Patents Assigned to Stamicarbon B.V.
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Patent number: 10759745Abstract: Processes and plants for the production of purified urea solution are described. In a described urea production process, urea is produced in a synthesis section without a high pressure stripper and the urea solution is subjected to purification after the recovery section, to give purified urea solution and off-gas. The purification comprises e.g. steam stripping.Type: GrantFiled: November 9, 2018Date of Patent: September 1, 2020Assignee: Stamicarbon B.V.Inventors: Ronny Albert Mathijs Pustjens, Johan Albert Arno Van Den Tillaart
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Publication number: 20200254419Abstract: Disclosed is a Hot Isostatic Pressed ferritic-austenitic steel alloy, as well objects thereof. The elementary composition of the alloy comprises, in percentages by weight: C ?0-0.05; Si 0-0.8; Mn 0-4.0; Cr more than 29-35; Ni 3.0-10;? Mo 0-4.0; N 0.30-0.55;?? Cu 0-0.8; W 0-3.0; S ?0-0.03; Ce 0-0.2; the balance being Fe and unavoidable impurities. The objects can be particularly useful in making components for a urea production plant that require processing such as machining or drilling. A preferred use is in making, or replacing, liquid distributors as used in a stripper as is typically present in the high-pressure synthesis section of a urea plant.Type: ApplicationFiled: April 24, 2020Publication date: August 13, 2020Applicant: Stamicarbon B.V.Inventors: Linn LARSSON, Daniel GULLBERG, Ulf KIVISÄKK, Martin ÖSTLUND, Alexander Aleida Antonius SCHEERDER
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Patent number: 10730002Abstract: Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 25 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m3/h)/(m3/h).Type: GrantFiled: April 24, 2017Date of Patent: August 4, 2020Assignee: Stamicarbon B.V.Inventors: Brian Sayre Higgins, John Marshall Tate, III, Robert Arthur Yates, Marcel Julien Pomerleau, Jon Michael Heon, Wilfried Marc Renaat Dirkx, Juan Coloma González
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Patent number: 10722831Abstract: Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 25 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m3/h)/(m3/h).Type: GrantFiled: September 6, 2019Date of Patent: July 28, 2020Assignee: Stamicarbon B.V.Inventors: Brian Sayre Higgins, John Marshall Tate, III, Robert Arthur Yates, Marcel Julien Pomerleau, Jon Michael Heon, Wilfried Marc Renatt Dirkx, Juan Coloma González
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Patent number: 10710047Abstract: Disclosed is a Hot Isostatic Pressed ferritic-austenitic steel alloy, as well objects thereof. The elementary composition of the alloy comprises, in percentages by weight: C ?0-0.05; Si 0-0.8; Mn 0-4.0; Cr more than 29-35; Ni 3.0-10;? Mo 0-4.0; N 0.30-0.55:? Cu 0-0.8; W 0-3.0; S ?0-0.03; Ce 0-0.2; the balance being Fe and unavoidable impurities. The objects can be particularly useful in making components for a urea production plant that require processing such as machining or drilling. A preferred use is in making, or replacing, liquid distributors as used in a stripper as is typically present in the high-pressure synthesis section of a urea plant.Type: GrantFiled: June 29, 2018Date of Patent: July 14, 2020Assignee: Stamicarbon B.V.Inventors: Linn Larsson, Daniel Gullberg, Ulf Kivisäkk, Martin Östlund, Alexander Aleida Antonius Scheerder
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Patent number: 10654758Abstract: The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises treating ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) with acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.Type: GrantFiled: September 12, 2019Date of Patent: May 19, 2020Assignee: Stamicarbon B.V.Inventors: Giusy Elisa Puci, Joey Dobree
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Patent number: 10654719Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H2S/O2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5:1.Type: GrantFiled: December 23, 2015Date of Patent: May 19, 2020Assignee: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTERInventors: Lucio Molinari, Fabio Angelini, Lucia Barbato
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Patent number: 10640428Abstract: The invention relates to a method for recovery of urea dust and ammonia from a gas stream by contacting said gas stream with an aqueous sulphuric acid solution, thus forming an acid solution of ammonium sulphate and urea, characterized in that the acid solution is concentrated to a melt comprising less than 5 wt % of water, which melt is subsequently transferred into solid particles comprising urea and ammonium sulphate.Type: GrantFiled: January 31, 2017Date of Patent: May 5, 2020Assignee: Stamicarbon B.V.Inventors: Jozef Hubert Meessen, Pantelis Orfanidis
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Publication number: 20200131039Abstract: Disclosed is a dual pressure plant for the production of nitric acid on the basis of the oxidation of ammonia. The plant comprises a reactor configured to produce a burner gas stream; a gas cooling section configured to form a cooled burner gas; a condensation section configured to form an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream; an absorption section configured to produce raw nitric acid and a tail gas; and a tail gas treatment system configured to form a purified tail gas. In a tail gas heating section a further heat exchanger configured to receive heat from the burner gas stream, said further heat exchanger being positioned relatively close to the reactor.Type: ApplicationFiled: December 31, 2019Publication date: April 30, 2020Applicant: Stamicarbon B.V.Inventors: Leonardus Hubertus POSTMA, Maria Paz MUÑOZ LÓPEZ, Martinus VOORWINDEN
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Patent number: 10633331Abstract: Disclosed is a process for the preparation of a urea product suitable for being diluted with water so as to form an aqueous urea comprising solution for use in a unit for the reduction of NOx in combustion engine exhaust gases, also known as Diesel Exhaust Fluid (DEF) or to be used in De NOx systems of exhaust vapor from industrial furnaces. The process comprises obtaining an aqueous urea solution from or after a recovery section in a urea production process. This solution, which has a low content of impurities, is subjected to flash crystallization at a low pressure, so as to obtain a solid crystallized urea containing product, which is a free-flowing powder containing less than 0.2 wt. % water. This product is packaged under conditions such that the water content in the packaged product is maintained below 0.2 wt. %. The invention can also be used in a method of increasing the capacity of an existing urea plant.Type: GrantFiled: July 16, 2015Date of Patent: April 28, 2020Assignee: Stamicarbon B.V.Inventor: Johannes Henricus Mennen
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Publication number: 20200095196Abstract: Disclosed is a novel method of controlling the formation of biuret in urea production, and particularly reducing, preventing or reversing such formation. This is accomplished by adding liquid ammonia to a urea aqueous stream. This addition is done at one or more positions downstream of a recovery section in a urea plant. The addition of liquid ammonia serves to shift the equilibrium of biuret formation from urea, to the side of the formation of urea from biuret and ammonia. The invention can be accomplished also in pre-existing urea plant, by the simple measure of providing an appropriate inlet for liquid ammonia, in fluid communication with a source of such liquid ammonia.Type: ApplicationFiled: November 27, 2019Publication date: March 26, 2020Applicant: STAMICARBON B.V.Inventor: Eelco MOSTERT
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Patent number: 10556796Abstract: Disclosed is a dual pressure plant for the production of nitric acid on the basis of the oxidation of ammonia. The plant comprises a reactor configured to produce a burner gas stream; a gas cooling section configured to form a cooled burner gas; a condensation section configured to form an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream; an absorption section configured to produce raw nitric acid and a tail gas; and a tail gas treatment system configured to form a purified tail gas. In a tail gas heating section a further heat exchanger configured to receive heat from the burner gas stream, said further heat exchanger being positioned relatively close to the reactor.Type: GrantFiled: September 19, 2017Date of Patent: February 11, 2020Assignee: Stamicarbon B.V.Inventors: Leonardus Hubertus Postma, Maria Paz Muñoz López, Martinus Voorwinden
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Patent number: 10526281Abstract: Disclosed is a novel method of controlling the formation of biuret in urea production, and particularly reducing, preventing or reversing such formation. This is accomplished by adding liquid ammonia to a urea aqueous stream. This addition is done at one or more positions downstream of a recovery section in a urea plant. The addition of liquid ammonia serves to shift the equilibrium of biuret formation from urea, to the side of the formation of urea from biuret and ammonia. The invention can be accomplished also in pre-existing urea plant, by the simple measure of providing an appropriate inlet for liquid ammonia, in fluid communication with a source of such liquid ammonia.Type: GrantFiled: April 28, 2017Date of Patent: January 7, 2020Assignee: STAMICARBON B.V.Inventor: Eelco Mostert
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Publication number: 20200002239Abstract: The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises treating ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) with acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.Type: ApplicationFiled: September 12, 2019Publication date: January 2, 2020Applicant: Stamicarbon B.V.Inventors: Giusy Elisa PUCI, Joey DOBREE
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Publication number: 20190388823Abstract: Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 25 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m3/h)/(m3/h).Type: ApplicationFiled: September 6, 2019Publication date: December 26, 2019Applicant: Stamicarbon B.V.Inventors: Brian Sayre HIGGINS, John Marshall TATE, III, Robert Arthur YATES, Marcel Julien POMERLEAU, Jon Michael HEON, Wilfried Marc Renatt DIRKX, Juan Coloma GONZÁLEZ
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Patent number: 10500535Abstract: Disclosed are methods and systems for removing submicron particles from a gas stream, in particular from urea prilling off-gas, wherein a Venturi ejector is used. A method comprises contacting a gas stream containing submicron particles in a Venturi ejector with an injected high velocity scrubbing liquid to provide a pumping action, wherein the scrubbing liquid has an initial velocity of at least 2 m/s and wherein the ratio of scrubbing liquid and gas flow is between 0.0005 and 0.0015 (m3/h)/(m3/h). The disclosure also pertains to a prilling tower having a gas stream treatment system comprising a Venturi ejector at the top of the prilling tower, and to a method of modifying an existing prilling tower.Type: GrantFiled: May 9, 2017Date of Patent: December 10, 2019Assignee: Stamicarbon B.V.Inventors: Brian Sayre Higgins, John Marshall Tate, III, Robert Arthur Yates, Marcel Julien Pomerleau, Jon Michael Heon, Wilfried Marc Renaat Dirkx, Juan Coloma González
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Publication number: 20190359559Abstract: Disclosed is a novel method of controlling the formation of biuret in urea production. This is accomplished by reducing or preventing the formation of biuret in a concentration section, particularly in one or more concentrators or evaporators. The method comprises controlling the residence time of a urea aqueous stream treated in such concentration section in a manner independently of the volume flow per time interval of said stream into said concentration section. The residence time can be controlled, e.g., by providing the concentration section with an adjustable volume or by adding a gas to the urea stream to be treated. A combination of such measures can also be applied.Type: ApplicationFiled: August 9, 2019Publication date: November 28, 2019Applicant: Stamicarbon B.V.Inventor: Eelco MOSTERT
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Patent number: 10457609Abstract: The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises treating ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) with acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.Type: GrantFiled: December 21, 2016Date of Patent: October 29, 2019Assignee: Stamicarbon B.V.Inventors: Giusy Elisa Puci, Joey Dobree
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Patent number: 10457633Abstract: Disclosed is a novel method of controlling the formation of biuret in urea production. This is accomplished by reducing or preventing the formation of biuret in a concentration section, particularly in one or more concentrators or evaporators. The method comprises controlling the residence time of a urea aqueous stream treated in such concentration section in a manner independently of the volume flow per time interval of said stream into said concentration section. The residence time can be controlled, e.g., by providing the concentration section with an adjustable volume or by adding a gas to the urea stream to be treated. A combination of such measures can also be applied.Type: GrantFiled: April 28, 2017Date of Patent: October 29, 2019Assignee: STAMICARBON B.V.Inventor: Eelco Mostert
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Publication number: 20190276392Abstract: The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises subjecting ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) to condensation under acidic conditions so as to form an acidic condensate, and using at least part of the acidic condensate as an acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.Type: ApplicationFiled: May 28, 2019Publication date: September 12, 2019Applicant: Stamicarbon B.V.Inventors: Giusy Elisa PUCI, Joey DOBREE