Patents Assigned to Solvay & Cie
  • Patent number: 4052459
    Abstract: A process for the manufacture of alkylacetophenones wherein (1) benzene is acylated, (2) the alkylaryl ketone thus obtained is hydrogenated catalytically, and (3) the alkylbenzene thus obtained is acetylated, in only one solvent chosen from among chlorinated aliphatic hydrocarbons containing 1 to 3 carbon atoms and 2 or 3 chlorine atoms per molecule, and their mixtures.
    Type: Grant
    Filed: July 9, 1975
    Date of Patent: October 4, 1977
    Assignee: Solvay & Cie
    Inventor: Pierre Malfroid
  • Patent number: 4049532
    Abstract: A coating composition for application to an electrically conductive and relatively inert support at least the surface layer of which is titanium or a titanium alloy, to form a coated electrode for electrochemical processes, the composition essentially containing thermally decomposable compounds of iridium and of at least one non noble element selected from the group consisting of lithium, boron, beryllium, magnesium, gallium and germanium, in a liquid vehicle, the atomic ratio of iridium/non noble element being between 1/4 and 8/1. An electrode provided with a coating of this composition exhibits, inter alia, increased service life.
    Type: Grant
    Filed: September 23, 1974
    Date of Patent: September 20, 1977
    Assignee: Solvay & Cie.
    Inventors: Lucien Clerbois, Louis Degueldre, Christian Biver, Albert Degols, Yves Gobillon
  • Patent number: 4049761
    Abstract: In the manufacture of oriented hollow articles made of thermoplastic material by the steps of extruding a continuous hot tubular parison of thermoplastic material; pre-blowing such parison in a pre-blowing mold to produce preforms having a cylindrical body with a diameter not more than 20% greater than that of the parison; thermally conditioning the resulting preforms at a temperature sufficient to cause orientation of the thermoplastic material when it is being stretched; and effecting a final blow-molding of the thermally conditioned preforms, the mechanical properties of the resulting articles in the vicinity of their base are improved by carrying out the pre-blowing step while holding each parison tightly between two half-molds defining a cavity which has the shape, at the location of the base of the preform, of a quarter sphere of diameter equal to that of the preform, and cutting off the resulting flash by means on an elongated blade having a semicircular cross section and a diameter corresponding to th
    Type: Grant
    Filed: March 11, 1975
    Date of Patent: September 20, 1977
    Assignee: Solvay & Cie.
    Inventors: Michel Lorge, Roger Houba
  • Patent number: 4048417
    Abstract: Process for preventing build-up in the reactors used in the free radical polymerization of ethylenically unsaturated monomers, and more particularly of vinyl chloride, in which the reactor walls are subjected to heat treatment before the reactors are charged in preparation for the polymerization process.
    Type: Grant
    Filed: January 14, 1976
    Date of Patent: September 13, 1977
    Assignee: Solvay & Cie.
    Inventor: Stephane Noel
  • Patent number: 4028208
    Abstract: The invention relates to improvements in electrolytic cells with vertical metal anode plates, such as diaphragm cells for the electrolysis of a brine. The cell according to the invention comprises a baseplate with slots passing therethrough and anode plates which pass through the slots in the baseplate and which are connected to a current lead-in disposed beneath the baseplate. Sealing joints are interposed between the anode plates and the faces of the slots and are supported by the current lead-in.
    Type: Grant
    Filed: November 18, 1975
    Date of Patent: June 7, 1977
    Assignee: Solvay & Cie
    Inventor: Umberto Giacopelli
  • Patent number: 4025593
    Abstract: A continuous fibrillated structure, formed by the abrupt pressure release of a two-phase liquid mixture of polymer and solvent at elevated temperature and pressure so as to cause the instantaneous vaporization of the solvent, is shredded by introducing a make-up fluid into the two-phase liquid mixture before the pressure release is complete.
    Type: Grant
    Filed: June 9, 1975
    Date of Patent: May 24, 1977
    Assignee: Solvay & Cie
    Inventors: Carlo Raganato, Georges Voituron
  • Patent number: 4022871
    Abstract: Process for the fabrication of boric acid by carboammoniac attack of a borate mineral, involving subjecting a borosodium ore, in its natural state or previously refined, and in a finely ground condition, to a treatment in an aqueous medium with carbonic anhydride and ammonia in a manner to precipitate sodium bicarbonate which is separated. The remaining mother liquor is cooled to obtain crystals of ammonium borate which are separated, redissolved, the obtained solution being decomposed by thermal means in order to form ammonia which is recycled to the ore treatment and a boric acid solution from which the acid is separated by crystallization. This process permits obtaining two valuable products: NaHCO.sub.3 and H.sub.3 BO.sub.3. When the ore is preliminarily refined, more effective utilization can be made of the ammonia.
    Type: Grant
    Filed: December 10, 1975
    Date of Patent: May 10, 1977
    Assignee: Solvay & Cie
    Inventor: Paul Demilie
  • Patent number: 4020024
    Abstract: Halogenated polyether-polyols lacking terminal primary chlorohydrin and hydroxyl groups are reacted with organic isocyanates to produce semi-rigid or rigid polyurethane foam having excellent physical, mechanical and processing characteristics and good fire-resistance. The polyether-polyols are used individually, as admixtures with each other and/or as admixtures with non-halogenated polyether-polyols.
    Type: Grant
    Filed: October 23, 1974
    Date of Patent: April 26, 1977
    Assignee: Solvay & Cie
    Inventors: Rene Walraevens, Andre Collin
  • Patent number: 4014776
    Abstract: Vertically stacked electrolytic cells are fluid-tightly separated from one another by separator and collector means generally horizontally disposed between superposed cells. Each of the cells has side walls and generally vertical and parallel spaced cathodes supported by the side walls, with generally vertical and parallel anode plates alternating with the cathodes. A current collector between the superposed cells is connected to lower ends of anode plates in the upper cell and to upper ends of anode plates in the lower cell so as to feed electric current to anode plates of both cells.
    Type: Grant
    Filed: July 1, 1974
    Date of Patent: March 29, 1977
    Assignee: Solvay & Cie
    Inventor: Umberto Giacopelli
  • Patent number: 4013536
    Abstract: An electrolytic cell having a base or bottom wall on which are supported sidewalls enclosing the anodes and cathodes within. A seal is constructed between the sidewalls and bottom wall and on which the sidewalls rest. The seal is constructed as a framework of flat bars of rectangular cross section made of rigid material encased in an envelope made of a resilient material having a U-shaped cross section. The envelope is closed on a portion facing into the interior of the cell and its two side legs are held between the framework and the sidewalls and between the sidewalls and the bottom wall respectively.
    Type: Grant
    Filed: January 20, 1975
    Date of Patent: March 22, 1977
    Assignee: Solvay & Cie
    Inventor: Emile Cabaraux
  • Patent number: 4010229
    Abstract: A process is provided for the manufacture of fibrils of short length by suddenly releasing the pressure acting on a two-phase liquid mixture of molten polymer and solvent and which is at a high pressure and a high temperature. The two-phase liquid mixture is ejected through a pressure release orifice so as to vaporize the solvent instantaneously and solidify the polymer, and the flow path of the two-phase liquid mixture is perturbed at the instant when it enters the pressure release orifice.Spinnerets are provided which have a perturbation chamber containing a supply orifice and a pressure release orifice.
    Type: Grant
    Filed: January 16, 1975
    Date of Patent: March 1, 1977
    Assignee: Solvay & Cie
    Inventors: Jean-Pierre Pleska, Michel Marechal
  • Patent number: 4007242
    Abstract: The production of oriented hollow plastic articles having no weakened zone particularly in their bottom is ensured by blow molding of preforms having a base sealed along a straight line of length practically the same as half the perimeter of their cylindrical lateral part and gradually by changing from the cylindrical shape to the rectilinear shape in the region of the base so that the perimeter remains practically constant throughout all cross-sections.
    Type: Grant
    Filed: January 24, 1975
    Date of Patent: February 8, 1977
    Assignee: Solvay & Cie
    Inventors: Michel Lorge, Roger Houba
  • Patent number: 4005136
    Abstract: Granules of ammonium or alkali metal poly-.alpha.-hydroxyacrylates having an apparent specific gravity of between 0.35 and 0.55 kg/dm.sup.3 and an ability to flow, expressed by the time taken for a weight of 250 g to flow through the 16 mm diameter orifice of an analysis funnel with a short stem, not exceeding 10 seconds are disclosed. The granules are prepared by agglomerating solid particles of small dimensions by spraying them in a fluid bed with a solution of poly-.alpha.-hydroxyacrylate.
    Type: Grant
    Filed: June 10, 1975
    Date of Patent: January 25, 1977
    Assignee: Solvay & Cie
    Inventor: Jean Brichard
  • Patent number: 4003554
    Abstract: Equipment for heating polar polymers to the temperature at which they become plastic comprises a microwave generator, a tubular component acting as a waveguide in conjunction with the generator, means for supplying the tubular component with the polar polymer and for causing the latter to travel through the tubular component and at least one static malaxating device positioned inside the tubular component.
    Type: Grant
    Filed: February 12, 1975
    Date of Patent: January 18, 1977
    Assignee: Solvay & Cie
    Inventor: Jean Chauffoureaux
  • Patent number: 4000204
    Abstract: A process is provided for purifying vinylidene chloride by removing dichloroacetylene. The vinylidene chloride to be purified is treated with a solution containing at least one compound selected from the group consisting of metal sulfites and metal hyposulfites to form a reaction mixture, and thereafter the purified vinylidene chloride is separated from the reaction mixture.
    Type: Grant
    Filed: July 29, 1975
    Date of Patent: December 28, 1976
    Assignee: Solvay & Cie
    Inventors: Rene Walraevens, Andre Devos
  • Patent number: 3997462
    Abstract: Novel granules containing sodium chlorite have an apparent specific weight between 1.3 and 1.45 kg/dm.sup.3 and are prepared from an aqueous medium containing sodium chlorite, by the steps of passing the medium into a fluidized bed drier for evaporting water from the medium, and maintaining in the drier a constant presence of seeds smaller than the required granules.
    Type: Grant
    Filed: July 25, 1974
    Date of Patent: December 14, 1976
    Assignee: Solvay & Cie
    Inventors: Jose Luis Denaeyer, Willy Kegelart
  • Patent number: 3997509
    Abstract: Phosphorus-containing halogenated unsaturated polyester compositions are prepared by heat treating halogenated unsaturated polyesters derived from at least one epihalohydrin and maleic anhydride. The heat treatment is carried out in the presence of an organic phosphite at a temperature of between 50.degree. and 200.degree. C.
    Type: Grant
    Filed: December 11, 1974
    Date of Patent: December 14, 1976
    Assignee: Solvay & Cie
    Inventor: Pierre Malfroid
  • Patent number: 3994969
    Abstract: A process is provided for the manufacture of salts of poly-alpha-hydroxyacrylic acids, which salts contain monomeric units of the formula ##EQU1## wherein R.sub.1 and R.sub.2 independently represent hydrogen or an alkyl group containing 1 to 3 carbon atoms and wherein M represents a cationic radical resulting from the dissociation of a base. A solid polylactone derived from the corresponding poly-alpha-hydroxyacrylic acid is reacted with the base in the presence of water and the reaction is carried out in a liquid medium containing a diluent so that the polyacetone and the salt produced do not dissolve in the medium.
    Type: Grant
    Filed: April 23, 1975
    Date of Patent: November 30, 1976
    Assignee: Solvay & Cie
    Inventors: Noel Vanlautem, Julien Mulders
  • Patent number: 3993634
    Abstract: Photodegradable compositions based on vinyl chloride polymers containing a ferrocene and an .alpha.-phenylindole as sensitizers to accelerate natural photodegradation and their use in the production of hollow bodies. Said compositions undergo photodegradation appreciably more quickly than known compositions based on vinyl chloride polymers containing solely a ferrocene.
    Type: Grant
    Filed: February 28, 1975
    Date of Patent: November 23, 1976
    Assignee: Solvay & Cie.
    Inventor: Philippe Burgaud
  • Patent number: 3989880
    Abstract: This invention relates to the polymerization and copolymerization of .alpha.-olefins and to catalysts and cocatalysts for that purpose wherein the polymerization is carried out in the presence of a catalyst composition comprising an organometallic compound and the cocatalyst reaction product of a halogenated transition metal compound and an organic compound of a divalent metal containing oxygen and nitrogen and being substantially free from hydroxyl groups attached to the divalent metal.
    Type: Grant
    Filed: February 11, 1972
    Date of Patent: November 2, 1976
    Assignee: Solvay & Cie
    Inventors: Eugene Berger, Pol Gerard, Andre Delbouille, Jean-Louis Derroitte