Publication number: 20240313216
Abstract: Provided is a transition metal-containing hydroxide capable of improving the cycle characteristics and safety of a secondary battery, while imparting an excellent battery capacity to the secondary battery, by preventing the elution of an additive metal element, which contained in the transition metal-containing hydroxide, due to phase transition or segregation. A transition metal-containing hydroxide that is a precursor of a positive electrode active material in a non-aqueous electrolyte secondary battery, the transition metal-containing hydroxide containing at least one main metal element selected from the group consisting of Ni, Co and Mn and at least one additive metal element selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zr, V, Nb, Cr, Mo, W, Fe, Ru, Cu, Zn, B, Al, Ga, Si, Sn, P and Bi, in which a cumulative pore volume in a BJH method measured by a gas adsorption method is 0.145 cm3/g or less.
Type:
Application
Filed:
May 24, 2024
Publication date:
September 19, 2024
Applicants:
TANAKA CHEMICAL CORPORATION, PANASONIC ENERGY CO., LTD.
Inventors:
Akari MAKIDA, Ryota KOBAYASHI, Masahiro TAKASHIMA, Kohei KINTSU, Shun NOMURA, Takeshi CHIBA, Takayuki ISHIKAWA, Takuya SHINOMIYA
Patent number: 11557754
Abstract: A positive electrode active material for a lithium secondary battery, comprising a lithium-containing composite metal oxide in the form of secondary particles formed by aggregation of primary particles capable of being doped and undoped with lithium ions, each of the secondary particles having on its surface a coating layer, the positive electrode active material satisfying the following requirements (1) to (3): (1) the metal oxide has an ?-NaFeO2 type crystal structure of following formula (A): Lia(NibCocM11-b-c)O2??(A) wherein 0.9?a?1.2, 0.9?b<1, 0<c?0.1, 0.9<b+c?1, and M1 represents at least one optional metal selected from Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In and Sn; (2) the coating layer comprises Li and M2, wherein M2 represents at least one optional metal selected from Al, Ti, Zr and W; and (3) the active material has an average secondary particle diameter of 2 to 20 ?m, a BET specific surface area of 0.1 to 2.
Type:
Grant
Filed:
January 26, 2015
Date of Patent:
January 17, 2023
Assignees:
SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATION
Inventors:
Tetsuri Nakayama, Kenji Takamori, Kyousuke Doumae, Takashi Kitamoto