Patents Assigned to Societe Anonyme
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Patent number: 12117127Abstract: A conditioning device for engaging with a filling and/or tapping connector of a pressurized-fluid container cock, including a body bearing at least one coupling member arranged about a longitudinal axis, a locking member which is movable with respect to the body and with respect to the coupling member, a valve pusher which is movable in a gas transfer duct, and a blocking member, wherein the upstream face of the blocking member includes a tightness seal arranged about the longitudinal axis to form sealing between the gas transfer duct and an internal circuit of a filling connector.Type: GrantFiled: September 8, 2020Date of Patent: October 15, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Antoine Frenal
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Publication number: 20240335786Abstract: The invention relates to a process for separating carbon dioxide from a raw hydrogen product stream to produce a hydrogen product stream and a carbon dioxide product stream. The process includes the absorption of carbon dioxide in an absorption stage in an absorption medium and subsequent desorption of the carbon dioxide from the laden absorption medium in a plurality of decompression stages. According to the invention carbon dioxide substreams withdrawn from the decompression stages are combined into a carbon dioxide total stream and compressed in a plurality of serially arranged compression stages. Each compression stage having a suction pressure value is assigned at least one decompression stage with a corresponding desorption pressure value and the number of decompression stages corresponds at least to the number of compression stages.Type: ApplicationFiled: April 4, 2024Publication date: October 10, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Sophia SCHMIDT, Matthias LINICUS
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Patent number: 12109528Abstract: Process and plant for membrane permeation treatment of a carbon dioxide and methane-containing biogas stream in which the biogas stream is compressed with a compressor and the compressed biogas stream is fed to a membrane separation unit comprising first and second modules each containing at least one membrane selective for carbon dioxide over methane. The first module separates the compressed biogas stream into a first, second, and third methane-deficient permeates (in comparison to the biogas stream) and a first methane-enriched retentate (in comparison to the biogas stream). The first permeate being richer in methane than the second or third permeates. The second module separates the first permeate into a fourth methane-deficient permeate and a second methane-enriched retentate. The second and third retentates are recycled back to an inlet of the compressor.Type: GrantFiled: March 22, 2022Date of Patent: October 8, 2024Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francois Barraud
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Patent number: 12109527Abstract: A process for separating two gaseous streams, including purifying a first gaseous stream in a first acid gas removal absorber, purifying in a first temperature swing adsorption unit, and then separating at a cryogenic temperature in a separation unit to produce a stream of fluid enriched in carbon monoxide and a stream of fluid enriched in hydrogen, sending a second gaseous stream containing at least carbon monoxide, hydrogen and at least one acid gas to a shift reaction unit, the shifted second stream is purified in a second acid gas removal absorber to remove carbon dioxide and the purified second stream is sent as a feed stream to a pressure swing adsorption unit to produce a hydrogen enriched stream, and sending at least part of the stream enriched in hydrogen from the separation unit as a feed stream to the pressure swing adsorption unit to produce the hydrogen-enriched stream.Type: GrantFiled: May 30, 2019Date of Patent: October 8, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Antoine Hernandez, Wei Guan
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Publication number: 20240327216Abstract: The present invention relates to a process and plant for producing a hydrogen- and carbon oxides-having synthesis gas by partial oxidation of a carbonaceous feedstock having nitrogen compounds. The invention takes advantage of the different solubility of NH3 and CO2 as the synthesis gas stream is cooled. Water is condensed continuously throughout the cooling of the synthesis gas stream. NH3 preferentially dissolves or condenses into the liquid phase during cooling, but at relatively high temperatures, above about 80 to 100° C. Further condensation at lower temperatures then preferentially dissolves or condenses CO2 into the liquid phase. Thus, the formation of ammonium salts during cooling of the synthesis gas is prevented.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Bryce WILLIAMS, Stefan WALTER
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Publication number: 20240327217Abstract: The present invention proposes a process and a plant for producing a synthesis gas product stream by steam reforming of hydrocarbons, wherein the emission of carbon monoxide which is discharged to the environment together with a carbon dioxide-rich gas stream is reduced. According to the invention a first portion of the carbon monoxide-containing carbon dioxide-rich gas stream is introduced into the reformer furnace via at least one burner and/or into the reformer furnace outside the burners and at a location in the reformer furnace at which the local gas temperature is at least 1000° C. and/or into the flue gas conduit and/or into the flue gas chimney. A second portion of the carbon monoxide-containing carbon dioxide-rich gas stream is introduced into the reformer tubes.Type: ApplicationFiled: April 3, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Alexander ROESCH, Mirko HUEBEL, Maximilian HELMLE
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Publication number: 20240327215Abstract: The invention relates to a partial oxidation reactor (POX reactor) for producing a raw synthesis gas stream by partial oxidation of a carbon-containing input stream in gaseous form, in liquid form or in solid, particulate form dispersed in a carrier liquid or a carrier gas in the presence of an oxygen-containing oxidant stream and optionally a moderator stream containing steam and/or carbon dioxide. The invention further relates to a process for producing a raw synthesis gas stream. The partial oxidation reactor according to the invention provides for introducing a cylindrical or frustoconical inlet region having a constant diameter or a diameter that is smaller on the entrance side. The inlet region is arranged upstream of a cylindrical main reactor portion and represents a bottleneck-like section since the largest diameter of the inlet region is smaller than the diameter of the cylindrical main reactor portion.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Karsten COVELLA, Hongbin XU, Matthias MUELLER-HAGEDORN
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Patent number: 12107477Abstract: Electric machine, in particular an electric motor for driving at least one compressor or circulator, comprising a stator and a rotor that are disposed in a casing, the machine comprising a cooling device disposed around the stator and comprising a circulation circuit for a cooling fluid, characterized in that the cooling device comprises a circulation pipe for the cooling fluid, comprising a portion embedded in a mass of material with high thermal conductivity such as metal or a metal alloy.Type: GrantFiled: June 23, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Fabien Durand, Loic Brunet Manquat, Guillaume Delautre
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Patent number: 12104130Abstract: A method of maintaining a syngas composition ratio during an upset condition, including detecting a reduction in the import carbon dioxide flow rate with a carbon dioxide import stream flow sensor, evaluating the reduction in carbon dioxide flow rate or carbon dioxide pressure in a controller, performing one or more predetermined corrective actions as instructed by the controller. Wherein the predetermined corrective actions are chosen from the following: opening a CO2 import stream flow valve, opening a hydrocarbon and steam stream feed valve, opening a CO2 backup stream control valve, opening a syngas backup letdown valve, and starting a composition adjustment unit.Type: GrantFiled: November 18, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yufeng Qian, Pierre-Philippe Guerif, Alexander Roesch
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Patent number: 12106940Abstract: A method for storage and supply of a F3NO-free FNO-containing gas comprises the steps of storing the F3NO-free FNO-containing gas in a NiP coated steel cylinder with a polished inner surface, releasing the F3NO-free FNO-containing gas from the cylinder to a manifold assembly by activating a cylinder valve in fluid communication with the cylinder and the manifold assembly, de-pressurizing the F3NO-free FNO-containing gas by activating a pressure regulator in the manifold assembly so as to divide the manifold assembly into a first pressure zone upstream of the pressure regulator and a second pressure zone downstream of the pressure regulator, and feeding the de-pressurized F3NO-free FNO-containing gas to a target reactor downstream of the second pressure zone.Type: GrantFiled: January 13, 2022Date of Patent: October 1, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Ayaka Nishiyama, Jiro Yokota, Chih-yu Hsu, Peng Shen, Nathan Stafford
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Publication number: 20240318645Abstract: The invention relates to a fluid compression device comprising a compression chamber accommodating a piston that is able to move between first and second ends of the compression chamber, the device comprising a regeneration circuit connecting the first and second ends of the compression chamber and having a regenerator, the supply pipe comprising a set of one or more valves, the device comprising at least one compressed-fluid discharge pipe comprising an upstream end connected to the compression chamber and a downstream end intended to be connected to a receiver of the compressed fluid, the device comprising a bypass pipe comprising an upstream end connected to the regeneration circuit and a downstream end connected to a recovery member, the bypass pipe being configured to draw a fluid fraction during a regeneration phase during which the piston is moved from the second end towards the first end of the compression chamber.Type: ApplicationFiled: March 21, 2024Publication date: September 26, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventor: Rasmey TRY
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Publication number: 20240318784Abstract: The invention relates to a device for compressing a fluid, said device having a compression chamber accommodating a piston that is able to move in translation between the first and second ends of the compression chamber, the device comprising a regeneration circuit connecting the first and second ends of the compression chamber and having a regenerator, the supply pipe comprising a set of one or more valves, the device comprising at least one pipe for discharging the compressed fluid, said discharge pipe comprising an upstream end connected to the compression chamber and a downstream end intended to be connected to a receiver of the compressed fluid, wherein the regeneration circuit comprises, between the regenerator and the first end of the compression chamber, a heat exchanger that is configured to ensure an exchange of heat between the flow of fluid that has passed through the regenerator and a cold source.Type: ApplicationFiled: March 21, 2024Publication date: September 26, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventor: Rasmey TRY
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Patent number: 12098805Abstract: A cryogenic fluid transfer device comprising a first tank, a second tank, and a fluid transfer circuit, wherein the first tank comprises a cryogenic fluid distribution tank configured to store a cryogenic fluid in a liquid phase in a lower part thereof and in a gaseous phase in an upper part thereof, wherein the second tank comprises a cryogenic receiving tank configured to house the cryogenic fluid in liquid phase in a lower part thereof and in gaseous phase in an upper part thereof, wherein the fluid transfer circuit is configured to connect the first and second tanks, the fluid transfer circuit comprising a first pipe connecting the upper parts of the first and second tanks and comprising at least one valve, and a second pipe connecting the lower part of the first tank to the second tank that comprises a pump that has an inlet connected to the first tank and an outlet connected to the second tank, wherein: the pump and the at least one valve of the first line are configured so as to ensure a fluidic connecType: GrantFiled: November 22, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12097463Abstract: A gas stream is purified by a TSA adsorption scheme including at least two adsorbers following, in an offset manner, a cycle including an adsorption phase, and a subsequently, a regeneration phase. The regeneration phase includes a depressurization step, a pre-regeneration step and a regeneration step. A gas circulator is used to circulate the gas within the adsorber in the pre-regeneration step in a closed loop while the circulating gas is heated with a heater.Type: GrantFiled: February 3, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Golo Zick
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Patent number: 12098883Abstract: An air gas separation plant comprising, in the direction of circulation of the air stream: a compression means that makes it possible to compress the air stream to a pressure P1 of between 1.15 bar abs and 2 bar abs, an adsorption unit of TSA type, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A and B each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and an air stream outlet, a fixed bed adsorbent mass, likewise of parallelepipedal shape, the faces of which are parallel to the faces of the casing; and a set of volumes allowing the air stream to pass through the adsorbent mass horizontally, over the entire cross-section and throughout the entire thickness thereof.Type: GrantFiled: February 12, 2020Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Benoit Davidian
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Publication number: 20240310117Abstract: An apparatus for separation of a flow containing at least 95 mol % of carbon dioxide and also at least one impurity lighter than carbon dioxide by distillation comprises a heat exchanger (20), a distillation column (30), expansion means (V3), means for sending the flow to be cooled in the heat exchanger, means for sending the cooled flow to be separated in the distillation column, means for withdrawing at the bottom of the column a liquid flow containing at least 99 mol % of carbon dioxide, means for sending at least a portion (12) of the liquid flow to be cooled in the heat exchanger to form a subcooled liquid (3), means for sending at least a portion of the subcooled liquid to the expansion means to produce a two-phase flow, a phase separator (40) for separating the two-phase flow to form a gas and a liquid, means for sending at least a portion (14) of the liquid from the phase separator to be vaporized in the heat exchanger and means for taking a portion (4) of the liquid from the phase separator.Type: ApplicationFiled: February 28, 2022Publication date: September 19, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Michael TRAN, Ludovic GRANADOS, Mathieu LECLERC, Guillaume RODRIGUES, Aurore TROPTARD
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Publication number: 20240310116Abstract: Disclosed is a device for liquefying a fluid, comprising a circuit for fluid to be cooled, the device comprising a set of one or more heat exchangers exchanging heat with the circuit of fluid to be cooled, at least one first cooling system exchanging heat with at least some of the set of one or more heat exchangers, the first cooling system being a refrigerator with refrigeration cycle of a cycle gas mostly comprising helium, the refrigerator comprising, arranged in series in a cycle circuit: a cycle gas compression mechanism at least one cycle gas cooling member, a mechanism for expansion of the cycle gas and at least one expanded cycle gas heating member, wherein the compression mechanism comprises at least four compression stages in series, consisting of a set of one or more centrifuge-type compressors, the compression stages being mounted on shafts rotated by a set of one or more motors, the expansion mechanism comprising at least three expansion stages in series, consisting of a set of centripetal turbinType: ApplicationFiled: February 1, 2022Publication date: September 19, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Pierre BARJHOUX, Fabien DURAND
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Publication number: 20240307796Abstract: The present invention relates to an insertion device for inserting at least one section of packing for a gas/liquid separation column into a cylindrical casing, characterized in that a deployment module comprises a main member centred about a main axis of the insertion device, and a plurality of peripheral members arranged circumferentially and uniformly around the main axis, each of the peripheral members comprising an attachment means configured to grasp hold of a packing section, the deployment module comprising a plurality of branches arranged as pairs of branches connecting the main member to one of the peripheral members, the deployment module being able to modify the dimension of the insertion device by modifying a radial distance between the main member and each of the peripheral members.Type: ApplicationFiled: May 28, 2024Publication date: September 19, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Cyrille BABINET, Eric GALLOPIN, Gilles LEBAIN
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Mono-substituted cyclopentadienes and metal cyclopentadienyl complexes and synthesis methods thereof
Patent number: 12091374Abstract: A metal cyclopentadienyl complex has the formula: wherein m?0; M is a Group I, II or III main group metal, alkali or transition metal; C5H4 represents a Cp ring where two hydrogens are substituted by M and R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The metal cyclopentadienyl complexes include Li(C5H4-2-C5H11) (CAS No: 2413046-23-6), K(C5H4-2-C5H11), Na(C5H4-2-C5H11), K(C5H4-1-F—C4H10), K(C5H4-1,1,1-3F—C4H6), Li(C5H4-2-C4H9), or In(C5H4-2-C5H11) (CAS No.: 2364634-67-1). A mono-substituted cyclopentadiene has the formula: wherein m?0; C5H5 represents the Cp ring where one hydrogen is substituted R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The mono-substituted cyclopentadienes include C5H5-1-F—C4H10, C5H5-2-C5H11, C5H5-2-C4H9, or C5H5-1,1,1-3F—C4H6.Type: GrantFiled: January 19, 2022Date of Patent: September 17, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Grigory Nikiforov -
Patent number: 12092394Abstract: A plate fin heat exchanger assembly (S) for a cryogenic air separation unit, comprising: a heat exchanger having at least two cryogenic liquid inlets (B,C) at least two cryogenic liquid outlets (B,C), at least one nitrogen-rich stream inlet (D) at a first end of the heat exchanger and at least one nitrogen-rich stream outlet at a second end of the heat exchanger, the heat exchanger configured to receive a flow of at least one nitrogen-rich stream (WN,LPGAN) of the air separation unit at the at least one nitrogen-rich stream inlet and separate flows of at least two cryogenic liquids (LOX,LIN,LR) at the at least two cryogenic liquid inlets; wherein the inlet of the first of the cryogenic liquids is closer to the first end than the outlet of the second of the cryogenic liquids.Type: GrantFiled: October 26, 2018Date of Patent: September 17, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jian-Wei Cao, Eric Day, Sophie Lazzarini