Abstract: The present invention pertains to a membrane for an electrochemical device, to a process for manufacturing said membrane and to use of said membrane in a process for manufacturing an electrochemical device.

Abstract: Process P1 for the manufacture of a secondary fatty alcohol, said process P1 comprising synthesizing an internal ketone K1 by a process P0 comprising the decarboxylative ketonization reaction of a fatty acid or the like in a liquid phase with a metal compound as catalyst in a reaction medium, wherein a ketone K2 at liquid state, which is identical or similar to the internal ketone K1, is introduced into the reaction medium, and subjecting the internal ketone K1 to a hydrogenation reaction with hydrogen gas as hydrogenating agent to form the secondary fatty alcohol. Use of the secondary fatty alcohol manufactured by the process P1 for the manufacture of an internal olefin or of an internal olefin sulfonate.

Abstract: The present invention concerns new lithium rare earth halides that may be used as solid electrolytes or in electrochemical devices. The invention also refers to wet and dry processes for the synthesis of such lithium rare earth halides and lithium rare earth halides susceptible to be obtained by these processes.

Abstract: Described herein are polymer compositions (PC) including a polyamide (PA) and a reactive impact modifier. As explained in detail below, the polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, a bis(aminoalkyl)cyclohexane, terephthalic acid, and, optionally, a cyclohexanedicarboxylic acid. It was surprisingly discovered that semi-aromatic polyamides derived from the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the specific combination of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane and the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid provided for polymer compositions (PC) having improved retention of mechanical properties (e.g. tensile strength and flexural strength) after aging in aqueous solutions, relative to analogous polyamides free of the bis(aminoalkyl)cyclohexane and the cyclohexanedicarboxylic acid.

Abstract: The invention relates to a process for preparing polymeric particles, based on the use of a polyester polymer (PE) comprising units from a dicarboxylic acid component and a diol component, wherein at least 2 mol. % of the diol component is a poly(alkylene glycol). The process comprises the melt-blending of the aromatic polymer (P) with the PE, the cooling the blend and the recovery of the particles by dissolution of the PE into water. The present invention relates to polymeric particles obtained therefrom and to the use of these particles in SLS 3D printing, coatings and toughening of thermoset resins.

Abstract: Described herein are electrical articles comprising a polyamide (PA). As explained in detail below, the polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, terephthalic acid, and a bis(aminoalkyl)cyclohexane or a cyclohexanedicarboxylic acid. It was surprisingly discovered that incorporation of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid into the polyamide provided for polymer compositions (PC) having significantly improved comparative tracking index (“CTI”) retention after heat aging, relative to analogous polyamides derived from only the aliphatic diamine and terephthalic acid. Due at least in part to the improved CTI retention, the polyamides (PA) can be desirably incorporated into articles that, during use, are exposed to elevated temperatures and benefit from high CTI performance.

Abstract: The invention relates to a fluorination process consisting in bringing an inorganic compound M into contact with an atmosphere comprising difluorine gas, the inorganic compound M being a garnet based on the elements Li, La, Zr, A and O and for which the relative composition of the Li, La, Zr and A cations corresponds to the formula (I): LixLa3ZrzAw.

Abstract: Provided is a method for degrading epoxy resins by enzymatic route, in particular by adding an epoxy resin in a solvent followed by treatment with a glutathione S-transferase. A method for recycling a composite material comprising epoxy resin as well as the use of glutathione 5-transferase and eventually para-hydroxybenzoate hydroxylase for degrading epoxy resins are also provided.

Abstract: The present invention pertains to the use of a coating composition comprising: —at least one polymer (ZW) comprising zwitterionic repeating units derived from at least one zwitterionic monomer (A), —at least one polymer (CA) different from polymer (ZW) comprising repeating units derived from at least one carboxylic acid and/or carboxylic anhydride containing monomer (B), and—at least one crosslinking agent (CL). The invention also pertains to the use of said coating composition (C) for making frost resistant a substrate and to articles coated with composition (C).

Abstract: The present invention relates to medical devices, such as catheters, made from a composition comprising at least one (per) fluoropolyether polymer; methods for the manufacture thereof; and their uses and applications in medicine.

Abstract: The present invention relates to a poly(arylene sulfide) (PAS) copolymer (P) comprising: at least one block of poly(arylene sulfide) (PAS) having a weight-average molecular weight (Mw) of at least 40,000 g/mol as determined by gel permeation chromatography, and at least one block of polyorganosiloxane (POS) having a weight-average molecular weight (Mw) of at most 5,000 g/mol as determined by gel permeation chromatography, wherein the weight ratio of PAS:POS is from 95:5 to 99.5:0.5.

Abstract: Described herein are polymer compositions (PC) including a polyamide and carbon fiber. As explained in detail below, the polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, terephthalic acid, and a bis(aminoalkyl)cyclohexane or a cyclohexanedicarboxylic acid. It was surprisingly discovered that incorporation of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the specific combination of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane and the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid into the polyamide provided for carbon fiber filled polymer compositions (PC) having significantly improved mechanical properties (e.g. tensile modulus and strength) at elevated temperatures, as well as significantly improved retention of mechanical properties after heat aging, relative to analogous polyamides free of the bis(aminoalkyl)cyclohexane and the cyclohexanedicarboxylic acid.

Abstract: The present invention pertains to lithiated polyamic acid derivatives and to their use as binders in electrodes for lithium ion batteries.

Abstract: The invention relates to aqueous dispersions of fluoropolymers comprising recurring units derived from vinylidene fluoride (VDF) in an amount of from 60% to 82% in moles and recurring units derived from trifluoroethylene (TrFE) in an amount of from 18% to 40% in moles, with respect to the total moles of recurring units, said fluoropolymers possessing an improved thermodynamic ordered structure in the ferroelectric phase.

Abstract: Use of a coating composition for making a frost resistant substrate, the coating composition comprises at least one copolymer (ZW-CA) comprising: (a) repeating units (RZW) derived from at least one zwitterionic monomer, monomer (B), and (b) repeating units (RCA) derived from at least one monomer containing carboxylic acid and/or carboxylic anhydride, monomer (B), and at least one crosslinking agent (CL).

Abstract: Provided are fluorinated block copolymers comprising alternating hard blocks and soft blocks, wherein both said hard and soft blocks comprise vinylidenfluoride (VDF). Also provided is the use of said block copolymers in applications for lithium batteries including an electrochemical cell and a separator for an electrochemical cell which is coated with a composition comprising the fluorinated block copolymers. Further provided is a process for the manufacture of the separator.

Abstract: A method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the 3D object from the part material comprising a polymeric component comprising, based on the total weight of the polymeric component: from 5 to 95 wt. % of at least one polymer (P1) comprising at least 50 mol. % of recurring units (R1) consisting of an arylene group comprising at least one benzene ring, each recurring unit (R1) being bound to each other through C—C bonds, wherein the recurring units (R1) are such that, based on the total number of moles of recurring units (R1):less than 90 mol. % are rigid rod-forming arylene units (R1-a), and at least 10 mol. % are kink-forming arylene units (R1-b), and from 5 to 95 wt. % of at least one polymer (P2), having a glass transition temperature (Tg) between 140° C. and 265° C., and no melting peak, as measured by differential scanning calorimetry (DSC) according to ASTM D3418.

Abstract: Described herein are polymer compositions including a liquid crystal polymer (“LCP”) and 1 weight percent (“wt. %”) to 25 wt. % of a semi-aromatic, semi-crystalline polyester, relative to the total weight of the LCP and semi-aromatic, semi-crystalline polyester. It was surprisingly discovered that polymer compositions including an LCP in conjunction with a semi-aromatic, semi-crystalline polymer could be melt-extruded into desirable films, as opposed to corresponding polymer compositions. It was further surprisingly discovered that the polymer compositions described herein had improved mechanical performance (tensile strength and tensile elongation), relative to corresponding polymer compositions. Still further, the polymer compositions also unexpectedly had reduced (Tm-Tc) relative to corresponding polymer compositions and, therefore, provided faster cycle times for molded articles formed from the polymer compositions.

Abstract: The invention pertains to a process for the manufacture of a polymer membrane based on a fluoropolymer hybrid organic/inorganic composite, to a polymer membrane obtained thereof and to use of said membranes obtained therefrom in various applications, especially in electrochemical and in photo-electrochemical applications.

Abstract: The present invention relates to a of amide copolymer produced from a carboxy-piperidine, preferably 4-piperidinecar-boxylic acid and an aminoacid or lactam, preferably 4-aminomethyl-benzoic acid, to a process for its manufacture and to the use thereof for the manufacture of thermoplastic composites, and articles manufactured via injection molding, extrusion and through additive manufacturing technologies.