Abstract: Method of chromatographically separating a mixture by contacting said mixture under chromatographic separation conditions with a chromatographic separation stationary phase comprising a polymer formed by coating substantially all of the surfaces of a microporous, comminuted substrate material with a monomer that is subsequently polymerized in situ with a cold-gas plasma discharge.
Abstract: Method of chromatographically separating a mixture by contacting said mixture under chromatographic separation conditions with a chromatographic separation stationary phase comprising an N-acyl diazepine polymer. In a preferred from, the polymer has been rendered substantially alkali-stable by substitution for the hydrogen at the C3 position on the diazepine ring.
Abstract: Method of chromatographically separating a mixture by contacting said mixture under chromatographic separation conditions with a chromatographic separation stationary phase comprising an N-acyl diazepine polymer. In a preferred form, the polymer has been rendered substantially alkali-stable by substitution for the hydrogen at the C3 position on the diazepine ring.
Abstract: A process of electrolessly metallizing a body on the surface thereof with a metal coating incorporating particulate matter therein, which process comprises contacting the surface of said body with a stable electroless metallizing bath comprising a metal salt, an electroless reducing agent, a complexing agent, an electroless plating stabilizer, a quantity of particulate matter which is essentially insoluble or sparingly soluble in the metallizing bath, and a particulate matter stabilizer (PMS), and maintaining said particulate matter in suspension in said metallizing bath during the metallizing of said body for a time sufficient to produce a metallic coating with said particulate matter dispersed therein.
Abstract: A method for the electroless coating of ferromagnetic substrates substantially free of microspheres or other unwanted auxillary matter, thereby reducing the roughness of the coated articles. The method and articles produced are subjected to a magnetic field and demagnetized prior to the plating step. The method is of particular utility in the coating of textile machinery parts operating at high rotational speed in the minimizing of dust and yarn damage. The method is also of great utility in the deposition of composite electroless coatings.
Abstract: A process of electrolessly metallizing a body on the surface thereof with a metal coating incorporating particulate matter therein, which process comprises contacting the surface of said body with a stable electroless metallizing bath comprising a metal salt, an electroless reducing agent, a complexing agent, an electroless plating stabilizer, a quantity of particulate matter which is essentially insoluble or sparingly soluble in the metallizing bath, and a particulate matter stabilizer (PMS), and maintaining said particulate matter in suspension in said metallizing bath during the metallizing of said body for a time sufficient to produce a metallic coating with said particulate matter dispersed therein.
Abstract: Disclosed are processes and articles for the preparation of composite electroless coatings which comprise a metal and/or metal alloy, plus particulate matter, the latter having at least two distinct nominal sizes.
Abstract: A method for the electroless coating of ferromagnetic substrates substantially free of microspheres or other unwanted auxiliary matter, thereby reducing the roughness of the coated articles. The method and articles produced are subjected to a magnetic field and demagnetized prior to the plating step. The method is of particular utility in the coating of textile machinery parts operating at high rotational speed in the minimizing of dust and yarn damage. The method is also of great utility in the deposition of composite electroless coatings.
Abstract: Metallic surfaces are imparted to non-conductor substrates by an electroless plating process comprising contacting the substrate with colloidal composition comprising colloids of catalytic metals capable of electroless plating initiation and activator(s) capable of modifying and extending the useful life-time for the colloidal composition from further deterioration.
Abstract: A resilient, composite surface material which is resistant to the effects of weather and traffic. It is constructed of a layer of resilient, shock-attenuating, closed-cell, elastomeric foam; a fabric binding layer, which can be adhesively or thermally bound to the foam layer; and a wear- and weather-resistant layer, applied in a fluid form, which binds mechanically to the fabric layer by saturating the fabric and then hardening. The resulting surface can be used for playgrounds or recreational areas, in industrial or commerical application, or in any location where a resilient, wear- and weather-resistant surface is desired.
Abstract: Disclosed herein are processes for the electroless (chemical) plating of substrates incorporating polyelectrolytes to increase the catalytic site density prior to the electroless (chemical) metal deposition step.
Abstract: An electric discharge surface conditioning apparatus includes a discharge electrode consisting of an assembly of alternating conductive and non-conductive discs which rotate about an axis. The surface of the conductive discs includes a specific pattern of slots to effect a pumping action thereby enhancing the electric discharge efficiency by circulating the fluid away from the surface of the workpiece being machined. A control arrangement for controlling the orientation of the described electrode is provided.
Abstract: Disclosed herein are processes for the electroless (chemical) plating of substrates incorporating polyelectrolytes to increase the catalytic site density prior to the electroless (chemical) metal deposition step.
Abstract: Disclosed are processes and articles for the preparation of composite electroless coatings which comprise a metal and/or metal alloy, plus particulate matter, the latter having at least two distinct nominal sizes.
Abstract: Disclosed are processes and articles for composite electroless coatings comprising at least two distinct layers, the first layer comprising a metal and/or a metal alloy plus particulate matter and the second layer comprising a metal and/or a metal alloy and being substantially free of particulate matter.
Abstract: Disclosed are processes and articles for composite electroless coatings comprising at least two distinct layers, the first layer comprising a metal and/or a metal alloy plus particulate matter and the second layer comprising a metal and/or a metal alloy and being substantially free of particulate matter.
Abstract: A process is described for the reception of composite electroless plating onto a non-catalytic metal or non-catalytic alloy, non-catalytic to composite electroless plating. The process comprises contacting the non-catalytic substrate with a promoter composition containing ions selected from the group of nickel, cobalt, iron, and mixtures thereof and a suitable reducing agent, and thereafter contacting the treated surface with a composite electroless plating bath comprising particulate matter to deposit a metallic layer with finely divided particulate matter dispersed throughout.
Abstract: Metallic surfaces are imparted to non-conductive or dielectric substrates by an electroless coating process comprising coating the surface of the substrate with a hydrous oxide colloid of non-precious metal ions preferably selected from the group consisting of cobalt, nickel and copper ions, reducing the selected metal ions to a reduced or zero valence state with a suitable reducing agent, and exposing the substrate to an electroless plating bath.
Abstract: Metallic surfaces are imparted to non-conductive or dielectric substrates by an electroless (chemical) coating process comprised of coating the surface of the substrate with colloids of catalytic non-precious metals wherein the metals are either part of an alloy or in the elemental state or a compound and wherein the colloidal suspension further comprises antioxidant as to minimize the surface oxidation of the colloids and are further admixed in a manner resulting in good colloidal stability.
Abstract: This invention is a method for depositing on an article a coating containing at least one member of the group metals and metal alloys plus particulate dispersed diamond comprising contacting the surface of the article with a stable electroless plating bath consisting essentially of an aqueous solution of soluble constituents of the group, electroless reducing agent therefor, a suspension of diamond particles therein and a stabilizer, and maintaining the diamond particles in suspension throughout the bath during the coating of the article for a time sufficient to produce a preselected depth of coating on the article, and the coated article pe se.This is a reissue of a patent which was the subject of a reexamination certificate No. B1 Re. 29,285, dated July 5, 1983, Request No. 90/000,120, Dec. 3, 1981.
Type:
Grant
Filed:
August 15, 1989
Date of Patent:
December 10, 1991
Assignee:
Surface Technology, Inc.
Inventors:
Theodore P. Christini, Albert L. Eustice, Arthur H. Graham