Abstract: The present disclosure relates to an additive manufacturing (AM) method for making a three-dimensional (3D) object, comprising a) the provision of providing a powdered polymer material (M) comprising at least one poly(ether ether ketone) (PEEK) polymer, and at least one poly(aryl ether sulfone) (PAES) polymer, b) the deposition of successive layers of the powdered polymer material; and c) the selective sintering of each layer prior to the deposition of the subsequent layer, wherein the powdered polymer material (M) is heated before step c) to a temperature Tp (° C.): Tp<Tg+40, wherein Tg (° C.) is the glass transition temperature of the PAES polymer, as measured by differential scanning calorimetry (DSC) according to ASTM D3418.

Abstract: The invention pertains to a fluoropolymer composition comprising certain tetrafluoroethylene/perfluoromethyvinylether copolymers having well-defined TFE/MVE monomer composition and possessing low molecular weight and a white pigment, to the use of this latter for manufacturing shaped articles, and to shaped articles therefrom, including components of light emitting apparatuses, e.g. LED assemblies.

Abstract: A chemical blowing agent for foaming a thermoplastic polymer, for example PVC plastisol or a polymer resin in an extrusion process, comprising a functionalized particulate bicarbonate containing at least one additive, preferably excluding an exothermic blowing agent. The additive may be selected from the group consisting of polymers; inorganic salts; oils; fats; resin acids, any derivative thereof, and salts thereof; amino acids; fatty acids; carboxylic or polycarboxylic acids, soaps; waxes; derivatives thereof; salts thereof; or any combinations thereof. The particulate bicarbonate may be functionalized by spray-drying, coating, extrusion or co-grinding with at least one additive. The functionalized particulate bicarbonate may comprise 50 wt % to less than 100 wt % of the bicarbonate component, and 0.02-50 wt % of the additive. A foamable polymer composition comprising such chemical blowing agent.

Abstract: Composition comprising a) a polymer comprising recurring units derived from vinylidene fluoride monomer and at least one monomer carrying at least one functional group selected from carboxyl groups, ester groups and hydroxyl groups, and b) a microporous adsorbent carbon material having a specific surface area (BET) of at least 700 m2/g, a pore volume in the range of from 0.1 to 0.7 m3/g, at least 60% of said pore volume being formed by micropores having a pore radius of 2 nm or less.

Abstract: Disclosed are methods of decreasing the concentration of a metal in a monomer composition including a bis(benzoyl)benzene, bis(benzoyl)benzene monomer compositions having a low total metal concentration, di-ketone polymers made from low metal bis(benzoyl)benzene monomers, and polymer compositions and shaped articles including the di-ketone polymers. It was surprisingly found that di-ketone polymers made by nucleophilic substitution of low metal bis(benzoyl)benzene monomers exhibit greater crystallinity, as compared with di-ketone polymers made with conventional monomers.

Abstract: A chemical blowing agent for foaming a thermoplastic polymer, for example PVC plastisol or a polymer resin in an extrusion process, said chemical blowing agent comprising a functionalized particulate bicarbonate containing at least one additive, preferably excluding an exothermic blowing agent. The additive may be selected from the group consisting of polymers; inorganic salts; oils; fats; resin acids, any derivative thereof, and salts thereof; amino acids; fatty acids; carboxylic or polycarboxylic acids, soaps; waxes; in derivatives thereof (such as esters); salts thereof; or any combinations thereof. The particulate bicarbonate may be functionalized by spray-drying, coating, extrusion or co-grinding with at least one additive. The functionalized particulate bicarbonate may comprise 50 wt % to less than 100 wt % of the bicarbonate component, and 0.02-50 wt % of the additive. A foamable polymer composition comprising such chemical blowing agent.

Abstract: The present invention relates to a process for the preparation of halogenated carboxylic anhydrides, e.g. for the preparation of trifluoroacetic anhydride. The preparation is achieved by reacting a halogenated carboxylic acid, e.g. trifluoroacetic acid, with sulfuric acid, oleum and/or disulfuric acid.

Abstract: The present invention pertains to a process for manufacturing a semi-crystalline fluoropolymer, to the fluoropolymer obtainable by said process and to uses of said fluoropolymer in various applications.

Abstract: The present invention relates to a polymer composition (C) comprising: —a polyphenylene sulfide (PPS), —at least 3 wt. % of polyamide 6 (PA6), —25 to 60 wt. % of reinforcing agents, —3 to 8 wt. % of a functionalized, non-aromatic elastomer, wherein the weight ratio PPS/PA6 is at least 4 and wherein wt. % are based on the total weight of the composition. The present invention also relates to articles incorporating the polymer composition and the use of polyamide 6 (PA6) as a heat-aging stabilizer in a polymer composition.

Abstract: The present invention relates to a polymer alloy comprising a sulphur-containing aromatic polymer and at least one fluoropolymer, which has improved dispersibility and improved mechanical properties. The invention also relates to a process for the preparation of said polymer alloy and to an article comprising the same.

Abstract: The present invention relates to a process for preparing a formulation comprising an alkali metal salt selected from the group consisting of alkali metal bicarbonate salts, alkali metal carbonate salts, alkali metal sesquicarbonate salts and combinations thereof, wherein said process comprises the step of extruding a paste-like composition comprising a functionalizing agent and the metal salt. The invention furthermore relates to a formulation obtainable from said process and to the use of this formulation in various applications such as in plastic foaming or in food and feed leavening compositions.

Abstract: The invention pertains to a method of making fluoropolymer dispersions using certain polyfunctional perfluoropolyether derivatives including a plurality of ionisable groups selected from the group consisting of —SO3Xa, —PO3Xa and —COOXa, whereas Xa is H, an ammonium group or a monovalent metal, and whereas said groups are comprised as pendant groups in the perfluoropolyether chain, and to fluoropolymer dispersions therefrom.

Abstract: The invention concerns methods for dielectrically insulating electrical active parts using certain fluorinated nitroalkanes, as well as compositions and apparatus comprising such compounds.

Abstract: A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.

Abstract: The present invention pertains to a multilayer assembly, to a process for the manufacture of said multilayer assembly, to a pipe comprising said multilayer assembly and to uses of said pipe in various applications.

Abstract: The invention pertains to a fluoropolymer composition comprising: —at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE) [ECTFE polymer]; —at least one water-soluble polyelectrolyte [polyelectrolyte (E)]; and—at least one antioxidant compound [compound (P)], said composition having improved thermal resistance.

Abstract: Described herein are polyamide polymer blends including a sulfonated polyamide polymer, an aromatic polyamide polymer and a reinforcing filler. Optionally, the polyamide polymer blend includes an additive. It was surprisingly discovered that blends including a sulfonated polyamide polymer in addition to an aromatic polyamide polymer had increased mechanical performance, relative to corresponding polyamide polymer blends having a non-sulfonated polyamide polymer. Furthermore, it was also surprisingly discovered that, when the sulfonated polyamide polymer included a sodium counter-ion, the mechanical performance of the polyamide polymer blend was further enhanced, relative to corresponding polyamide polymer blends having a sulfonated polyamide polymer including a lithium counter-ion in place of a sodium counter-ion.

Abstract: Disclosed is a polymer-metal junction including a polymer composition in contact with a metal substrate, where the polymer composition comprises a polymer component including a PEEK-PEDEK copolymer having a PEEK/PEDEK mole ratio ranging from about 60/40 to about 30/70 and a melting point (Tm) greater than 320° C., and where the polymer composition includes less than 10 wt. % of a sulfur-or-carbonyl-containing solvent, based on the total weight of the polymer composition. Also disclosed are methods of making the polymer-metal junction and articles including the polymer-metal junction.

Abstract: Electrolyte compositions containing a solvent, a co-solvent, certain cyclic carboxylic acid anhydride additives, certain phosphorus-containing additives, and an electrolyte salt are described. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries where they provide significantly improved cycle life with no loss of discharge capacity.

Abstract: The invention pertains to a polymer composition possessing improved resistance towards degradation and discolouring phenomena induced by UV radiation, said composition comprising at least one aromatic sulfone polymer; at least one organic UV absorber and at least one basic compound selected from the group consisting of (i) basic oxides and hydroxides of divalent metals and (ii) salts of a weak acid, and to methods for its manufacture and to shaped articles obtained therefrom.