Abstract: A moisture-crosslinkable primer which comprises a solution of a hydrogenated polybutadiene into which has been introduced a silyl group of the formula: ##STR1## wherein R is an alkyl group having 1 to 5 carbon atoms, R' is an alkoxy group having 1 to 5 carbon atoms or a halogen atom, and n is an integer of from 1 to 3, in an organic solvent, which has excellent heat-resistant adhesion and durable adhesion and is useful for adhering between polyolefinic substances or between polyolefinic substances and other organic substances.

Abstract: A one-pack epoxy structural adhesive for automobile which comprises 100 parts by weight of a mixture of a bisphenol epoxy resin and either one or both of an urethane-modified epoxy resin and an acrylonitrile/butadiene-modified epoxy resin as an epoxy resin component, 10 to 300 parts by weight of a polyester resin having carboxyl group at its termini, and 0.1 to 30 parts by weight of a latent curing agent. The adhesive of the present invention can be used as a structural adhesive for the weld bonding method in the structural parts of automobile wherein the adhesive shows an excellent shower resistance and the overflow of the adhesive can easily be wiped off. The adhesive of the present invention can easily be bead-applied at a temperature of around 40.degree. C., and hence, is suited for use in the assembly or bonding of car body.

Abstract: A moisture-curing hot-melt adhesive comprises (A) a urethane prepolymer comprising hard and soft segment moieties and having an isocyanate group at the terminus which is prepared by reacting stepwise a polyol having a molecular weight of 1,000 to 8,000 and a thermoplastic saturated polyester polyol having a molecular weight of 1,000 to 6,000, a melting point of 50.degree. C. or higher and a glass transition temperature of 10.degree. C. or higher with an diisocyanate compound in a overall NCO/OH ratio of 1.6 to 3.0, and (B) a urethane prepolymer comprising a soft segment moiety and having an isocyanate group at the terminus which is prepared by reacting a polyol having a molecular weight of not more than 8,000 with a diisocyanate compound in an NCO/OH ratio of 1.6 to 3.0, said component (A) and component (B) being mixed in a ratio of 10:90 to 90:10 by weight.

Abstract: A hot melt adhesive crosslinkable by UV irradiation comprising a hot melt adhesive base, a saturated hydrocarbon oligomer containing at least one acryloyl group in a molecule for affording crosslinkability by UV irradiation, and a photopolymerization initiator, an optical disc comprising a pair of substrate, at least one of which is provided with an information recording layer, adhered to each other by means of a hot melt adhesive crosslinkable by UV irradiation and the process for preparing the same are disclosed. The adhesive of the present invention has a high heat resistance and heat stability, is applicable at a low temperature and at a low viscosity, has high softening point and high viscosity by UV irradiation. The optical disc of the present invention has high productivity, no corrosion and high heat resistance.

Abstract: Primer composition comprising a silane coupling agent, an alkoxysilylated NCO-containing urethane prepolymer which is prepared by reacting a polyisocyanate with a diol to give an NCO-containing urethane prepolymer, and reacting the resulting NCO-containing urethane prepolymer with a trialkoxysilane having a functional group active to NCO group wherein a part of whole of the remaining NCO groups of the high molecular weight polyisocyanate are reacted with the silane. Said primer composition has excellent plasticizer resistance, solvent resistance and film-forming properties and further improved adhesin properties to glass, metals, ceramics, and is useful as a primer for various adhesives, particularly for applying to glass, metals, and ceramics.

Abstract: A moisture-curing sealant composition which comprises a urethane prepolymer containing free NCO group as a main component and di[2-(3,5-dimethylmorpholino)ethyl] ether of the formula: ##STR1## as a curing catalyst, said curing catalyst being incorporated in an amount of 0.2 to 2% by weight based on the whole amount of the moisture-curing sealant composition. The moisture-curing sealant composition shows an excellent storage stability and curability both at ordinary and lower temperature.

Abstract: A silicon-containing polymer having comb-shape structure comprising a unit of an organopolysiloxane as the main chain and a vinyl polymer as the side chain of the following formula: ##STR1## wherein R.sup.1 is C.sub.1-4 alkylene, R.sup.2, R.sup.3 and R.sup.4 are each C.sub.1-4 alkyl, R is H or methyl, X.sup.1 is hydroxycarbonyl, C.sub.2-5 alkoxycarbonyl, C.sub.3-8 cycloalkyl-oxycarbonyl or phenyl, n is 1-100,000, R.sup.5 is C.sub.1-4 alkyl or phenyl, X.sup.2 is H, C.sub.1-4 alkyl, phenyl, chlorine, C.sub.1-4 alkoxysilyl, or C.sub.1-4 alkyl which is substituted by one to three of --NH.sub.2, --NH--, --SH, --CN or F, l is 2-20, m is 0 or 1-10, which has excellent migration property and is useful as agents for giving water-repellency, adhesion, surface activity, etc. in paints or other compositions, and an intermediate macromonomer, and process for the production thereof.

Abstract: Polymer dispersing agent comprising a graft polymer prepared by graft-polymerizing an organopolysiloxane having a mercapto group on the side chain with at least one acrylic or methacrylic monomer, and epoxy resin composition comprising epoxy resin, silicone resin and the above polymer dispersing agent. The polymer dispersing agent has an excellent effect for dispersing the silicone resin into the epoxy resin, and thereby the epoxy resin composition thus prepared has high dispersion stability and exhibits improved impact resistance and relaxation of residual internal stress and is useful as a sealing agent for IC, a coating agent, a paint composition, an adhesive, and a prepreg.

Abstract: One-pack type heat pre-curable moisture-curing sealant composition which comprises as the main component(A) a urethane prepolymer having a content of an active free isocyanate group (NCO) of 0.5 to 13% by weight which is prepared by reacting a polyol and an excess amount of an aromatic polyisocyanate compound, and(B) a vinyl polymer containing a siloxy group, and as an additive(C) a filler in an amount of 20 to 50% by weight based on the whole weight of the sealant, and(D) a plasticizer in an amount of 5 to 30% by weight based on the whole weight of the sealant, which can be precured at a comparatively lower temperature within a short period of time and cured with moisture in air and is useful for adhering various parts in automobile and construction industries without a temporary holding means.

Abstract: An adhesion-improver which comprises a reaction product of an amino compound having a primary and/or secondary amino group in the molecule or a modified amino compound obtained by modifying the amino compound with a compound having an epoxy group, and a carbonyl compound, particularly a dicarbonyl compound of the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each an alkyl having 1 to 16 carbon atoms, an aryl having 6 to 12 carbon atoms or an alkoxy having 1 to 4 carbon atoms, R.sup.3 is a hydrocarbon group having one or more carbon atoms, and n is 0 or 1, is used to prepare a curable composition such as an adhesive, sealing agent, paint or pourable compound.

Abstract: A two part primer composition comprising a main component comprising at least one styrene-ethylene-butene-styrene block copolymer or styrene-ethylene-propylene-styrene copolymer, said copolymer being copolymerized with maleic anhydride hydrogenated, and an amine catalyst, and a curing component comprising an epoxy resin having two or more functional groups, which has excellent heat-resistant adhesion and durable adhesion and is suitable for adhering between polyolefinic substances or between an polyolefinic substance and other organic substance.

Abstract: Two part epoxy resin system comprising a main component comprising a bisphenol type epoxy resin having not more than 0.08% by weight of a content of a saponifiable chlorine-containing group and a curing component comprising a modified aromatic polyamine and a liquid imidazole, which has a long pot-life at room temperature and is curable even at an intermediate temperature such as about 50.degree. to 60.degree. C., and is useful as a paint composition, an adhesive, a lining material, a molding material and a floor covering material.

Abstract: A moisture-curing hot-melt sealant which comprises a polyurethane prepolymer which is prepared by reacting (a) a polyol component comprising a mixture of a thermoplastic saturated polyester polyol having a hydroxyl group at the terminus and having a molecular weight of 8,000 to 25,000 and a thermoplastic or liquid polyol having a hydroxyl group at the terminus and having a molecular weight of not more than 5,000 which is compatible with the thermoplastic saturated polyester polyol in a ratio of 1:1 to 1:8 by mole, and (b) a polyisocyanate compound having two or more isocyanate groups in the molecule thereof in an equivalent ratio of isocyanate group/hydroxyl group of 1.4 to 3 in admixture with the conventional additives. Said sealant has excellent heat resistance and initial properties and is suitable for adhering, for example, window glass of automobiles, particularly in cold district.

Abstract: A plastisol composition comprising polyvinyl chloride as a main component, a plasticizer and a blocked compound of diisocyanate polymer with styrenated phenol as an adhesion-improver, and optionally a powdery curing agent having a melting point of 50.degree. to 150.degree. C. which is surface-treated, said composition having improved adhesion properties when gelated under low temperature conditions such as at 110.degree. to 130.degree. C. for 15 to 30 minutes and being useful as an adhesive, a sealant, or a coating agent, particularly as a sealant for the body of automobiles, and a novel blocked polyisocyanurate compound useful as an adhesion-improver for the above plastisol composition and also as an adhesive, a coating agent, a sealant, and an crosslinking agent for an active hydrogen-containing high molecular weight compound.

Abstract: A vinyl polymer having alkoxysilyl groups at both terminals of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each an alkyl having 1 to 4 carbon atoms, R.sup.3 is an alkylene having 1 to 4 carbon atoms, n is an integer of 0 to 2, Z is at least one group of the formulae: ##STR2## (wherein R.sup.4 is hydrogen or methyl, Y.sup.1 is an ester residue having 2 to 11 carbon atoms, phenyl or a halogen, Y.sup.2 is an ester residue having 2 to 6 carbon atoms or a halogen, and Y.sup.3 is fluorine or chlorine atom), m is 10 to 10,000, which has excellent physical strength and is useful as an ingredient for paints, adhesives, sealing agents, and tacking agents, and an intermediate therefor, and a process for the production thereof.

Abstract: A plastisol composition which comprises a polyvinyl chloride, a plasticizer and a blocked isocyanate compound as an adhesion-modifier, supplemented with a powdery curing agent for an epoxy resin having a melting point of 50.degree. to 150.degree. C. which is surface-treated. The plastisol composition of the present invention has an improved adhesion property at a lower temperature and is useful as an adhesive, sealing agent and coating agent.

Abstract: An adhesion-improver which comprises a reaction product of an amino compound having a primary and/or secondary amino group in the molecule or a modified amino compound obtained by modifying the amino compound with a compound having an epoxy group, and a carbonyl compound, particularly a dicarbonyl compound of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each an alkyl having 1 to 16 carbon atoms, an aryl having 6 to 12 carbon atoms or an alkoxy having 1 to 4 carbon atoms, R.sup.3 is a hydrocarbon group having one or more carbon atoms, and n is 0 or 1, which is useful for improving adhesion of curable compositions such as adhesives, sealing agents, paints and pourable compounds, and a curable composition comprising a conventional main component and the adhesion-improver as set forth above which has excellent adhesion and curing characteristics.

Abstract: Primer composition for glass comprising a silane coupling agent, a reaction product of a polyisocyanate and a silane compound, a film-forming agent, and an acidic carbon black having pH 2.5 to 4. Said primer composition has extremely high weatherability and is useful as a primer for glass, particularly for applying to window glass of automobiles.

Abstract: A structural adhesive having excellent anti-corrosion properties which comprises: (A) a rubber modified epoxy resin prepared by reaction of a bisphenol epoxy resin and a butadiene-acrylonitrile-(meth)acrylic acid copolymer, (B) an urethane modified epoxy resin, (C) a latent curing agent, and (D) a rust inhibiting pigment selected from the group consisting of: (i) a rust inhibiting pigment comprising aluminum orthophosphate and a zinc compound, (ii) a rust inhibiting pigment comprising aluminum metaphosphate, a zinc compound and/or an alkaline earth metal compound, and (iii) a rust inhibiting pigment comprising aluminum metaphosphate and a zinc compound and optionally an alkaline earth metal compound, wherein the adhesive contains said rubber modified epoxy resin (A) and said urethane modified epoxy resin (B) in a weight ratio of 1:9 to 3:1, and said latent curing agent (C) and said rust inhibiting pigment (D) at 0.

Abstract: A process for preparing a telechelic vinyl resin of a low molecular weight having alkoxysilylalkyl thioether groups at both termini, which comprises subjecting 1 to 20 parts by weight of one or more of a disulfide compound, 0.01 to 1 part by weight of one or more of a tetrasulfide compound, and 100 parts by weight of a vinyl monomer to photopolymerization reaction, a part of the vinyl monomer being optionally substituted with a monomer having an alkoxysilyl group, and the resin prepared by said process. The resin of the present invention provides a crosslinkable resin having an excellent physical strength after curing and can be used for paints, adhesives, sealants, pressure-sensitive adhesives and the like.