Abstract: Disclosed is making a particular inorganic crystalline vanadium III oxidic compound from a pentavalent vanadium compound and at least one other or more metal cations, which process comprises (1) reducing a pentavalent vanadium oxidic compound to the V.sup.III state by heating at 100.degree. C. or less an aqueous medium slurry or solution of said pentavalent compound containing a reducing agent selected from hydrazine and hydrocarbylhydrazine, (2) providing in said aqueous medium, either before, during or after said reducing step, said other metal cation(s) in solution in the ratio called for by said particular crystalline compound, (3) removing the liquid aqueous medium, and (4) calcining the resulting dry solid at a temperature in the range from 400.degree. to 800.degree. C. in an inert atmosphere.Also disclosed is the vapor phase catalytic dehydrogenation of paraffins using certain spinels and perovskites as catalysts.
Type:
Grant
Filed:
October 29, 1987
Date of Patent:
March 28, 1989
Assignee:
The Standard Oil Company
Inventors:
Andrew T. Guttmann, James F. Brazdil, Robert K. Grasselli
Abstract: A gasket having an integral formed corner is disclosed. The corner includes a resilient member having a first and second portion. The first and second portions have free depending ends which are secured to gasket strips to form a peripheral gasket. The other end of the first and second portions are joined together such that the portions are angled with respect to one another. Also, the first and second portions each have a first face and a pair of glass securing wings which project from each of the first and second portions. A channel to receive glass is formed between each pair of the wings. A first and second cavity to receive locking strips are formed in the first face of the first and second portion, respectively. A plug is formed at the junction of the first and second portions such that the plug separates the first cavity from the second cavity to enable locking strips to abut against the plug. The plug exerts force to enhance the seal of the glass in the channel.
Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
Type:
Grant
Filed:
January 13, 1988
Date of Patent:
March 21, 1989
Assignee:
The Standard Oil Company
Inventors:
Robert K. Grasselli, Michael A. Tenhover, Jonathan H. Harris
Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst comosition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.
Type:
Grant
Filed:
March 28, 1988
Date of Patent:
March 21, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
Abstract: A glass reveal molding has a symmetrical generally C-shaped clamping portion which has a substantially equal amount of mass above and below its center clamping axis and exerts substantially even gripping pressure on both top and bottom surfaces of the glass. The equalized pressure of the clamping portion will substantially eliminate gapping around the radius and retain the molding on the windshield without gapping or rolling of the molding. The molding also has a crown with a stabilizing tail that nests with the C-shaped clamping portion.
Abstract: A composition is disclosed which comprises:(A) a compound represented by the formula ##STR1## wherein: R.sup.1 and R.sup.2 are independently hydrocarbyl groups of from about 2 to about 24 carbon atoms; R.sup.3 is a trivalent hydrocarbyl group of from 1 to about 16 carbon atoms; R.sup.4 is CH.sub.2 CH.sub.2 O, CH.sub.2 CH.sub.2 CH.sub.2 O or a mixture thereof; X is SO.sub.3.sup.-, SO.sub.4.sup.- or COO.sup.- ; and Y is an alkali metal or ##STR2## wherein R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are independently hydrogen or methyl; and n is a number ranging from zero to about 15; and(B) a compound represented by the formula R.sup.9 -(R.sup.10).sub.m A.sup.-D.sup.+wherein: R.sup.9 is a hydrocarbyl group of from about 8 to about 24 carbon atoms; R.sup.10 is CH.sub.2 CH.sub.2 O, CH.sub.2 CH.sub.2 CH.sub.2 O or a mixture thereof; A is SO.sub.3.sup.-, SO.sub.4.sup.- or COO.sup.- ; D is an alkali metal or ##STR3## wherein R.sup.11, R.sup.12, R.sup.13 and R.sup.
Abstract: An optical fibre is provided with a coating by coating the fibre (1) with a coating material (4) on-line with the fibre drawing process (2) and employing a laser beam (6) to locally heat the coating material whereby to change its physical or chemical properties. Metallic glass coated fibres, useful for hermeticity and sensor applications, can thus be achieved in multikilometer lengths by fusing metallic glass forming alloy coatings to a fibre. Alternatively, polymer coatings may be cured by laser beam local heating.
Abstract: A compressor discharge valve assembly including a valve seat, a valve cage, and an annular ring-type valve operating therebetween. The valve cage includes a recess into which the valve retracts when in an open position, or in an alternative embodiment, the valve cage includes a lip portion for shielding the valve. In either embodiment, a reduction in valve flutter and the noise, known as chatter, which results from valve flutter is realized. The valve in alternative embodiments also includes an annular dished portion oriented toward the valve seat for directing the flow of discharge gas smoothly from the compressor and thereby further reducing valve chatter.
Abstract: The present invention relates to an amorphous metal alloys of the formula:Cr.sub.a X.sub.b M.sub.cwhereinX is at least one element selected from the group consisting of Pt, Pd, Ir, Rh and Ru;M is at least one element selected from the group consisting of P, B, N, C, As, Sb and S; and wherein a ranges from about 0.60 to abotu 0.96;b ranges from greater than zero to about 0.01;c ranges from about 0.04 to about 0.40; and with the provisor that a+b+c equals 1.00.
Type:
Grant
Filed:
December 28, 1987
Date of Patent:
March 7, 1989
Assignee:
The Standard Oil Company
Inventors:
Richard S. Henderson, Gary A. Shreve, Michael A. Tenhover
Abstract: A continuous process for the preparation of tetrahydrofuran comprises, in a single-stage process, catalytically hydrogenating the solution which results when at least one of maleic anhydride or succinic anhydride is dissolved in a monohydric aliphatic alcohol in the presence of hydrogen and a catalyst comprising the mixed oxides of copper, zinc and aluminum.
Abstract: The present invention provides a method and apparatus for reconditioning a draft gear assembly friction clutch mechanism. The apparatus comprises a generally rectangular substantial flat plate member having at least one protuberance extending outwardly from one side of such plate member. The friction clutch mechanism reconditioning method includes the steps of removing each component of the friction clutch mechanism from an open end of the draft gear housing. Then engaging the plate member with an outer surface of one of the outer stationary plates of the friction clutch mechanism in a position such that the protuberance extends into a recess on the outer surface. Thereafter reassembling the friction clutch mechanism into the open end of the draft gear housing in a position such that an opposite surface of the plate member engages a portion of a wall surface of the housing.
Abstract: A light pen for converting a conventional graphics plotter into a photoplotter includes a housing containing an electrically powered light source, a battery and a normally open switch. The housing has an aperture opposite the light source. The light pen replaces an ink pen in the plotter. When the light pen is urged against a photosensitive sheet in the plotter, the normally open switch is closed, the light pen is energized and the light pen is transmitted to the sheet to illuminate it. The self-contained light pen is free of trailing electrical and optical cables that might interfere with plotter speed and accuracy.
Abstract: A catalyst is disclosed which comprises a molybdenum-tungsten-containing complex represented by the formulaMo.sub.a W.sub.b M.sub.c A.sub.d O.sub.
Abstract: A method of producing polarization-maintaining single-mode optical waveguides is provided wherein the preform from which the optical waveguide is produced consists of a tube, a rod of core and cladding material centrally disposed in said tube, and two differently doped pairs of filler rods disposed about said rod, the two rods of each pair being disposed diametrically opposed to each other with respect to said rod. Maximum polarization maintenance of the optical waveguide being produced is achieved by choosing the diameter ratios so that each filler rod rests against the central rod, against the inside wall of the tube, and directly against the two filler rods of the respective other pair.
Abstract: A hydraulic power unit for a hydropneumatic brake actuator having a power piston comprising a force piston formed with a bore therein and a take-up piston operative in the force piston bore for movement relative thereto during a brake application. This relative movement is controlled by a check valve device carried with the force piston to establish or interrupt fluid pressure communication between the respective pistons and establishes a positive clearance between a brake shoe and wheel tread, for example, during a subsequent brake release.
Abstract: A method and system for geophysical exploration including obtaining, processing, displaying and interpreting seismic data. Seismic energy is imparted into the earth's subterranean formation along at least two linear independent lines of action in a seismic survey. At least two linearly independent components of the seismic wave energy imparted along each line of action are detected within the seismic survey. A concord of seismic signals is produced from the seismic wave energy detected for selected combinations of receiver and source locations. An orientation module operates on the concord of the seismic signals so as to generate synthetic concords of seismic signals so as to focus on a particular component of the seismic wave energy in order to infer the geologic characteristics of the earth's subterranean formations.
Type:
Grant
Filed:
July 20, 1984
Date of Patent:
February 7, 1989
Assignee:
Standard Oil Company (Indiana), now Amoco Corp.