Abstract: The invention is a synergistic combination of inhibitors which effectively prevents corrosion in automotive cooling systems containing antifreeze solution based on water-soluble alcohols. The combination includes sodium tetraborate, sodium benzoate, sodium metaborate, sodium metasilicate and tolyltriazole or benzotriazole.
Abstract: This invention relates to a method of synthesizing single cell protein from residual oils and/or coal by a mutually advantageous combination of a synthesis gas generation process or a coal gasification process in the production of methanol and ammonia, and their use by the protein producing bacteria.
Abstract: Covers N-(3-dimethylaminopropyl)-N'-(3-morpholino-propyl)urea. Also covers a method of producing a polyurethane by utilizing said above compound as a catalyst in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.
Type:
Grant
Filed:
May 22, 1979
Date of Patent:
December 2, 1980
Assignee:
Texaco Development Corporation
Inventors:
George P. Speranza, Robert L. Zimmerman
Abstract: An epoxy resin having superior resistance to thermal shock comprises a vicinal polyepoxide, a curing amount of a certain bicyclic anhydride and an effective amount of a certain bicyclic anhydride and an additive comprising a polyoxyalkylenepolyamine-maleic anhydride condensation product having (thio)carbamoyl, carbamoyl or thioformyl or formyl end groups.
Abstract: Covers a method for preparing a para-alkyl substituted phenyl aldehyde by reacting carbon monoxide and an alkyl mono-substituted benzene in presence of a tantalum, niobium or antimony pentafluoride-hydrogen fluoride catalyst.
Abstract: Hydrocarbons are recovered from a subterranean hydrocarbon-bearing formation penetrated by an injection well and a production well by displacing hydrocarbons toward the production well using a drive fluid such as water thickened with a polymer comprising repeating units of vinyl sulfonic acid alkoxylated with 2,3-epoxy-1-propanol. Optionally, the drive fluid can be saturated with carbon dioxide and/or natural gas at the injection pressure.
Abstract: A novel catalyst material of a boron containing substance for catalyzing the liquid phase oxidation of an olefin with an organic hydroperoxide to the corresponding oxirane is disclosed. The novel catalyst materials are characterized as binary or ternary boride compounds having the general formula M.sub.x B.sub.y or M.sub.x B.sub.y R.sub.z wherein x is an integer from 1-5; y is an integer from 1-2; z is an integer from 1-4; B is boron; M is an element selected from the groups II-A, III-B, IV-B, V-B, VI-B, VII-B, VIII, III-A, IV-A, and V-A of the Periodic Table, the rare earths, and the actinides; and R is an element different from M selected from the same group of elements in the Periodic Table as M. The preferred catalyst materials are those boron containing substances which are substantially insoluble in the reaction mixture containing the organic hydroperoxides, olefins and products.
Abstract: A novel catalyst material of a boron containing substance for catalyzing the liquid phase oxidation of an olefin with an organic hydroperoxide to the corresponding oxirane is disclosed. The novel catalyst materials are characterized as binary or ternary boride compounds having the general formula M.sub.x B.sub.y or M.sub.x B.sub.y R.sub.z wherein x is an integer from 1-5; y is an integer from 1-2; z is an integer from 1-4; B is boron; M is an element selected from the groups II-A, III-B, IV-B, V-B, VI-B, VII-B, VIII, III-A, IV-A, and V-A of the Periodic Table, the rare earths, and the actinides; and R is an element different from M selected from the same group of elements in the Periodic Table as M. The preferred catalyst materials are those boron containing substances which are substantially insoluble in the reaction mixture containing the organic hydroperoxides, olefins and products.
Abstract: A novel catalyst material of a boron containing substance for catalyzing the liquid phase oxidation of an olefin with an organic hydroperoxide to the corresponding oxirane is disclosed. The novel catalyst materials are characterized as binary or ternary boride compounds having the general formula M.sub.x B.sub.y or M.sub.x B.sub.y R.sub.2 wherein x is an integer from 1-5; y is an integer from 1-2; z is an integer from 1-4; B is boron; M is an element selected from the groups II-A, III-B, IV-B, V-B, VI-B, VII-B, VIII, III-A, IV-A, and V-A of the Periodic Table, the rare earths, and the actinides; and R is an element different from M selected from the same group of elements in the Periodic Table as M. The preferred catalyst materials are those boron containing substances which are substantially insoluble in the reaction mixture containing the organic hydroperoxides, olefins and products.
Abstract: Covers a method of preparing diaminodiphenylmethanes and higher homologues thereof which comprises the step of condensing aniline and formaldehyde in the presence of hydroxy ethane sulfonic acid catalyst.
Type:
Grant
Filed:
February 16, 1979
Date of Patent:
July 15, 1980
Assignee:
Texaco Development Corporation
Inventors:
Edward T. Marquis, Walter H. Brader, Jr.
Abstract: Covers a new composition of matter comprising an acrylamide or methacrylamide monomer characterized by the following structural formula: ##STR1## where R.sub.1 is hydrogen or methyl, R.sub.2 and R.sub.3 are lower alkyl, R.sub.4 is a linear or branched alkyl group containing 7-20 carbon atoms, X is an anion of an organic or mineral acid having a valence m and A is a divalent lower alkyl group.
Type:
Grant
Filed:
April 23, 1979
Date of Patent:
July 15, 1980
Assignee:
Texaco Development Corporation
Inventors:
Philip Hotchkiss, Robert M. Gipson, Edward C. Y. Nieh
Abstract: An improved method is disclosed for the vapor phase epoxidation of ethylene to ethylene oxide which includes intimately contacting an ethylene-containing feed stream with an epoxidizing amount of molecular oxygen epoxidizing agent in the presence of a catalytically effective amount of a novel supported, activated silver catalyst and, preferably in the presence of an effective amount of at least one inhibitor which retards combustion of ethylene to carbon dioxide at a temperature of from about 200.degree. C. to about 300.degree. C.The novel silver catalyst is best described in terms of its method of preparation. The catalyst is prepared by impregnating certain inorganic porous substrates with a specific silver carboxylate/amine complex impregnating solution. The impregnated support is then heated in order to evaporate volatiles, decompose the complex and activate the catalyst.
Abstract: This is a continuous process for producing ammonia synthesis gas and includes the partial oxidation of particles of solid carboniferous fuels entrained in nitrogen. In the process, air is separated into high pressure nitrogen and substantially pure oxygen. A first stream of said nitrogen is used as a safe pneumatic vehicle in a grinding and transport operation which introduces ground, finely divided solid carbonaceous fuel into a venturi injector where the particles of solid fuel are dispersed in a second stream of said nitrogen. The solid fuel-nitrogen gaseous dispersion is then reacted with a free-oxygen containing gas preferably in the absence of supplemental H.sub.2 O, other than any moisture normally found in the reactants, in a freeflow partial oxidation synthesis gas generator. The nitrogen stream serves as a carrier for the particles of solid carbonaceous fuel and as a temperature moderator in the gas generator. After cleaning, shifting, and purifying the raw synthesis gas, a gaseous mixture of N.sub.
Type:
Grant
Filed:
May 30, 1978
Date of Patent:
April 8, 1980
Assignee:
Texaco Development Corporation
Inventors:
James R. Muenger, Frank E. Guptill, Jr.
Abstract: A novel epoxy resin curing accelerator comprises a mixture of N-aminoethylpiperazine (AEP) and triethanolamine (TEA). The resins comprise a vicinal polyepoxide, a curing agent, and an amount of AEP/TEA mixture effective for accelerating the cure of the polyepoxide. The accelerator combination is synergistic for accelerating the curing of an epoxy resin cured with an amine at ambient or elevated temperatures. The epoxy resin products are useful in protective coatings, adhesives, seamless and terrazzo flooring, castings, laminates, and in grouting, potting, encapsulating, caulking and sealing compositions.
Abstract: Covers certain aromatic-amine amides which comprise the reaction product of a bis-amino-n propyl ether and an isatoic anhydride of the formula: ##STR1## where R is selected from the group consisting of hydrogen, alkyl, nitro, halo, hydroxy, amino, and cyano, and n is a number of 1-4. Also covers the use of said compounds as chain-extenders in polyurethane compositions. Such chain-extenders provide for the production of polyurethane elastomers having improved tensile strength, tear strength and elongation properties.
Abstract: Covers N-(3-dimethylaminopropyl)-N'-(3-morpholinopropyl)urea. Also covers a method of producing a polyurethane by utilizing said above compound as a catalyst in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.
Type:
Grant
Filed:
October 16, 1978
Date of Patent:
March 18, 1980
Assignee:
Texaco Development Corporation
Inventors:
George P. Speranza, Robert L. Zimmerman
Abstract: A wide dynamic range automatic high speed gain ranging amplifier system includes a receiver circuit adapted to receive an analog input signal. A single stage amplifier is connected to the receiver circuit which amplifies a received analog signal to provide an output signal. A control circuit connected to the receiver circuit and to the amplifier controls the gain of the amplifier in accordance with the output signal and provides digital gain signals corresponding thereto.
Abstract: Spray oil compositions capable of defoliating and/or desiccating the foliage of leguminous plants so as to facilitate the harvesting thereof are disclosed. The parameter of properties constituent oils must have to provide these effects is given.
Type:
Grant
Filed:
October 18, 1978
Date of Patent:
March 11, 1980
Assignees:
Texaco Trinidad, Inc., Texaco Development Corporation
Inventors:
Clarence A. L. Phillips, Henry W. Archer
Abstract: Clean HCN-free synthesis gas is produced from raw synthesis gas leaving a partial-oxidation gas generator by a continuous process comprising the steps of partial cooling, scrubbing with condensate, cooling below the dew point by indirect heat exchange preferably with a rich liquid absorbent from a downstream acid-gas-removal zone, and scrubbing with cold aqueous absorbent. The rich HCN-containing aqueous absorbent is then safely processed, without polluting the environment. For example, the HCN-containing aqueous absorbent may be stripped or reacted in the gas generator. Optionally, other acid gases, if present, may be removed from the synthesis gas in said acid-gas-removal zone.
Abstract: A novel epoxy resin curing accelerator comprises a mixture of piperazine, N-aminoethylpiperazine (AEP) and triethanolamine (TEA). The resins comprise a vicinal polyepoxide, a curing agent, and an amount of piperazine, AEP and TEA mixture effective for accelerating the cure of the polyepoxide. The accelerator combination is synergistic for accelerating the curing of an epoxy resin cured with an amine at ambient or elevated temperatures. The epoxy resin products are useful in protective coatings, adhesives, seamless and terrazzo flooring, castings, laminates, and in grouting, potting, encapsulating, caulking and sealing compositions.