Patents Assigned to Sumita Optical Glass, Inc.
  • Patent number: 6784128
    Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %): P2O5   32 to 40% Li2O   6 to 21% Na2O   8 to 31% K2O   4 to 22% Al2O3  7.4 to 16% ZnO   0 to 19.6% BaO   0 to 12% and Sum of Li2O + Na2O + K2O 35.1 to 49%.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: August 31, 2004
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Otsuka, Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
  • Publication number: 20030153450
    Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %): 1 P2O5   32 to 40% Li2O   6 to 21% Na2O   8 to 31% K2O   4 to 22% Al2O3  7.4 to 16% ZnO   0 to 19.6% BaO   0 to 12% and Sum of Li2O + Na2O + K2O 35.
    Type: Application
    Filed: July 12, 2002
    Publication date: August 14, 2003
    Applicant: Sumita Optical Glass, Inc.
    Inventors: Masaaki Otsuka, Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6372155
    Abstract: The object of the present invention is to provide an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by &ggr;-rays, X-rays, UV-rays, etc. and light emission can be continued for a long time even after stopping the excitation. That is, the present invention relates to an oxide glass capable of exhibiting a long lasting afterglow and photostimulated luminescence, characterized by a constitutional composition comprising, at least, terbium oxide (Tb2O3) or manganese oxide (MnO), gallium oxide (Ga2O3) or aluminum oxide (Al2O3), alkali metal oxide or alkaline earth metal oxide and boron oxide (B2O3) or silicon oxide (SiO2) or zinc oxide (ZnO).
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: April 16, 2002
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6333282
    Abstract: The present invention provides an optical glass for precision molding, having excellent properties, i.e. yield temperature (At) of at most 550° C., refractive index (nd) of at least 1.83 and Abbe number (&ngr;d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented, in term of atoms for making up the glass, by the following chemical composition (wt %) P2O5 14.0 to 31.0% B2O3   0 to 5.0% GeO2   0 to 14.0% Sum of P2O5 + B2O3 + GeO2 14.0 to 35.0% Li2O   0 to 6.0% Na2O  2.5 to 14.0% Sum of Li2O + Na2O  2.5 to 15.0% Nb2O5 22.0 to 50.0% WO3   0 to 30.0% Bi2O3  5.0 to 36.0% BaO   0 to 22.0%.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 25, 2001
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Koji Nakahata, Koichi Tsuchiya, Shinobu Nagahama
  • Patent number: 6271160
    Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of &ggr;-rays, X-rays or UV-rays images and further can be used as an optical recording material of such a type that can be read. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %): GeO2 21 to 80% ZnO 0 to 50% Ga2O2 0 to 55% (ZnO + Ga2O3 = 3 to 55%) Tb2O3 0 to 10% MnO 0 to 2% (Tb2O3 + MnO = 0.01 to 10%) R2O 0 to 45% (R: at least one atom selected from Li, Na, K and Cs) R′O 0 to 40% (R′: at least one atom selected from Mg, Ca, Sr and Ba) R2O + R′O 0.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: August 7, 2001
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Masaaki Yamazaki, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6123872
    Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by .gamma.-rays, X-rays, UV-rays, etc., light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for night illumination or night signal, but also as a material for confirming an infrared laser or controlling an optical axis because of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing of .gamma.-rays, X-rays or UV-rays images. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 1 to 55% B.sub.2 O.sub.3 1 to 50% (SiO.sub.2 + B.sub.2 O.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: September 26, 2000
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 5961883
    Abstract: A glass material is provided which is capable of exhibiting fluorescence in the visible region by ultraviolet ray excitation. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 2 to 60%, B.sub.2 O.sub.3 5 to 70% (SiO.sub.2 + B.sub.2 O.sub.3 = 50 to 70%) RO 5 to 30% (R: at least one atom selected from Mg, Ca, Sr and Ba) ZnO 0 to 15% ZrO.sub.2 0 to 10%, Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3 2 to 15% (containing either of Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3) Ln.sub.2 O.sub.3 0 to 20% (Ln: at least one atom selected from Y, La, Gd, Yb, Lu, Sm, Dy and Tm) CeO.sub.2 0 to 1% Bi.sub.2 O.sub.3 0 to 2% Sb.sub.2 O.sub.3 0.01 to 0.5% and R'.sub.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: October 5, 1999
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Masaaki Otsuka, Hideaki Takaku, Naruhito Sawanobori
  • Patent number: 5755998
    Abstract: According to the present invention, there is provided a fluorophosphate fluorescent glass, capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a fluorophosphate fluorescent glass capable of exhibiting fluorescence in the visible region, having a chemical composition comprising, at least, (I) phosphorus (P), oxygen (O) and fluorine (F), as glass constituting components, and (II) at least one member selected from the group consisting of divalent europium, terbium, samarium and manganese, as a fluorescent agent, the divalent europium being contained as an essential component and at least one of samarium and manganese being contained as an essential component when terbium is contained.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: May 26, 1998
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Masaaki Otsuka, Shinobu Nagahama, Naruhito Sawanobori
  • Patent number: 5635109
    Abstract: According to the present invention, there is provided a fluorescent glass of the present invention is capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a Tb- or Eu-containing fluorophosphate fluorescent glass having a chemical composition comprising, at least, phosphorus (P), oxygen (O) and fluorine (F), and further containing Tb or Eu as a fluorescent agent, and specifically comprising, in terms of atoms for making up the glass (mol %):______________________________________ P 1.about.15 Al 1.about.18 Mg 0.about.12 Ca 0.about.18 Sr 0.5.about.21 Ba 0.5.about.28 Zn 0.about.3.5 R 0.about.10 Ln 0.8.about.8 Ln' 0.about.6.5 Ce 0.about.0.2 O 4.about.55 F 15.about.
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: June 3, 1997
    Assignee: Sumita Optical Glass, Inc.
    Inventor: Masaaki Otsuka
  • Patent number: 5545595
    Abstract: A high efficiency wavelength up-conversion transparent glass ceramics composition is provided containing a rare earth ion, which can be applied to short wavelength solid lasers, full color displays, infrared light detecting sensors, etc. The ceramic composition has the following chemical composition, in which fluoride fine crystals containing rare earth ions are preferentially precipitated:______________________________________ SiO.sub.2 10-60 mol % AlO.sub.1.5 0-40 mol % GaO.sub.1.5 0-40 mol % PbF.sub.2 5-60 mol % CdF.sub.2 0-60 mol % GeO.sub.2 0-30 mol % TiO.sub.2 0-10 mol % ZrO.sub.2 0-10 mol % ReF.sub.3 or ReO.sub.1.5 0.05-30 mol % (Re = Er, Tm, Ho, Yb, Pr, etc.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: August 13, 1996
    Assignees: Sumita Optical Glass, Inc., Nippon Telegraph and Telephone Corporation
    Inventors: Yuhu Wang, Junichi Ohwaki
  • Patent number: 5541012
    Abstract: A new infrared-to-visible up-conversion material is provided which can be applied to an infrared light identification element having a useful conversion efficiency and sensitivity for infrared light in the wavelength of 1.5 .mu.m band, 0.98 .mu.m band and 0.8 .mu.m band without the necessity of previous excitation of the material. This infrared-to-visible up-conversion material consists of an inorganic material comprising at least two elements of erbium (Er) and a halogen or compounds thereof.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: July 30, 1996
    Assignees: Nippon Telegraph and Telephone Corporation, Sumita Optical Glass, Inc.
    Inventors: Junichi Ohwaki, Yuhu Wang, Atsushi Shibukawa, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 5472471
    Abstract: An optical fiber bundle for heat resistance and vacuum resistance which can be used even at a very high temperature or high vacuum is provided in economical manner. This is accomplished by a process for the production of an optical fiber bundle for heat resistance and vacuum resistance, which comprises making up optical fiber filaments each having a core part and a clad part into a bundle, closely fusion-bonding the end of the optical fiber bundle with a bonding glass and then subjecting the bonding glass to a crystallization treatment to increase the heat resistance.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: December 5, 1995
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Nobuyoshi Baba, Shinobu Nagahama, Koji Moriya, Junya Yamauchi
  • Patent number: 5420080
    Abstract: A high efficiency wavelength up-conversion transparent glass ceramics composition is provided containing a rare earth ion, which can be applied to short wavelength solid lasers, full color displays, infrared light detecting sensors, etc. The ceramic composition has the following chemical composition, in which fluoride fine crystals containing rare earth ions are preferentially precipitated:______________________________________ SiO.sub.2 10-60 mol % AlO.sub.1.5 0-40 mol % GaO.sub.1.5 0-40 mol % PbF.sub.2 5-60 mol % CdF.sub.2 0-60 mol % GeO.sub.2 0-30 mol % TiO.sub.2 0-10 mol % ZrO.sub.2 0-10 mol % ReF.sub.3 or ReO.sub.1.5 0.05-30 mol % (Re = Er, Tm, Ho, Yb, Pr, etc.).
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: May 30, 1995
    Assignees: Sumita Optical Glass, Inc., Nippon Telegraph and Telephone Corporation
    Inventors: Yuhu Wang, Junichi Ohwaki
  • Patent number: 5322541
    Abstract: A method of producing a glass blank, comprising the steps of: supplying a desired weight of molten glass material to a bearer heated to a temperature of not more than a softening point of the glass material; performing and cancelling, at a temperature of not less than the softening point, pressing of the glass material supplied to the bearer so as to adjust a thickness of the glass material; and cooling the glass material to a temperature of not more than the softening point.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: June 21, 1994
    Assignees: Matsushita Electric Industrial Co., Ltd., Sumita Optical Glass, Inc.
    Inventors: Yoshiyuki Shimizu, Shoji Nakamura, Tadayoshi Yonemoto, Masaaki Sunohara, Tadao Shioyama, Noriyuki Kawata
  • Patent number: 5284501
    Abstract: The invention provides a method of manufacturing extremely precise glass optical element by thermally deforming optical glass on the optical surf ace of a thermal processing jig coated with chemically stable thin film, followed by the molding of optical glass preform having free surf ace on one side and transcribed surface from the optical surface of the thermal processing jig by means of a press mold which thermally presses the optical glass preform.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: February 8, 1994
    Assignees: Sumita Optical Glass, Inc., Matsushita Electric Industrial Co., Ltd.
    Inventors: Hideto Monji, Kiyoshi Kuribayashi, Makoto Umetani, Noriyuki Kawata
  • Patent number: 5171347
    Abstract: The invention provides a method of manufacturing extremely precise glass optical element by thermally deforming optical glass on the optical surface of a thermal processing jig coated with chemically stable thin film, followed by the molding of optical glass preform having free surface on one side and transcribedsurface from the optical surface of the thermal processing jig by means of a press mold which thermally presses the optical glass preform.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: December 15, 1992
    Assignees: Matsushita Electric Industrial Co., Ltd., Sumita Optical Glass, Inc.
    Inventors: Hideto Monji, Kiyoshi Kuribayashi, Makoto Umetani, Noriyuki Kawata
  • Patent number: 5120343
    Abstract: An apparatus of producing an optical glass element of the present invention comprises the steps of displacing a gob of optical glass on a first heat working jig to a second heat working jig by making the gob of optical glass to adhere to the second heat working jig on the basis of the difference in wettability with high temperature glass between the first heat working jig and the second heat working jig, thermally deforming the gob of optical glass on the second heat working jig to form an optical glass preform, and forming the optical glass preform under heating and pressure by using pressing moulds to form an optical glass element.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: June 9, 1992
    Assignees: Matsushita Electric Industrial Co., Ltd., Sumita Optical Glass, Inc.
    Inventors: Hideto Monji, Kiyoshi Kuribayashi, Masaaki Sunohara, Tadayoshi Yonemoto, Noriyuki Kawata, Tadao Shioyama, Makoto Umetani
  • Patent number: 5087279
    Abstract: A method and apparatus are provided for producing an optical glass element, including displacing a gob of optical glass on a first heat working jig to a second heat working jig by making the gob of optical glass adhere to the second heat working jig due to a difference in wettability with high temperature glass between the first heat working jig and the second heat working jig. The gob of optical glass on the second heat working jig is thermally deformed to form an optical glass preform. The optical glass preform is formed under heat and pressure by using pressure molds to form an optical glass element.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: February 11, 1992
    Assignees: Matsushita Electric Industrial Co., Ltd., Sumita Optical Glass, Inc.
    Inventors: Hideto Monji, Kiyoshi Kuribayashi, Masaaki Sunohara, Tadayoshi Yonemoto, Noriyuki Kawata, Tadao Shioyama, Makoto Umetani
  • Patent number: 5017520
    Abstract: A fluorophosphate optical glass having optical constants, i.e. a refractive index of 1.45 to 1.54 and an Abbe number of 75 to 90, preferably 75 to 89.5, useful as a lens for an optical instrument to obtain a good quality image, is provided, which has a chemical composition (% by mole) comprising:______________________________________ P.sub.2 O.sub.5 6.8-19.0% Al.sub.2 O.sub.3 1.5-6.0% BaO 0.3-6.6% AlF.sub.3 16.6-26.3% MgF.sub.2 2.5-19.0% CaF.sub.2 8.0-28.0% SrF.sub.2 9.7-35.0% BaF.sub.2 7.9-35.0% NaF 0.5-4.0% Gd.sub.2 O.sub.3 1.0-6.0% Y.sub.2 O.sub.3 0-3.5% La.sub.2 O.sub.3 0-3.5% Yb.sub.2 O.sub.3 0-3.5% sum of Gd.sub.2 O.sub.3, Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Yb.sub.2 O.sub.3 1.0-6.0% GdF.sub.3 0-2.0% CaO 0-3.5% SrO 0-3.5% ZnO 0-3.5% MgO 0-3.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: May 21, 1991
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Otsuka, Masayuki Komiya, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 4990468
    Abstract: A fluorophosphate optical glass having optical constants, i.e. refractive index (nd) of 1.54 to 1.60 and Abbe number (.nu.d) of 68 to 75 and having abnormal partial dispersion represented by a relative partial dispersion of at least 0.537 is provided, which has a chemical composition (% by weight) comprising:______________________________________ Al(PO.sub.3).sub.3 15-32% Ba(PO.sub.3).sub.2 0-10% Sr(PO.sub.3).sub.2 0-10% Ca(PO.sub.3).sub.2 0-10% Mg(PO.sub.3).sub.2 0-10% sum of metaphosphates 20-32% BaF.sub.2 20-70% SrF.sub.2 5-40% CaF.sub.2 0-15% MgF.sub.2 0-10% AlF.sub.3 0-5% GdF.sub.3 0-5% sum of fluorides 55-75% Gd.sub.2 O.sub.3 5-22% La.sub.2 O.sub.3 0-7% Y.sub.2 O.sub.3 0-10% Yb.sub.2 O.sub.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: February 5, 1991
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masayuki Komiya, Masaaki Otsuka, Naruhito Sawanobori, Shinobu Nagahama