originating from an apparatus for separation by distillation and/or stripping and/or partial condensation, the gas exiting from the separation apparatus at a temperature of at most 103K containing at least 99.9 mol % of hydrogen and at a pressure between 20 and 30 bar, is sent to a hydrogen liquefier, without having heated the hydrogen-rich gas to a temperature above 0° C.Type: ApplicationFiled: February 14, 2022Publication date: February 15, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Axelle GAERTNER, Marie-Khuny KHY
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Publication number: 20240053066Abstract: Disclosed is a dilution refrigeration device comprising a working circuit, a mixing chamber, a still and a transfer component, a circuit configured to connect an outlet of the mixing chamber to an inlet of the still and an outlet of the still to an inlet of the transfer component, the circuit also being configured to connect an outlet of the transfer component to an inlet of the mixing chamber, the device further comprising at least one cooling component in thermal exchange with the working circuit, the at least one cooling component comprising a cryogenerator, the device comprising a support, a sealed enclosure, with an open end of the enclosure being mechanically connected to the support via a sealed flexible bellows, an upper end of the cryogenerator being fixed on the support, the device further comprising a sealed sheath housed in the enclosure, a lower end of the cryogenerator extending into the sheath inside the bellows so that the enclosure and the sheath are at least partially mechanically isolated fType: ApplicationFiled: November 30, 2021Publication date: February 15, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Olivier GUIA, Marc STORA
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Publication number: 20240053097Abstract: The method for reducing or removing non-volatile impurities in a high-purity oxygen liquid comprises: an oxygen vaporization step for vaporizing a high-purity oxygen liquid obtained from a high-purity oxygen rectification column in an air separation unit for producing the high-purity oxygen liquid; and an oxygen recondensing step for recondensing oxygen gas vaporized in the oxygen vaporization step. This method may also comprise a high-purity oxygen liquid extraction step for extracting a condensate obtained in the oxygen recondensing step.Type: ApplicationFiled: August 9, 2023Publication date: February 15, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventor: Kenji HIROSE
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Publication number: 20240053098Abstract: An air separation unit comprises: a first waste gas control valve which is provided in a first waste gas pipe; a first waste gas flow rate control unit which measures a gas flow rate in the first waste gas pipe and adjusts a degree of opening of the first waste gas control valve so that a measured value which has been measured reaches a preset first waste gas flow rate set value; a second waste gas control valve which is provided in a second waste gas pipe; a regeneration gas flow rate control unit which measures the gas flow rate in a regeneration gas pipe and outputs a first output value based on a measured value which has been measured and a preset regeneration gas flow rate set value; and a control unit which uses, as a target set value of the flow rate of a second waste gas, a value obtained by subtracting the first waste gas flow rate set value of the first flow rate measuring unit from the flow rate set value of the regeneration gas flow rate, compares the first output value with a second output valueType: ApplicationFiled: August 10, 2023Publication date: February 15, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Takuya KANEDA
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Publication number: 20240051675Abstract: Disclosed is a drive device, in particular for a flying vehicle such as an aircraft or a spacecraft, comprising at least one engine and a device for cooling the engine, the device for cooling the engine comprising a cryogenic refrigerator, i.e. refrigerating to a temperature between ?100° C. and ?273° C.Type: ApplicationFiled: September 8, 2020Publication date: February 15, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Martin STAEMPFLIN, Guillaume DELAUTRE, Loic JEUNESSE, Baptiste ZIMMERMANN