Abstract: Catalysts having the general formula:V.sub.1 Bi.sub.a Sb.sub.b Fe.sub.c X.sub.d Y.sub.c Z.sub.f O.sub.gwherein,X=Mo, Cu, W, Nb, Te, P, Sn, Ge, AsY=Co, Ni, Ce, La, Mn, CrZ=Alkali, alkaline earth, B, Tl and,a=0.1-10,b=0.01-20,c=0.01-5,d=0-5,e=o-3,f=0-1, and g is determined by the valance requirements of the elements present,are produced by first forming and calcining an iron-antimony oxide composition which is subsequently combined with compounds of vanadium, bismuth and other elements. The catalysts are useful in the formation of phthalonitriles from the reaction of xylenes with oxygen and ammonia at elevated temperatures.

Abstract: A process for producing a dialkyl ester (i.e. BTDE) from its corresponding dianhydride (i.e., BTDA) comprising mixing the dianhydride, an organic solvent, solid catalyst and an alcohol capable of reacting with the dianhydride stirring the solution until the dianhydride and alcohol have reacted to form the dialkyl ester, separating the dialkyl ester from the catalyst and drying the ester to form a solid paticulate product. The product has a purity of over 85%.

Abstract: A method for the treatment of fluid feedstreams comprises the steps of providing at least one wafer (200) comprising a central area (202) providing a plurality of members (18) arranged in a plurality of layers (201) and peripheral support means (203) encompassing the central area, arranged axially in a module (180) having first and second ports (185, 208); a plurality of separate bore fluid chambers (198, 199) generally encompassing the peripheral support means and communicable with the members within the central area, and a plurality of separate bore fluid ports (192, 193) communicable with the bore fluid chambers; directing the feedstream through the first port and over the wafer; and transferring materials between the central area in the wafer and the feedstream. Related methods employ other multi port apparatus (220, 240) as well as wafers (240, 280, 300, 320, 350, 410, 460) for use therein.

Abstract: Olefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile, and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and molecular oxygen-containing gas in the presence of a catalyst containing the oxides of bismuth, molybdenum, iron, nickel and magnesium, at least one element selected from the group comprising potassium and cesium, and optionally one element selected from the group comprising cobalt, phosphorus, manganese, tellurium, sodium, cerium, chromium, antimony and tungsten wherein the sum of cesium and potassium is at least 0.1 to 0.

Abstract: Disclosed is a process for making an .alpha., .beta.-unsaturated mononitrile by the catalytic reaction of a paraffin containing 3-5 carbon atoms with molecular oxygen and ammonia by catalytic contact of the foregoing reactants in a reaction zone with a metal oxide catalyst containing the elements indicated by the empirical formula,Cr.sub.a Mo.sub.b Te.sub.c M.sub.d O.sub.x (formula 1)whereM=one or more of Mg, Ni, Sb, Ti, La, P, Ce, Fe, Nb, W, V, and Cu, each of a, b & c is 0.1 to 10d is zero to 10a+b+c>1.5d, andx is determined by the valence requirements of the other elements present, andwherein the reactants fed to the reaction zone contain a mole ratio of said paraffin:NH.sub.3 in the range from 2.5 to 16 and a mole ratio of said paraffin:O.sub.2 in the range from 1 to 10.

Abstract: A process for adhering high nitrile resins onto a plastic material. The process comprises the steps of selecting a high nitrile resin having a nitrile content of at least about 60 percent by weight and prepared by the copolymerization of an olefinically unsaturated monovinyl nitrile and a monovinyl monomer copolymerizable therewith in the presence of a conjugated diene rubber, preparing a solution comprising from about one to 70 percent by weight of the high nitrile resin in a photopolymerizable solvent comprising from about 30 to 99 percent by weight of the solution and from about 0.

Abstract: A fiber-optic sensor is formed from three optical fibers. The distal ends of the fibers are optically linked by bonding their cores and directing their ends to mirrors. A portion of one of the fibers near the bonded point is exposed directly to the fluid to be sensed. The transmission characteristics of this fiber, the signal fiber, is then affected by the chemical constituents of the fluid. Light directed into the proximal end of one of the other fibers, the input fiber, is split between the signal fiber and the remaining fiber, the reference fiber. The ratio of the light in the signal fiber to the light in the reference fiber provides an indication of the chemical constituents that minimizes errors introduced by factors such as bends in the fibers and temperature.

Abstract: Polymers are disclosed which comprise the reaction product of (A) at least about 60 weight percent of at least one .alpha., .beta.-unsaturated polycarboxylic acid or anhydride; and (B) about 0.5 to about 40 weight percent of at least one acrylamide represented by the formula VI:CH.sup.2 .dbd.C(R.sup.5)C(O)N(R.sup.6)R.sup.7 (VI)wherein R.sup.5, R.sup.6 and R.sup.7 are each independently hydrogen or lower alkyl groups provided that at least one of R.sup.6 and R.sup.7 is a lower hydro-carbyl group, and further provided that the mixture is free of a vinyl sulfonic acid. The monomers react at elevated temperatures to form polycarboxylate scale inhibitors having a number average molecular weight of from about 400 to 10,000. The polymers have particular application in the inhibition of scales during oil field operations, but also may be employed in any environment where deposition of mineral scales is undesirable.

Abstract: A multi port apparatus (220,440) provides for the treatment of material.

Abstract: Coated reinforcement material for metal matrix composites comprising a carbon or silicon-containing reinforcement having a coating of the general formula:A.sub.100-x M.sub.xwherein A is at least one of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; M is at least one of Mo, W or Re; and x is from about 10 to about 90.

Abstract: Oxygen is separated from an oxygen-containing gas by introducing the gas into a first zone of a gas separation apparatus, the apparatus comprising first and second zones separated by a mixed metal oxide membrane, the membrane having a first surface open to the first zone, a second surface open to the second zone, and an empirical formula ofBiA.sub.x M.sub.y M'.sub.z O.sub.nwhere A is at least one of Mg, Ca, Sr, Ba, Y, Th, U, and the lanthanide elements; M is at least one of Sc, Ti, Cr, Mn, Fe, Ni, Cu and Zn; and M' is at least one of Co, Rh, Pd, Pt or Ru. The oxygen separated from the oxygen-containing gas can be recovered from the second surface of the membrane either as molecular oxygen, or it can be reacted with an oxygen-consuming substance, such as a hydrocarbon gas, which can be introduced into the second zone of the separation apparatus and brought in contact with the second surface of the membrane.

Abstract: The subject invention relates to a coated reinforcement material comprising a SiC reinforcement having a coating of at least three layers, wherein the layers are alternately A-material layers of the general formula:Al.sub.x O.sub.y N.sub.zwherein x is up to about 60 atomic % of the coating;y is from about 20 atomic % to about 55 atomic % of the coating; andz is from about 5 atomic % to about 45 atomic % of the coating, with the proviso that x+y+z=100, and B-material layers comprising a metal alloy, such that the first and last layers of the coating are A-material layers. The invention further relates to a high strength, high temperature performance composite containing the above-specified coated reinforcement.

Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one azo dye flame luminosity enhancing agent.

Abstract: A method employed by an expert system for batch scheduling the multiple-pass manufacture of a plurality of parts (12) by at least one parts process (22), where the parts (12) have a plurality of delivery dates and the parts (12) and parts processor (22) have a plurality of production constraints variable during manufacture, includes creating a knowledge base of select characteristics of the parts processor and parameters of the parts, and generating a plurality of rules expressing a scheduling and planning strategy that substantially satisfies parts delivery dates, substantially maximizes use of the parts processor, substantially maximizes part throughput, substantially minimizes energy utilization of the parts processor and meets the production constraints. Parts (12) suitable for simultaneous processing by the parts processor are combined into all possible preferred combinations by applying a first plurality of the rules to the knowledge base.

Abstract: A system to mitigate the effect of an environmental release of a contaminant gas. The system includes at least one first fluid effect device (13) positioned in the vicinity of the environmental release (33). A first fluid stream (20), a second fluid stream (23) and a flame (24) may each selectively be discharged from the first fluid device (13) in proximity to the contaminant gas. At least one second fluid effect device (25) also may be positioned in the vicinity of the environmental release (33) and the first fluid effect device (13). A third fluid stream (30) may be discharged from the second fluid device (25) proximate to the contaminant gas. A method to mitigate the effect of an environmental release of a contaminant gas employing the foregoing system is likewise embodied herein.

Abstract: A technique for measuring the coefficient of thermal expansion of calcined petroleum coke. This technique involves pressing a pellet of calcined coke to determine the coefficient of thermal expansion. It has the advantage of eliminating the graphitization and machining steps resulting in reduced manpower and turnaround time and requires less sample which allows CTE determination of laboratory scale cokers. Results show good correlation between this technique and traditional extrusion techniques.

Abstract: A high temperature, preferably polycrystalline, ceramic fiber having a selectable diameter of between 1 and 200 microns. The fiber is stable in an inert atmosphere at a temperature above about 1700.degree. C. and is often stable even in air at a temperature above 1500.degree. C. The fiber comprises a sintered ceramic powder having a maximum particle size less than the diameter of the fiber and an average particle size less than 0.2 times the diameter of the fiber. The ceramic powder is also stable in an inert atmosphere at a temperature above about 1700.degree. C. At least 90% of the ceramic is selected from borides, nitrides, carbides, and silicides. The fiber is characterized by a smooth surface and is preferably out of round.The invention further comprises a textilable sinterable filament, comprising a flexible polymer matrix containing high temperature sinterable ceramic powder particles. The ceramic powder particles are selected from ceramic borides, nitrides, carbides, and silicides.

Abstract: A laminate having high strength and excellent resistance to moisture comprised of a fiberglass reinforced polyester panel adhesively attached with a water reactive adhesive to a tempered hardboard panel.

Abstract: A facilitated liquid membrane for the separation of olefins from a gaseous feed stream comprises a porous support structure (10, 15) and a liquid membrane which comprises an aqueous solution containing a metal salt facilitator capable of coordinating with olefin gases, and an alkyl carbonate co-solvent. A process for the separation of olefins from gaseous feed streams comprises the steps of passing a gaseous feed stream over one side of a facilitated liquid membrane according to the present invention and collecting the olefins on the other side of the membrane.

Abstract: Olefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile, and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and molecular oxygen-containing gas in the presence of a catalyst containing the oxides of molybdenum, bismuth, iron, cobalt, nickel, and chromium, and either phosphorus or antimony or mixtures thereof, and an alkali metal or mixture thereof, and optionally one element selected from the group of an alkaline earth metal, a rare earth metal, niobium, thallium, arsenic, magnesium, zinc, cadmium, vanadium, boron, calcium, tin, germanium, manganese, tungsten, tellurium, or mixtures thereof.