Patents Assigned to Teroson GmbH
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Patent number: 7163976Abstract: The addition of pulverulent monosaccharides, disaccharides or oligosaccharides to plastisols based on pulverulent organic polymers and plasticizers results in plastisols with good adhesion properties on a large number of substrates employed in automobile construction. These plastisols are distinguished by good adhesion properties and a high resistance to ageing, and can be employed in automobile construction both in shell construction and in the lacquering line and in the trim shop for adhesive, sealing and coating tasks.Type: GrantFiled: December 16, 2003Date of Patent: January 16, 2007Assignee: Henkel-Teroson GmbHInventor: Guenter Butschbacher
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Patent number: 6919397Abstract: The use of benzoate plasticizers in two-component insulating glass adhesives/sealants based on polysulfide polymers or polymercaptan polymers enables simpler production due to the low viscosity thereof. Improved miscibility of the two components and an improved rate of curing are observed. In addition, the use of phthalate plasticizers, which may possibly cause an endocrinal effect in humans and animals, is avoided.Type: GrantFiled: May 10, 2001Date of Patent: July 19, 2005Assignee: Henkel-Teroson GmbH (Henkel-Teroson)Inventors: Manfred Proebster, Stefan Grimm
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Publication number: 20040181013Abstract: The present invention relates to phenol terminated or aminophenyl terminated products and compositions containing the same. The phenol-terminated or amino-terminated products are produced by reacting a stoichiometric excess of a carboxylic anhydride or dianhydride with a diamine or polyamine, and reacting the excess carboxylic anhydride groups or carboxylic acid groups with at least one polyphenol or aminophenol to form the phenol-terminated or aminophenyl-terminated products. The compounds are preferably utilized in adhesive compositions.Type: ApplicationFiled: March 23, 2004Publication date: September 16, 2004Applicant: Henkel Teroson GmbHInventor: Hubert Schenkel
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Patent number: 6776869Abstract: A high strength adhesive having a good impact strength at low temperatures, below 0° C., and at temperatures of 90° C. is provided. The adhesive comprises a copolymer having at least one glass transition temperature of −30° C. or lower having epoxy reactive end groups or a reaction product of the copolymer with a polyepoxide, a reaction product of a polyurethane prepolymer and a polyphenol or polyaminophenol and at least one epoxy resin.Type: GrantFiled: November 7, 2001Date of Patent: August 17, 2004Assignee: Henkel-Teroson GmbHInventor: Hubert Schenkel
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Patent number: 6573309Abstract: Foamable compositions which exhibit reduced surface tack and better handling characteristics are obtained through the use of specific combinations of epoxy resins. One or more solid epoxy resins are utilized together with liquid and/or semi-solid epoxy resins. The compositions, which preferably contain hollow glass microspheres, are capable of providing foams which are useful in the manufacture of reinforced structural members.Type: GrantFiled: August 31, 2001Date of Patent: June 3, 2003Assignee: Henkel Teroson GmbHInventors: Dirk Reitenbach, Xaver Muenz
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Patent number: 6559213Abstract: Monoesters of fatty acids containing at least 12 carbon atoms may replace a considerable percentage of conventional plasticizers based on phthalic acid esters, alkyl sulfonic acid esters of phenol or other known plasticizers in plastisol compositions. The methyl and/or ethyl esters of fatty acids of renewable fats and oils, such as tall oil fatty acids, rapeseed oil fatty acids, linseed oil fatty acids or safflower oil fatty acids, are preferably used for these secondary plasticizers. These plastisols are preferably used as adhesives, sealing materials or coatings in automobile construction.Type: GrantFiled: May 15, 2001Date of Patent: May 6, 2003Assignee: Henkel-Teroson GmbHInventor: Karl Wesch
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Patent number: 6518346Abstract: The cross-linking of cross-linkable compositions containing hydroxyl-bearing and carboxylate-bearing addition polymers of 1,3-butadiene is achieved using catalysts containing alkali metal salts of carboxylic acids.Type: GrantFiled: June 12, 2001Date of Patent: February 11, 2003Assignees: Henkel Teroson GmbH, Th. Goldschmidt. AGInventors: Peter Born, Uwe Weinbrecht, Dieter Guhl
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Patent number: 6448338Abstract: Hot-pumpable, heat-curing compositions based on solid ethylene/vinyl acetate copolymers and liquid reactive plasticizers containing olefinically unsaturated double bonds and at least one peroxidic crosslinking agent are suitable as sealing compounds for sealing fine and rough seams in vehicle manufacture. By adding expanding agents, the compositions may be used as lining adhesives. The preferred applications are at the white-shell stage of car manufacture.Type: GrantFiled: March 28, 2000Date of Patent: September 10, 2002Assignee: Henkel Teroson GmbHInventors: Peter Born, Klaus Hoellriegel
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Patent number: 6361643Abstract: One-component, heat-curing reactive compositions based on liquid rubbers containing reactive olefinic double bonds and optionally solid rubbers and vulcanization systems based on sulfur have high maxima of the acoustic loss factor over a broad in-use temperature range of around +10° C. to +40° C. in their vulcanized state. These compositions optionally contain fine-particle thermoplastic polymers as an additional component. The compositions are suitable for use as acoustically damping adhesives, sealing compounds or coating compositions.Type: GrantFiled: January 26, 2001Date of Patent: March 26, 2002Assignee: Henkel Teroson GmbHInventors: Peter Born, Hubert Schenkel
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Patent number: 6117971Abstract: The invention relates to a process for recycling cured or partly cured polysulfide and/or polymercaptan compositions. Recycling is carried out in a non-volatile liquid with addition of a depolymerizing agent, preferably a sulfur-containing vulcanization accelerator known from rubber technology. The depolymerisate may be added to the curing component of two-component polysulfide and/or polymercaptan adhesives/sealants or coating materials in large quantities without any significant effect on its stability in storage or curing characteristics.Type: GrantFiled: February 5, 1999Date of Patent: September 12, 2000Assignee: Henkel-Teroson GmbHInventors: Stefan Grimm, Karl-Heinz Pressel, Manfred Proebster
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Patent number: 6096791Abstract: Heat-curing, expanding mouldings based on solid polybutadiene rubber and vulcanization systems free from elemental sulfur are distinguished by the following advantageous properties: in the uncured state in which they are supplied, they have minimal rubber-elastic resilience and are readily formable. During the curing process, no unpleasant odors are given off and, after curing, a soft and elastic foam with a continuous outer skin is formed.Type: GrantFiled: April 29, 1999Date of Patent: August 1, 2000Assignee: Henkel-Teroson GmbHInventors: Peter Born, Klaus Hoellriegel, Rudolf Neubauer
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Patent number: 6079871Abstract: The invention is a device and a method for combining at least two fluid media. The device comprises a flow region (1) which is attached to and/or formed with an opening of a first chamber (2) and which is designed to accommodate the fluid medium coming from the first chamber and to transport it to the outlet (3) of the flow region (1) which is preferably followed by a mixing zone. A second chamber (9) designed to be filled with a second fluid medium is connected to the flow region and/or to the first chamber through at least one first opening element (inlet opening) (11) for diverting part of the first fluid medium from the first into the second chamber. The second chamber is provided with at least one second opening element (second opening) (12) opening into or adjoining the flow region (1) for discharging the second fluid medium displaced into it by the first fluid medium. Several first chambers (2) or second chambers (9) may be provided.Type: GrantFiled: December 5, 1996Date of Patent: June 27, 2000Assignee: Henkel-Teroson GmbHInventors: Konrad H. Jonas, Hansjoerg Maier, Klaus Langendorf
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Patent number: 6025416Abstract: Two component adhesive/sealing masses based on silane terminated prepolymers contain a component A which is a one-component, humidity hardening adhesive/sealing mass with high initial adhesiveness, and a component B which is a crosslinking agent and/or accelerator for component A are disclosed. These adhesive/sealing masses are suitable for gluing without primer parts made of metals or other materials such as aluminum, steel, glass, wood or plastics. In a particularly preferred embodiment, component B consists of a viscous, stable mixture of plasticisers, water, thickeners and other optional auxiliary substances.Type: GrantFiled: March 24, 1998Date of Patent: February 15, 2000Assignee: Henkel Teroson GmbHInventors: Manfred Proebster, Werner Schumacher
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Patent number: 6015865Abstract: A reactive hot melt adhesive contains, as resin component, a reaction product ofa) 30 to 50 wt-% of an epoxy resin, solid at root temperature, prepared from bisphenol A and/or bisphenol F and epichlorhydrin with an epoxide equivalent weight of 400 to 700,b) 10 to 25 wt-% of an epoxy resin, liquid at room temperature, prepared from bisphenol A and/or bisphenol F and epichlorhydrin with an epoxide equivalent weight of 150 to 220 andc) 35 to 50 wt-% amino-terminated polyethylene and/or polypropylene glycols.Type: GrantFiled: October 22, 1997Date of Patent: January 18, 2000Assignee: Henkel-Teroson GmbHInventors: Norman E. Blank, Hubert K. Schenkel
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Patent number: 6004425Abstract: One-component hot-curing structural adhesives based on liquid rubbers, which may optionally contain functional groups, solid rubbers, thermoplastic polymer powders and sulfur and also vulcanization accelerators are suitable for bonding metal parts. Tensile shear strengths of more than 15 MPa and high breaking elongations of more than 15% can be obtained. These adhesives are substantially free from low molecular weight epoxy resins and are particularly suitable for use in white-shell assembly in the car industry.Type: GrantFiled: July 25, 1997Date of Patent: December 21, 1999Assignee: Henkel-Teroson GmbHInventors: Peter Born, Frank Dittrich
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Patent number: 5994422Abstract: Hot-curing, foamable reactive compositions based on natural and/or synthetic rubbers containing olefinic double bonds, vulcanizing agents and blowing agents with a high percentage content of sulfur give foamed rubber compositions exhibiting high structural strength and high volume expansion. These compositions are suitable as multifunctional filling materials for hollow structures or hollow profiles in vehicle or machine construction. At one and the same time, they perform a sealing function, damp acoustic vibration and stiffen the hollow structures to a considerable extent.Type: GrantFiled: November 18, 1997Date of Patent: November 30, 1999Assignee: Henkel-Teroson GmbHInventors: Peter Born, Frank Dittrich, Michael Hirthammer
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Patent number: 5976291Abstract: A Process for Joining Plastic Moldings Plastic moldings can be joined with one-component or two-component adhesives, the connecting joint being spanned by metal strips. The metal strips are at least partly embedded in the adhesive layer. This process is particularly suitable for repairing damaged plastic moldings, more particularly automobile parts, for example fenders. The moldings repaired by the process according to the invention are restored to their original performance properties, more particularly dimensional rigidity, impact strength and appearance. In the event of scrapping, the moldings thus repaired are fully recyclable by conventional methods.Type: GrantFiled: March 7, 1997Date of Patent: November 2, 1999Assignee: Henkel Teroson GmbHInventor: Michael Schaetzle
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Patent number: 5965645Abstract: A plastisol composition containing plasticizers, fillers and styrene copolymers selected from (a) styrene, .alpha.-methyl styrene and p-methyl styrene, and (b) 3 to 20% by weight, based on the weight of the styrene copolymers, of a comonomer selected from methacrylic acid, acrylic acid and itaconic acid, and optionally (c) a crosslinking comonomer, wherein the maximum of the molecular weight distribution of said copolymers is greater than 1 million as determined by gel permeation chromatography.Type: GrantFiled: December 4, 1996Date of Patent: October 12, 1999Assignee: Teroson GmbHInventors: Michael Beck, Wolfgang Ritter, Klaus Ruch
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Patent number: 5919857Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.Type: GrantFiled: April 7, 1997Date of Patent: July 6, 1999Assignee: Teroson GmbHInventors: Klaus Ruch, Ingolf Scheffler
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Patent number: 5756555Abstract: Plastisol compositions based on vinyl chloride/vinyl acetate copolymers produced by suspension polymerization have a low viscosity, even with low polymer-to-plasticizer ratios, so that they may be used for plastisol formulations suitable for airless spraying. The compositions are stable in storage and show good gelation properties. Coatings based on these plastisols have a good noise-damping effect, even with high vinyl acetate contents.Type: GrantFiled: December 20, 1996Date of Patent: May 26, 1998Assignee: Henkel Teroson GmbHInventors: Karl Wesch, Klaus Ruch