Patents Assigned to The Dow Chemical Co.
  • Patent number: 4360656
    Abstract: Alternating copolyestercarbonate resins having repeating units of the formula: ##STR1## wherein R.sup.1 is para-phenylene; each R is independently an aromatic hydrocarbylene or inertly substituted aromatic hydrocarbylene, e.g., ##STR2## and x is a number from 0.05 to 0.65 exhibit physical properties such as heat resistance, clarity and impact strength that are superior to the comparable properties of corresponding random copolymers. Such resins are useful for making transparent tough films and molded articles having high heat resistance.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: November 23, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Daniel J. Swart, Jacqueline S. Kelyman
  • Patent number: 4358594
    Abstract: Compounds are prepared corresponding to the formula ##STR1## wherein Y represents chloro or R'; R represents ##STR2## wherein X independently represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkyl sulfonyl of 1 to 4 carbon atoms, trifluoromethyl, chloro, fluoro or bromo; n represents an integer of 0 to 2 or X.sub.n represents 3,4-methylenedioxy and R' represents R with the proviso that R and R' can be the same or different. The compounds are useful as intermediates for the preparation of insecticidal substituted pyridine methyl esters of cyclopropane carboxylic acids.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: November 9, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Sudarshan K. Malhotra
  • Patent number: 4358405
    Abstract: A dehydration catalyst and process for making an alkylenimine from an alkanolamine wherein the catalyst contains oxides of either tantalum or niobium together with the oxides of iron and chromium and in which the ratios of the metals are:M.sub.10 Fe.sub.0.5-2.9 Cr.sub.0.3-1.7wherein M is tantalum or niobium.
    Type: Grant
    Filed: March 25, 1981
    Date of Patent: November 9, 1982
    Assignee: The Dow Chemical Co.
    Inventors: William V. Hayes, David L. Childress
  • Patent number: 4358334
    Abstract: An improved high speed cast process for fusing fasteners, with strips of film at their base, to separately extruded film or sheet stock for making containers with integral closure means. The process makes available multiple sets of male and female fastener elements, with variable spacing, in a single extrusion operation. The apparatus is configured so that adhesion between the fastener elements and the film or sheet occurs very closely to the die lips before significant cooling of the extrudate occurs. Containers with improved profiles are obtained because the base permits the profiles to remain relatively rigid during closing and opening.
    Type: Grant
    Filed: April 20, 1981
    Date of Patent: November 9, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Thomas A. Sutrina, R. Douglas Behr
  • Patent number: 4357327
    Abstract: Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: November 2, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Chester E. Pawloski
  • Patent number: 4357168
    Abstract: A cellulosic composition of a cellulosic such as ethyl cellulose, a surfactant such as polyoxyethylene sorbitan monolaurate and a heat stabilizer such as triaryl phosphite can be mixed with an oil extender to form a hot melt composition which does not discolor upon extended heating at elevated temperatures.
    Type: Grant
    Filed: March 2, 1981
    Date of Patent: November 2, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Maurice L. Zweigle, Janet C. Hickman
  • Patent number: 4357328
    Abstract: Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: November 2, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Chester E. Pawloski
  • Patent number: 4352766
    Abstract: A scrap-free, substantially solid phase, relatively low temperature economical process for rapidly making plastic articles from resinous powders wherein the resultant articles can comprise various polymers including oriented polymers; polymers with a high practical heat distortion temperature; expanded polymers; ultra high molecular weight polymers; blended structures of two or more materials; or multilayered structures. The resinous powders are initially compressed into briquettes, which briquettes are heated to a temperature in the range from about the alpha transition temperature to less than the melting point or melt temperature of the polymer therein to both somewhat soften and sinter the briquettes. The sintered briquettes are forged under conditions which permit substantial plug flow deformation into preforms whereby fusion of the sintered resin powder particles occurs.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: October 5, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Norbert L. Bradley, Kenneth J. Cleereman, Ritchie A. Wessling
  • Patent number: 4351909
    Abstract: An ion-exchange composition comprising a substrate of a macroporous synthetic resin having ion-exchanging sites at least on its available surface; and finely divided, synthetic resin particles having a volume average diameter less than 0.1 micron and greater than about 0.005 micron and having, at least on their outer surfaces, ion-exchanging sites which attract the ion-exchanging sites of the substrate, irreversibly attached as a monolayer to the available surface of the substrate. The composition is used for removal and separation of ions, and is especially useful in liquid ion-exchange chromatography.
    Type: Grant
    Filed: May 21, 1981
    Date of Patent: September 28, 1982
    Assignees: The Dow Chemical Co., Dionex Corporation
    Inventor: Timothy S. Stevens
  • Patent number: 4351933
    Abstract: Compounds represented by the formula: ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X-- is chlorine, hydroxy, carboxy or:--AC--R).dbd.CH.sub.2--R is hydrogen or methyl, --R--' is an ethylene or propylene group and--AC--R).dbd.CH.sub.2is one of: ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula: ##STR3## is polymerized with an azobis (isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
    Type: Grant
    Filed: June 8, 1981
    Date of Patent: September 28, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Thomas A. Chamberlin, Donald A. Tomalia
  • Patent number: 4351943
    Abstract: Compounds are prepared corresponding to the formula ##STR1## wherein Y represents chloro or R'; R represents ##STR2## wherein X independently represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkyl sulfonyl of 1 to 4 carbon atoms, trifluoromethyl, chloro, fluoro or bromo; n represents an integer of 0 to 2 or X.sub.n represents 3,4-methylenedioxy and R' represents R with the proviso that R and R' can be the same or different. The compounds are useful as intermediates for the preparation of insecticidal substituted pyridine methyl esters of cyclopropane carboxylic acids.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: September 28, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Sudarshan K. Malhotra
  • Patent number: 4350830
    Abstract: A method for preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium, copper and titanium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios ofMo.sub.15 V.sub.5-10 Cu.sub.2-5 Cr.sub.0.2-2 Ti.sub.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: September 21, 1982
    Assignee: The Dow Chemical Co.
    Inventors: David L. Childress, William V. Hayes, Richard L. Poppe
  • Patent number: 4350601
    Abstract: Viscosifiers for addition to high zinc salt brines, used as oil well workover and completion fluids, are prepared from polysaccharide gums or gelatin by treatment with formaldehyde and/or an aliphatic dialdehyde containing from 2 to 6 carbons. The treated viscosifiers have improved dispersibility and give increased viscosity effects in the brines. Preferably, the viscosifiers are prepared from carrageenan, locust bean gum, hydroxyethyl cellulose, or gelatin by treatment with a mixture of formaldehyde and glyoxal.
    Type: Grant
    Filed: May 18, 1981
    Date of Patent: September 21, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Benjamin Mosier, Jack L. McCrary, Karl G. Guilbeau
  • Patent number: 4349457
    Abstract: Corrosion-inhibitor compositions and protective covers for the protection of metal surfaces against corrosion, particularly at elevated temperatures. A preferred method is the dispositon of the corrosion-inhibitor compositions in or on the metal-contacting surface of the thermal insulation. The composition of the corrosion inhibitor comprises borate, nitrite, and molybdate salts; and may further include an epoxy resin binder, an epoxy resin hardener, and a thinning agent.
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: September 14, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Michael T. Orillion
  • Patent number: 4349482
    Abstract: Vicinal epoxides and alkylene dihalides are produced by decomposing a .beta.-haloalkyl carbonate of the general formula ##STR1## in the presence of a quaternary ammonium or phosphonium salt.
    Type: Grant
    Filed: February 25, 1981
    Date of Patent: September 14, 1982
    Assignee: The Dow Chemical Co.
    Inventors: James M. Renga, Albert H. Emmons
  • Patent number: 4347949
    Abstract: A generally cylindrical tank is insulated by affixing thermal insulation panels on the side walls thereof using generally helically disposed tension elements such as wire to maintain the panels in position at least during installation.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: September 7, 1982
    Assignee: The Dow Chemical Co.
    Inventor: Robert B. Bennett
  • Patent number: 4347194
    Abstract: Polyhydroxyl polyether compounds containing at least one monomeric unit each of the formulae: ##STR1## are disclosed. Polymeric condensation resins are prepared by allowing the polyhydroxyl polyethers to react with polyfunctional chain-forming compounds containing functional groups reactive with the hydroxyl groups of polyhydroxyl polyethers. The polyhydroxyl polyether compounds enhance the flame-retardant properties of polymeric condensation resins such as polyurethanes.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: August 31, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Sally P. Ginter, Chester E. Pawloski, Violete L. Stevens
  • Patent number: 4341658
    Abstract: Catalysts for reacting vicinal epoxides with an aromatic hydroxyl-containing material result from the treatment of a solid substrate containing a plurality of ion-exchangeable cations with a polymer containing a multiplicity of quaternary onium cations in association with a reactive anion such that after treatment, there remains a sufficient quantity of the quaternary onium cations in association with the reactive anion to catalyze the reaction. These catalysts reduce the quantity of side reactions.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: July 27, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Georgia A. Monnerat, George E. Ham, Thomas J. Hairston, Melvin J. Hatch
  • Patent number: 4341606
    Abstract: A process for operating an electrolytic cell having a relatively-massive dual porosity gas electrode particularly well suited and adapted for utilization as a vertically-disposed oxygen gas-bearing electrochemically reducing cathode in electrolytic cells wherein, for efficient and practical, commercially-large-scale-output operations, there are required to be employed substantial electrolyte liquid depths creating considerable head pressures generally greater than at least about 1 psi (ca. 0.69 dynes/cm.sup.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: July 27, 1982
    Assignee: The Dow Chemical Co.
    Inventors: James A. McIntyre, Robert F. Phillips, Joseph D. Lefevre
  • Patent number: 4331785
    Abstract: Compounds represented by the formula ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X- is chlorine, hydroxy, carboxy or-AC-R).dbd.CH.sub.2-R is hydrogen or methyl, -R' is an ethylene or propylene group and-AC-R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
    Type: Grant
    Filed: December 28, 1979
    Date of Patent: May 25, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Thomas A. Chamberlin, Donald A. Tomalia